CN102175665B - Experiment device for simulating atomic oxygen oxidation ground of super-high temperature heat-protection material - Google Patents
Experiment device for simulating atomic oxygen oxidation ground of super-high temperature heat-protection material Download PDFInfo
- Publication number
- CN102175665B CN102175665B CN 201110036102 CN201110036102A CN102175665B CN 102175665 B CN102175665 B CN 102175665B CN 201110036102 CN201110036102 CN 201110036102 CN 201110036102 A CN201110036102 A CN 201110036102A CN 102175665 B CN102175665 B CN 102175665B
- Authority
- CN
- China
- Prior art keywords
- input end
- output terminal
- quartz ampoule
- atomic oxygen
- pressure
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title claims abstract description 69
- 230000003647 oxidation Effects 0.000 title claims abstract description 22
- 238000007254 oxidation reaction Methods 0.000 title claims abstract description 22
- 239000000463 material Substances 0.000 title claims abstract description 11
- 238000002474 experimental method Methods 0.000 title claims description 19
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 48
- 239000010453 quartz Substances 0.000 claims abstract description 46
- 238000010438 heat treatment Methods 0.000 claims abstract description 12
- 230000005674 electromagnetic induction Effects 0.000 claims abstract description 11
- 230000006698 induction Effects 0.000 claims abstract description 8
- 239000001301 oxygen Substances 0.000 claims description 43
- 229910052760 oxygen Inorganic materials 0.000 claims description 43
- 239000003708 ampul Substances 0.000 claims description 42
- 238000001816 cooling Methods 0.000 claims description 11
- 239000013307 optical fiber Substances 0.000 claims description 11
- 230000005284 excitation Effects 0.000 claims description 9
- 238000001228 spectrum Methods 0.000 claims description 9
- 239000007789 gas Substances 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- 230000009467 reduction Effects 0.000 claims description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 4
- 239000000498 cooling water Substances 0.000 claims description 4
- 229910052802 copper Inorganic materials 0.000 claims description 4
- 239000010949 copper Substances 0.000 claims description 4
- 238000003466 welding Methods 0.000 claims description 4
- 230000007306 turnover Effects 0.000 claims description 2
- 238000011160 research Methods 0.000 abstract description 6
- 239000003779 heat-resistant material Substances 0.000 abstract 4
- 238000004088 simulation Methods 0.000 abstract 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 6
- 239000000919 ceramic Substances 0.000 description 6
- HPNSNYBUADCFDR-UHFFFAOYSA-N chromafenozide Chemical compound CC1=CC(C)=CC(C(=O)N(NC(=O)C=2C(=C3CCCOC3=CC=2)C)C(C)(C)C)=C1 HPNSNYBUADCFDR-UHFFFAOYSA-N 0.000 description 6
- 239000002131 composite material Substances 0.000 description 6
- 239000012774 insulation material Substances 0.000 description 6
- 229910010271 silicon carbide Inorganic materials 0.000 description 6
- 229910052726 zirconium Inorganic materials 0.000 description 6
- 239000010432 diamond Substances 0.000 description 5
- 229910003460 diamond Inorganic materials 0.000 description 5
- 238000000295 emission spectrum Methods 0.000 description 5
- QFXZANXYUCUTQH-UHFFFAOYSA-N ethynol Chemical group OC#C QFXZANXYUCUTQH-UHFFFAOYSA-N 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 230000001590 oxidative effect Effects 0.000 description 5
- 238000005498 polishing Methods 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 4
- 230000001105 regulatory effect Effects 0.000 description 3
- 230000005540 biological transmission Effects 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 238000013519 translation Methods 0.000 description 2
- 230000009471 action Effects 0.000 description 1
- 230000003026 anti-oxygenic effect Effects 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- JJWKPURADFRFRB-UHFFFAOYSA-N carbonyl sulfide Chemical compound O=C=S JJWKPURADFRFRB-UHFFFAOYSA-N 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 239000004035 construction material Substances 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000003384 imaging method Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000005381 potential energy Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
Images
Landscapes
- Crystals, And After-Treatments Of Crystals (AREA)
Abstract
超高温防热材料原子氧氧化地面模拟实验装置，涉及超高温防热材料原子氧氧化地面模拟实验装置，解决了目前没有模拟这种高温、低压、原子氧氧化环境的实验装置问题，适用于模拟不同状态超高温防热材料的原子氧氧化环境；它包括石英管、原子氧发生装置、电磁感应加热装置和压力控制装置，原子氧发生装置的输出端连接在石英管的原子氧输入端，石英管的空气输出端连接在压力控制装置的空气输入端，加热装置的输出端分别连接套在石英管中部外壁的感应加热线圈的一个输入端，满足温度在1000～2000℃之间、压力在10～5000Pa之间的高超声速飞行器防热材料的原子氧氧化的实验要求，适用于高温材料原子氧环境下的氧化行为研究。
The ground simulation experiment device for atomic oxygen oxidation of ultra-high temperature heat-resistant materials relates to the ground simulation experiment device for atomic oxygen oxidation of ultra-high temperature heat-resistant materials. The atomic oxygen oxidation environment of ultra-high temperature heat-resistant materials in different states; it includes a quartz tube, an atomic oxygen generator, an electromagnetic induction heating device and a pressure control device, the output of the atomic oxygen generator is connected to the atomic oxygen input of the quartz tube, and the quartz The air output end of the tube is connected to the air input end of the pressure control device, and the output end of the heating device is respectively connected to one input end of the induction heating coil sleeved on the outer wall of the middle part of the quartz tube, satisfying the temperature between 1000 and 2000 °C and the pressure at 10 Experimental requirements for atomic oxygen oxidation of heat-resistant materials for hypersonic vehicles between ~5000Pa, suitable for research on oxidation behavior of high-temperature materials in atomic oxygen environments.
Description
Technical field
The present invention relates to experiment device for simulating atomic oxygen oxidation ground of super-high temperature heat-protection material.
Background technology
Earth orbital flight device and other celestial body detecting devices, such as lunar orbiter, reenter and be about first, the second cosmic velocity, the reentry velocity of intercontinental missile bullet is about 7km/s, aircraft has very high initial kinetic energy when reentering, be subjected to simultaneously the terrestrial gravitation field action, also has high potential energy, along with the decline of height, these energy change into kinetic energy, and aircraft will have very high flying speed, in the high-speed flight process, aircraft surface contacts with air, causes sharply compression and temperature rises rapidly of gas volume, so that the hypersonic aircraft surface temperature is near 2000 ℃; In the aerocraft real flight course, since the high-speed flight characteristics determined gas on vehicle construction material surface owing to Fast Compression is dissociated into plasma environment, the activity of this plasma induced by atomic oxygen will be far above the air under the state of nature, so under the plasma environment elemental oxygen to the oxidation of material apparently higher than air, the antioxygenic property of hypersonic aircraft surfacing under true Service Environment is a critical problem always, and the various countries scholar has carried out a large amount of experimental studies to this, but the oxidation of practical study hypersonic aircraft surfacing is limited by the restriction of equipment, carries out oxidation experiment research and can't form atomic oxygen environment; What various countries' scholar's research oxidation was adopted usually all is the air of a standard atmospheric pressure, and aircraft is along with the variation of flying height, the air pressure of its flight experience obviously reduces, and does not simulate the experimental provision of superhigh temperature heat insulation material under the high temperature under the true Service Environment, low pressure, elemental oxygen well-oxygenated environment at present.
Summary of the invention
The present invention is in order to solve the problem of the experimental provision of also not simulating at present the high temperature of superhigh temperature heat insulation material under true Service Environment, low pressure, elemental oxygen oxidation, and then a kind of experiment device for simulating atomic oxygen oxidation ground of super-high temperature heat-protection material is provided.The purpose of this invention is to provide the atomic oxygen environment of a kind of basic reproduction conduction superhigh temperature thermally protective materials under hypersonic service condition, and can carry out easily the device that parameter regulates to study material atomic oxygen oxidation behavior under the different conditions.
Experiment device for simulating atomic oxygen oxidation ground of super-high temperature heat-protection material, it comprises quartz ampoule 1, elemental oxygen generating means 2, electromagnetic induction heater 3 and pressure control device 4, the output terminal of elemental oxygen generating means 2 is connected to the elemental oxygen input end of quartz ampoule 1, the air output terminal of quartz ampoule 1 is connected to the air input end of pressure control device 4, and the output terminal difference adapter sleeve of electromagnetic induction heater 3 is at an input end of the load coil 9 of quartz ampoule 1 middle part outer wall.
The present invention is directed to the experimental provision of transition metal boride based ultra-high temperature heat insulation material elemental oxygen oxidation susceptibility research under the hypersonic flight plasma ambient, the present invention also is applicable to have the elemental oxygen oxidation behavior research work of other high-temperature materials of excellent conductive performance.Satisfied temperature of the present invention between 1000～2000 ℃, the requirement of experiment of the elemental oxygen oxidation of the hypersonic aircraft heat insulation material of pressure between 10～5000Pa.
Description of drawings
Fig. 1 is the structural representation of apparatus of the present invention, Fig. 2 is the structural representation of elemental oxygen generating means of the present invention, Fig. 3 is the structural representation of pressure control device of the present invention, Fig. 4 is the structural representation of electromagnetic induction heater of the present invention, Fig. 5 is the schematic diagram of apparatus of the present invention, and Fig. 6 is that specimen size of the present invention is Φ 10 * 3mm
3The time experimentation temperature and pressure curve map (fine rule representation temperature curve, thick line representative pressure curve among the figure, the line style among Fig. 8, Figure 10, Figure 12, Figure 14 herewith), Fig. 7 is that specimen size of the present invention is Φ 10 * 3mm
3The time experiment induced by atomic oxygen utilizing emitted light spectrogram, Fig. 8 is that specimen size of the present invention is Φ 15 * 4mm
3The time experimentation temperature and pressure curve map, Fig. 9 is that specimen size of the present invention is Φ 15 * 4mm
3The time experiment induced by atomic oxygen utilizing emitted light spectrogram, Figure 10 is that specimen size of the present invention is Φ 20 * 3mm
3The time experimentation temperature and pressure curve map, Figure 11 is that specimen size of the present invention is Φ 20 * 3mm
3The time experiment induced by atomic oxygen utilizing emitted light spectrogram, Figure 12 specimen size of the present invention is Φ 25 * 4mm
3The time experimentation temperature and pressure curve map, Figure 13 is that specimen size of the present invention is Φ 25 * 4mm
3The time experiment induced by atomic oxygen utilizing emitted light spectrogram, Figure 14 is that specimen size of the present invention is Φ 30 * 3mm
3The time experimentation temperature and pressure curve map, Figure 15 is that specimen size of the present invention is Φ 30 * 3mm
3The time experiment induced by atomic oxygen utilizing emitted light spectrogram.
Embodiment
Embodiment one
In conjunction with Fig. 1, Fig. 5 present embodiment is described, it comprises quartz ampoule 1, elemental oxygen generating means 2, electromagnetic induction heater 3 and pressure control device 4 present embodiment, the elemental oxygen output terminal of elemental oxygen generating means 2 is connected to the elemental oxygen input end of quartz ampoule 1, the air output terminal of quartz ampoule 1 is connected to the air input end of pressure control device 4, and the output terminal difference adapter sleeve of electromagnetic induction heater 3 is at an input end of the load coil 9 of quartz ampoule 1 middle part outer wall.
This experimental provision is a kind of environment that can reproduce the high temperature of hypersonic aircraft in flight course, low pressure, elemental oxygen, experimental provision to the research of electric conductivity heat insulation material oxidation behavior, it is 1000～2000 ℃ that this experimental provision can adapt in temperature range, pressure is the experiment in 10～5000Pa scope, and this device can produce microwave power 0～1500W.
Embodiment two
In conjunction with Fig. 2, Fig. 5 illustrates present embodiment, the elemental oxygen generating means 2 of present embodiment comprises welding bottle 18, reduction valve 17, flowrate control valve 14, microwave generator 5, jet vectoring valve 15 and excitation cavity 16, the output terminal of welding bottle 18 is connected to the input end of reduction valve 17, the output terminal of reduction valve 17 is connected to the input end of flowrate control valve 14, the oxygen output terminal of flowrate control valve 14 is connected to the oxygen input end of microwave generator 5, the output terminal of microwave generator 5 is connected to the input end of jet vectoring valve 15, the output terminal of jet vectoring valve 15 is connected to the input end of excitation cavity 16, and the output terminal of excitation cavity 16 is connected to the elemental oxygen input end of quartz ampoule 1.Other composition is identical with embodiment one with annexation.
Embodiment three
In conjunction with Fig. 3, Fig. 5 present embodiment is described, the pressure control device 4 of present embodiment comprises vacuum pump 10, gas outlet 11, thermocouple vacuum gauge 12 and pressure-sensitive vacuum meter 13, the air output terminal of quartz ampoule 1 is connected to the air input end of vacuum pump 10, the air output terminal of vacuum pump 10 is connected to the air input end of gas outlet 11, and the internal pressure signal output part of quartz ampoule 1 is connected to the input end of thermocouple vacuum gauge 12 and pressure-sensitive vacuum meter 13.Other composition is identical with embodiment one with annexation.
Embodiment four
In conjunction with Fig. 4, Fig. 5 present embodiment is described, the electromagnetic induction heater 3 of present embodiment comprises two colorimetric infrared pyrometers 6 and induction heating power 7, adapter sleeve is at an input end of the load coil 9 of quartz ampoule 1 middle part outer wall respectively for the output terminal of induction heating power 7, and two colorimetric infrared pyrometers 6 are suspended on the top of quartz ampoule 1 and camera lens and quartz ampoule 1 dead in line of two colorimetric infrared pyrometers 6.Other composition is identical with embodiment one with annexation.
Embodiment five
In conjunction with Fig. 4, Fig. 5 present embodiment is described, not being both it and also comprising plus lens 21, optical fiber 20 and spectrometer 8 of present embodiment and embodiment four, the spectrum of quartz ampoule 1 induced by atomic oxygen focuses on the spectrum input end of optical fiber 20 through plus lens 21, the spectrum output terminal of optical fiber 20 is connected to the spectrum input end of spectrometer 8.Other composition is identical with embodiment one with annexation.
Embodiment six
In conjunction with Fig. 4, Fig. 5 present embodiment is described, not being both it and also comprising cooling device 19 of present embodiment and embodiment five, load coil 9 is that the hollow copper tubing coiling forms, the cooling water circulation in-out end of hollow copper tubing is communicated with by the two ends of high-pressure water pipe with cooling device 19 respectively, excitation cavity 16 is arranged in the cooling jacket, and the cooling water circulation in-out end of cooling jacket is communicated with the turnover water end (W.E.) of cooling device 19 by high-pressure water pipe respectively.Other composition is identical with embodiment one with annexation.
The object of the present invention is achieved like this: it comprises microwave generator 5, and microwave energy forms the elemental oxygen jet body through waveguide transmission system to the resonator cavity energized oxygen and enters quartz ampoule 1 reaction zone; Control pressurer system 4 links to each other with quartz ampoule 1 with microwave generator 5 respectively by corrugated tube, and by control pressurer system 4 control reacting gas flow velocity and quartz ampoule 1 reaction zone internal pressures; Experimental stand places in the quartz ampoule 1; Load coil 9 is enclosed within quartz ampoule 1 outer wall and parallel with stand, and load coil 9 links to each other with induction heating power 7 and control system; The excitation cavity of microwave generator 5, transmission system, reaction chamber, pressure vacuum pump 10, induction heating power 7 and load coil 9 link to each other with cooling device 19 by high-pressure water pipe; Two colorimetric infrared pyrometers 6 hang on the upper end of quartz ampoule 1, and link to each other with controller; Tested zirconium boride-carborundum ceramic matric composite test specimen polishes smooth, and surface smoothness is lower than 1 μ m, and clamping places the elemental oxygen flow field to stand; High temperature atomic oxygen flow field focuses on by long burnt plus lens 21, images in the end face of silica fibre 20, and signal carries out data communication by optical fiber 20 input spectrum instrument 8 and with computing machine.
Regulate pressure control device 4 and microwave generator 5 regulating and controlling reaction zone environmental pressures, elemental oxygen jet velocity, regulate induction heating current Control Assay heating rate and surface heating temperature, reproduce heat insulation material surface atom oxygen oxidation behavior in the hypersonic flight plasma ambient, spectrometer 8, pressure control device 4 and electromagnetic induction heater 3 all carry out exchanges data by data line and computing machine, realize Real-time Measuring quantitative response district environmental pressure, elemental oxygen intensity and specimen surface temperature data.
Elemental oxygen test platform fine position assembly is comprised of helical riser, horizontal translation platform (having connected the micrometer screw mandrel), on the horizontal translation platform aperture is set, by jackscrew one end of optical fiber 20 is fixed, the fine position assembly can be regulated height and the horizontal level of optical fiber 20, degree of regulation is 0.01mm, described imaging plus lens 21 and optical fiber 20 are installed on the guide rail by regulating support respectively, and plus lens 21 and optical fiber 20 can move freely at moving guide rail.
Specific embodiment one:
In conjunction with Fig. 6, Fig. 7 present embodiment is described, the experiment exemplar that present embodiment adopts the zirconium boride-carborundum ceramic matric composite to make is of a size of Φ 10 * 3mm
3, adopt diamond paste that the exemplar surface finish is lower than below the 1 μ m to smooth finish.Sample after the polishing is put on the experimental stand of airtight quartz ampoule 1 two colorimetric infrared pyrometers 6 registration coupon centers; Preset 1100 ℃ of sample microwave oxidizing temperatures, the pressure in the quartz ampoule 1 is controlled at 2000Pa, and microwave generator anode current value is controlled at 200mA.Experimental period is 17 minutes, and experimentation temperature and pressure control curve as shown in Figure 6; The elemental oxygen emission spectrum as shown in Figure 7; In the experimentation, the specimen surface temperature is 1100 ± 10 ℃ of fluctuations, from Fig. 6, can obviously find out the fluctuation of temperature, for the temperature stability of oxy-acetylene (200 ℃ of temperature fluctuations) or other high-temperature heaters (20～30 ℃ of temperature fluctuations), this experimental provision temperature reliability is high; Pressure is in 2000 ± 10Pa fluctuation, and collecting the elemental oxygen wavelength is 844.61nm, and relative intensity is 3668;
Specific embodiment two:
In conjunction with Fig. 8, Fig. 9 present embodiment is described, the experiment exemplar that present embodiment adopts the zirconium boride-carborundum ceramic matric composite to make is of a size of Φ 15 * 4mm
3, adopt diamond paste that the exemplar surface finish is lower than below the 1 μ m to smooth finish.Sample after the polishing is put on the experimental stand of airtight quartz ampoule 1 two colorimetric infrared pyrometers 6 registration coupon centers; Preset 1200 ℃ of sample microwave oxidizing temperatures, the pressure in the quartz ampoule 1 is controlled at 1000Pa, and microwave generator anode current value is controlled at 240mA.Experimental period is 15 minutes, and experimentation temperature and pressure control curve as shown in Figure 8; The elemental oxygen emission spectrum as shown in Figure 9; In the experimentation, the specimen surface temperature is 1200 ± 15 ℃ of fluctuations, from Fig. 8, can obviously find out the fluctuation of temperature, for the temperature stability of oxy-acetylene (200 ℃ of temperature fluctuations) or other high-temperature heaters (20～30 ℃ of temperature fluctuations), this experimental provision temperature reliability is high; Pressure is in 1000 ± 10Pa fluctuation, and collecting the elemental oxygen wavelength is 844.61nm, and relative intensity is 4649;
Specific embodiment three:
In conjunction with Figure 10, Figure 11 present embodiment is described, the experiment exemplar that present embodiment adopts the zirconium boride-carborundum ceramic matric composite to make is of a size of Φ 20 * 3mm
3, adopt diamond paste that the exemplar surface finish is lower than below the 1 μ m to smooth finish.Sample after the polishing is put on the experimental stand of airtight quartz ampoule 1 two colorimetric infrared pyrometers 6 registration coupon centers; Preset 1300 ℃ of sample microwave oxidizing temperatures, the pressure in the quartz ampoule 1 is controlled at 500Pa, and microwave generator anode current value is controlled at 270mA.Experimental period is 16 minutes, and experimentation temperature and pressure control curve as shown in figure 10; The elemental oxygen emission spectrum as shown in figure 11; In the experimentation, the specimen surface temperature is 1300 ± 15 ℃ of fluctuations, from Figure 10, can obviously find out the fluctuation of temperature, for the temperature stability of oxy-acetylene (200 ℃ of temperature fluctuations) or other high-temperature heaters (20～30 ℃ of temperature fluctuations), this experimental provision temperature reliability is high; Pressure is in 500 ± 10Pa fluctuation, and collecting the elemental oxygen wavelength is 844.61nm, and relative intensity is 5149;
Specific embodiment four:
In conjunction with Figure 12, Figure 13 present embodiment is described, the experiment exemplar that present embodiment adopts the zirconium boride-carborundum ceramic matric composite to make is of a size of Φ 25 * 4mm
3, adopt diamond paste that the exemplar surface finish is lower than below the 1 μ m to smooth finish.Sample after the polishing is put on the experimental stand of airtight quartz ampoule 1 two colorimetric infrared pyrometers 6 registration coupon centers; Preset 1400 ℃ of sample microwave oxidizing temperatures, the pressure in the quartz ampoule 1 is controlled at 100Pa, and microwave generator anode current value is controlled at 300mA.Experimental period is 13 minutes, and experimentation temperature and pressure control curve as shown in figure 12; The elemental oxygen emission spectrum as shown in figure 13; In the experimentation, the specimen surface temperature is 1400 ± 20 ℃ of fluctuations, from Figure 12, can obviously find out the fluctuation of temperature, for the temperature stability of oxy-acetylene (200 ℃ of temperature fluctuations) or other high-temperature heaters (20～30 ℃ of temperature fluctuations), this experimental provision temperature reliability is high; Pressure is in 100 ± 5Pa fluctuation, and collecting the elemental oxygen wavelength is 844.61nm, and relative intensity is 5362;
Specific embodiment five:
In conjunction with Figure 14, Figure 15 present embodiment is described, the experiment exemplar that present embodiment adopts the zirconium boride-carborundum ceramic matric composite to make is of a size of Φ 30 * 3mm
3, adopt diamond paste that the exemplar surface finish is lower than below the 1 μ m to smooth finish.Sample after the polishing is put on the experimental stand of airtight quartz ampoule 1 two colorimetric infrared pyrometers 6 registration coupon centers; Preset 1500 ℃ of sample microwave oxidizing temperatures, the pressure in the quartz ampoule 1 is controlled at 40Pa, and microwave generator anode current value is controlled at 350mA.Experimental period is 10 minutes, and experimentation temperature and pressure control curve as shown in figure 14; The elemental oxygen emission spectrum as shown in figure 15; In the experimentation, the specimen surface temperature is 1500 ± 25 ℃ of fluctuations, from Figure 14, can obviously find out the fluctuation of temperature, for the temperature stability of oxy-acetylene (200 ℃ of temperature fluctuations) or other high-temperature heaters (20～30 ℃ of temperature fluctuations), this experimental provision temperature reliability is high; Pressure is in 40 ± 5Pa fluctuation, and collecting the elemental oxygen wavelength is 844.61nm, and relative intensity is 6010.
Claims (1)
1. experiment device for simulating atomic oxygen oxidation ground of super-high temperature heat-protection material, it is characterized in that it comprises quartz ampoule (1), elemental oxygen generating means (2), electromagnetic induction heater (3), pressure control device (4), plus lens (21), optical fiber (20), spectrometer (8) and cooling device (19), the output terminal of elemental oxygen generating means (2) is connected to the elemental oxygen input end of quartz ampoule (1), the air output terminal of quartz ampoule (1) is connected to the air input end of pressure control device (4), and the output terminal adapter sleeve of electromagnetic induction heater (3) is at an input end of the load coil (9) of quartz ampoule (1) middle part outer wall;
Elemental oxygen generating means (2) comprises welding bottle (18), reduction valve (17), flowrate control valve (14), microwave generator (5), jet vectoring valve (15) and excitation cavity (16), the output terminal of welding bottle (18) is connected to the input end of reduction valve (17), the output terminal of reduction valve (17) is connected to the input end of flowrate control valve (14), the oxygen output terminal of flowrate control valve (14) is connected to the oxygen input end of microwave generator (5), the output terminal of microwave generator (5) is connected to the input end of jet vectoring valve (15), the output terminal of jet vectoring valve (15) is connected to the input end of excitation cavity (16), and the output terminal of excitation cavity (16) is connected to the elemental oxygen input end of quartz ampoule (1);
Pressure control device (4) comprises vacuum pump (10), gas outlet (11), thermocouple vacuum gauge (12) and pressure-sensitive vacuum meter (13), the air output terminal of quartz ampoule (1) is connected to the air input end of vacuum pump (10), the air output terminal of vacuum pump (10) is connected to the air input end of gas outlet (11), and the internal pressure signal output part of quartz ampoule (1) is connected to the input end of thermocouple vacuum gauge (12) and pressure-sensitive vacuum meter (13);
Electromagnetic induction heater (3) comprises two colorimetric infrared pyrometers (6) and induction heating power (7), the output terminal adapter sleeve of induction heating power (7) is at an input end of the load coil (9) of quartz ampoule (1) middle part outer wall, and two colorimetric infrared pyrometers (6) are suspended on the top of quartz ampoule (1) and camera lens and quartz ampoule (1) dead in line of two colorimetric infrared pyrometer (6);
The spectrum of quartz ampoule (1) induced by atomic oxygen focuses on the spectrum input end of optical fiber (20) through plus lens (21), the spectrum output terminal of optical fiber (20) is connected to the spectrum input end of spectrometer (8);
Load coil (9) is that the hollow copper tubing coiling forms, the cooling water circulation in-out end of hollow copper tubing is communicated with by the two ends of high-pressure water pipe with cooling device (19) respectively, excitation cavity (16) is arranged in the cooling jacket, and the cooling water circulation in-out end of cooling jacket is communicated with by the turnover water end (W.E.) of high-pressure water pipe with cooling device (19) respectively.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110036102 CN102175665B (en) | 2011-02-11 | 2011-02-11 | Experiment device for simulating atomic oxygen oxidation ground of super-high temperature heat-protection material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110036102 CN102175665B (en) | 2011-02-11 | 2011-02-11 | Experiment device for simulating atomic oxygen oxidation ground of super-high temperature heat-protection material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102175665A CN102175665A (en) | 2011-09-07 |
| CN102175665B true CN102175665B (en) | 2013-01-16 |
Family
ID=44518872
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201110036102 Active CN102175665B (en) | 2011-02-11 | 2011-02-11 | Experiment device for simulating atomic oxygen oxidation ground of super-high temperature heat-protection material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102175665B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103344777A (en) * | 2013-06-20 | 2013-10-09 | 哈尔滨工业大学 | High-temperature and low-pressure oxygen dissociation environment test device for heat protection material |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102749851B (en) * | 2012-07-24 | 2015-01-28 | 北京航空航天大学 | Fine anti-interference tracking controller of flexible hypersonic vehicle |
| CN103234956A (en) * | 2013-04-28 | 2013-08-07 | 哈尔滨工业大学 | Testing device for catalytic coefficient of thermal shielding material and method for testing catalytic coefficient of thermal shielding material by utilizing device |
| CN104375161B (en) * | 2014-11-05 | 2017-02-15 | 北京卫星环境工程研究所 | atomic oxygen beam energy testing system |
| CN105188173B (en) * | 2015-08-05 | 2018-01-16 | 哈尔滨工业大学 | A kind of structure thermal environment simulation method and device based on sensing heating |
| CN108974398B (en) * | 2018-09-18 | 2020-08-11 | 上海空间电源研究所 | A kind of multi-angle atomic oxygen test online monitoring device and monitoring method |
| CN112965364B (en) * | 2021-02-08 | 2021-11-26 | 南京工业大学 | Modeling and iPID (induced draft identification) method for aerodynamic thermal ground simulation system of hypersonic aircraft |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101710059A (en) * | 2009-10-13 | 2010-05-19 | 中国航天科技集团公司第五研究院第五一〇研究所 | Microwave coaxial source atomic oxygen ground-based simulation equipment |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03122000A (en) * | 1989-10-04 | 1991-05-23 | Kyoichi Kuriki | Space simulated gas generating device |
-
2011
- 2011-02-11 CN CN 201110036102 patent/CN102175665B/en active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101710059A (en) * | 2009-10-13 | 2010-05-19 | 中国航天科技集团公司第五研究院第五一〇研究所 | Microwave coaxial source atomic oxygen ground-based simulation equipment |
Non-Patent Citations (7)
| Title |
|---|
| High Temperature Oxidation Behavior of ZrB2-SiC-Graphite Composite Heated by High Electric Current;Hongbo Chen等;《Advanced Materials Research》;20101231;第105-106卷;第162-163页 * |
| Hongbo Chen等.High Temperature Oxidation Behavior of ZrB2-SiC-Graphite Composite Heated by High Electric Current.《Advanced Materials Research》.2010,第105-106卷第162-163页. |
| JP平3-122000A 1991.05.23 |
| 多树旺等.聚合物及复合材料的原子氧效应实验研究.《功能材料 增刊》.2008,第39卷第439-440页. |
| 孙晓军等.模拟原子氧环境的真空摩擦试验装置.《摩擦学学报》.2002,第22卷(第6期),第463-464页. |
| 模拟原子氧环境的真空摩擦试验装置;孙晓军等;《摩擦学学报》;20021130;第22卷(第6期);第463-464页 * |
| 聚合物及复合材料的原子氧效应实验研究;多树旺等;《功能材料 增刊》;20081231;第39卷;第439-440页 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103344777A (en) * | 2013-06-20 | 2013-10-09 | 哈尔滨工业大学 | High-temperature and low-pressure oxygen dissociation environment test device for heat protection material |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102175665A (en) | 2011-09-07 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102175665B (en) | Experiment device for simulating atomic oxygen oxidation ground of super-high temperature heat-protection material | |
| CN103344777B (en) | High-temperature and low-pressure oxygen dissociation environment test device for heat protection material | |
| McGilvray et al. | The oxford high density tunnel | |
| Baccarella et al. | Development and testing of the ACT-1 experimental facility for hypersonic combustion research | |
| Stewart | Surface catalysis and characterization of proposed candidate TPS for access-to-space vehicles | |
| Li et al. | Development of integrated high temperature sensor for simultaneous measurement of wall heat flux and temperature | |
| CN106248726A (en) | ORC tests device at 500～2300 DEG C of interval thermal shock/thermal fatigue properties and radiation characteristic | |
| O'connor et al. | Turbulent mixing of an axisymmetric jet of partially dissociated nitrogen with ambient air. | |
| Vandervort et al. | Development of a vapor-based method for seeding alkali metals in shock tube facilities | |
| NEREM et al. | Shock-tube studies of equilibrium air radiation | |
| Liu et al. | Heat transfer of supercritical endothermic fuel in 3-mm diameter channels: comparison between asymmetric and uniform heating | |
| Kong et al. | Ignition and combustion characteristics of overloaded wire insulations under weakly buoyancy or microgravity environments | |
| Uhl et al. | Pyrolysis simulation in an icp torch facility | |
| Baccarella et al. | Characterization of University of Tennessee High-Enthalpy Tunnel with Nitrogen Flow | |
| CN106124559A (en) | ORC is at 500～1500 DEG C of interval antioxygenic property test devices | |
| CN114755265A (en) | A thermal insulation performance testing device and testing method for thermal protection material selection | |
| Graziani et al. | Effect of free surface radiation in axisymmetric thermocapillary flows | |
| Jarrel et al. | Development and Characterization of an Inductively Coupled Plasma Jet for High-Temperature Testing | |
| Sakharov et al. | A blunted cone in a supersonic high-enthalpy nonequilibrium air flow | |
| Ito et al. | Evaluation of surface catalytic effect on TPS in 110kW ICP-heated wind tunnel | |
| Gernoth et al. | TMF test based validation of numerical methods for the analysis of heat-loaded walls | |
| Wang et al. | Theoretical and experimental study on constant volume heating of CO2 by porous electric heaters | |
| Holden et al. | Hypervelocity studies in the LENS facility | |
| Murakami | Combined Thermal Protection and Thermal Propulsion for Aerogravity Assist Missions | |
| Huang et al. | Solar Thermal Thruster |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |