CN102154040A - Biochemical crude oil - Google Patents
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- CN102154040A CN102154040A CN2011100691256A CN201110069125A CN102154040A CN 102154040 A CN102154040 A CN 102154040A CN 2011100691256 A CN2011100691256 A CN 2011100691256A CN 201110069125 A CN201110069125 A CN 201110069125A CN 102154040 A CN102154040 A CN 102154040A
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- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
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Abstract
The invention discloses biochemical crude oil which mainly consists of biological oil and petroleum and/or alcohol ether fuel. In the invention, fossil petroleum is subversively replaced with a biomass from the raw material phase, so that an economic structure which does not depend on the fossil petroleum is established, and by ecological restoration of saline alkali and mineral waste lands, the greening of the heavy chemical industry is promoted simultaneously when biorefinery is developed; the biochemical crude oil is prepared by the existing petroleum production, refining and sale system or equipment of oil refining enterprises, chemical plants, clean fuel enterprises and the like; and the biochemical crude oil can be pumped and stored by a pump and is conveyed by a pipeline, a road, a railway and an oil tanker. Therefore, the original eliminated unenlightened or polluted productivity is converted into the productivity of a green oil field, a low sulphur oil refinery and a greening industry; the biochemical crude oil not only has little investment and low cost and is rapid to start; in the developing process, the environment is protected, the original huge productivity is prevented from changing into waste properties so as to promote the forward development of the emerging industry and the low-carbon economy.
Description
Technical field
The present invention relates to a kind of cleaning substitute energy.
Background technology
Oil, coal and biomass are the main energy sources in the world.At present, China is from middle-east, the north African Imported oil reached 1.3 hundred million tons, and externally interdependency surpasses 56%, and more than 8,000 ten thousand tons of U.S.'s imports.From economic law, decision that country of 21 century key that can go before is that can it set up one and have the economic structure that does not rely on or rely on Nonrenewable energy resources less.Along with polluting and non-renewable problem increasingly serious, change the Economic development mode, it is very urgent that substitute energy is cleaned in development.Country promotes economy energetically and enters innovation driving, the interior development track that increases of giving birth to now.And " innovation drives " that do not rely on fossil energy will be done from the source.World's bioenergy all is to carry out alternate from the finished product stage at present, such as alcohol fuel, biofuel.If carry out subversive technological innovation, just substitute from feed stage (crude oil), allow " biorefinery " raw material be compounded among the Green Development process of coal-based chemistry, petroleum base chemistry; In the development biorefinery, promote the greenization of oil, coal heavy chemical industry; Make the backwardness of eliminating originally or pollute production capacity and be transformed into " green oil field " " low-sulfur refinery " and " greenization factory ".Not only less investment, cost low, go up detective, and in the process of exploitation, protect environment, also avoided original huge production capacity to become " useless assets ".Promote the spanning development of strategic new industry and low-carbon economy.
Bio oil is to utilize the biofuel of a kind of similar crude oil that various agriculture and forestry organic waste materials (as stalk, sawdust, bagasse, rice chaff etc.) are prepared from.Cause is similar with oil, is known as " biomass crude oil ", is different from the biofuel and the alcohol fuel that are mixed and use in the processed oil stage.Biofuel is the important channel that substitutes oil and realize the heavy chemical industry greenization.Because the same characteristics with ecology " zero " discharging with biofuel and ethanol of bio oil, a kind of green substitute that is processed to heavy oil/diesel oil is applied to Thermal Equipments such as boiler, kiln so that heating or generating.Because the fluctuation of crude oil price produces great effect with the counterweight chemical industry, especially refine oil leading type enterprise and be the chemical enterprise of raw material with crude oil, raising up of oil price can directly enter cost.If therefore we change the chemical constitution of bio oil, at transformed refinery, complete energy of bio oil and crude oil are mixed, and join together to process.Again through refining, just can obtain sulphur, oxygen, motor spirit and diesel oil that the nitrogen equal size is low, as petrol engine and use for diesel engine clean fuel; Through deep processing, can also obtain the chemical and the industrial chemicals of high added value.The benefit of this subversive technological innovation is:
---less investment.One of China's Petroleum Industry important feature is that the catalyzed cracking processing ability is far longer than catalytic reforming and shortening working ability, and the limited in one's ability of premium-type gasoline and diesel component is provided at present.And the refinery of China designs according to the processing sweet crude oil, and existing hydrodesulfurization unit deficiency then drops into huge as transformation.The principal feature of China's gasoline is sulphur content and olefin(e) centent height, and same diesel oil sulphur content is also high.Current, the main developed country in the world all falling doctor negative content as the most important thing of producing cleaning vapour, diesel oil, is paid much attention to.European Union regards reduction vapour, diesel oil sulphur content to lower level as prerequisite that introducing can be carried out the advanced automotive engineering of Europe III and Europe IV emission standard, and gasoline and the diesel oil of bringing into use sulphur content to be lower than 10ppm in 2005, finished transition in 2011 to this low-sulfur fuel.At present both at home and abroad the petrochemical complex industrial community is all striven for improving gasoline and production of diesel oil and is improved the product Environmental indicators making a great effort, but technical difficulty is very high, invests huge.If the advantage separately of performance bio oil and oil, only change at present from the finished product stage and carry out alternate technology, the bio oil and the oil that substitute oil are re-used after feed stage is mixed, can address these problems well, reduce the cost that greenization is transformed greatly.
Oil in the world can only be with 100 years now, and the reserves of coal are also few.But according to estimation, it is 1,800 hundred million tons that the annual biomass energy that produces in the whole world gets reserves, is inexhaustible, nexhaustible resource.Accelerated development substitutes the low-sulfur clean fuel of oil, reduces oil consumption and satisfies emission standard, and is extremely urgent.Because alcohol fuel and biofuel go up not sulfur-bearing and aromatic hydrocarbons substantially.The countries in the world alternate way of all taking to be mixed in processed oil is produced the low-sulfur clean fuel, and the input of " beginning all over again " is huge like this.Compare with the fossil oil, bio oil sulphur, oxygen, nitrogen content are low, and ash content is few, and environmental pollution is little.Just substituting with reduction sulphur, oxygen, nitrogen equal size from feed stage is the same with alternate effect processed oil.In addition, bio oil can be by aspirating, store with pump the same fully mode of fossil crude oil today and passing through highway, railway and Oil Carrier Transportation, and this greatly facilitates the processing of biomass or cleaning raw material and has reduced huge investment.
Though bio oil is very approaching with performance, purposes, the refining process of fossil crude oil, price is also low than alcohol fuel, biofuel, but make quality obtain high added value chemical and industrial chemicals as petrol engine and use for diesel engine fuel or deep processing near common motor spirit and diesel oil, also to invest a set of equipment again, huge new input must be arranged.For satisfying the suitability for industrialized production demand of bio oil, must collect biomass such as stalk at wide geographic area.Yet the remote transportation of the biomass material that takes up space that energy density is low is uneconomic.Therefore, concentrate the dispersive biomass material and be converted to " bio oil " that is easy to handle and store, make this production unit " miniaturization ", can further reduce the production cost of bio oil, but also need new input.In addition, the input-output ratio of domestic at present " coal become oil " is slave unit only, and producing 10,000 tons of oil just needs 100,000,000 yuan investment, and the input-output ratio of coastal refinery enlarging is that per 10,000 tons input is 1,000 ten thousand yuan, and only 1/10th.Two accounts are compared, and coal liquefaction was invested huge, do not have profit to say.
---cost is low.Current, the key that influences world's biofuel development is raw material and price.For example, China belongs to the third generation, contains the biofuel of 5% little algae, will sell in the part city.Contain 5% " little algae diesel oil " as popularization, demand will be 6,000,000 tons.Min's academician of the Chinese Academy of Sciences and Chinese Academy of Engineering bounties are thought, at first are costs.The industrial chain of little algae diesel oil project is very long, and the cultivation cost of algae is very high, and the price of finished product is the doubly a lot of of present oil; Secondly, little algae diesel oil project will be gone into operation, and scale will just can be done very greatly, and the industrial scale of each research institution is all very little now; Once more, be difficult to find suitable production site.In algae culture, the density of algae can only arrive 1%～2%, and is too close, and algae just can't absorb sunlight.Micro algae growth needs large-scale place to the high request of sunlight and water.In addition, the application and the international oil price of biofuel are closely related, and price is the key factor of " innovation drives " often.In the period of 1982～1993, Shell company utilizes agriculture and forestry organic waste material to develop the bio oil product, about 20～40 dollars/barrel of production cost.Afterwards, the production cost of fossil crude oil only is 12 dollars/barrel.Therefore very uneconomical in the application of bio oil at that time.In fact, the seventies in 20th century, many substitute energy projects once appearred in the U.S., with the high at that time oil price of reply.But to the eighties, when oil price falls after rise to some extent, after new forms of energy have just been thrown brain.In case oil price falls to 60～70 dollars/barrel, everybody will say goodbye with the application of these renewable energy sources.
Today after 30 years, international oil price has broken through 100 dollars, and the low price advantage of bio oil highlights.Utilize " biomass crude oil " part to replace " fossil oil ", just substitute from feed stage (crude oil), allow " biorefinery " raw material be compounded among the Green Development process of coal-based chemistry, petroleum base chemistry, cost is minimum.Particularly utilize the bio oil of manufacturings such as stalk and the bamboo willow of not planting on the bare place, saltings of long grain, sweet sorghum, cotton can obtain high yield, its peak rate of conversion is up to 70%, only more than 1000 yuan of per ton cost.And the price of present crude oil per ton is more than 4000 yuan.Just substitute in feed stage (crude oil), the bio oil that is mixed in crude oil is to substitute fossil crude oil, and not only processing is simple, and the raw material price is less than 1/3 of oil.By contrast, if the way by the bio oil that is mixed in processed oil is at present calculated, add bio oil is finish-machined to the cost that can be used as petrol motor and diesel-fuel, can produce 2 tons of bio oil according to 4 tons of agriculture and forestry organic waste materials, suitable 1 ton of gasoline of 2 tons of bio oil calorific values of gained or diesel oil, alternative 1 ton of gasoline or diesel oil; Fossil processed oil price is 7000 yuan per ton, and the bio oil price that is mixed in processed oil is approximately per ton to be 6000 yuan.
---go up detective.China will bring into play in the riverine and coastal area effect of port traffic, develops the large-scale petroleum and the coal heavy chemical industry of detective on some, and economy is had huge pushing effect.But because the environmental protection threshold is very high, business and government often is among the facing a difficult choice of " environmental protection " and " development ", has great risk of policy making.Compare with homemade crude oil, the sulphur content height of imported crude oil along with the ratio of import high-sulfur crude oil increases year by year, is accelerated development the low-sulfur clean fuel, will promote the development of China's energy-conserving and environment-protective industry greatly.Coal and crude refining are the technology that a kind of factory countless in the whole world obtains using." sweet crude oil " the same " old product " that belongs to different qualities with " high-sulfur crude oil ", " bio oil+fossil crude oil ", just substitute from feed stage (crude oil), " sweet crude oil " that contain biomass material that obtains can use existing old technology and standard fully through revision.Equally,, also can use existing old technology and standard fully, like this, generally just launch products can be arranged then through revision with the low sulfur product that " sweet crude oil " refining is produced.And " refining biological oil+processed oil " resulting " low-sulfur processed oil " that contains biomass material is a kind of product innovation, cannot use existing technology and standard.Equally, producing chemical and the industrial chemicals that obtains with the bio oil refining, is a kind of new biochemicals and industrial chemicals, obviously can not use existing old " fossil crude oil " technology and standard.And product innovation will be put on market, except wanting various formalities, also to formulate new technology and standard, through in a few years even the test of more than ten years and test manufacture, evaluation and declaration.Flashed several years, perhaps international oil price has fallen after rise again, after this moment, everybody can throw brain with this product innovation again, has said goodbye with the application of these renewable energy sources.
Mention " coastland ", people always expect flourishing plentiful, the economy of the convenient and high speed development in harbour.But huge personnel and financial loss that Japanese violent earthquake and tsunami cause, and the nuclear power plant accident that takes place frequently, impel people to think deeply once more, whether " economy and energy center of gravity " is placed on coastal suitable? the main energy sources in coastal too busy to get away oil, coal and these worlds of biomass.The prosperous Ning Huopufu of the chairman of GDCh points out in the preamble of " biorefinery ": after coal-based chemical developer 150 years, petroleum base chemical developer 50 years, technical chemistry has entered a new era.21 century, renewable raw-material utilization will occupy prior status in the chemical conversion of technical scale material.Economic form is adjusted into economy based on renewable starting material, needs to use new method.From based on the chemistry of fossil feedstock to carry out necessary transformation based on biological modern science and technology, be an intelligence challenge.Yet, because biochemical industry and fossil industry barrier between different departments are done things in his own way, isolate relatively, formation is not closely connected and causes both not giving full play to " biorefinery " huge effect, causes the idle waste of fossil resource again.Up to the present, the content of " biorefinery " only is based on microbiological " bio-based economy ", and to substituting based on green material (cleaning, renewable), i.e. method by " biomass+fossil crude oil " on the source, transform coal-based and the petroleum base chemistry, and then accelerate the green chemical industry process, but nobody relates to.In fact, even business and government will develop " bio-based economy " upward green chemical industry project at present, but " beginning all over again " investment is huge, and valuable product, also will strive market with original production capacity.Will induce enterprise to slide to like this and do little chemical industry, little smelting, the old road of the low-level construction that repeats to go over.Therefore only be " bio-based economy ", be unfavorable for promoting that new industry is done on a large scale, built up strengths, composition optimizes, the lifting of matter attitude.
Compare with " biorefineries " such as alcohol fuel, biofuel, " biomass+fossil crude oil " route has better ecological benefits.One, development " biomass+fossil crude oil " is water not.Existing " biorefinery " needs great amount of water resources, and the waste water that produces of refining not only destroyed environment but also consumes energy, and at present domestic have: the resource shortage; The short situation of three kinds of water resourcess such as engineering shortage and contaminative shortage.And the protection water resources problem is more more outstanding than " 1,800,000,000 mu " arable land red line.Its two, utilizing agriculture and forestry organic waste material to produce alcohol fuel and biofuel, that is that all right is ripe.Present best raw material is " grain and an oil ", and this must " strive ground with the people, strive fertilizer with grain ", and waste water and dregs also will destroy soil.With brassinosteroid biosynthesis diesel oil is example, and 0.07 hectare can be received 1000 jin of Semen Brassicae campestris, needs 50 jin of urea, 200～300 jin of chemical fertilizer, 100 jin of phosphate fertilizer.3 jin of vegetable seed press 1 jin of oil, and 0.07 hectare can approximately be produced 333 jin can be as the rapeseed oil of biofuel.But, give the chemical fertilizer of these vegetable seed fertilisings and urea also from fossil energy, the biofuel of final 0.07 hectare supply is less than 100 kilograms, and the calorific value of biofuel is less than 90% of fossil diesel fuel.The best raw material of bio oil is exactly an agriculture and forestry organic waste material, just can be fuel-displaced in the bio oil equipment as long as waste is put into.Its three, utilize bio oil to pass through comparatively simple technology and can prepare fertilizer and soil redeposition.It contains various trace elements, can control soil acidity, stimulating plant growth, the pollution problem that might solve the rivers and lakes that cause because of independent use nitrogen fertilizer simultaneously.One of bio oil working method is to pulverize post-heating to make it be decomposed into compound, again these compounds is become liquid fuel afterwards.General per kilogram raw material can obtain the combustible gas of 0.5～0.7 kilogram of bio oil, 0.20 kilogram of biological carbon (can collect and make also field of fertilizer) and 0.20 kilogram after processing.Not only the bio oil waste residue does not destroy soil, can also improve the soil, for restoration of the ecosystem is contributed.
The raw material of bio oil also can be badly in need of saltings, the mineral products abandoned land of restoration of the ecosystem from China.Not only biomass is big but also salt tolerant alkali is fit to the restoration of the ecosystem of saline and alkaline or mineral products abandoned land very much such as, plants such as bamboo willow, sweet sorghum, cotton.At present, the high energy of one mu of bamboo willow energy forest 1 year produces 6～7 tons of bio oil, as producing 1.6 tons of calculating so that 4 annuals such as bamboo willow, sweet sorghum, stalk are annual, 2000 mu of saline and alkaline or mineral products abandoned lands can produce 3200 tons of bio oil every year, and investment is produced the production unit of 3600 tons of bio oil per year and is no more than 5,000,000 yuan.The price of crude oil per ton is more than 4000 yuan in the world now.If the price of bio oil is by 1000～3000 yuan of sale, 2000 mu of saline and alkaline or annual sales volumes of abandoned land bio oil are 320～9,600,000 yuan.Less than the production unit cost that promptly can regain bio oil in 1 year.According to statistics, in China available reserve soil, the saltings just has 1.6 hundred million mu.The ruined soil of accumulative total, mining area, the whole nation reaches 4,320 ten thousand mu, and only big-and-middle-sized colliery just accounts for 2430 mu.Before this, national big-and-middle-sized colliery has 102 in forest farm, 2,100,000 mu of forest lands.If utilize 8,000 ten thousand mu of saline and alkaline or mineral products abandoned land kind bamboo willows, sweet sorghum, cotton etc., can produce 1.28 hundred million tons of bio oil every year, facility investment is no more than 200,000,000,000 yuan.The price of bio oil is as pressing 2000 yuan of sale, and annual sales volume reaches 2,560 hundred million yuan.Like this, by 1.28 hundred million tons of bio oil utilizing 8,000 ten thousand mu of saline and alkaline or mineral products abandoned lands to produce substitute from middle-east, 1.3 hundred million tons of oil of north African import, the external interdependency of China's oil will be dropped to approach zero, thereby thoroughly break away from dependence Imported oil.
In addition, utilize 8,000 ten thousand mu to produce " biomass crude oil ", 2,000 ten thousand raw material production posies can also newly be provided, the raw material processing income of 260,000 processing posies and 32,000,000,000 yuan.This just quite moved to green oil field one by one saline and alkaline or the mineral products abandoned land on, each saline and alkaline or mineral products abandoned land of 2000 mu just is equivalent to can produce every year " the green oil well " of 1800～2100 tons of bio oil; One is had only the poor village of saline and alkaline or abandoned land just quite to have the green factory of a bite oil well.And construction cost only is equivalent to 1/5 of middle-size and small-size oil field, 1/2～1/3 of suitable oil field of construction period, and be never exhausted " green oil field and low-carbon (LC) oil well ".In addition,, allow them use the raw material that is mixed by bio oil and crude oil, join together to produce with bio oil as transforming idle fossil crude oil refinery factory, the chemical plant that maybe will eliminate of a collection of large, medium and small script again.Can get the low gasoline of sulphur, oxygen, nitrogen equal size and " green chemical and the industrial chemicals " of diesel oil and high added value through refining.
Alcohol-ether fuel is generally had an optimistic view of the desirable clean fuel that substitutes oil in the world.Its cost and pollute all is lower than people and endeavours low pollution alternative fuel such as the liquid propane gas developed and compressed natural gas in recent years.Bio oil can not be dissolved each other with varsols such as toluene, benzene, but dissolves in " alcohol-ether fuels " such as methyl alcohol, ethanol, propyl alcohol, butanols, dme.Bio oil is made boiler oil and is used, and is particularly suitable for the transformation of medium and small coal firing boiler, with the discharging of its generation coal minimizing coal ash.With preceding being exactly to add alcohol-ether fuel to reduce acidity, increase calorific value about 30%, reduce flash-point and viscosity simultaneously.Can also obtain spices, solvent, resin etc. through fractionation.General methyl alcohol, dme are to be raw material with biomass or coal or Sweet natural gas, by synthetic gas (CO/H2), the oxygenated fuel that catalyzed conversion forms under certain temperature and pressure.Because alcohol ether is purer compound, not sulfur-bearing and other complex organic compound are so have advantages such as environmental protection, thermo-efficiency height, adaptability be strong.China's high-sulfur inferior coal account for total reserves half, general 1.5～1.6 tons of coals can be made one ton of alcohol-ether fuel, 4.5 ton tangible cost advantage arranged with 3.5 tons in coal and indirect liquefaction system oil ton with coal compared with direct liquefaction system oil ton, import coal is more cheap than homemade at present, and the alcohol-ether fuel production cost is substantially about 30～50 dollars every barrel.Coal gas that discharges when utilizing cheap high sulphur coal and coking or import coal system alcohol-ether fuel low production cost.
In addition, can make methyl alcohol with synthetic gas, as walk one step of key of logical " methanol-to-olefins ", " alcohol generation oil " is just become possibility.But extracting solution gasification, gasoline, diesel oil and fuel and industrial raw material such as ethene, propylene from oil carry out polymerization to ethene, propylene, can produce various Chemicals.2006, co-partnership company was set up in the group of Shenhua of coal-mining industry group of China's maximum and Dalian Inst of Chemicophysics, Chinese Academy of Sciences's cooperation, built the first cover in the world, the maximum coal system olefin hydrocarbon apparatus in the whole world, can produce 600000 tons in alkene per year.Drop into 1,800,000 tons of methyl alcohol, methyl alcohol almost 100% transforms, and obtains 600,000 tons of alkene, and the content of ethene and propylene surpasses 80%.Isolated thus ethene and propylene have become film common in qualified polyethylene, the polypropylene-daily life, plastics casing, housing of TV set or the like, all use their processings." alcohol generation oil " will enrich the energy reserves mode of China, can " bring back to life " the methyl alcohol industry of China simultaneously.Owing to several years ago jump on the bandwagon, China's methyl alcohol industry production capacity surplus and production cost are too high, if new technology is promoted, the product that can be these methyl alcohol enterprises finds new outlet.Just locating low ebb owing to the world market methanol prices again, and the standing storage of methyl alcohol energy, China also can consider to store up methyl alcohol, as a kind of resources reserve.
Methyl alcohol can be made alkene, and propylene can be made butanols (oxo synthesis) and can also make acetone (direct oxidation method) China gasifying biomass synthesizing methanol, butanols etc. an incomparable advantage uniqueness, external is arranged, just be that there are large, medium and small Methanol Plant more than 200 families in China, wherein the overwhelming majority is the connection alcohol in the small nitrogen fertilizer business, and these join pure producer, major part all adopts Shell, GSP, Lurgi and grace Coal Gasification Technology to produce synthetic gas, perhaps is the feedstock production synthetic gas with the Sweet natural gas.Find that when substituting diesel oil sneaking into butanols can obviously improve the engine ignition performance, and can prevent the generation of black smoke.At present butanols is regarded as gasoline dope by EPA, can degree of mixing up to 11%.The test of Argonne National Laboratory shows that butanols-diesel oil of 20% has been successfully applied to the diesel motor of 100% combustion diesel fuel, and can reduce the discharging of pollutent.The ratio of mixture of acetone and butanols and processed oil is higher, need not vehicle is transformed, and just can use the almost acetone and the butanols of 100% concentration, and the blended economy is higher.China is the country of coal, weak breath, oil starvation more than.The coal resources total amount is more relatively, and the east is the large electricity consumer, and import coal is also more cheap than homemade.Press present technical qualification, can build up with 25,000,000,000 dollars and produce 100000000 tons of alcohol-ether fuels per year, can replace 200,000,000 tons of oil; Invest 60,000,000,000 dollars, can build up and produce 2.4 hundred million tons of alcohol-ether fuels per year, replace 4.8 hundred million tons of oil.Therefore, utilize alcohol-ether fuel to substitute oil, then might guarantee 100 years energy securities and only need 1/10th of the used foreign exchange of Imported oil.
Summary of the invention
The object of the present invention is to provide a kind ofly to substitute the fossil oil with biomass, cost is low, the biochemical crude oil of protection environment.
Technical solution of the present invention is:
A kind of biochemical crude oil is characterized in that: mainly be made up of following weight composition:
Bio oil 0.1～50 %;
Oil and/or alcohol-ether fuel 50～99.9 %;
The additive that also contains 0～15% weight.
Additive is butanols, acetone, hydrogen, coke, zeolite, abendoned oil, properties-correcting agent or organic nitric acid fat compound.
The biofuel, vegetable and animals oils or the ammonia that also contain 0～49% weight.
Described biochemical crude oil, form by the composition of following weight percent:
Bio oil 0.1～49%;
Oil and/or alcohol-ether fuel 49～99.7%
Additive 0.1～15%
Biofuel, vegetable and animals oils or ammonia 0.1～49%.
During manufacturing: utilize existing fossil oil production refining marketing system and pipeline or oil refining enterprise, chemical plant Infrastructure or Clean Fuel Production sale enterprise Infrastructure and special-purpose vehicle, equipment etc. as blending equipment.With pump suction, store and by highway, railway and Oil Carrier Transportation.By computer metering,, finished allotment in the time of adding by mediation, stirring or pump circulation or direct the adding in the equipment that is mixed.Sending each feed point by pipeline or tank car or tank car sells.
The present invention just with the subversive alternative fossil oil of biomass, sets up an economic structure that does not rely on the fossil oil from feed stage, by the saline and alkaline and restoration of the ecosystem mineral products abandoned land, promotes the greenization of heavy chemical industry in the development biorefinery; Utilize existing oil production refining marketing system or apparatus preparings such as oil refining, chemical plant and clean fuel enterprise; Pumpable, storage reach by pipeline, highway, railway and Oil Carrier Transportation.Make the backwardness of eliminating originally or pollute production capacity and be transformed into " green oil field " " low-sulfur refinery " and " greenization factory "; not only less investment, cost low, go up detective; in the process of exploitation, protect environment; avoid original huge production capacity to become " useless assets ", thereby promote the spanning development of new industry and low-carbon economy.
The invention will be further described below in conjunction with embodiment:
Embodiment 1:
A kind of biochemical crude oil, form by following weight composition:
Bio oil 20 %; Alcohol-ether fuel 18 %; Oil 62 %.
Utilize existing fossil oil production refining marketing system and pipeline or oil refining enterprise, chemical plant Infrastructure or Clean Fuel Production sale enterprise Infrastructure and special-purpose vehicle, equipment etc. as blending equipment.With pump suction, store and by highway, railway and Oil Carrier Transportation.By computer metering,, finished allotment in the time of adding by mediation, stirring or pump circulation or direct the adding in the equipment that is mixed.Sending each feed point by pipeline or tank car or tank car sells.
Embodiment 2:
A kind of biochemical crude oil, form by following weight composition:
Bio oil 0.1 %; Oil 88.9%;
Biofuel, vegetable and animals oils or ammonia 11%.All the other are with embodiment 1.
Embodiment 3:
A kind of biochemical crude oil, form by following weight composition:
Bio oil 50 %; Alcohol-ether fuel 3 %;
Oil 47 %; All the other are with embodiment 1.
Embodiment 4:
A kind of biochemical crude oil, form by following weight composition:
Bio oil 15 %; Oil 85 %; All the other are with embodiment 1.
Embodiment 5:
A kind of biochemical crude oil, form by following weight composition:
Bio oil 5 %; Oil 70%;
Butanols (or acetone, hydrogen, coke, zeolite, abendoned oil, properties-correcting agent or organic nitric acid fat compound) 15%; Biofuel, vegetable and animals oils or ammonia 10 %; All the other are with embodiment 1.
Embodiment 6:
A kind of biochemical crude oil, form by following weight composition:
Bio oil 0.9 %; Alcohol-ether fuel 50 %;
Butanols (or acetone, hydrogen, coke, zeolite, abendoned oil, properties-correcting agent or organic nitric acid fat compound) 0.1%; Biofuel, vegetable and animals oils or ammonia 49%; All the other are with embodiment 1.
Claims (5)
1. biochemical crude oil is characterized in that: mainly be made up of the composition of following weight percent:
Bio oil 0.1～50%;
Oil and/or alcohol-ether fuel 50～99.9%.
2. biochemical crude oil according to claim 1 is characterized in that: the additive that also contains 0～15% weight.
3. biochemical crude oil according to claim 2 is characterized in that: additive is butanols, acetone, hydrogen, coke, zeolite, abendoned oil, properties-correcting agent or organic nitric acid fat compound.
4. according to claim 1,2 or 3 described biochemical crude oil, it is characterized in that: the biofuel, vegetable and animals oils or the ammonia that also contain 0～49% weight.
5. according to claim 1,2 or 3 described biochemical crude oil, it is characterized in that: the composition by following weight percent is formed:
Bio oil 0.1～49%;
Oil and/or alcohol-ether fuel 49～99.7%
Additive 0.1～15%
Biofuel, vegetable and animals oils or ammonia 0.1～49%.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103394505A (en) * | 2013-08-05 | 2013-11-20 | 中国科学院城市环境研究所 | Method for using plants to control and restore soil and to generate biological fuel |
| CN106281502A (en) * | 2016-09-13 | 2017-01-04 | 孔祥兴 | A kind of efficient environment-friendly energy-saving diesel fuel additive |
| CN110551533A (en) * | 2019-08-26 | 2019-12-10 | 珠海市三悦石油化工有限公司 | Environment-friendly fuel composition |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN1807559A (en) * | 2005-01-20 | 2006-07-26 | 窦观一 | Biochemical fuel |
| CN101974356A (en) * | 2010-11-18 | 2011-02-16 | 窦观一 | Low-carbon type biological product oil |
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1807559A (en) * | 2005-01-20 | 2006-07-26 | 窦观一 | Biochemical fuel |
| CN101974356A (en) * | 2010-11-18 | 2011-02-16 | 窦观一 | Low-carbon type biological product oil |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103394505A (en) * | 2013-08-05 | 2013-11-20 | 中国科学院城市环境研究所 | Method for using plants to control and restore soil and to generate biological fuel |
| CN103394505B (en) * | 2013-08-05 | 2015-04-29 | 中国科学院城市环境研究所 | Method for using plants to control and restore soil and to generate biological fuel |
| CN106281502A (en) * | 2016-09-13 | 2017-01-04 | 孔祥兴 | A kind of efficient environment-friendly energy-saving diesel fuel additive |
| CN110551533A (en) * | 2019-08-26 | 2019-12-10 | 珠海市三悦石油化工有限公司 | Environment-friendly fuel composition |
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