CN102167927A - Ink composition with high-weather-resistance black dye for ink-jet printing - Google Patents
Ink composition with high-weather-resistance black dye for ink-jet printing Download PDFInfo
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- CN102167927A CN102167927A CN2011101031889A CN201110103188A CN102167927A CN 102167927 A CN102167927 A CN 102167927A CN 2011101031889 A CN2011101031889 A CN 2011101031889A CN 201110103188 A CN201110103188 A CN 201110103188A CN 102167927 A CN102167927 A CN 102167927A
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- 239000000203 mixture Substances 0.000 title claims abstract description 47
- 238000007641 inkjet printing Methods 0.000 title claims abstract description 19
- 239000008367 deionised water Substances 0.000 claims abstract description 24
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 24
- 238000001914 filtration Methods 0.000 claims abstract description 17
- 239000002904 solvent Substances 0.000 claims abstract description 17
- 239000000843 powder Substances 0.000 claims abstract description 13
- 238000010612 desalination reaction Methods 0.000 claims abstract description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000000975 dye Substances 0.000 claims description 51
- 238000003756 stirring Methods 0.000 claims description 24
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 18
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 12
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 12
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 10
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 9
- 239000002253 acid Substances 0.000 claims description 8
- 235000003140 Panax quinquefolius Nutrition 0.000 claims description 7
- 240000005373 Panax quinquefolius Species 0.000 claims description 7
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 6
- 229960000583 acetic acid Drugs 0.000 claims description 6
- 239000012362 glacial acetic acid Substances 0.000 claims description 6
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 6
- 239000003960 organic solvent Substances 0.000 claims description 6
- KMUONIBRACKNSN-UHFFFAOYSA-N potassium dichromate Chemical compound [K+].[K+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O KMUONIBRACKNSN-UHFFFAOYSA-N 0.000 claims description 6
- 229940095064 tartrate Drugs 0.000 claims description 6
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 claims description 5
- 238000000746 purification Methods 0.000 claims description 5
- COBPKKZHLDDMTB-UHFFFAOYSA-N 2-[2-(2-butoxyethoxy)ethoxy]ethanol Chemical compound CCCCOCCOCCOCCO COBPKKZHLDDMTB-UHFFFAOYSA-N 0.000 claims description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 4
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 4
- WGYFACNYUJGZQO-UHFFFAOYSA-N aminomethanetriol Chemical compound NC(O)(O)O WGYFACNYUJGZQO-UHFFFAOYSA-N 0.000 claims description 4
- 229940028356 diethylene glycol monobutyl ether Drugs 0.000 claims description 4
- JCGNDDUYTRNOFT-UHFFFAOYSA-N oxolane-2,4-dione Chemical compound O=C1COC(=O)C1 JCGNDDUYTRNOFT-UHFFFAOYSA-N 0.000 claims description 4
- 229960004418 trolamine Drugs 0.000 claims description 4
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 3
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 claims description 3
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 3
- 229940051250 hexylene glycol Drugs 0.000 claims description 3
- 229920001451 polypropylene glycol Polymers 0.000 claims description 3
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 claims description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 2
- 239000013543 active substance Substances 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 2
- 235000011187 glycerol Nutrition 0.000 claims description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 2
- -1 polyoxyethylene Polymers 0.000 claims description 2
- 238000001816 cooling Methods 0.000 claims 3
- ZQWICJYATMSSSD-UHFFFAOYSA-M chembl2028584 Chemical compound [Na+].C1=CC=C2C(N=NC3=C4C=CC=CC4=CC=C3O)=C(O)C=C(S([O-])(=O)=O)C2=C1 ZQWICJYATMSSSD-UHFFFAOYSA-M 0.000 claims 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 abstract description 12
- 238000010438 heat treatment Methods 0.000 abstract description 11
- 238000007639 printing Methods 0.000 abstract description 8
- 238000000034 method Methods 0.000 abstract description 7
- 230000003287 optical effect Effects 0.000 abstract description 3
- 239000003899 bactericide agent Substances 0.000 abstract description 2
- 230000000844 anti-bacterial effect Effects 0.000 abstract 1
- 239000004094 surface-active agent Substances 0.000 abstract 1
- 239000000976 ink Substances 0.000 description 52
- 238000012360 testing method Methods 0.000 description 16
- 239000012528 membrane Substances 0.000 description 13
- 238000001728 nano-filtration Methods 0.000 description 11
- DPDMMXDBJGCCQC-UHFFFAOYSA-N [Na].[Cl] Chemical compound [Na].[Cl] DPDMMXDBJGCCQC-UHFFFAOYSA-N 0.000 description 8
- 238000009775 high-speed stirring Methods 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- 230000003068 static effect Effects 0.000 description 5
- 239000004743 Polypropylene Substances 0.000 description 4
- 239000006227 byproduct Substances 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 230000000149 penetrating effect Effects 0.000 description 4
- 238000000108 ultra-filtration Methods 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000009413 insulation Methods 0.000 description 3
- 230000004075 alteration Effects 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000004043 dyeing Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 2
- 230000001680 brushing effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000012790 confirmation Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 238000011158 quantitative evaluation Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
Abstract
The invention discloses an ink composition with a high-weather-resistance black dye for ink-jet printing. The composition is prepared by mixing following components in percentage by weight: 6-12 percent of polyhydroxy alcohol, 13-30 percent of solvents, 0.1-3 percent of surfactants, 0-0.5 percent of pH regulators, 0.1-0.3 percent of bactericides, 20-40 percent of mordant black dye paste and the balance of deionized water. The invention also provides a method for purifying the mordant black dye paste, which comprises the following steps of: mixing mordant black dye raw powder and deionized water based on a weight ratio of 1:9, heating, filtering, and performing desalination treatment to obtain the mordant black dye paste. The ink composition with the high-weather-resistance black dye for ink-jet printing, disclosed by the invention, has extremely high light fastness and ozone resistance, the printing quality is good, the optical density is high, the quality guarantee period is long, and a nozzle is not blocked.
Description
[technical field]
The present invention relates to the water-soluble dye composition for ink that spray ink Printing is used, particularly relate to a kind of ink composition for ink-jet printing with high-weatherability black dyes.
[background technology]
The dye ink that is used for ink-jet printer is the ink of molecular level CL, is composite solution completely.Be easy to by absorbed after the dye ink air brushing, it is printed on the smooth slick paper, and excellent to the radiation performance of light, color restoration capability is stronger, therefore obtains extensively with using.But because there is the protection of one layer of polymeric on dye ink surface unlike paint ink; the look material of dye ink is that individual molecule independently exists; under gaseous corrosions such as the irradiation of UV-light and ozone; molecule decomposes easily and destroys; cause color to change; cause and fade, make the application cycle of outdoor use shorten.
[summary of the invention]
The present invention is intended to solve the sun-resistant and anti-ozone problem of aqueous dye ink, and provide a kind of by to the purifying of media black dyes improving the light fastness and the ozone resistance of aqueous black dye ink, and do not stop up the ink composition for ink-jet printing with high-weatherability black dyes of shower nozzle.
The present invention also aims to provide a kind of purification process of media black dye paste.
For achieving the above object, the invention provides a kind of ink composition for ink-jet printing with high-weatherability black dyes, this composition for ink is mixed by following component by weight percentage:
Optimum ratio with ink composition for ink-jet printing of high-weatherability black dyes of the present invention is:
Polyhydroxy-alcohol is selected from glycerine, glycol ether, ethylene glycol, 1, one or more in 2-hexylene glycol, polyoxyethylene glycol, polypropylene glycol, the propylene glycol;
Solvent is selected from one or more in nitrogenous hydrophilic organic solvent, pure ether solvent, the high volatilization hydrophilic solvent, and the weight percent content of solvent in composition for ink is:
Nitrogenous hydrophilic organic solvent 5～12
Alcohol ether solvent 8～12
High volatilization hydrophilic solvent 0～6;
Nitrogenous hydrophilic organic solvent is selected from N-N-methyl-2-2-pyrrolidone N-, 1, one or more in 3-dimethyl-imidazolinone, 2-Pyrrolidone, the N,N-dimethylacetamide; The alcohol ether solvent is selected from a kind of in diethylene glycol monobutyl ether, triglycol monobutyl ether, the butyl glycol ether; High volatilization hydrophilic solvent is selected from a kind of in Virahol, the ethylene glycol ethyl ether;
Tensio-active agent is selected from worried 104, the worried TG that disappears of disappearing, it is worried 440 to disappear, it is worried 465 to disappear, a kind of in worried 485 disappears;
The pH regulator agent is selected from a kind of in diethanolamine, trolamine, the trihydroxy-aminomethane;
Sterilant is selected from a kind of in the shield GXL of government office in feudal China, bright Sheng D7, P 91 anticorrosion and bactericidal agents;
The Mordant Black dye paste is selected from a kind of in Mordant Black PV, medium black P 2 B, Mordant Black T or the acid black 172;
Surplus is a deionized water.
Contribution of the present invention is that it efficiently solves the sun-resistant and anti-ozone problem of dye ink.Owing to contain through the Mordant Black dye paste in the composition for ink of the present invention, this Mordant Black dye paste has good dyeing behavior, the dyeing circulation ratio is splendid, the tinctorial strength height, equalization is good, and high light fastness and ozone resistance are arranged, good with the image quality that composition for ink of the present invention is printed, the optical density (OD) height, long quality-guarantee period, and nonchoking nozzle.
[embodiment]
The following example is to further explanation of the present invention and explanation, and the present invention is not constituted any limitation.
Embodiment 1
1, the purifying of Mordant Black dye paste
Get 30 kilograms in the former powder of Mordant Black PV, join in the electrically heated stirring tank of the deionized water that fills 270 kilograms, heating while stirring, treat that temperature reaches 80 degree back restir 1 hour, after the whole dissolvings of the dyestuff powder that guarantees to add, carry out coarse filtration with 5 microns PP filter core again, carry out filtration treatment with ultra-filtration membrane and the nanofiltration membrane assembled filter that can remove sodium-chlor when temperature is lower than 60 again when spending, to remove the by product and the sodium-chlor of molecular weight at 30,000 above materials.Replenish deionized water in the process of purifying, guaranteeing the penetrating amount of film, and detect the specific conductivity of the liquid that leaches, specific conductivity stops to add deionized water when 20ms/cm is following, continues nanofiltration and the volume of mill base is controlled at about 200 liters, promptly reaches requirement; Stop purifying, barrelling.
Get 100 kilograms of Mordant Black PV mill bases behind the above-mentioned purifying, join volume and be in 200 liters the electrically heated stirring tank, heating while stirring, after treating that temperature reaches 80 degree, add 10.1 kilograms of potassium bichromate, heating while stirring, after being heated to 96 degree, add 0.345 mole Glacial acetic acid or tartrate, insulation reaction is after 3 hours under the condition of 96 to 99 degree, cool to 50 degree, with the sodium hydroxide adjust pH is about 7 to 9, and the concentration of carrying out desalination and controlling mill base with nanofiltration equipment gets high-weatherability black PV mill base 13～18% again, can stop purifying and barrelling, ink to be prepared this moment.
2, the ink composition for ink-jet printing with high-weatherability black dyes is prepared by following proportioning, referring to table 1.
Table 1
| Proportioning | Weight (WT%) |
| Triglycol | 6 |
| The N-N-methyl-2-2-pyrrolidone N- | 8 |
| The triglycol monobutyl ether | 8 |
| Virahol | 3 |
| Disappear worried 104 | 0.2 |
| High-weatherability ink-jet black PV mill base | 30 |
| The trihydroxy-aminomethane | 0.1 |
| The bright Sheng of sterilant D7 | 0.1 |
| Deionized water | 44.6 |
| Add up to | 100 |
3, testing method:
Press the composition for ink that example 1 proportioning becomes, even, static through high-speed stirring, use 1un, 0.45un after the filter membrane of 0.2un filters step by step, obtains having the ink composition for ink-jet printing of high-weatherability black dyes.It is printed on above ink composition on the printing paper of selling on the market with Epson stylus Photo T50 model ink-jet printer.
Embodiment 2:
1, the purifying of Mordant Black dye paste
Get 30 kilograms in the former powder of medium black P 2 B, join in the electrically heated stirring tank of the deionized water that fills 270 kilograms, heating while stirring, treat that temperature reaches 80 degree back restir 1 hour, after the whole dissolvings of the dyestuff powder that guarantees to add, carry out coarse filtration with 5 microns PP filter core again, carry out filtration treatment with ultra-filtration membrane and the nanofiltration membrane assembled filter that can remove sodium-chlor when temperature is lower than 60 again when spending, to remove the by product and the sodium-chlor of molecular weight at 30,000 above materials.Replenish deionized water in the process of purifying, guaranteeing the penetrating amount of film, and detect the specific conductivity of the liquid that leaches, specific conductivity stops to add deionized water when 20ms/cm is following, continues nanofiltration and the volume of mill base is controlled at about 200 liters, promptly reaches requirement; Stop purifying, barrelling.
Get 100 kilograms of medium black P 2 B mill bases behind the above-mentioned purifying, join volume and be in 200 liters the electrically heated stirring tank, heating while stirring, after treating that temperature reaches 80 degree, add 9.19 kilograms of potassium bichromate, heating while stirring, after being heated to 96 degree, add 0.314 mole Glacial acetic acid or tartrate, insulation reaction is after 3 hours under the condition of 96 to 99 degree, cool to 50 degree, with the sodium hydroxide adjust pH is about 7 to 9, and the concentration of carrying out desalination and controlling mill base with nanofiltration equipment gets high-weatherability ink-jet black P2B mill base 13～18% again, can stop purifying and barrelling, ink to be prepared this moment.
2, the ink composition for ink-jet printing with high-weatherability black dyes is prepared by following proportioning, referring to table 2.
Table 2
| Proportioning | Weight (WT%) |
| Propylene glycol | 8 |
| 1, the 3-dimethyl-imidazolinone | 8 |
| Diethylene glycol monobutyl ether | 12 |
| Ethylene glycol ethyl ether | 3 |
| Disappear worried 465 | 1 |
| High-weatherability ink-jet black P2B mill base | 20 |
| Trolamine | 0.3 |
| The bright Sheng of sterilant P91 | 0.3 |
| Deionized water | 47.4 |
| Add up to | 100 |
3, testing method:
Press the composition for ink that example 2 proportionings become, even, static through high-speed stirring, use 1un, 0.45un after the filter membrane of 0.2un filters step by step, obtains having the ink composition for ink-jet printing of high-weatherability black dyes.It is printed on above ink composition on the printing paper of selling on the market with Epson stylus Photo T50 model ink-jet printer.
Embodiment 3
1, the purifying of Mordant Black dye paste
Get 30 kilograms in the former powder of Mordant Black T, join in the electrically heated stirring tank of the deionized water that fills 270 kilograms, heating while stirring, treat that temperature reaches 80 degree back restir 1 hour, after the whole dissolvings of the dyestuff powder that guarantees to add, carry out coarse filtration with 5 microns PP filter core again, carry out filtration treatment with ultra-filtration membrane and the nanofiltration membrane assembled filter that can remove sodium-chlor when temperature is lower than 60 again when spending, to remove the by product and the sodium-chlor of molecular weight at 30,000 above materials.Replenish deionized water in the process of purifying, guaranteeing the penetrating amount of film, and detect the specific conductivity of the liquid that leaches, specific conductivity stops to add deionized water when 20ms/cm is following, continues nanofiltration and the volume of mill base is controlled at about 200 liters, promptly reaches requirement; Stop purifying, barrelling.
Get 100 kilograms of Mordant Black T mill bases behind the above-mentioned purifying, join volume and be in 200 liters the electrically heated stirring tank, heating while stirring, after treating that temperature reaches 80 degree, add 8.55 kilograms of potassium bichromate, heating while stirring, after being heated to 96 degree, add 0.292 mole Glacial acetic acid or tartrate, insulation reaction is after 3 hours under the condition of 96 to 99 degree, cool to 50 degree, with the sodium hydroxide adjust pH is about 7 to 9, and the concentration of carrying out desalination and controlling mill base with nanofiltration equipment gets the black T mill base of high-weatherability ink-jet black 13～18% again, can stop purifying and barrelling, ink to be prepared this moment.
2, the ink composition for ink-jet printing with high-weatherability black dyes is prepared by following proportioning, referring to table 3.
| Proportioning | Weight (WT%) |
| Polypropylene glycol | 6 |
| 2-Pyrrolidone | 5 |
| In the butyl glycol ether | 8 |
| Disappear worried 440 | 0.3 |
| High-weatherability ink-jet black is deceived the T mill base | 40 |
| Diethanolamine | 0.1 |
| The shield GXL of sterilant government office in feudal China | 0.1 |
| Deionized water | 40.5 |
| Add up to | 100 |
3, testing method:
Press the composition for ink that example 3 proportionings become, even, static through high-speed stirring, use 1un, 0.45un after the filter membrane of 0.2un filters step by step, obtains having the ink composition for ink-jet printing of high-weatherability black dyes.It is printed on above ink composition on the printing paper of selling on the market with Epson stylus Photo T50 model ink-jet printer.
Embodiment 4
1, the purifying of Mordant Black dye paste
Get 30 kilograms in the former powder of acid black 172, join in the electrically heated stirring tank of the deionized water that fills 270 kilograms, heating while stirring, treat that temperature reaches 80 degree back restir 1 hour, after the whole dissolvings of the dyestuff powder that guarantees to add, carry out coarse filtration with 5 microns PP filter core again, carry out filtration treatment with ultra-filtration membrane and the nanofiltration membrane assembled filter that can remove sodium-chlor when temperature is lower than 60 again when spending, to remove the by product and the sodium-chlor of molecular weight at 30,000 above materials.In the process of purifying, replenish deionized water, guaranteeing the penetrating amount of film, and detect the specific conductivity of the liquid that leaches, specific conductivity is when 20ms/cm is following, stop to add deionized water, continue nanofiltration and the volume of mill base is controlled at about 200 liters, concentration is controlled at 13～18% and promptly reaches requirement; Get ink-jet black 172 mill bases, can stop purifying and barrelling, ink to be prepared this moment.
2, the ink composition for ink-jet printing with high-weatherability black dyes is prepared by following proportioning, referring to table 4.
Table 4
| Proportioning | Weight (WT%) |
| 1, the 2-hexylene glycol | 12 |
| N,N-dimethylacetamide | 5 |
| Diethylene glycol monobutyl ether | 12 |
| Ethylene glycol ethyl ether | 3 |
| Worried TG disappears | 0.5 |
| Purified back acid black 172 mill base | 22 |
| Trolamine | 0.1 |
| The bright Sheng of sterilant D7 | 0.3 |
| Deionized water | 45.1 |
| Add up to | 100 |
3, testing method:
Press the composition for ink that example 4 proportionings become, even, static through high-speed stirring, use 1un, 0.45un after the filter membrane of 0.2un filters step by step, obtains having the ink composition for ink-jet printing of high-weatherability black dyes.It is printed on above ink composition on the printing paper of selling on the market with Epson stylus Photo T50 model ink-jet printer.
Embodiment 5
1, the ink composition for ink-jet printing with high-weatherability black dyes is prepared by following proportioning, referring to table 5.
Table 5
| Proportioning | Weight (WT%) |
| Triglycol | 6 |
| The N-N-methyl-2-2-pyrrolidone N- | 12 |
| The triglycol monobutyl ether | 8 |
| Ethylene glycol ethyl ether | 1 |
| Disappear worried 485 | 1 |
| Bright Sheng black SP mill base | 30 |
| The trihydroxy-aminomethane | 0.3 |
| The bright Sheng of sterilant P91 | 0.1 |
| Deionized water | 41.6 |
| Add up to | 100 |
2, testing method:
Press the composition for ink that example 5 proportionings become, even, static through high-speed stirring, use 1un, 0.45un after the filter membrane of 0.2un filters step by step, obtains having the ink composition for ink-jet printing of high-weatherability black dyes.It is printed on above ink composition on the printing paper of selling on the market with Epson stylus Photo T50 model ink-jet printer.
Example 1 is deposited through the high temperature freezing and 60 one weeks of degree in subzero 24 one weeks of degree to the ink of example 5, stable performance, the injection print cartridge can clean and be printed to China ink continuously to the greatest extent, can satisfy the requirement of ink-jet after the selected high-weatherability black dyes of confirmation the present invention is purified.
The weathering resistance test:
Cause that the weathering resistance reduction mainly is the ozone in daylight middle-ultraviolet lamp and the atmosphere, has proposed easy light fastness testing method and ozone proof testing method in view of the above.Progressively improve test process through repetition test.Utilize the principle of aberration that this method has been appended quantitative evaluation, set up contact between aberration and light fastness rank and the anti-ozone rank by analysis, can extrapolate the rank of light fastness, anti-ozone rank, simple and fast by rate of fall-off or value of chromatism Δ E.
With the colour density of optics scenograph Eye-one test case 1, example 2, example 3, example 4, example 5 printing color lumps, under the UV lamp, shone 3 hours then, in its colour density of test, calculate the colour density rate of fall-off of color lump before and after the UV light irradiation.The colour density rate of fall-off is big more, shows that light permanency is poor more.On the contrary, the colour density rate of fall-off is low more, and light permanency is good more.
Print the colour density of color lump with optics scenograph Eye-one test case 1, example 2, example 3, example 4, example 5, under ozone environment (ozone disinfection cabinet) 3 hours then, in its colour density of test, calculate the colour density rate of fall-off of color lump before and after ozone disinfection cabinet is deposited.The colour density rate of fall-off is big more, shows that anti-ozone is poor more.On the contrary, the colour density rate of fall-off is low more, and anti-ozone is good more.
The sun-proof detailed data is as follows:
Table 1
Anti-ozone detailed data is as follows:
Table 2
Find from above test result, by example 1, example 2, example 3 good light fastness and ozone resistance are arranged all, the rate of fall-off of example 5 is bigger, light fastness and ozone resistance are relatively poor, 5 the contrast from example 1 to example, explanation is fine through the ink sun-proof and the anti-ozone of the preparation of the dye paste behind the purifying, and ink (example 5) sun-proof and the anti-ozone of the bright Sheng black SP mill base preparation that sell the market are very poor.In the delta data of table 1 and table 2 optical density (OD), confirm that example 1 has reached the effect of black dyes ink weather resistance of the presently claimed invention to example 3.Test data from example 4, acid black 172 is because be metallized dye, so it is better on the sun-proof performance, but the common ink-jet dye with present usefulness on ozone resistance does not have too many lifting, has only as example 1 and is undertaken being configured to sun-proof and the anti-ozone problem that ink could solve the aqueous black ink again behind the purifying by selecting the media black dyes to example 3.
More than embodiments of the invention are had been described in detail, but described content only is preferred embodiment of the present invention, can not be considered to be used to limit practical range of the present invention.All equalizations of doing according to the present patent application scope change and (the metallized dye acid black 172 being used for ink for ink-jet print such as comprising) such as improvement, all should still belong within the patent covering scope of the present invention.
Claims (10)
1. the ink composition for ink-jet printing with high-weatherability black dyes is characterized in that, this composition for ink is mixed by following component by weight percentage:
2. composition for ink according to claim 1 is characterized in that this composition for ink is mixed by following component by weight percentage:
3. composition for ink as claimed in claim 1 or 2 is characterized in that described polyhydroxy-alcohol is selected from glycerine, glycol ether, ethylene glycol, 1, one or more in 2-hexylene glycol, polyoxyethylene glycol, polypropylene glycol, the propylene glycol; Described tensio-active agent is selected from one or several in the worry 104 that disappears, the worried TG that disappears, the worry 440 that disappears, the worry 465 that disappears, the worry 485 that disappears; It is in diethanolamine, trolamine, the trihydroxy-aminomethane one or several that described pH regulator agent is selected from; It is in the shield GXL of government office in feudal China, bright Sheng D7, P 91 sterilant one or several that described sterilant is selected from.
4. composition for ink as claimed in claim 1 or 2, it is characterized in that, described solvent is selected from one or more in nitrogenous hydrophilic organic solvent, pure ether solvent, the high volatilization hydrophilic solvent, and the weight percent content of described solvent in composition for ink is:
Nitrogenous hydrophilic organic solvent 5～12
Alcohol ether solvent 8～12
High volatilization hydrophilic solvent 0～6.
5. as composition for ink as described in the claim 4, it is characterized in that described nitrogenous hydrophilic organic solvent is selected from N-N-methyl-2-2-pyrrolidone N-, 1, one or more in 3-dimethyl-imidazolinone, 2-Pyrrolidone, the N,N-dimethylacetamide; Described pure ether solvent is selected from a kind of in diethylene glycol monobutyl ether, triglycol monobutyl ether, the butyl glycol ether; Described high volatilization hydrophilic solvent is selected from a kind of in Virahol, the ethylene glycol ethyl ether.
6. composition for ink as claimed in claim 1 or 2 is characterized in that, described Mordant Black dye paste is selected from a kind of in Mordant Black PV, medium black P 2 B, Mordant Black T or the acid black 172 dye paste.
7. as composition for ink as described in the claim 6, it is characterized in that the purification process of described Mordant Black PV dye paste is as follows:
A, to get part by weight be that 1: 9 former powder of Mordant Black PV and deionized water joins in the electrically heated stirring tank, heated and stirred, temperature reach 80～90 degree backs and stirred 1～2 hour, carry out lowering the temperature after the coarse filtration, cool to 50～70 and carry out filtration treatment when spending, Mordant Black PV mill base;
B, get Mordant Black PV mill base, join in the electrically heated stirring tank, heated and stirred, temperature reaches 80～90 degree, adds potassium bichromate again, is heated to 96～99 degree, add Glacial acetic acid or tartrate then, and cooling to 40～60 degree after being incubated 3～4 hours, desalination is handled and the concentration of control mill base with carrying out behind the sodium hydroxide adjust pH, obtains high-weatherability ink-jet black PV mill base.
8. as composition for ink as described in the claim 6, it is characterized in that the purification process of described medium black P 2 B dyestuff mill base is as follows:
A, to get part by weight be that 1: 9 former powder of medium black P 2 B and deionized water joins in the electrically heated stirring tank, heated and stirred, temperature reach 80～90 degree backs and stirred 1～2 hour, carry out lowering the temperature after the coarse filtration, cool to 50～70 and carry out filtration treatment when spending, the medium black P 2 B mill base;
B, get the medium black P 2 B mill base, join in the electrically heated stirring tank, heated and stirred, temperature reaches 80～90 degree, adds potassium bichromate again, is heated to 96～99 degree, add Glacial acetic acid or tartrate then, and cooling to 40～60 degree after being incubated 3～4 hours, desalination is handled and the concentration of control mill base with carrying out behind the sodium hydroxide adjust pH, obtains high-weatherability ink-jet black P2B mill base.
9. as composition for ink as described in the claim 6, it is characterized in that the purification process of described Mordant Black T dye paste is as follows:
A, to get part by weight be that 1: 9 former powder of Mordant Black T and deionized water joins in the electrically heated stirring tank, heated and stirred, temperature reach 80～90 degree backs and stirred 1～2 hour, carry out lowering the temperature after the coarse filtration, cool to 50～70 and carry out filtration treatment when spending, Mordant Black T mill base;
B, get Mordant Black T mill base, join in the electrically heated stirring tank, heated and stirred, temperature reaches 80～90 degree, adds potassium bichromate again, is heated to 96～99 degree, add Glacial acetic acid or tartrate then, and cooling to 40～60 degree after being incubated 3～4 hours, desalination is handled and the concentration of control mill base with carrying out behind the sodium hydroxide adjust pH, obtains the black T mill base of high-weatherability ink-jet black.
10. as composition for ink as described in the claim 6, it is characterized in that the purification process of described Mordant Black 17 2 dye pastes is as follows:
Former powder of acid black 172 and the deionized water getting part by weight and be 1: 9 join in the electrically heated stirring tank, heated and stirred, temperature reaches 80～90 degree backs and stirred 1～2 hour, carry out lowering the temperature after the coarse filtration, cool to 50～70 and carry out filtration treatment when spending, concentration is controlled at 13～18%, gets the acid black 172 dye paste.
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| CN 201110103188 CN102167927B (en) | 2011-04-25 | 2011-04-25 | Ink composition with high-weather-resistance black dye for ink-jet printing |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102993829A (en) * | 2012-11-29 | 2013-03-27 | 陈小康 | Ink for black ink box of ink-jet printer |
| CN107338658A (en) * | 2017-06-08 | 2017-11-10 | 恒升化工有限公司 | A kind of liquid metallized acid dye composition and preparation method thereof |
| CN109651885A (en) * | 2019-01-16 | 2019-04-19 | 深圳市墨库图文技术有限公司 | A kind of gray dyes ink and preparation method thereof that ozone-resistant is sun-resistant |
| CN115960493A (en) * | 2022-12-15 | 2023-04-14 | 郑州鸿盛数码科技股份有限公司 | Weather-resistant cyan ink-jet ink |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH11315220A (en) * | 1998-05-07 | 1999-11-16 | Minolta Co Ltd | Recording fluid |
| US6323257B1 (en) * | 1999-04-23 | 2001-11-27 | Hewlett-Packard Company | Ink-jet ink compositions containing reactive macromolecular chromophores for digital and textile printing |
| CN1393493A (en) * | 2001-07-02 | 2003-01-29 | 明碁电通股份有限公司 | Light-tolerant water-proof carmine ink for ink jet |
| CN102020889A (en) * | 2011-01-14 | 2011-04-20 | 深圳市墨库图文技术有限公司 | Anti-sunburn red inkjet ink combination for spray ink printing |
-
2011
- 2011-04-25 CN CN 201110103188 patent/CN102167927B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH11315220A (en) * | 1998-05-07 | 1999-11-16 | Minolta Co Ltd | Recording fluid |
| US6323257B1 (en) * | 1999-04-23 | 2001-11-27 | Hewlett-Packard Company | Ink-jet ink compositions containing reactive macromolecular chromophores for digital and textile printing |
| CN1393493A (en) * | 2001-07-02 | 2003-01-29 | 明碁电通股份有限公司 | Light-tolerant water-proof carmine ink for ink jet |
| CN102020889A (en) * | 2011-01-14 | 2011-04-20 | 深圳市墨库图文技术有限公司 | Anti-sunburn red inkjet ink combination for spray ink printing |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102993829A (en) * | 2012-11-29 | 2013-03-27 | 陈小康 | Ink for black ink box of ink-jet printer |
| CN107338658A (en) * | 2017-06-08 | 2017-11-10 | 恒升化工有限公司 | A kind of liquid metallized acid dye composition and preparation method thereof |
| CN109651885A (en) * | 2019-01-16 | 2019-04-19 | 深圳市墨库图文技术有限公司 | A kind of gray dyes ink and preparation method thereof that ozone-resistant is sun-resistant |
| CN115960493A (en) * | 2022-12-15 | 2023-04-14 | 郑州鸿盛数码科技股份有限公司 | Weather-resistant cyan ink-jet ink |
| CN115960493B (en) * | 2022-12-15 | 2023-11-10 | 郑州鸿盛数码科技股份有限公司 | Weather-resistant cyan ink-jet ink |
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|---|---|
| CN102167927B (en) | 2013-07-31 |
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