CN102167556A - Concrete material with high resistance to stray current, chloride ions and carbonization - Google Patents

Concrete material with high resistance to stray current, chloride ions and carbonization Download PDF

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Publication number
CN102167556A
CN102167556A CN2011100247246A CN201110024724A CN102167556A CN 102167556 A CN102167556 A CN 102167556A CN 2011100247246 A CN2011100247246 A CN 2011100247246A CN 201110024724 A CN201110024724 A CN 201110024724A CN 102167556 A CN102167556 A CN 102167556A
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China
Prior art keywords
concrete
carbonization
stray current
cement
admixture
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CN2011100247246A
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CN102167556B (en
Inventor
蒋林华
朱乔
徐金霞
蒋俣
储洪强
张研
徐怡
濮琦
杨虎
宋子健
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Hohai University HHU
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Hohai University HHU
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention relates to a concrete material with high resistance to stray current, chloride ions and carbonization. The concrete material is characterized by comprising the following components in each cubic meter of concrete: 120 to 200kg of cement, 60 to 90kg of fly ash, 120 to 180kg of mineral powder, 1.2 to 4.0kg of mica powder, 740 to 820kg of fine aggregate, 1,040 to 1,120kg of coarse aggregate, 3.9 to 4.5kg of additive and 140 to 180kg of water. A preparation method comprises the following steps of: mixing and stirring the fine aggregate and the coarse aggregate uniformly; adding the cement, the fly ash, the mineral powder and the mica powder, and stirring uniformly; and adding the additive and the water, and stirring uniformly to obtain the concrete material with high resistance to stray current, chloride ion corrosion and carbonization. The production cost is low.

Description

The concrete material of a kind of high anti-stray current, chlorion and carbonization
Technical field
The invention belongs to civil engineering material technical field, be specifically related to the concrete material of a kind of high anti-stray current, chlorion and carbonization.
Background technology
Along with China's big and medium-sized cities traffic pressure increases day by day, the track traffic of quick environmental protection becomes one of optimal vehicles in city day by day, but it faces following problem: 1, rail tends to reveal stray current, and reinforcing bar in the concrete structure is produced serious corrosive nature; 2, the project subject structure is generally darker apart from the face of land, and it is also comparatively serious corroded by chlorion; 3, the underground environment carbon dioxide content is higher, and is serious to the graphitic corrosion of engineering structure.In a word, the concrete structure of railway traffic engineering is in the corrosive environment of stray current, chlorion and carbonization coexistence.
In order to tackle above environment, the concrete material that is applied to railway traffic engineering generally need possess the performance that is different from normal concrete, generally be on the basis of normal concrete material, with cement is major ingredient, add certain subsidiary material again, the engineering that for example has is singly mixed mineral admixture (flyash or breeze), flyash can be in hydration reaction later stage and the effect of hydrated cementitious product, form a large amount of filler particles, make internal structure constantly closely knit, thereby effectively raise concrete impermeability, performances such as resistivity, but other is to concrete strength, particularly the early strength influence is bigger, especially under the volume condition with higher, influences bigger.Equally, along with the increase of contents of ground slag, early age strength of concrete obviously reduces, and volume is high more, and it is obvious more to descend.So, consider the concrete strength index, it is generally acknowledged that the mineral admixture volume generally must not surpass 30% of binder total amount.The patent of invention that number of patent application 200810046967.8, name are called a kind of high-impedance high-impermeability concrete material and preparation method thereof proposes to add the insulated type polymkeric substance again on the basis of singly mixing mineral admixture, because the insulativity of polymkeric substance, improved concrete resistivity indirectly, but this measure meeting increases production cost greatly.
Summary of the invention
In order to overcome the deficiencies in the prior art, the object of the present invention is to provide a kind of concrete material that is applicable to the high anti-stray current corrosive power of having of railway traffic engineering, high resisting chloride ion penetration erosional competency and high anti-graphitic corrosion ability.
In order to realize above-mentioned technical purpose, the present invention is achieved by the following technical solutions:
The concrete material of a kind of high anti-stray current, chlorion and carbonization is characterized in that each components contents is as follows in the component that comprises and the every cubic meter of concrete: cement 120~200Kg, flyash 60~90Kg, breeze 120~180Kg, mica powder 1.2~4.0Kg, fine aggregate 740~820Kg, coarse aggregate 1040~1120Kg, admixture 3.9~4.5Kg, water 140~180Kg.
The concrete material of aforesaid high anti-stray current, chlorion and carbonization is characterized in that described cement is P I type, P II type silicate cement; Described flyash is I level, II level flyash; Described breeze is S95, S105 level ground blast furnace slag.
Described mica powder is a white mica powder, and granularity is 325 orders~1250 orders.
Described fine aggregate is that fineness modulus is 2.3~2.8 river sand.
Described coarse aggregate is that particle diameter is the continuous grading rubble of 5~40mm.
Described admixture is a polycarboxylate high performance water-reducing agent.
The preparation method of the concrete material of a kind of high anti-stray current, chlorion and carbonization, it is characterized in that fine aggregate and coarse aggregate mixing and stirring, add cement, flyash, breeze and mica powder again, stir, add admixture and water again, stir, obtain the concrete of high anti-stray current, chlorion and carbonization.
The cement consumption that the present invention adopts is a binder total amount 30%~50%, breeze and coal ash powder binder total amount 50%~70%, and behind the interpolation mica powder, obtain the concrete material that intensity, anti-stray current ability, resisting chloride ion penetration erosional competency and anti-carbonization ability index all meet railway traffic engineering mechanical property and endurance quality requirement, and material cost reduces.Particularly, the concrete strength of the present invention's preparation is higher than design strength 5%~10%; Concrete anti-stray current ability is 4.2~5.1 times of normal concrete, is concrete 1.4~2.3 times of admixture 30% mineral admixture (singly mixing or two fly ash and breeze); The chlorion average diffusion degree of depth is 0.39~0.56 times of normal concrete, is concrete 0.62~0.76 times of admixture 30% mineral admixture; Each, carbonation depth all was lower than the concrete of normal concrete or single fly ash and breeze in the length of time.
Embodiment
Embodiment 1
Measure following component by the usefulness of every cubic meter of concrete: cement 152 kg, flyash 76 kg, breeze 152 kg, mica powder 2.3 kg, fine aggregate 781 kg, coarse aggregate 1079 kg, admixture 4.175 kg, water 160 kg.Cement is the peaceful sheep board P II 42.5R silicate cement of gold; Flyash is II level flyash; Breeze is a S95 level ground blast furnace slag; Mica powder is 500 purpose white mica powders; Fine aggregate is that fineness modulus is 2.6 river sand; Coarse aggregate is that particle diameter is the continuous grading rubble of 5~40mm; Admixture is JM-PCA(I) the type high-performance water reducing agent.
Fine aggregate and coarse aggregate are mixed together stirring 1~2 minute, add cement, flyash, breeze and white mica powder again, continue to stir 1~2 minute, add admixture and water again, continue to stir 2~5 minutes, obtain the concrete of a kind of high anti-stray current, chlorion and carbonization.
Cement consumption is a binder total amount 40% in the present embodiment, breeze and coal ash powder binder total amount 60%, and the concrete of high anti-stray current, chlorion and the carbonization of preparation, intensity is higher than the design strength 8% of C30; Concrete anti-stray current ability is 4.7 times of normal concrete, is concrete 1.9 times of admixture 30% mineral admixture (singly mixing or two fly ash and breeze); The chlorion average diffusion degree of depth is 0.42 times of normal concrete, is concrete 0.69 times of admixture 30% mineral admixture; Each, carbonation depth all was lower than the concrete of normal concrete or single fly ash and breeze in the length of time.
Embodiment 2
Measure following component by the usefulness of every cubic meter of concrete: cement 120 kg, flyash 90 kg, breeze 180 kg, mica powder 4.0 kg, fine aggregate 770kg, coarse aggregate 1090kg, admixture 3.9 kg, water 170 kg.
Cement is peaceful sheep board P I 42.5 silicate cements of gold; Flyash is I level flyash; Breeze is a S105 level ground blast furnace slag; Mica powder is 1000 purpose white mica powders; Fine aggregate is that fineness modulus is 2.7 river sand; Coarse aggregate is that particle diameter is the continuous grading rubble of 5~40mm; Admixture is JM-PCA(I) the type high-performance water reducing agent.The preparation method is with embodiment 1.
Cement consumption is a binder total amount 30% in the present embodiment, breeze and coal ash powder binder total amount 70%, and the concrete of high anti-stray current, chlorion and the carbonization of preparation, intensity is higher than the design strength 5% of C30; Concrete anti-stray current ability is 5.1 times of normal concrete, is concrete 2.2 times of admixture 30% mineral admixture (singly mixing or two fly ash and breeze); The chlorion average diffusion degree of depth is 0.39 times of normal concrete, is concrete 0.65 times of admixture 30% mineral admixture; Each, carbonation depth all was lower than the concrete of normal concrete or single fly ash and breeze in the length of time.
Embodiment 3,
Measure following component by the usefulness of every cubic meter of concrete: cement 200 kg, flyash 70kg, breeze 120 kg, mica powder 1.2 kg, fine aggregate 790 kg, coarse aggregate 1060 kg, admixture 4.4 kg, water 150 kg.
Cement is the peaceful sheep board P II 42.5R silicate cement of gold; Flyash is II level flyash; Breeze is a S105 level ground blast furnace slag; Mica powder is 325 purpose white mica powders; Fine aggregate is that fineness modulus is 2.4 river sand; Coarse aggregate is that particle diameter is the continuous grading rubble of 5~40mm; Admixture is a HLC-IX type high-performance water reducing agent.The preparation method is with embodiment 1.
Cement consumption is a binder total amount 50% in the present embodiment, breeze and coal ash powder binder total amount 50%, and the concrete of high anti-stray current, chlorion and the carbonization of preparation, intensity is higher than the design strength 10% of C30; Concrete anti-stray current ability is 4.3 times of normal concrete, is concrete 1.5 times of admixture 30% mineral admixture (singly mixing or two fly ash and breeze); The chlorion average diffusion degree of depth is 0.52 times of normal concrete, is concrete 0.73 times of admixture 30% mineral admixture; Each, carbonation depth all was lower than the concrete of normal concrete or single fly ash and breeze in the length of time.
Embodiment 4
Measure following component by the usefulness of every cubic meter of concrete: cement 140 kg, flyash: 80kg, breeze 160kg, mica powder 2.5 kg, fine aggregate 740 kg, coarse aggregate 1120kg, admixture 4.0 kg, water 180 kg.
Embodiment 5
Measure following component by the usefulness of every cubic meter of concrete: cement 180 kg, flyash 60kg, breeze 135kg, mica powder 3.0 kg, fine aggregate 820 kg, coarse aggregate 1040kg, admixture 4.5kg, water 140 kg.
Embodiment 4,5 is except the content of record, and all the other are all identical with embodiment 1.
Above-mentioned embodiment does not limit technical scheme of the present invention in any form, and the technical scheme that mode obtained that every employing is equal to replacement or equivalent transformation all drops on protection scope of the present invention.

Claims (2)

1. the concrete material of a high anti-stray current, chlorion and carbonization is characterized in that each components contents is as follows in the component that comprises and the every cubic meter of concrete: cement 120~200Kg, flyash 60~90Kg, breeze 120~180Kg, mica powder 1.2~4.0Kg, fine aggregate 740~820Kg, coarse aggregate 1040~1120Kg, admixture 3.9~4.5Kg, water 140~180Kg.
2. the concrete material of high anti-stray current according to claim 1, chlorion and carbonization is characterized in that described cement is P I type, P II type silicate cement; Described flyash is I level, II level flyash; Described breeze is S95, S105 level ground blast furnace slag; Described mica powder is a white mica powder, and granularity is 325 orders~1250 orders; Described fine aggregate is that fineness modulus is 2.3~2.8 river sand; Described coarse aggregate is that particle diameter is the continuous grading rubble of 5~40mm; Described admixture is a polycarboxylate high performance water-reducing agent.
CN2011100247246A 2011-01-24 2011-01-24 Concrete material with high resistance to stray current, chloride ions and carbonization Expired - Fee Related CN102167556B (en)

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2474547C1 (en) * 2012-01-25 2013-02-10 Юлия Алексеевна Щепочкина Raw mix for natural stone imitation
CN102976694A (en) * 2012-12-11 2013-03-20 张庆彬 Anti-corrosion concrete
RU2479531C1 (en) * 2012-01-25 2013-04-20 Юлия Алексеевна Щепочкина Crude mixture for imitation of natural stone
RU2506239C1 (en) * 2012-10-08 2014-02-10 Юлия Алексеевна Щепочкина Raw material mixture for manufacturing fine-grained concrete
RU2508263C1 (en) * 2012-11-06 2014-02-27 Юлия Алексеевна Щепочкина Crude mixture for imitation of natural stone
RU2613065C1 (en) * 2016-02-29 2017-03-15 Юлия Алексеевна Щепочкина Raw material mixture for manufacturing fine-grained concrete
CN109577108A (en) * 2019-01-09 2019-04-05 扬州大学 A kind of track plates of anti-stray current and preparation method thereof

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109574593A (en) * 2019-01-08 2019-04-05 大连理工大学 A kind of concrete material of anti-stray current and preparation method thereof

Citations (2)

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CN101445339A (en) * 2008-12-25 2009-06-03 戴春燕 Debris concrete
CN101445351A (en) * 2008-12-25 2009-06-03 戴春燕 Marine C50 pumpcrete

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101445339A (en) * 2008-12-25 2009-06-03 戴春燕 Debris concrete
CN101445351A (en) * 2008-12-25 2009-06-03 戴春燕 Marine C50 pumpcrete

Non-Patent Citations (1)

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Title
《淮阴工学院学报》 20090228 张杰等 《耐久性混凝土的组分优化及配合比设计研究》 第82-88页 1-2 第18卷, 第1期 *

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2474547C1 (en) * 2012-01-25 2013-02-10 Юлия Алексеевна Щепочкина Raw mix for natural stone imitation
RU2479531C1 (en) * 2012-01-25 2013-04-20 Юлия Алексеевна Щепочкина Crude mixture for imitation of natural stone
RU2506239C1 (en) * 2012-10-08 2014-02-10 Юлия Алексеевна Щепочкина Raw material mixture for manufacturing fine-grained concrete
RU2508263C1 (en) * 2012-11-06 2014-02-27 Юлия Алексеевна Щепочкина Crude mixture for imitation of natural stone
CN102976694A (en) * 2012-12-11 2013-03-20 张庆彬 Anti-corrosion concrete
CN102976694B (en) * 2012-12-11 2014-04-16 张庆彬 Anti-corrosion concrete
RU2613065C1 (en) * 2016-02-29 2017-03-15 Юлия Алексеевна Щепочкина Raw material mixture for manufacturing fine-grained concrete
CN109577108A (en) * 2019-01-09 2019-04-05 扬州大学 A kind of track plates of anti-stray current and preparation method thereof

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