CN102190450A - Device and method for slag afterheat self-decomposition - Google Patents

Device and method for slag afterheat self-decomposition Download PDF

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Publication number
CN102190450A
CN102190450A CN201010120679XA CN201010120679A CN102190450A CN 102190450 A CN102190450 A CN 102190450A CN 201010120679X A CN201010120679X A CN 201010120679XA CN 201010120679 A CN201010120679 A CN 201010120679A CN 102190450 A CN102190450 A CN 102190450A
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China
Prior art keywords
slag
oneself
waste heat
tank
explains
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CN201010120679XA
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Chinese (zh)
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CN102190450B (en
Inventor
孙健
钱雷
王纯
范永平
董春柳
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Central Research Institute of Building and Construction Co Ltd MCC Group
China Jingye Engineering Corp Ltd
MCC Energy Saving and Environmental Protection Co Ltd
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Central Research Institute of Building and Construction Co Ltd MCC Group
China Jingye Engineering Corp Ltd
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Application filed by Central Research Institute of Building and Construction Co Ltd MCC Group, China Jingye Engineering Corp Ltd filed Critical Central Research Institute of Building and Construction Co Ltd MCC Group
Priority to CN201010120679XA priority Critical patent/CN102190450B/en
Priority to PCT/CN2010/075797 priority patent/WO2011109993A1/en
Publication of CN102190450A publication Critical patent/CN102190450A/en
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Publication of CN102190450B publication Critical patent/CN102190450B/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B5/00Treatment of  metallurgical  slag ; Artificial stone from molten  metallurgical  slag 
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B3/00General features in the manufacture of pig-iron
    • C21B3/04Recovery of by-products, e.g. slag
    • C21B3/06Treatment of liquid slag
    • C21B3/08Cooling slag
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B2400/00Treatment of slags originating from iron or steel processes
    • C21B2400/02Physical or chemical treatment of slags
    • C21B2400/022Methods of cooling or quenching molten slag
    • C21B2400/024Methods of cooling or quenching molten slag with the direct use of steam or liquid coolants, e.g. water
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B2400/00Treatment of slags originating from iron or steel processes
    • C21B2400/05Apparatus features
    • C21B2400/066Receptacle features where the slag is treated
    • C21B2400/068Receptacle features where the slag is treated with a sealed or controlled environment
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B2400/00Treatment of slags originating from iron or steel processes
    • C21B2400/05Apparatus features
    • C21B2400/066Receptacle features where the slag is treated
    • C21B2400/072Tanks to collect the slag, e.g. water tank
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

Abstract

A device for slag afterheat self-decomposition disclosed in the invention comprises: a slag afterheat self-decomposition pot body (1), an opening (2), a slag chute (3) for placing steel slags, a support (4) for arranging the slag chute, a track (5) for transporting slags, a water injector (6) arranged at the top of the inner wall of the body, a control device (7) arranged on the inner wall of the body for controlling the process of self-decomposition. The method for slag afterheat self-decomposition comprises the following steps: the slag chute (3) with slags having certain temperature is put into the slag afterheat self-decomposition pot body (1); cooling water is sprayed to the hot slags by the water injector (6) to make the surface of the slags split and generate cracks; certain pressure is built by steam followed by water spraying to make the slags further split and pulverized; the stabilization and pulverization treatments of the slags are realized in a short time by self-decomposition. According to the invention, the slags are treated by utilizing the slag afterheat in a sealing pressure container, with the advantages of no extra energy consumption, short processing cycle, good effect of pulverization, and fully decomposing free CaO in the slags. The treated slags have good stability and can be used in building materials, road and the like, so as to recycle the slags.

Description

A kind of slag waste heat has to press explains device and method by oneself
Technical field
The bessemer furnace slag that the present invention relates to be produced in UTILIZATION OF VESIDUAL HEAT IN, solid waste processing and application technology as the second resource, the especially convertor steelmaking process in the ferrous metallurgy process is handled, and being specifically related to a kind of slag waste heat has treatment unit and the method explained by oneself of pressing.
Background technology
At present, the mode that slag is handled is a lot, and hot application method, hot vexed method, water quenching, wind quench method, cylinder shotting and granulation wheel method etc. are arranged.The hot application method is that the fused solution slag is poured in the hot application field, by fetching water or the air naturally cooling, carries out fragmentation, magnetic separation processing subsequently; The vexed method of heat is that the fused solution slag is poured in the hot vexed pond, by the cooling of fetching water, treats that the laggard row of slag efflorescence is broken, magnetic separation is handled; Water quenching is when toppling over the fused solution slag, with high pressure water with molten steel slag cooling and smash into particle; The wind method of quenching is similar to water quenching, and the wind method of quenching is with the molten steel slag cooling and smash into particle with high-pressure air.It is low that the hot application method is handled slag efficient, contaminate environment; The vexed method of heat, water quenching and the wind method of quenching adopts air or water to force cooling, and efficient is higher, and still hot vexed method, may be blasted because water directly contacts with molten steel slag with water quenching; Though the wind method of quenching is broken with the force air cooling, but compressed air consumption is big, noise is big.After drum process is meant and pours liquid steel slag into slag ladle, be transported between the processing of cylinder slag through slag car, through crane cylinder slag input device notch is arrived in the slag ladle handling then, and pour in the drum apparatus, liquid steel slag is discharged to the slag field through apron conveyor finish water spray cooling, curing, fragmentation simultaneously in cylinder after.This technology has problem to be solved: the slag processing rate is low generally below 50%, still has a large amount of dry residue emissions; System device power consumption height, breakdown rate is higher, and investment is big; Slag is difficult for the granulation that is crashed to pieces, and is serious to equipment attrition, and interior dress steel ball is often changed.Granulation wheel technology is after liquid steel slag is transported to treatment plant; adopt crane that slag ladle is slowly sling; pour in the granulation wheel of high speed rotating, make the slag crushing granulation, fall into the pond after the water spray cooling; slag is after granulation wheel shrend method is handled; granularity is little, and the slag compact crystallization is difficult levigate; its gelling property variation influences slag and uses at building material industry.
Summary of the invention
It is a cover pressurized vessel equipment that a kind of slag waste heat has pressure to explain device by oneself, and mainly comprise: waste heat is explained tank, jar door, slag chute, slag chute support, the track of mucking haulage, waterworks, control device, release gear, water-freeing arrangement and cooling system by oneself and formed; Wherein control device comprises pressure-detecting device, temperature-detecting device and security device.
Its waste heat has to press to be explained treatment process by oneself and is, the slag chute that certain temperature (300 ~ 800 ℃) slag will be housed pushes waste heat and explains by oneself in the tank and be positioned on the slag chute support; Close jar door and sealing locking; Explained by oneself the waterworks at tank top sprays water to slag by waste heat; Warm sludge is met water quick cooling, and the top layer lowers the temperature rapidly, and the stress that is produced by the temperature difference makes cracked and generation crack, slag top layer; And the slag waste heat add a large amount of low-pressure water steams that produce behind the hot water be covered in very soon slag the surface and infiltrate in the crack, react generation Ca (OH) 2 rapidly with the free state CaO in the slag, its weave construction changes, proportion diminishes, because increasing to produce, solid volume expands, have expansion stress, caused the rapid efflorescence of slag cracked.Because reaction process is to carry out in airtight pressurized vessel, the water vapour that the water spray back forms does not efflux, form certain pressure and temperature atmosphere in jar, under the effect of pressure, steam reacts by the inside that microscopic checks can be deep into block slag, rather than only rest on the surface of slag, and improved speed of response, make that clinker is further cracked rapidly, efflorescence.Said process carries out repeatedly, and from outward appearance to inner essence, the free state CaO in slag fully clears up and slag self efflorescence, makes the slag that has pressure to explain processing by oneself through waste heat reach stabilizing treatment and efflorescence processing two big purposes at short notice.Therefore waste heat has and presses that to explain treatment technology by oneself be to have solved bessemer furnace slag rapid stabilization and the advanced treatment technology of atomizing simultaneously.
It is a horizontal cylindric pressure vessel that described waste heat is explained tank by oneself, is provided with a jar door at the one end; Waste heat is explained tank by oneself and is used to form enclosed space with a jar door, makes slag explain efflorescence by oneself at this enclosed space.
Described slag chute is a clamshell structure, two lobes about being divided into, and two lobes can rotate around the rotating shaft at center, can automatic dischargings after opening from the bottom, slag chute is used to hold slag.
Described slag chute support is used to support slag chute.
The described track of mucking haulage is positioned at waste heat and explains a jar inwall bottom by oneself, and slag chute is explained tank by oneself by the track turnover waste heat of mucking haulage.
It is axial arranged that described waterworks is explained jar inwall top by oneself along waste heat, and waterworks is used for spraying water to warm sludge.
Described control device comprises pressure-detecting device, temperature-detecting device and security device, and control device is arranged in a plurality of positions that waste heat is explained tank and jar door by oneself, prevents that waste heat from explaining jar Yin Wendu or hypertonia by oneself and explode.
Described release gear is positioned at waste heat and explains tank outer wall top by oneself, and gas barrier is used to discharge waste heat and explains jar interior steam by oneself to keep a jar interior constant voltage.
Described water-freeing arrangement is positioned at waste heat and explains tank outer wall bottom by oneself, and water-freeing arrangement is used to get rid of the water that waste heat is explained tank inside by oneself.
Described cooling system comprises tank interior cooling and tank body exterior cooling two portions.The tank interior cooling can be cooled off slag chute, slag chute support and inner tank wall, and the tank body exterior cooling is cooled off a tank wall and a jar door.
The diameter of described jar door equates with tank diameter, opens afterwards waste heat and explains jar by oneself and can all open wide; The jar door is furnished with closing mechanism, locking mechanism and sealing mechanism, and closing mechanism is used for opening and closing jar door; Locking mechanism is used for locking jar door; Sealing mechanism is used for sealed can door and tank body.
The present invention utilizes the slag waste heat in the seal-off pressure container slag to be handled, and does not consume extra power, can not produce dust, energy-conserving and environment-protective; In the treating processes, water does not contact with molten steel slag, and pressurized vessel is furnished with security device, and is safe and reliable; Present method processing cycle lacks in addition, and efflorescence is effective, can fully clear up the free state CaO in the slag, and the slag good stability after the processing can be used for aspects such as building materials and road, can realize the resource utilization recycle of slag.
Description of drawings
Fig. 1 is a front view of the present invention.
Fig. 2 is the vertical view among Fig. 1.
Fig. 3 is the left view among Fig. 1.
Fig. 4 is the right view among Fig. 1.
The main nomenclature of accompanying drawing
1 waste heat is explained 2 jars of doors of tank, 3 slag chutes, 4 slag chute supports 5 track 6 waterworkss 7 control device 7-1 pressure-detecting device 7-2 temperature-detecting device 7-3 security devices 8 release gears 9 water-freeing arrangements 10 cooling systems of mucking haulage by oneself
Embodiment
Press the structural representation explain treatment unit by oneself as Fig. 1,2,3 for a kind of slag waste heat of the present invention has, comprise that waste heat explains tank 1, jar door 2, slag chute 3, slag chute support 4, the track 5 of mucking haulage, waterworks 6, control device 7, release gear 8, water-freeing arrangement 9 and cooling system 10 by oneself; Wherein control device comprises pressure-detecting device 7-1, temperature-detecting device 7-2 and security device 7-3.
It is a horizontal cylindric pressure vessel that described waste heat is explained tank 1 by oneself, and the one end is provided with a jar door 2; Waste heat is explained filling tank body 1 by oneself and is used to form enclosed space with a jar door 2, makes slag explain efflorescence by oneself in this enclosed space.
Described slag chute 3 is a clamshell structure, two lobes about being divided into, and two lobes can rotate around the rotating shaft at center, can automatic dischargings after opening from the bottom, slag chute is used to hold slag.
Described slag chute support 4 is used to support slag chute 3.
The described track 5 of mucking haulage is positioned at waste heat and explains tank 1 inwall bottom by oneself, and slag chute 3 is explained tank 1 by oneself by the track 5 turnover waste heats of mucking haulage.
It is axial arranged that described waterworks 6 is explained tank 1 inwall top by oneself along waste heat, and waterworks 6 is used for spraying water to warm sludge.
Described control device 7 comprises pressure-detecting device 7-1, temperature-detecting device 7-2 and security device 7-3, pressure-detecting device 7-1, temperature-detecting device 7-2 and security device 7-3, be arranged in waste heat and explain tank 1 and jar door a plurality of positions of 2 by oneself, prevent that waste heat from explaining tank 1 by oneself and exploding because of temperature or hypertonia.
Described security device 7-3 is made of safety valve and rupture disk.
Described release gear 8 is positioned at waste heat and explains tank 1 outer wall top by oneself, and release gear 8 is used to discharge waste heat and explains tank 1 interior steam by oneself to keep a jar interior level pressure.
Described water-freeing arrangement 9 is positioned at waste heat and explains tank 1 outer wall bottom by oneself, and water-freeing arrangement 9 is used to get rid of the water that waste heat is explained tank 1 inside by oneself.
Described cooling system 10 comprises tank interior cooling and tank body exterior cooling two portions.The tank interior cooling can be cooled off slag chute 3, slag chute support 4 and inner tank wall, and the tank body exterior cooling is cooled off a tank wall and a jar door 2.
Diameter and the waste heat of described jar door 2 are explained tank 1 equal diameters by oneself, open afterwards waste heat and explain tank 1 by oneself and can all open wide; Jar door 2 is furnished with closing mechanism, locking mechanism and sealing mechanism; Closing mechanism is used for opening and closing jar door 2; Locking mechanism is used for locking jar door 2; Sealing mechanism is used for sealed can door 2 and tank body 1.
Described a kind of slag waste heat has to press to be explained method by oneself and comprises the steps:
(1) dress slag, with the certain temperature solid state heat slag slag chute 3 of packing into, slag chute 3 enters waste heat by the track 5 of mucking haulage and explains by oneself in the tank 1, closes jar door 2 and locking;
(2) water spray boosts, the slag water spray of waterworks 6 in slag chute 3, and water is met warm sludge and is produced steam and explain tank 1 inner accumulated by oneself at waste heat, thereby forms certain pressure; The water that sprays into simultaneously makes the slag chilling, causes cracked and generation crack, slag top layer;
(3) have pressure to explain by oneself, the slags in the slag chute 3 produce in certain vapor pressure atmosphere explains efflorescence by oneself, thereby realizes the slag stabilization treatment;
(4) control reaction is pressed in the process of explaining by oneself having, by control device 7 in real time the control waste heats explain important parameters such as pressure, temperature and the water yield in the tank 1 by oneself;
(5) cooling, treat the slag waste heat have press explain end by oneself after, continue to the slag water spray, so that described slag is continued to cool;
(6) slag tap, open release gear 8 and water-freeing arrangement 9, discharge residual steam and water; Open a jar door 2, the slag after efflorescence and the stabilization treatment is transported by the track 5 of mucking haulage.

Claims (16)

1. a slag waste heat has to press and explains device by oneself, and it is characterized in that: this device comprises: waste heat is explained tank (1), jar door (2) by oneself, holds the slag chute (3) of slag, is laid the slag chute support (4) of slag chute, be provided with on the track of mucking haulage (5), the waterworks (6) that is provided with at the inner tank wall top and the inner tank wall be used to control the control device (7) that pressure is explained process by oneself.
2. slag waste heat according to claim 1 has to press explains device by oneself, and it is characterized in that: it is a horizontal cylindric pressure vessel that waste heat is explained tank (1) by oneself, is provided with a jar door (2) at the one end.
3. slag waste heat according to claim 1 has to press explains device by oneself, and it is characterized in that: waste heat is explained tank (1) bottom by oneself and is provided with slag chute support (4), and the slag chute (3) that holds slag is placed on the slag chute support (4).
4. slag waste heat according to claim 1 has to press explains device by oneself, and it is characterized in that: waste heat is explained by oneself and is provided with the track of mucking haulage (5) in the tank (1), finishes slag chute (3) turnover waste heat by the track of mucking haulage (5) and explains tank (1) by oneself.
5. slag waste heat according to claim 1 has to press explains device by oneself, and it is characterized in that: waste heat is explained tank (1) inwall top by oneself and is provided with waterworks (6), and it is axial arranged that waterworks (6) is explained tank (1) inwall top by oneself along waste heat.
6. slag waste heat according to claim 1 has to press explains device by oneself, it is characterized in that: be provided for controlling the control device (7) of pressing the process of explaining by oneself on the inner tank wall, be included in waste heat and explain pressure-detecting device (7-1), temperature-detecting device (7-2) and the security device (7-3) that the different positions of tank (1) is provided with by oneself, explode to prevent waste heat from explaining tank (1) Yin Wendu or hypertonia by oneself.
7. there is pressure to explain device by oneself according to claim 1 or 6 described slag waste heats, it is characterized in that: waste heat is explained tank (1) by oneself and is provided with release gear (8), water-freeing arrangement (9) and cooling system (10), and release gear (8) lays respectively at the top and bottom that waste heat is explained tank (1) outer wall by oneself with water-freeing arrangement (9).
8. slag waste heat according to claim 7 has to press explains device by oneself, it is characterized in that: waste heat is explained the last cooling system (10) that is provided with of tank (1) by oneself and is comprised tank interior cooling and tank body exterior cooling two portions, the tank interior cooling can be cooled off slag chute (3), slag chute support (4) and inner tank wall, and the tank body exterior cooling is cooled off a tank wall and a jar door (2).
9. slag waste heat according to claim 1 has to press explains device by oneself, it is characterized in that: diameter and the waste heat of jar door (2) are explained tank (1) equal diameters by oneself, and this waste heat was explained tank (1) by oneself and can all be opened wide after opened jar (2).
10. have pressure to explain device by oneself according to claim 1 or 9 described slag waste heats, it is characterized in that: described jar of door (2) is furnished with closing mechanism, locking mechanism and sealing mechanism.
11. have pressure to explain device by oneself according to claim 1 or 6 or 8 described slag waste heats, it is characterized in that: described slag chute (3) is a clamshell structure, two lobes about being divided into, and two lobes can rotate around the rotating shaft at center, can the automatic discharging from the bottom after opening.
Explain device by oneself 12. slag waste heat according to claim 1 has to press, it is characterized in that: this device is a cover pressurized vessel equipment.
Explain treatment process by oneself 13. a slag waste heat has to press, it is characterized in that comprising the steps:
(1) dress slag, with the certain temperature solid state heat slag slag chute (3) of packing into, slag chute (3) enters waste heat by the track of mucking haulage (5) and explains by oneself in the tank (1), closes jar door (2) and locking;
(2) water spray boosts, the slag water spray of waterworks (6) in slag chute (3), and water is met warm sludge and is produced steam and explain tank (1) inner accumulated by oneself at waste heat, thereby forms certain pressure; The water that sprays into simultaneously makes the slag chilling, causes cracked and generation crack, slag top layer;
(3) have pressure to explain by oneself, the slag in the slag chute (3) produces in certain vapor pressure atmosphere explains efflorescence by oneself, thereby realizes the slag stabilization treatment;
(4) control reaction in the process that has pressure to explain by oneself, is controlled waste heat in real time by control device (7) and is explained the interior important parameters such as pressure, temperature and the water yield of tank (1) by oneself;
(5) cooling, treat the slag waste heat have press explain end by oneself after, continue to the slag water spray, so that described slag is continued to cool;
(6) slag tap, open release gear (8) and water-freeing arrangement (9), discharge residual steam and water; Open a jar door (2), the slag after efflorescence and the stabilization treatment is transported by the track of mucking haulage (5).
14. having to press, slag waste heat according to claim 13 explains treatment process by oneself, it is characterized in that: described control device is included in waste heat and explains pressure-detecting device (7-1), temperature-detecting device (7-2) and the security device (7-3) that the different positions of tank (1) is provided with by oneself, explodes to prevent waste heat from explaining tank (1) Yin Wendu or hypertonia by oneself.
15. have pressure to explain treatment process by oneself according to claim 13 or 14 described slag waste heats, it is characterized in that: the slag in the slag chute of packing into is 300 ~ 800 ℃ of solid state heat slags.
16. have pressure to explain treatment process by oneself according to claim 14 or 15 described slag waste heats, it is characterized in that: the slag in the slag chute produces in the vapor pressure atmosphere of 0.3 ~ 0.6MPa explains efflorescence by oneself.
CN201010120679XA 2010-03-08 2010-03-08 Device and method for slag afterheat self-decomposition Active CN102190450B (en)

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CN201010120679XA CN102190450B (en) 2010-03-08 2010-03-08 Device and method for slag afterheat self-decomposition
PCT/CN2010/075797 WO2011109993A1 (en) 2010-03-08 2010-08-09 Steel slag self-slaking device using residual heat and pressure and method thereof

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CN102190450B CN102190450B (en) 2013-04-10

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CN105063255A (en) * 2015-08-06 2015-11-18 中冶节能环保有限责任公司 Vertical steel slag pressure hot-disintegration still kettle and slag processing method
CN107447065A (en) * 2017-10-11 2017-12-08 中冶节能环保有限责任公司 A kind of cold conditions slag efficient stable processing unit and method
CN111826486A (en) * 2020-08-03 2020-10-27 中冶节能环保有限责任公司 High-temperature soft molten steel slag accurate-control efficient cleaning crushing treatment device and method
CN115505655A (en) * 2022-09-29 2022-12-23 一重集团大连工程技术有限公司 Thermal state steel slag crushing equipment and thermal braising treatment system

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Cited By (6)

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Publication number Priority date Publication date Assignee Title
CN105063255A (en) * 2015-08-06 2015-11-18 中冶节能环保有限责任公司 Vertical steel slag pressure hot-disintegration still kettle and slag processing method
CN107447065A (en) * 2017-10-11 2017-12-08 中冶节能环保有限责任公司 A kind of cold conditions slag efficient stable processing unit and method
CN111826486A (en) * 2020-08-03 2020-10-27 中冶节能环保有限责任公司 High-temperature soft molten steel slag accurate-control efficient cleaning crushing treatment device and method
CN111826486B (en) * 2020-08-03 2023-10-20 中冶节能环保有限责任公司 High-temperature soft molten steel slag accurate control efficient clean crushing treatment device and method
CN115505655A (en) * 2022-09-29 2022-12-23 一重集团大连工程技术有限公司 Thermal state steel slag crushing equipment and thermal braising treatment system
CN115505655B (en) * 2022-09-29 2024-04-30 一重集团大连工程技术有限公司 Thermal state slag crushing equipment and thermal stewing system

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