The specific embodiment
Below in conjunction with the accompanying drawing in the embodiment of the invention, the technical scheme in the embodiment of the invention is clearly and completely described, obviously, described embodiment only is the present invention's part embodiment, rather than whole embodiment.Based on the embodiment among the present invention, those of ordinary skills belong to the scope of protection of the invention not making the every other embodiment that obtains under the creative work prerequisite.
Fig. 1 has the structural representation of bypass flue desulfurization system for design in the prior art; The flue gas that produces in the boiler enters flue collector 101, enters absorption tower 103 under the air inducing effect of air-introduced machine 102, flue gas carries out desulfurization in absorption tower 103 handle after through demister 104 go out in the flue gas (drop is discharged in the atmosphere finally by crossing chimney 105.Available technology adopting desulfurization absorbent supply system is carried out desulfurization to the flue gas in the absorption tower, the desulfurization absorbent supply system comprises that transfer pump 107 is constantly sent into the absorbent in the absorbent case 106 in the absorption tower be used to the absorbent case 106 of depositing absorbent and transfer pump 107.
Fig. 2 is the structure chart of embodiment of the invention flue desulfurization absorbent supplying system; As shown in Figure 2, described system comprises: slurries supply equipment 201 is used for supplying desulfurization absorbent to desulfuration absorbing tower.PH value acquiring unit 202 is for the pH value of obtaining described desulfuration absorbing tower gypsum slurries.PH value judging unit 203 is used for judging whether the described pH value of obtaining is lower than default minimum pH value, and default minimum pH value can be 4.5, the invention is not restricted to this.Device control cell 204 is used for the standby slurries supply equipment of control and supplies desulfurization absorbent to the melt pit of described desulfuration absorbing tower.Concrete being used for generates the device start signal, and supplies desulfurization absorbent according to the standby slurries supply equipment of described device start signal controlling in the melt pit of described desulfuration absorbing tower.
When the described pH value of obtaining when described pH value judgment unit judges was higher than default the highest pH value, described device control cell generated the equipment stop signal, closes described standby slurries supply equipment.Described the highest default pH value is 5.3, the invention is not restricted to this.
Described standby slurries supply equipment comprises: the absorbent storehouse is used for the storage absorbent powder; Discharger couples with described absorbent storehouse, is used for the absorbent powder in absorbent storehouse is sent in the desulfuration absorbing tower melt pit; Water supply installation is used for supplying water to the desulfuration absorbing tower melt pit.
Described standby slurries supply equipment also comprises: auger conveyor is used for the absorbent powder that described discharger unloads is sent into the desulfuration absorbing tower melt pit.
Fig. 3 is embodiment of the invention flue desulfurization absorbent Supply Method flow chart; As shown in Figure 3, described method comprises:
Step S301: adopt the slurries supply equipment in desulfuration absorbing tower, to supply desulfurization absorbent.
Step S302: the pH value of obtaining gypsum slurries in the described desulfuration absorbing tower.
Step S303: judge whether the described pH value of obtaining is lower than default minimum pH value, if carry out step S304.
Step S304: control standby slurries supply equipment and in the melt pit of described desulfuration absorbing tower, supply desulfurization absorbent.The standby slurries supply equipment of described control supply desulfurization absorbent in the melt pit of described desulfuration absorbing tower comprises: generate the device start signal; In the melt pit of described desulfuration absorbing tower, supply desulfurization absorbent according to the standby slurries supply equipment of described device start signal controlling.
Further, in step S303, if the described pH value of obtaining is higher than default minimum pH value, then carry out step S302, continue to obtain the pH value of gypsum slurries in the described desulfuration absorbing tower.
The supply desulfurization absorbent is supply absorbent powder and water in the melt pit of described desulfuration absorbing tower in the melt pit of described desulfuration absorbing tower.Absorbent powder can the invention is not restricted to this for limestone powder, lime powder or calcium hydroxide powder.
After step S304, described method comprises: the pH value of obtaining gypsum slurries in the desulfuration absorbing tower; Judge whether the described pH value of obtaining is higher than the highest default pH value; If control standby slurries supply equipment and stop in described desulfuration absorbing tower melt pit, supplying desulfurization absorbent.Describedly stop that the supply desulfurization absorbent comprises in the described desulfuration absorbing tower melt pit: generate the equipment stop signal; Close described standby slurries supply equipment according to described equipment stop signal.
After supplying in the desulfuration absorbing tower melt pit according to described switch open signal, described method comprises: the pH value of obtaining gypsum slurries in the desulfuration absorbing tower; Judge whether the described pH value of obtaining is higher than the highest default pH value; If stop in described desulfuration absorbing tower melt pit, supplying desulfurization absorbent; Describedly stop that the supply desulfurization absorbent comprises in the described desulfuration absorbing tower melt pit: generate the switch shutdown signal; Close absorbent storehouse and water supply installation according to described switch shutdown signal.
Specify embodiments of the invention below.
Fig. 4 is the structural representation of embodiment of the invention flue desulfurization absorbent supplying system; The embodiment of the invention adopts lime stone slurry as desulfurization absorbent, the invention is not restricted to this.In conjunction with Fig. 1, shown in Figure 4, flue gas enters absorption tower 401 from the smoke inlet 402 on absorption tower, and the exhanst gas outlet 403 from desulfuration absorbing tower 401 after the desulfurization enters demister 104, is discharged in the atmosphere then.Desulfuration absorbing tower 401 left sides are existing slurries supply system, formed by limewash slurries case 404 and connected transfer pump 405, and two transfer pumps of limewash slurries case 404 general connections, an operation, another is standby.When the transfer pump of operation breaks down, enable standby transfer pump.
The pH value of gypsum slurries can not be lower than 4.5 in the absorption tower, if be lower than 4.5, can cause desulfurization not thorough.During lime stone slurry supply system operate as normal, the pH value of gypsum slurries generally can be stabilized in 5 ~ 5.5 the scope.But when the lime stone slurry supply system breaks down (two transfer pumps all break down), will can in the absorption tower, not supply lime stone slurry.Along with SO in the flue gas
2Constantly with the absorption tower in gypsum slurries in lime stone slurry reaction, the pH value of gypsum slurries will be lower than 4.5, if do not continue to supply lime stone slurry in desulfuration absorbing tower 401 SO in the flue gas
2Can not eliminate fully, atmosphere will be polluted, and can cause absorption tower equipment sour corrosion, reduce service life.
In order to guarantee that when the lime stone slurry supply system breaks down desulfurization is complete, the invention provides a kind of flue desulfurization absorbent supplying system, as shown in Figure 4, described system comprise the slurries supply equipment, be subjected to scattered control system (Distributed Control System DCS) control control appliance 406 and standby slurries supply equipment.Described control appliance 406 comprises the pH value acquiring unit 202 among Fig. 2, pH value judging unit 203 and device control cell 204.Standby slurries supply equipment comprises: absorbent storehouse 408, and discharger 409 and water supply installation 410, water supply installation can be feedwater piping.Control appliance 406 be connected to desulfuration absorbing tower 401, slurries supply system 404, transfer pump 405, control cabinet 407.Whether control appliance 406 can monitor transfer pump 405 and break down, and obtains the pH value of gypsum slurries in the desulfuration absorbing tower 401 in real time.When monitoring two transfer pumps 405 when all breaking down, control appliance 406 judges whether the pH value of gypsum slurries is lower than default minimum pH value (for example being 4.5), when the pH of gypsum slurries value was lower than default minimum pH value, control appliance 406 was to control cabinet 407 transmit button start signal.Control cabinet 407 is according to the standby slurries supply equipment of switch open unblanking, the water filling in the desulfuration absorbing tower melt pit 412 of the trigger switch of opening water supply installation 410, the motor of opening discharger 409 is discharged to the absorbent powder in the absorbent storehouse 408 on the auger conveyor 414, and auger conveyor 414 is sent into absorbent powder in the desulfuration absorbing tower melt pit 412.In another embodiment, discharger 409 is directly sent into absorbent powder in the desulfuration absorbing tower melt pit 412, as shown in Figure 5.
Fixed in order to prevent the absorbent powder in the absorbent storehouse 408, can also be in the absorbent storehouse 408 storehouse fluidizer (not shown)s be installed.
A melt pit agitator 413 is arranged in the desulfuration absorbing tower melt pit 412, absorbent powder and water are mixed, when the flue desulfurization absorbent supplying system in the desulfuration absorbing tower melt pit 412 during the supply absorbent, the very fast arrival sump pump 415 of liquid level that breaks away from the absorption tower melt pit 412 starts the liquid level that need reach, and sump pump 415 is just sent into the absorbent that mixes in the desulfuration absorbing tower.
The useful technique effect of the embodiment of the invention: cross when low when desulfurization absorbent supply system fault causes pH value in the absorption tower, desulfurization absorbent supply system of the present invention can in time be supplied desulfurization absorbent in the desulfuration absorbing tower melt pit, prevent the SO in the flue gas
2Contaminated air.
The above-described specific embodiment; purpose of the present invention, technical scheme and beneficial effect are further described; institute is understood that; the above only is the specific embodiment of the present invention; and be not intended to limit the scope of the invention; within the spirit and principles in the present invention all, any modification of making, be equal to replacement, improvement etc., all should be included within protection scope of the present invention.