CN102174752A - Preparation method of wood pulp for fibranne - Google Patents
Preparation method of wood pulp for fibranne Download PDFInfo
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- CN102174752A CN102174752A CN 201110020836 CN201110020836A CN102174752A CN 102174752 A CN102174752 A CN 102174752A CN 201110020836 CN201110020836 CN 201110020836 CN 201110020836 A CN201110020836 A CN 201110020836A CN 102174752 A CN102174752 A CN 102174752A
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Abstract
The invention relates to a preparation method of wood pulp for fibranne. The method comprises a material preparation process, an alkali liquor preparation process, a spiral squeezing process, a stewing process, a washing process, an impurity removal process and a pulp copying process. The alkali liquor preparation process comprises the following steps of: controlling the temperature to be between 30 and 40 DEG C; and adding 3 to 4 percent of sodium hydroxide, 0.2 to 0.25 percent of boiling agent, 2.5 to 4 percent of hydrogen peroxide, 0.1 to 0.2 percent of anthraquinone and 0.1 to 0.2 percent of bioactivity complex enzyme according to oven dry stock amount respectively to obtain alkali liquor. The prepared wood pulp has high alpha cellulose content, high yield, high reactivity and low non-fibrous impurity content and meets the quality requirements of preparing fibranne; and by the method, the chemical oxygen demand (COD) content of discharged wastewater is 1,100 to 1,300 mg/l which belongs to low pollution, and pollution to the environment is reduced.
Description
Technical field
The present invention relates to a kind of pulping process, relating in particular to a kind of papermaking level wood pulps that adopts is the method for feedstock production short rayon fiber Wesy wood pulps.
Background technology
Domestic enterprise is many with the raw materials for production of the cotton pulp dregs of rice as viscose.The resource of raw material cotton linter is subjected to the restriction of cultivated area and growth cycle and shortage day by day, along with the development of viscose industry, and the expansion of production capacity, there is lack of raw materials has restricted the development of China's viscose industry.Existing for this reason enterprise is used for viscose glue production with dissolving pulp, but price height, the shortage of import dissolving pulp, has influenced the normal operation and the economic benefit of enterprise, seeks the substitute of dissolving pulp, is a vital task of enterprise.
At present, China's import a large amount of papermaking level wood-pulp boards because different with the pulping process technology of import dissolving pulp, there are shortcomings such as degree of polymerization height, reactivity worth difference and non-cellulosic impurity content height in the papermaking level wood-pulp board.The enterprise that has adopts the high alkaline boiling of high temperature mostly with papermaking level wood-pulp board production wood pulps, and chlorine, sodium hypochlorite bleaching though can be used for the production of viscose staple fibre, also reach the index of import dissolving pulp, and there is following defective in existing processes:
(1) all adopt boiling, two sections pulping ways of bleaching, pulping process is loaded down with trivial details, complicated, the energy consumption height.
(2) chlorinated with chlorine, sodium hypochlorite bleaching are adopted in bleaching, produce organohalogen compounds and carcinogenic material bioxin, and environment and water source are polluted.
(3) reach short rayon fiber Wesy wood pulp index though make wood pulp, but non-fiber impurity content height, in the viscose staple fibre production process, reactivity worth is poor, easily form micelle, micelle, filterability is poor, and easily stifled filter cloth can not use separately, must be used with a certain proportion of cotton pulp, ratio generally can not surpass 10%, and the viscose staple fibre spinnability that makes is poor, can not mention in the same breath with the dissolving grade wood pulp.
(4) cooking section adopts high temperature, high-alkali technology, destroys greatly first is fine.
Summary of the invention
The technical problem to be solved in the present invention is at above defective, the preparation method of a kind of short rayon fiber Wesy wood pulps is provided, the viscose of the method preparation fine content height of wood pulp first, good and the cotton pulp of reactivity worth cooperates when producing viscose staple fibre, and adding proportion surpasses 80%, and when using wood pulp with the method production viscose, waste water COD content is low, does not produce organohalogen compounds and carcinogenic material bioxin, has reduced environment and pollution of waterhead.
For addressing the above problem, the present invention adopts following technical scheme: the preparation method of a kind of short rayon fiber Wesy wood pulps is characterized in that: described preparation method comprises and gets the raw materials ready, alkali lye preparation, screw press, boiling, washing, removal of impurities, copies dregs of rice operation;
The alkali lye preparation process is: temperature is controlled at 30-40 ℃, the NaOH that to add relative oven dry stock amount be 3-4%, the oven dry stock amount is the digesting agent of 0.2-0.25% relatively, the oven dry stock amount is the hydrogen peroxide of 2.5-4% relatively, the oven dry stock amount is the anthraquinone of 0.1-0.2% relatively, the oven dry stock amount is the hemicellulose biologically active complex enzyme of 1-2 ‰ relatively, is mixed with alkali lye;
Described screw press operation is: in papermaking level wood pulp and alkali lye is 1: the ratio of 4-4.5, in pressafiner, alkali lye is sprayed on the papermaking level wood pulp, and alkali lye mixes with the papermaking level wood pulp, changes over to then in the rotary spherical digester;
Described cooking process is: in rotary spherical digester, and cold commentaries on classics 20min, a heating-up time control 30min, holding temperature is controlled at 45-55 ℃, and insulation 70-80min once after the insulation, carries out secondary temperature elevation;
The secondary temperature elevation time is controlled at 30min, and temperature is controlled at 88-92 ℃, behind the temperature retention time 60-70min, carries out three times and heats up;
Three heating-up times are controlled at 30min, and temperature is controlled at 115-120 ℃, behind the temperature retention time 50-60min, carry out steam bleeding for the third time then, and after the boiling, the degree of polymerization is 480-520, change beater over to after washing twice.
As further improvement in the technical proposal:
Described washing procedure is: in beater, carries out, and making beating electric current 50-90A, the washing control time after the washing, changes desander at 60min in beater.
Described removal of impurities operation is: in desander, carries out, and pressure 0.28-0.33MPa, slurry concentration is controlled at 0.5-0.6%, after the desanding, changes thickener over to.
The described dregs of rice operation of copying is: carry out in thickener, slurry concentration is controlled at 3.5-4.5%, after concentrating, again through the machine of manufacturing paper with pulp, makes finished product after manufacturing paper with pulp.
Described procedure for preparation is: wood pulps is cut into the rectangular of 2-6cm with cutting dregs of rice machine, delivers to pressafiner by cyclone separator.
The present invention adopts technique scheme, has the following advantages:
In the technology of the present invention, the first time of cooking process is in the insulating process, but non-cellulosic impurities such as hemicellulose biologically active complex enzyme efficient degradation xylan and pectin, simultaneously with most of water-soluble substances and the low stripping that divides subbundle.In second and third time insulation digestion process, what at first react is materials such as oligosaccharides and lignin, be used by anthraquinone, digesting agent and NaOH, main purpose is to allow material generation saponification such as contained fat in the cotton linter, pectin, hemicellulose, lignin, chemical reactions such as emulsification, generate water-soluble material, these non-cellulose materials are removed from fiber, the water-soluble substances dissolution rate is accelerated, make alkali lye fully be penetrated into fibrous inside, can help cellulosic refining purification, the degree of polymerization is effectively controlled; In three insulating processes, along with variations in temperature, cellulosic degradation speed is accelerated in the papermaking level wood pulp, and is with most of water-soluble substances and the low stripping that divides subbundle, under boiling temperature of the present invention, little to the destruction of first fibre simultaneously.
In cooking process; hydrogen peroxide not only can improve whiteness; and can shorten digestion time, and simplify processing step, make chemical reaction targeted; protected fibre strength effectively; removed the impurity of cooking liquor, controlled the boiling degree of polymerization effectively, hydrogen peroxide and cotton seed hulls pigment reaction simultaneously; whole pulping process waste water COD discharge capacity is reduced, alleviated waste water control pressure.
In cooking process, anthraquinone both can have been accelerated the speed of delignification, shortened digestion time, improved paper pulp yield, reduced the waste liquid load; But non-cellulosic impurities such as hemicellulose biologically active complex enzyme efficient degradation xylan and pectin.
The present invention prepares the method for viscose staple fibre pulp slurry, the fine content of the wood pulps first that makes reaches more than 93%, the yield height, reactivity worth is good, non-fiber impurity content is low, meets the quality requirement of making viscose staple fibre, and this method waste discharge COD content 1100-1300mg/l, belong to low the pollution, reduced pollution environment.
Below in conjunction with embodiment the present invention is elaborated.
The specific embodiment
Embodiment 1, and the preparation method of a kind of short rayon fiber Wesy wood pulps comprises and gets the raw materials ready, alkali lye preparation, screw press, boiling, washing, removal of impurities, copies dregs of rice operation;
Procedure for preparation is: wood pulps is cut into the rectangular of 2cm with cutting dregs of rice machine, delivers to screw press by cyclone separator;
The alkali lye preparation process is: temperature is controlled at 30 ℃, add relative oven dry stock amount and be 3% NaOH, the oven dry stock amount is 0.2% digesting agent relatively, the oven dry stock amount is 2.5% hydrogen peroxide relatively, the oven dry stock amount is 0.1% anthraquinone relatively, the oven dry stock amount is 2 ‰ hemicellulose biologically active complex enzyme relatively, be mixed with alkali lye, digesting agent is that the happy Fine Chemical Co., Ltd in sea, Qingdao produces, the HaiYi board, model is the digesting agent of SDO-A, and hemicellulose biologically active complex enzyme is the Ca-sho1 hemicellulose biologically active complex enzyme that Shanghai thing Science and Technology Ltd. of fringe Hang Seng produces;
The screw press operation is: in papermaking level wood pulp and alkali lye is 1: 4 ratio, in pressafiner alkali lye is sprayed on the papermaking level wood pulp, and alkali lye mixes with the papermaking level wood pulp, changes over to then in the rotary spherical digester;
Cooking process is: in rotary spherical digester, and cold commentaries on classics 20min, a heating-up time control 30min, holding temperature is controlled at 45 ℃, and insulation 70min once after the insulation, carries out secondary temperature elevation;
The secondary temperature elevation time is controlled at 30min, and temperature is controlled at 88 ℃, behind the temperature retention time 60min, carries out three times and heats up;
Three heating-up times are controlled at 30min, and temperature is controlled at 115 ℃, behind the temperature retention time 50min, carry out steam bleeding for the third time then, and after the boiling, the degree of polymerization is 520, change beater over to after washing twice.
Washing procedure is: in beater, carries out, and making beating electric current 50A, the washing control time after the washing, changes desander at 60min in beater.
The removal of impurities operation is: carry out in desander, pressure is 0.28MPa, and slurry concentration is controlled at 0.5%, after the desanding, changes thickener over to.
Copying dregs of rice operation is: carry out in thickener, slurry concentration is controlled at 3.5%, after concentrating, again through the machine of manufacturing paper with pulp, makes finished product after manufacturing paper with pulp.
The key technical indexes of gained wood pulps is as follows:
| Project | Index | Project | Index |
| Whiteness | 84％ | The degree of polymerization | 519 |
| The first fibre | 94.5％ | Reactivity worth | 28s |
| Big dust | 1.0mm 2/kg | Little dust | 64mm 2/kg |
| Irony | 8ppm | Moisture content | 8.5％ |
| Constant volume is heavy | 612g/m 2 | Inhale base number | 650％ |
From above data as can be seen, the fine content height of the first of gained wood pulps, the whiteness height, non-fiber impurity content is low.
Embodiment 2, and the preparation method of a kind of short rayon fiber Wesy wood pulps comprises and gets the raw materials ready, alkali lye preparation, screw press, boiling, washing, removal of impurities, copies dregs of rice operation;
Procedure for preparation is: wood pulps is cut into the rectangular of 3cm with cutting dregs of rice machine, delivers to screw press by cyclone separator;
The alkali lye preparation process is: temperature is controlled at 32 ℃, add relative oven dry stock amount and be 3.2% NaOH, the oven dry stock amount is 0.21% digesting agent relatively, the oven dry stock amount is 2.8% hydrogen peroxide relatively, the oven dry stock amount is 0.12% anthraquinone relatively, the oven dry stock amount is 1.2 ‰ hemicellulose biologically active complex enzyme relatively, be mixed with alkali lye, digesting agent is that the happy Fine Chemical Co., Ltd in sea, Qingdao produces, the HaiYi board, model is the digesting agent of SDO-A, and hemicellulose biologically active complex enzyme is the Ca-sho1 hemicellulose biologically active complex enzyme that Shanghai thing Science and Technology Ltd. of fringe Hang Seng produces;
The screw press operation is: in papermaking level wood pulp and alkali lye is 1: 4.1 ratio, in pressafiner alkali lye is sprayed on the papermaking level wood pulp, and alkali lye mixes with the papermaking level wood pulp, changes over to then in the rotary spherical digester;
Cooking process is: in rotary spherical digester, and cold commentaries on classics 20min, a heating-up time control 30min, holding temperature is controlled at 47 ℃, and insulation 72min once after the insulation, carries out secondary temperature elevation;
The secondary temperature elevation time is controlled at 30min, and temperature is controlled at 89 ℃, behind the temperature retention time 62min, carries out three times and heats up;
Three heating-up times are controlled at 30min, and temperature is controlled at 116 ℃, behind the temperature retention time 52min, carry out steam bleeding for the third time then, and after the boiling, the degree of polymerization is 512, change beater over to after washing twice.
Washing procedure is: in beater, carries out, and making beating electric current 60A, the washing control time after the washing, changes desander at 60min in beater.
The removal of impurities operation is: carry out in desander, pressure is 0.29MPa, and slurry concentration is controlled at 0.52%, after the desanding, changes thickener over to.
The operation that concentrates, manufactures paper with pulp is: carry out in thickener, slurry concentration is controlled at 3.7%, after concentrating, again through the machine of manufacturing paper with pulp, makes finished product after manufacturing paper with pulp.
The key technical indexes of gained wood pulps is as follows:
| Project | Index | Project | Index |
| Whiteness | 84.6％ | The degree of polymerization | 510 |
| The first fibre | 94.2％ | Reactivity worth | 25s |
| Big dust | 1.0m 2/kg | Little dust | 58mm 2/kg |
| Irony | 7ppm | Moisture content | 8.9％ |
| Constant volume is heavy | 637g/m 2 | Inhale base number | 627％ |
From above data as can be seen, the fine content height of the first of gained wood pulps, the whiteness height, non-fiber impurity content is low.
Embodiment 3, and the preparation method of a kind of short rayon fiber Wesy wood pulps comprises and gets the raw materials ready, alkali lye preparation, screw press, boiling, washing, removal of impurities, copies dregs of rice operation;
Procedure for preparation is: wood pulps is cut into the rectangular of 3.5cm with cutting dregs of rice machine, delivers to screw press by cyclone separator;
The alkali lye preparation process is: temperature is controlled at 34 ℃, add relative oven dry stock amount and be 3.4% NaOH, the oven dry stock amount is 0.22% digesting agent relatively, the oven dry stock amount is 3.0% hydrogen peroxide relatively, the oven dry stock amount is 0.14% anthraquinone relatively, the oven dry stock amount is 1.4 ‰ hemicellulose biologically active complex enzyme relatively, be mixed with alkali lye, digesting agent is that the happy Fine Chemical Co., Ltd in sea, Qingdao produces, the HaiYi board, model is the digesting agent of SDO-A, and hemicellulose biologically active complex enzyme is the Ca-sho1 hemicellulose biologically active complex enzyme that Shanghai thing Science and Technology Ltd. of fringe Hang Seng produces;
The screw press operation is: in papermaking level wood pulp and alkali lye is 1: 4.2 ratio, in pressafiner alkali lye is sprayed on the papermaking level wood pulp, and alkali lye mixes with the papermaking level wood pulp, changes over to then in the rotary spherical digester;
Cooking process is: in rotary spherical digester, and cold commentaries on classics 20min, a heating-up time control 30min, holding temperature is controlled at 49 ℃, and insulation 74min once after the insulation, carries out secondary temperature elevation;
The secondary temperature elevation time is controlled at 30min, and temperature is controlled at 89.5 ℃, behind the temperature retention time 64min, carries out three times and heats up;
Three heating-up times are controlled at 30min, and temperature is controlled at 117 ℃, behind the temperature retention time 54min, carry out steam bleeding for the third time then, and after the boiling, the degree of polymerization is 506, change beater over to after washing twice.
Washing procedure is: in beater, carries out, and making beating electric current 65A, the washing control time after the washing, changes desander at 60min in beater.
The removal of impurities operation is: carry out in desander, pressure is 0.30MPa, and slurry concentration is controlled at 0.54%, after the desanding, changes thickener over to.
The operation that concentrates, manufactures paper with pulp is: carry out in thickener, slurry concentration is controlled at 3.9%, after concentrating, again through the machine of manufacturing paper with pulp, makes finished product after manufacturing paper with pulp.
The key technical indexes of gained wood pulps is as follows:
| Project | Index | Project | Index |
| Whiteness | 85％ | The degree of polymerization | 504 |
| The first fibre | 94.0％ | Reactivity worth | 19s |
| Big dust | 1.0mm 2/kg | Little dust | 51mm 2/kg |
| Irony | 8ppm | Moisture content | 8.6％ |
| Constant volume is heavy | 673/m 2 | Inhale base number | 596％ |
From above data as can be seen, the fine content height of the first of gained wood pulps, the whiteness height, non-fiber impurity content is low.
Embodiment 4, and the preparation method of a kind of short rayon fiber Wesy wood pulps comprises and gets the raw materials ready, alkali lye preparation, screw press, boiling, washing, removal of impurities, copies dregs of rice operation;
Procedure for preparation is: wood pulps is cut into the rectangular of 4cm with cutting dregs of rice machine, delivers to screw press by cyclone separator;
The alkali lye preparation process is: temperature is controlled at 35 ℃, add relative oven dry stock amount and be 3.5% NaOH, the oven dry stock amount is 0.23% digesting agent relatively, the oven dry stock amount is 3.2% hydrogen peroxide relatively, the oven dry stock amount is 0.15% anthraquinone relatively, the oven dry stock amount is 1.5 ‰ hemicellulose biologically active complex enzyme relatively, be mixed with alkali lye, digesting agent is that the happy Fine Chemical Co., Ltd in sea, Qingdao produces, the HaiYi board, model is the digesting agent of SDO-A, and hemicellulose biologically active complex enzyme is the Ca-sho1 hemicellulose biologically active complex enzyme that Shanghai thing Science and Technology Ltd. of fringe Hang Seng produces;
The screw press operation is: in papermaking level wood pulp and alkali lye is 1: 4.3 ratio, in pressafiner alkali lye is sprayed on the papermaking level wood pulp, and alkali lye mixes with the papermaking level wood pulp, changes over to then in the rotary spherical digester; Cooking process is: in rotary spherical digester, and cold commentaries on classics 20min, a heating-up time control 30min, holding temperature is controlled at 50 ℃, and insulation 75min once after the insulation, carries out secondary temperature elevation;
The secondary temperature elevation time is controlled at 30min, and temperature is controlled at 90 ℃, behind the temperature retention time 65min, carries out three times and heats up;
Three heating-up times are controlled at 30min, and temperature is controlled at 117 ℃, behind the temperature retention time 55min, carry out steam bleeding for the third time then, and after the boiling, the degree of polymerization is 499, change beater over to after washing twice.
Washing procedure is: in beater, carries out, and making beating electric current 70A, the washing control time after the washing, changes desander at 60min in beater.
The removal of impurities operation is: carry out in desander, pressure is 0.32MPa, and slurry concentration is controlled at 0.55%, after the desanding, changes thickener over to.
The operation that concentrates, manufactures paper with pulp is: carry out in thickener, slurry concentration is controlled at 4.0%, after concentrating, again through the machine of manufacturing paper with pulp, makes finished product after manufacturing paper with pulp.
The key technical indexes of gained wood pulps is as follows:
| Project | Index | Project | Index |
| Whiteness | 85.3％ | The degree of polymerization | 496 |
| The first fibre | 93.8％ | Reactivity worth | 16s |
| Big dust | 1.0mm 2/kg | Little dust | 45mm 2/kg |
| Irony | 8ppm | Moisture content | 9％ |
| Constant volume is heavy | 709g/m 2 | Inhale base number | 577％ |
From above data as can be seen, the fine content height of the first of gained wood pulps, the whiteness height, non-fiber impurity content is low.
Embodiment 5, and the preparation method of a kind of short rayon fiber Wesy wood pulps comprises and gets the raw materials ready, alkali lye preparation, screw press, boiling, washing, removal of impurities, copies dregs of rice operation;
Procedure for preparation is: wood pulps is cut into the rectangular of 4.5cm with cutting dregs of rice machine, delivers to screw press by cyclone separator;
The alkali lye preparation process is: temperature is controlled at 36 ℃, add relative oven dry stock amount and be 3.6% NaOH, the oven dry stock amount is 0.23% digesting agent relatively, the oven dry stock amount is 3.5% hydrogen peroxide relatively, the oven dry stock amount is 0.16% anthraquinone relatively, the oven dry stock amount is 1.6 ‰ hemicellulose biologically active complex enzyme relatively, be mixed with alkali lye, digesting agent is that the happy Fine Chemical Co., Ltd in sea, Qingdao produces, the HaiYi board, model is the digesting agent of SDO-A, and hemicellulose biologically active complex enzyme is the Ca-sho1 hemicellulose biologically active complex enzyme that Shanghai thing Science and Technology Ltd. of fringe Hang Seng produces;
The screw press operation is: in papermaking level wood pulp and alkali lye is 1: 4.3 ratio, in pressafiner alkali lye is sprayed on the papermaking level wood pulp, and alkali lye mixes with the papermaking level wood pulp, changes over to then in the rotary spherical digester;
Cooking process is: in rotary spherical digester, and cold commentaries on classics 20min, a heating-up time control 30min, holding temperature is controlled at 51 ℃, and insulation 76min once after the insulation, carries out secondary temperature elevation;
The secondary temperature elevation time is controlled at 30min, and temperature is controlled at 90 ℃, behind the temperature retention time 66min, carries out three times and heats up;
Three heating-up times are controlled at 30min, and temperature is controlled at 118 ℃, behind the temperature retention time 56min, carry out steam bleeding for the third time then, and after the boiling, the degree of polymerization is 492, change beater over to after washing twice.
Washing procedure is: in beater, carries out, and making beating electric current 75A, the washing control time after the washing, changes desander at 60min in beater.
The removal of impurities operation is: carry out in desander, pressure is 0.31MPa, and slurry concentration is controlled at 0.56%, after the desanding, changes thickener over to.
Copying dregs of rice operation is: carry out in thickener, slurry concentration is controlled at 4.1%, after concentrating, again through the machine of manufacturing paper with pulp, makes finished product after manufacturing paper with pulp.
The key technical indexes of gained wood pulps is as follows:
| Project | Index | Project | Index |
| Whiteness | 85.8％ | The degree of polymerization | 491 |
| The first fibre | 93.7％ | Reactivity worth | 14s |
| Big dust | 1.0mm 2/kg | Little dust | 42mm 2/kg |
| Irony | 7ppm | Moisture content | 9.2％ |
| Constant volume is heavy | 728g?/m 2 | Inhale base number | 556％ |
From above data as can be seen, the fine content height of the first of gained wood pulps, the whiteness height, non-fiber impurity content is low.
Embodiment 6, and the preparation method of a kind of short rayon fiber Wesy wood pulps comprises and gets the raw materials ready, alkali lye preparation, screw press, boiling, washing, removal of impurities, copies dregs of rice operation;
Procedure for preparation is: wood pulps is cut into the rectangular of 5cm with cutting dregs of rice machine, delivers to screw press by cyclone separator;
The alkali lye preparation process is: temperature is controlled at 38 ℃, add relative oven dry stock amount and be 3.8% NaOH, the oven dry stock amount is 0.24% digesting agent relatively, the oven dry stock amount is 3.7% hydrogen peroxide relatively, the oven dry stock amount is 0.18% anthraquinone relatively, the oven dry stock amount is 1.8 ‰ hemicellulose biologically active complex enzyme relatively, be mixed with alkali lye, digesting agent is that the happy Fine Chemical Co., Ltd in sea, Qingdao produces, the HaiYi board, model is the digesting agent of SDO-A, and hemicellulose biologically active complex enzyme is the Ca-sho1 hemicellulose biologically active complex enzyme that Shanghai thing Science and Technology Ltd. of fringe Hang Seng produces;
The screw press operation is: in papermaking level wood pulp and alkali lye is 1: 4.4 ratio, in pressafiner alkali lye is sprayed on the papermaking level wood pulp, and alkali lye mixes with the papermaking level wood pulp, changes over to then in the rotary spherical digester;
Cooking process is: in rotary spherical digester, and cold commentaries on classics 20min, a heating-up time control 30min, holding temperature is controlled at 53 ℃, and insulation 78min once after the insulation, carries out secondary temperature elevation;
The secondary temperature elevation time is controlled at 30min, and temperature is controlled at 91 ℃, behind the temperature retention time 68min, carries out three times and heats up;
Three heating-up times are controlled at 30min, and temperature is controlled at 119 ℃, behind the temperature retention time 58min, carry out steam bleeding for the third time then, and after the boiling, the degree of polymerization is 487, change beater over to after washing twice.
Washing procedure is: in beater, carries out, and making beating electric current 80A, the washing control time after the washing, changes desander at 60min in beater.
The removal of impurities operation is: carry out in desander, pressure is 0.32MPa, and slurry concentration is controlled at 0.58%, after the desanding, changes thickener over to.
Copying dregs of rice operation is: carry out in thickener, slurry concentration is controlled at 4.3%, after concentrating, again through the machine of manufacturing paper with pulp, makes finished product after manufacturing paper with pulp.
The key technical indexes of gained wood pulps is as follows:
| Project | Index | Project | Index |
| Whiteness | 86.3％ | The degree of polymerization | 486 |
| The first fibre | 93.4％ | Reactivity worth | 11s |
| Big dust | 1.0mm 2/kg | Little dust | 38mm 2/kg |
| Irony | 7ppm | Moisture content | 9％ |
| Constant volume is heavy | 749g/m 2 | Inhale base number | 541％ |
From above data as can be seen, the fine content height of the first of gained wood pulps, the whiteness height, non-fiber impurity content is low.
Embodiment 7, and the preparation method of a kind of short rayon fiber Wesy wood pulps comprises and gets the raw materials ready, alkali lye preparation, screw press, boiling, washing, removal of impurities, copies dregs of rice operation;
Procedure for preparation is: wood pulps is cut into the rectangular of 6cm with cutting dregs of rice machine, delivers to screw press by cyclone separator;
The alkali lye preparation process is: temperature is controlled at 40 ℃, add relative oven dry stock amount and be 4% NaOH, the oven dry stock amount is 0.25% digesting agent relatively, the oven dry stock amount is 4% hydrogen peroxide relatively, the oven dry stock amount is 0.2% anthraquinone relatively, the oven dry stock amount is 2 ‰ hemicellulose biologically active complex enzyme relatively, be mixed with alkali lye, digesting agent is that the happy Fine Chemical Co., Ltd in sea, Qingdao produces, the HaiYi board, model is the digesting agent of SD0-A, and hemicellulose biologically active complex enzyme is the Ca-sho1 hemicellulose biologically active complex enzyme that Shanghai thing Science and Technology Ltd. of fringe Hang Seng produces;
The screw press operation is: in papermaking level wood pulp and alkali lye is 1: 4.5 ratio, in pressafiner alkali lye is sprayed on the papermaking level wood pulp, and alkali lye mixes with the papermaking level wood pulp, changes over to then in the rotary spherical digester;
Cooking process is: in rotary spherical digester, and cold commentaries on classics 20min, a heating-up time control 30min, holding temperature is controlled at 55 ℃, and insulation 80min once after the insulation, carries out secondary temperature elevation;
The secondary temperature elevation time is controlled at 30min, and temperature is controlled at 92 ℃, behind the temperature retention time 70min, carries out three times and heats up;
Three heating-up times are controlled at 30min, and temperature is controlled at 120 ℃, behind the temperature retention time 60min, carry out steam bleeding for the third time then, and after the boiling, the degree of polymerization is 483, change beater over to after washing twice.
Washing procedure is: in beater, carries out, and making beating electric current 90A, the washing control time after the washing, changes desander at 60min in beater.
The removal of impurities operation is: carry out in desander, pressure is 0.33MPa, and slurry concentration is controlled at 0.6%, after the desanding, changes thickener over to.
Copying dregs of rice operation is: carry out in thickener, slurry concentration is controlled at 4.5%, after concentrating, again through the machine of manufacturing paper with pulp, makes finished product after manufacturing paper with pulp.The key technical indexes of gained wood pulps is as follows:
| Project | Index | Project | Index |
| Whiteness | 86.7％ | The degree of polymerization | 481 |
| The first fibre | 93％ | Reactivity worth | 9s |
| Big dust | 1.0mm 2/kg | Little dust | 36mm 2/kg |
| Irony | 7ppm | Moisture content | 9.1％ |
| Constant volume is heavy | 765g?/m 2 | Inhale base number | 523％ |
From above data as can be seen, the fine content height of the first of gained wood pulps, the whiteness height, non-fiber impurity content is low, and the product combination property that embodiment is 6 is best.
Among the above embodiment, the relative oven dry stock amount of NaOH percentage, the relative oven dry stock amount of SDO-A digesting agent percentage, the relative oven dry stock amount of hydrogen peroxide percentage, the relative oven dry stock amount of hemicellulose biologically active complex enzyme percentage, anthraquinone relative oven dry stock amount percentage and slurry percent concentration are weight percent concentration percentage.
Prepare short rayon fiber Wesy wood pulps according to above method, digesting agent can also use the digesting agent JN-94 of Shandong sunlight pigment Co., Ltd, the digesting agent AC-170 of Shaoxin City's applied chemistry research institute or the digesting agent that Jingzhou City Ford's textile auxiliary Manufacturing Co., Ltd produces.
Above hemicellulose biologically active complex enzyme also can use other can degradation of xylan and the complex enzyme of non-cellulosic impurity such as pectin.
Claims (5)
1. the preparation method of a short rayon fiber Wesy wood pulps is characterized in that: described preparation method comprises and gets the raw materials ready, alkali lye preparation, screw press, boiling, washing, removal of impurities, copies dregs of rice operation;
The alkali lye preparation process is: temperature is controlled at 30-40 ℃, the NaOH that to add relative oven dry stock amount be 3-4%, the oven dry stock amount is the digesting agent of 0.2-0.25% relatively, the oven dry stock amount is the hydrogen peroxide of 2.5-4% relatively, the oven dry stock amount is the anthraquinone of 0.1-0.2% relatively, the oven dry stock amount is the hemicellulose biologically active complex enzyme of 1-2 ‰ relatively, is mixed with alkali lye;
Described screw press operation is: in papermaking level wood pulp and alkali lye is 1: the ratio of 4-4.5, in pressafiner, alkali lye is sprayed on the papermaking level wood pulp, and alkali lye mixes with the papermaking level wood pulp, changes over to then in the rotary spherical digester;
Described cooking process is: in rotary spherical digester, and cold commentaries on classics 20min, a heating-up time is controlled at 30min, and holding temperature is controlled at 45-55 ℃, and insulation 70-80min once after the insulation, carries out secondary temperature elevation;
The secondary temperature elevation time is controlled at 30min, and temperature is controlled at 88-92 ℃, behind the temperature retention time 60-70min, carries out three times and heats up;
Three heating-up times are controlled at 30min, and temperature is controlled at 115-120 ℃, behind the temperature retention time 50-60min, carry out steam bleeding for the third time then, and after the boiling, the degree of polymerization is 480-520, change beater over to after washing twice.
2. the preparation method of short rayon fiber Wesy wood pulps according to claim 1, it is characterized in that: described washing procedure is: in beater, carry out, making beating electric current 50-90A, the washing control time after the washing, changes desander at 60min in beater.
3. the preparation method of short rayon fiber Wesy wood pulps according to claim 1, it is characterized in that: described removal of impurities operation is: in desander, carry out, pressure 0.28-0.33MPa, slurry concentration is controlled at 0.5-0.6%, after the desanding, changes thickener over to.
4. state the preparation method of short rayon fiber Wesy wood pulps as claim 1, it is characterized in that: the described dregs of rice operation of copying is: carry out in thickener, slurry concentration is controlled at 3.5-4.5%, after concentrating, again through the machine of manufacturing paper with pulp, makes finished product after manufacturing paper with pulp.
5. the preparation method of short rayon fiber Wesy wood pulps according to claim 1, it is characterized in that: described procedure for preparation is: wood pulps is cut into the rectangular of 2-6cm with cutting dregs of rice machine, delivers to pressafiner by cyclone separator.
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| CN103061180A (en) * | 2012-12-21 | 2013-04-24 | 新疆博湖苇业股份有限公司 | Preparation method of Reed pulp used for viscose staple fiber |
| CN103103842A (en) * | 2012-12-14 | 2013-05-15 | 中冶美利纸业股份有限公司 | Pulping method for waste Renminbi |
| CN104389217A (en) * | 2014-10-23 | 2015-03-04 | 广东比伦生活用纸有限公司 | Production method for environment-friendly and energy-saving living paper wood pulp |
| CN109338790A (en) * | 2018-09-04 | 2019-02-15 | 江苏星光新材料科技有限公司 | A kind of environmental protection wood pulp technique |
| CN112011885A (en) * | 2020-08-31 | 2020-12-01 | 无锡恒诺纺织科技有限公司 | Viscose fiber knitted fabric manufacturing method |
| CN113818270A (en) * | 2021-08-13 | 2021-12-21 | 湖北金汉江精制棉有限公司 | Production method for controlling depolymerization during cooking of purified cotton |
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| CN101818460A (en) * | 2009-12-17 | 2010-09-01 | 宜宾长毅浆粕有限责任公司 | Method for preparing wood dissolving pulp by modifying true color unbleached wood pulp |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103103842A (en) * | 2012-12-14 | 2013-05-15 | 中冶美利纸业股份有限公司 | Pulping method for waste Renminbi |
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| CN109338790A (en) * | 2018-09-04 | 2019-02-15 | 江苏星光新材料科技有限公司 | A kind of environmental protection wood pulp technique |
| CN112011885A (en) * | 2020-08-31 | 2020-12-01 | 无锡恒诺纺织科技有限公司 | Viscose fiber knitted fabric manufacturing method |
| CN113818270A (en) * | 2021-08-13 | 2021-12-21 | 湖北金汉江精制棉有限公司 | Production method for controlling depolymerization during cooking of purified cotton |
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Application publication date: 20110907 |