CN102181723A - Uniform dispersion method for boron nitride particles in semisolid slurry consisting of 11.4 weight percent of nickel, 83.6 weight percent of titanium and 5 weight percent of boron nitride particles - Google Patents
Uniform dispersion method for boron nitride particles in semisolid slurry consisting of 11.4 weight percent of nickel, 83.6 weight percent of titanium and 5 weight percent of boron nitride particles Download PDFInfo
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- CN102181723A CN102181723A CN 201110088806 CN201110088806A CN102181723A CN 102181723 A CN102181723 A CN 102181723A CN 201110088806 CN201110088806 CN 201110088806 CN 201110088806 A CN201110088806 A CN 201110088806A CN 102181723 A CN102181723 A CN 102181723A
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Abstract
The invention discloses a uniform dispersion method for boron nitride particles in semisolid slurry consisting of 11.4 weight percent of nickel, 83.6 weight percent of titanium and 5 weight percent of boron nitride particles, and belongs to the field of study on uniform dispersion of boron nitride particles in semisolid slurry consisting of 11.4 weight percent of nickel, 83.6 weight percent of titanium and 5 weight percent of boron nitride particles. According to the invention, an electromagnetic and mechanical preparation method is adopted and a double-blade-layer mechanical disperser is used for performing uniform dispersion on the boron nitride particles in semisolid slurry consisting of 11.4 weight percent of nickel, 83.6 weight percent of titanium and 5 weight percent of boron nitride particles under the condition that the radians of the concave arc surfaces of arc-shaped blades on up and down layers are respectively 64 to 66 degrees and 77 to 79 degrees, so the boron nitride particles are uniformly distributed and the uniform dispersion time can be shortened to 8 minutes 20 seconds.
Description
Technical field
The present invention relates to the homodisperse method of boron nitride particle in a kind of titanium 12 nickel-5 boron nitride semi solid slurry.
Background technology
Publication number: CN1768979A, denomination of invention: on " a kind of QTi3.5-10 graphite semi-solid slurry preparation method ", set forth the electromagnetism+mechanical preparation method of QTi3.5-10 graphite semi-solid slurry, promptly, utilize electromagnetic mixing apparatus to stir, smash the primary dendrite that forms in the QTi3.5 titanium bronze alloy liquid process of setting, form the QTi3.5 titanium bronze semi solid slurry that constitutes by nascent solid phase particles and liquid phase earlier; Then, by the mechanical dispersion device and move up and down control device, constantly the graphite granule that swims in QTi3.5 titanium bronze semi solid slurry top in the crucible is distributed in the QTi3.5 titanium bronze semi solid slurry.In this electromagnetism+mechanical preparation method, the mechanical dispersion device is single blade layer mechanical dispersion device, adopt the individual layer blade, in effective contact range of blade and semi solid slurry, by blade graphite granule is applied dissipation of ferees, constantly graphite granule is distributed in the semi solid slurry, the radian of disclosed mechanical dispersion device individual layer arc shaped blade cancave cambered surface is under 40～90 ° of conditions in patent CN1768979A, single blade layer mechanical dispersion device and moving up and down after the control device operation is homodisperse 15～20min can obtain the equally distributed QTi3.5-10 graphite semi-solid slurry of graphite granule.
Preparation for titanium 12 nickel-5 boron nitride semi solid slurry, realizing under the equally distributed prerequisite of boron nitride particle, mechanical dispersion device and the working time that moves up and down control device thereof are that the homodisperse time is short more, energy consumption is more little, cost is low more, and the pollution that titanium 12 nickel-5 boron nitride semi solid slurry is subjected to is also few more, and its quality is high more, therefore can realize that the homodisperse time of equally distributed titanium 12 nickel-5 of boron nitride particle boron nitride semi solid slurry is short more good more.
Summary of the invention
Technical problem to be solved by this invention is, overcome the deficiency of existing electromagnetism+mechanical preparation method " the homodisperse time is long ", provide a kind of and can realize the homodisperse method of boron nitride particle in the titanium 12 nickel-5 boron nitride semi solid slurry fast, further shorten and realize the equally distributed homodisperse time of boron nitride particle.
The technical solution adopted for the present invention to solve the technical problems is: adopt electromagnetism+mechanical preparation method, utilize double leaf lamella mechanical dispersion device, be respectively at levels arc shaped blade cancave cambered surface radian under the condition of 64～66 ° and 77～79 °, titanium 12 nickel-5 boron nitride semi solid slurry is carried out homodisperse.
The invention has the beneficial effects as follows: for the particle in the melt, want to finish as early as possible its dispersion in melt, must strengthen disperseing intensity.In semi solid slurry electromagnetism+mechanical preparation method, if after the individual layer blade is implemented to disperse to the particle in the semi solid slurry, and then utilize another layer blade to implement to disperse for the second time again, so, the particulate dispersion effect will be clearly better in the semi solid slurry, realize that the homodisperse time that uniform particles distributes will further shorten, the present invention utilizes the continuous quadratic of the twi-tier blade after the optimum combination of levels arc shaped blade cancave cambered surface radian to disperse, further promote the uniform distribution of boron nitride particle in semi solid slurry, thereby reached the purpose that shortens the homodisperse time.Utilize the present invention, titanium 12 nickel-5 boron nitride semi solid slurry is carried out homodisperse, realize that the equally distributed homodisperse time of boron nitride particle can shorten to 8 minutes and 20 seconds, shortened 40% at least than the 14 minutes the shortest homodisperse time of adopting the CN1768979A patented method.
Description of drawings
Fig. 1 carries out the front view of homodisperse device to boron nitride particle in the titanium 12 nickel-5 boron nitride semi solid slurry for the inventive method.
Among the figure, the tail rod 2 of mechanical dispersion device, the arc shaped blade 3 of mechanical dispersion device, ceramic crucible 4, heating tube 5, cooling tube 6, stop up 7, titanium 12 nickel-5 boron nitride semi solid slurry 8, outer cover 9, loam cake 10, Ar tracheae 11, thermopair 12, orienting sleeve 13, motor 14, transmission rig 15, upper stroke switch 16, lower stroke switch 17, support 18.
Fig. 2 carries out the A-A view of homodisperse device to boron nitride particle in the titanium 12 nickel-5 boron nitride semi solid slurry for the inventive method.
Among the figure, the electromagnetic pole of electromagnetic mixing apparatus is to 1.
Fig. 3 is the microtexture of the titanium 12 nickel-5 boron nitride semi solid slurry that adopts the inventive method that boron nitride particle in the titanium 12 nickel-5 boron nitride semi solid slurry is carried out to obtain behind the homodisperse.
Embodiment
As follows to specifying of boron nitride particle device in the inventive method homodisperse titanium 12 nickel-5 boron nitride semi solid slurry in conjunction with the accompanying drawings:
The boron nitride particle device comprises in the homodisperse titanium 12 nickel-5 boron nitride semi solid slurry: electromagnetic mixing apparatus, mechanical dispersion device and move up and down control device, ceramic crucible 4, loam cake 10, stop up 7, outer cover 9, Ar tracheae 11 and thermopair 12.
The power of electromagnetic mixing apparatus is 10kW, its three pairs of electromagnetic poles are distributed on around the ceramic crucible 41, and between the crucible outer wall are 5mm apart from a, heating tube 5 and cooling tube 6 uniformly at intervals in the sidewall of crucible, be connected with the cooling fluid plenum system with external power source respectively, electromagnetic pole adds outer cover 9 to 1 outside;
The mechanical dispersion device is a double leaf lamella mechanical dispersion device, by square tail rod 2 and at interval b be that two blade layers up and down of 20mm constitute, material is a heat-stable ceramic, four other shapes and the identical arc shaped blade 3 of corresponding distribution except cancave cambered surface radian difference are respectively arranged in two blade layers, four arc shaped blades 3 of lower floor, be positioned at tail rod 2 bottoms, with four Surface Vertical of tail rod 2 and with it with wide, be mutually 90 °, cancave cambered surface down, be circular arc, radian is 77～79 °, arranges that in face of melt circumferential movement direction cancave cambered surface top tangent line is parallel with sea line, the lower surface of cancave cambered surface bottom and tail rod 2 is located in the same horizontal plane, and the distance c between blade outer end and the crucible inwall is 5mm; The arc shaped blade cancave cambered surface radian on upper strata is 64～66 °;
The mechanical dispersion device moves up and down control device and is made of motor 14, transmission rig 15, upper stroke switch 16 and lower stroke switch 17.Transmission rig 15 is between mechanical dispersion device tail rod 2 tops and motor 14, constitute by rack and pinion, turbine and worm drive, turning to of motor 14 by upper stroke switch 16 and lower stroke switch 17 controls, just, when the upper strata of mechanical dispersion device blade is moved upwards up to semi solid slurry 8 tops, tail rod 2 touches upper stroke switch 16, and motor 14 changes turn to, and the mechanical dispersion device is moved down; When the lower leave of mechanical dispersion device was moved down into ceramic crucible 4 bottoms, tail rod 2 touched lower stroke switch 17, and motor 14 changes turn to, and the mechanical dispersion device is moved up;
The mechanical dispersion device move up and down speed control at 1～10mm/s, tail rod 2 relies on orienting sleeve 13 location, Ar tracheae 11 and thermopair 12 insert crucible by hole on the loam cake 10 and the hole between the mechanical dispersion device blade, stop up 7 and be positioned at crucible bottom, motor 14, transmission rig 15, upper stroke switch 16, lower stroke switch 17, orienting sleeve 13 adopt mechanical connection manner to be fixed on the support 18.
Boron nitride particle homodisperse method in a kind of titanium 12 nickel-5 boron nitride semi solid slurry, utilize electromagnetic mixing apparatus to stir, smash the primary dendrite that forms in the titanium 12 nickelalloy liquid process of setting, form the titanium 12 nickel semi solid slurries that constitute by nascent solid phase particles and liquid phase earlier; Then, by the mechanical dispersion device and move up and down control device, constantly the boron nitride particle that swims in titanium 12 nickel semi solid slurry tops in the crucible is distributed in the titanium 12 nickel semi solid slurries, obtain equally distributed titanium 12 nickel-5 of boron nitride particle boron nitride semi solid slurry, may further comprise the steps:
Step 1, preparation titanium 12 nickelalloy liquid, temperature is controlled at 1550 ℃;
Embodiment one, the speed of moving up and down at the mechanical dispersion device is that 3mm/s, homodisperse temperature are under 1250 ℃, when the levels arc shaped blade cancave cambered surface radian of double leaf lamella mechanical dispersion device is respectively 64 ° and 77 °, realize that the homodisperse time of equally distributed titanium 12 nickel-5 of boron nitride particle boron nitride semi solid slurry is 8 minutes and 20 seconds.
Embodiment two, the speed of moving up and down at the mechanical dispersion device is that 1mm/s, homodisperse temperature are under 1250 ℃, when the levels arc shaped blade cancave cambered surface radian of double leaf lamella mechanical dispersion device is respectively 64 ° and 79 °, realize that the homodisperse time of equally distributed titanium 12 nickel-5 of boron nitride particle boron nitride semi solid slurry is 8 minutes and 10 seconds.
Embodiment three, the speed of moving up and down at the mechanical dispersion device is that 10mm/s, homodisperse temperature are under 1370 ℃, when the levels arc shaped blade cancave cambered surface radian of double leaf lamella mechanical dispersion device is respectively 66 ° and 77 °, realize that the homodisperse time of equally distributed titanium 12 nickel-5 of boron nitride particle boron nitride semi solid slurry is 8 minutes.
Embodiment four, the speed of moving up and down at the mechanical dispersion device is that 10mm/s, homodisperse temperature are under 1370 ℃, when the levels arc shaped blade cancave cambered surface radian of double leaf lamella mechanical dispersion device is respectively 66 ° and 79 °, realize that the homodisperse time of equally distributed titanium 12 nickel-5 of boron nitride particle boron nitride semi solid slurry is 8 minutes and 10 seconds.
Embodiment five, the speed of moving up and down at the mechanical dispersion device is that 5mm/s, homodisperse temperature are under 1323 ℃, when the levels arc shaped blade cancave cambered surface radian of double leaf lamella mechanical dispersion device is respectively 65 ° and 78 °, realize that the homodisperse time of equally distributed titanium 12 nickel-5 of boron nitride particle boron nitride semi solid slurry is 8 minutes.
As seen, under the levels arc shaped blade cancave cambered surface radian of double leaf lamella mechanical dispersion device is respectively 64～66 ° and 77～79 ° of conditions, titanium 12 nickel-5 boron nitride semi solid slurry is carried out homodisperse, realize that the equally distributed homodisperse time of boron nitride particle can shorten to 8 minutes and 20 seconds.
Claims (1)
1. boron nitride particle homodisperse method in the titanium 12 nickel-5 boron nitride semi solid slurry, utilize electromagnetic mixing apparatus to stir, smash the primary dendrite that forms in the titanium 12 nickelalloy liquid process of setting, form the titanium 12 nickel semi solid slurries that constitute by nascent solid phase particles and liquid phase earlier; Then, by the mechanical dispersion device and move up and down control device, constantly the boron nitride particle that swims in titanium 12 nickel semi solid slurry tops in the crucible is distributed in the titanium 12 nickel semi solid slurries, obtain equally distributed titanium 12 nickel-5 of boron nitride particle boron nitride semi solid slurry, may further comprise the steps:
Step 1, preparation titanium 12 nickelalloy liquid, temperature is controlled at 1550 ℃;
Step 2 is poured titanium 12 nickelalloy liquid and 230 purpose boron nitride particles in the ceramic crucible into, and crucible is preheating to 1250 ℃ by the heating tube in its wall, cover loam cake after, connect Ar gas with anti-oxidation;
Step 3, start electromagnetic mixing apparatus, stir, simultaneously, close in the power supply of heating tube and the cooling tube in sidewall of crucible and to connect water coolant and cool off, melt is cooled to 1250～1370 ℃ of homodisperse temperature after, close water coolant, open and regulate the power supply of heating tube, make melt temperature be stabilized in this homodisperse temperature;
Step 4, under this homodisperse temperature, induction stirring started mechanical decollator and moves up and down control device after 5 minutes, behind the homodisperse certain hour, obtained the titanium 12 nickel-5 boron nitride semi solid slurry of homogeneous microstructure;
It is characterized in that the mechanical dispersion device is a double leaf lamella mechanical dispersion device, its levels arc shaped blade cancave cambered surface radian is respectively 64～66 ° and 77～79 °.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110088806 CN102181723A (en) | 2011-04-10 | 2011-04-10 | Uniform dispersion method for boron nitride particles in semisolid slurry consisting of 11.4 weight percent of nickel, 83.6 weight percent of titanium and 5 weight percent of boron nitride particles |
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| CN 201110088806 CN102181723A (en) | 2011-04-10 | 2011-04-10 | Uniform dispersion method for boron nitride particles in semisolid slurry consisting of 11.4 weight percent of nickel, 83.6 weight percent of titanium and 5 weight percent of boron nitride particles |
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| CN102181723A true CN102181723A (en) | 2011-09-14 |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1768979A (en) * | 2005-09-22 | 2006-05-10 | 北京交通大学 | Method for preparing QTi3.5-10 graphite semi-solid state slurry |
| CN1858278A (en) * | 2006-06-08 | 2006-11-08 | 北京交通大学 | Method for preparing aluminium 20 tin semi solid slurry by mechanically stirring |
| CN1888801A (en) * | 2006-06-08 | 2007-01-03 | 北京交通大学 | QTi3.5-10 graphite semi-solid size mechanical stirring producing method |
| CN101232937A (en) * | 2005-07-25 | 2008-07-30 | 东京油墨株式会社 | Dispersing device and dispersing method, and method of manufacturing dispersion |
| CN201693159U (en) * | 2010-06-20 | 2011-01-05 | 浙江工贸职业技术学院 | Semisolid slurry stirring preparation device for light metal |
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2011
- 2011-04-10 CN CN 201110088806 patent/CN102181723A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101232937A (en) * | 2005-07-25 | 2008-07-30 | 东京油墨株式会社 | Dispersing device and dispersing method, and method of manufacturing dispersion |
| CN1768979A (en) * | 2005-09-22 | 2006-05-10 | 北京交通大学 | Method for preparing QTi3.5-10 graphite semi-solid state slurry |
| CN1858278A (en) * | 2006-06-08 | 2006-11-08 | 北京交通大学 | Method for preparing aluminium 20 tin semi solid slurry by mechanically stirring |
| CN1888801A (en) * | 2006-06-08 | 2007-01-03 | 北京交通大学 | QTi3.5-10 graphite semi-solid size mechanical stirring producing method |
| CN201693159U (en) * | 2010-06-20 | 2011-01-05 | 浙江工贸职业技术学院 | Semisolid slurry stirring preparation device for light metal |
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Application publication date: 20110914 |