CN102153938B - Self-leveling composition for anticorrosive lining conductive leveling layer of cement matrix and preparation method thereof - Google Patents
Self-leveling composition for anticorrosive lining conductive leveling layer of cement matrix and preparation method thereof Download PDFInfo
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- CN102153938B CN102153938B CN 201110050137 CN201110050137A CN102153938B CN 102153938 B CN102153938 B CN 102153938B CN 201110050137 CN201110050137 CN 201110050137 CN 201110050137 A CN201110050137 A CN 201110050137A CN 102153938 B CN102153938 B CN 102153938B
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Abstract
The invention relates to an anticorrosive lining composition, in particular to a composition for an anticorrosive lining conductive leveling layer and a preparation method thereof. The self-leveling composition for the anticorrosive lining conductive leveling layer of cement matrix comprises the following components in part by weight: a, 100 parts of vinyl resin; b, 1 to 3 parts of cobalt naphthenate; c, 1 to 3 parts of leveling agent; d, 1 to 3 parts of methyl ethyl ketone peroxide; and e, 50 to 100 parts of conductive powder. The preparation method for the self-leveling composition for the anticorrosive lining conductive leveling layer of the cement matrix comprises the following steps of: pre-stirring the components a, b and c uniformly, adding the component d during use, stirring the components for at least one minute, then adding the component e, and stirring the components uniformly to form plaster. The composition has self-leveling property and good adhesion with a lining material.
Description
Technical field
The present invention relates to the corrosion protective lining composition, relate in particular to a kind of corrosion protective lining conduction screed-coat composition and method of making the same.
Background technology
At chemical industry equipment, the cement matrix surface of electric field dust removal installation, sea water desalting equipment etc. needs anticorrosive coating, and the bonding of cement matrix surface and corrosion protective lining is not fine, and because of the matrix poorly conductive, can not detect the defective of preservative coat with the electrical spark detector, so need between to form one and cement matrix and preservative coat bonding favorable conductive screed-coat.Multiple conduction self-leveling coating is arranged in the market, be embedded with conductive electrode (tinsel or wire netting etc.) in this coating, its effect is to derive the static that matrix surface produces, and the bond performance of it and corrosion protective lining (rubber lining and vinyl scale lining) is bad, can't be applied to this occasion.
Summary of the invention
The present invention is intended to address the aforementioned drawbacks, and provides the corrosion protective lining screed-coat of cement matrix with conducting electricity from the levelling composition and method of making the same.Composition of the present invention can be from levelling, and and the antisepticise lining material bond performance good, and have good electrical conductivity and heatproof, erosion resistance, solvent resistance.
The present invention realizes like this: a kind of corrosion protective lining conduction screed-coat of cement matrix is used from the levelling composition, and it comprises following component:
Component a: epoxies Vinylite, 100 parts;
Components b: cobalt naphthenate, 1-3 part;
Amount of component b: flow agent, 1-3 part;
Component d: methylethyl ketone peroxide, 1-3 part;
Component e: conducting powder, 50-100 part;
Described umber is parts by weight.
Described Vinylite is the epoxies Vinylite.
Described flow agent is: a kind of in aerosil or the organobentonite.
Described conducting powder is one or more the mixture in metal-powder, carbon dust or the Graphite Powder 99.Described cobalt naphthenate is that commercially available concentration is 1% ~ 10% cobalt naphthenate.
The corrosion protective lining of described cement matrix conduction screed-coat is used from levelling preparation of compositions method, and described component a, b and c item are stirred in advance, adds component d when to be used and stirs at least 1 minute, stirs and becomes clay adding component e then.
But the clay blade coating of composition of the present invention preparation is to cement matrix, but Automatic Levelling (namely from levelling), air-dry after, having electroconductibility can be at its surface lining antiseptic rubber lining or vinyl scale clay.
To rubber lining, after the binding agent of lining parches (after general 48 hours), available electrical spark detector detects rubber lined defective (for example: pin hole, crackle, crack, impurity etc.).
To vinyl scale clay lining, solidify back (after general 48 hours) at clay, available electrical spark detector detects the defective (for example: pin hole, crackle, crack, impurity etc.) of vinyl scale clay lining.
If on cement matrix, do not add this conduction screed-coat, directly serve as a contrast rubber or clay, because there not being conductive layer, can not detect the defective of rubber lining and scale clay lining with the electrical spark detector, the little defective of this part can cause whole rot-resistant to lose efficacy.
Embodiment
The present invention is further illustrated below by embodiment: a kind of corrosion protective lining conduction screed-coat of cement matrix is used from the levelling composition, and it comprises following component:
Component a: epoxies Vinylite, 100 parts;
Components b: cobalt naphthenate, 1-3 part;
Amount of component b: flow agent, 1-3 part;
Component d: methylethyl ketone peroxide, 1-3 part;
Component e: conducting powder, 50-100 part;
Described umber is parts by weight.
Described Vinylite is the epoxies Vinylite, and it comprises bisphenol-A epoxy Vinylite, phenolic aldehyde epoxy vinyl ester resin etc.The bisphenol-A epoxy Vinylite has good agglutinating value(of coal) and erosion resistance, is applicable to the etch of corrosive mediums such as the following most of acid of 100 ° of C, alkali, salt; Phenolic aldehyde epoxy vinyl resin has good agglutinating value(of coal) and good solubility-resistence, higher heat-drawn wire, and to oxidizing acid, contain chlorine solution and have good resistivity, maximum operation (service) temperature can reach 200 ° of C.
Described flow agent is: a kind of in aerosil or the organobentonite.
Described conducting powder is one or more the mixture in metal-powder, carbon dust or the Graphite Powder 99.
Described cobalt naphthenate is that commercially available concentration is 1% ~ 10% cobalt naphthenate.
The corrosion protective lining of described cement matrix conduction screed-coat is used from levelling preparation of compositions method, and described component a, b and c item are stirred in advance, adds component d when to be used and stirs at least 1 minute, stirs and becomes clay adding component e then.
Embodiment one
A kind of corrosion protective lining conduction screed-coat of cement matrix is used from levelling composition (clay), and it comprises following component:
Component a: Vinylite (Ripoxy R-802), 100 parts;
Components b: cobalt naphthenate, 1.5 parts
Amount of component b: flow agent, 2.7 parts
Component d: methylethyl ketone peroxide, 2.8 parts
Component e, conducting powder, 50-100 part;
Described umber is parts by weight.
The making of clay: a in will filling a prescription, b, 3 components of c stir in advance, are adding the d component during use, stir at least 1 minute, stir adding the e component then, are conduction flat bed (clay) early.
The corrosion protective lining of filling a prescription in this is applicable to the environment that 100 ° of C are following with conduction screed-coat composition, is called universal corrosion protective lining with conducting electricity the screed-coat composition.
Embodiment two,
A kind of corrosion protective lining conduction screed-coat of cement matrix is used from levelling composition (clay), and it comprises following component:
Component a: the phenolic aldehyde epoxy vinyl ester resin (for example: Ripoxy H-630), 100 parts;
Components b: cobalt naphthenate, 2 parts
Amount of component b: flow agent, 2.5 parts
Component d: methylethyl ketone peroxide, 1.7 parts
Component e, conducting powder, 50-100 part;
Described umber is parts by weight.
The making of clay: a in will filling a prescription, b, 3 components of c stir in advance, are adding the d component during use, stir at least 1 minute, stir adding the e component then, are conduction flat bed (clay) early.
The corrosion protective lining of filling a prescription in this is applicable to the environment that 200 ° of C are following with conduction screed-coat composition, is called the high temperature modification corrosion protective lining with conducting electricity the screed-coat composition.
Construction: this clay that will prepare with scraper (bricklayer's cutter) scrapes on the cement matrix.(note cement matrix before this material of blade coating must be do, do not have loose skin, no grease, free from smutting during, preferably pass through sandblast or grinding process)
Lining rubber: after this conduction screed-coat solidifies, after at least 48 hours, can be at its external coating rubber lining with primary coat (for example: the SP-1 primary coat) and sizing agent (SP-1 sizing agent), then the sheet rubber that also scribbles binding agent (for example: SP-802 prevulcanized rubber plate) be attached on the clay, after air-dry 48 hours, available electrical spark detects the lining defective.
Lining scale clay: at this conduction screed-coat, after air-dry 6 ~ 48 hours, can be at the direct blade coating vinyl scale clay (for example: SP-940, SP-950 vinyl scale clay) in its surface.After vinyl scale clay solidified, available electrical spark detected the defective of vinyl scale clay lining after general 48 hours.Detection voltage suggestion: the thick rubber lining of 3KV/mm or vinyl clay.Electrical spark detects the zone of finding conduction and chimes of doom being arranged, and has defectives such as pin hole or crackle, answers mark, and repairs.
Claims (5)
1. the corrosion protective lining of cement matrix conduction screed-coat is used from the levelling composition, it is characterized in that it comprises following component:
Component a: epoxies Vinylite, 100 parts;
Components b: cobalt naphthenate, 1-3 part;
Amount of component b: flow agent, 1-3 part;
Component d: methylethyl ketone peroxide, 1-3 part;
Component e: conducting powder, 50-100 part;
Described umber is parts by weight.
2. the corrosion protective lining of cement matrix according to claim 1 conduction screed-coat is used from the levelling composition, it is characterized in that described cobalt naphthenate is that commercially available concentration is 1% ~ 10% cobalt naphthenate.
3. the corrosion protective lining of cement matrix according to claim 1 conduction screed-coat is used from the levelling composition, it is characterized in that described flow agent is: aerosil or organobentonite.
4. the corrosion protective lining of cement matrix according to claim 1 conduction screed-coat is used from the levelling composition, it is characterized in that, described conducting powder is one or more the mixture in metal-powder, carbon dust or the Graphite Powder 99.
5. the corrosion protective lining of cement matrix according to claim 1 conduction screed-coat is used from levelling preparation of compositions method, it is characterized in that, described component a, b and c item are stirred in advance, add component d when to be used and stirred at least 1 minute, stir that to become clay be described from the levelling composition adding component e then.
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Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3639653A (en) * | 1969-03-19 | 1972-02-01 | British Columbia Res Council | Protective coating for metal and wood surfaces |
CN101074337A (en) * | 2007-06-25 | 2007-11-21 | 沈阳市航达科技有限责任公司 | Zinc-aluminum composite coating paint and preparation method thereof |
CN101760115A (en) * | 2009-11-30 | 2010-06-30 | 北方涂料工业研究设计院 | Preparation method of low shrink air dry vinyl ester heavy-duty anti-corrosive paint |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4939621A (en) * | 1972-08-23 | 1974-04-13 | ||
JPH0939621A (en) * | 1995-08-02 | 1997-02-10 | Shizuo Isono | Getting-on/off device for vehicle |
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2011
- 2011-03-02 CN CN 201110050137 patent/CN102153938B/en active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3639653A (en) * | 1969-03-19 | 1972-02-01 | British Columbia Res Council | Protective coating for metal and wood surfaces |
CN101074337A (en) * | 2007-06-25 | 2007-11-21 | 沈阳市航达科技有限责任公司 | Zinc-aluminum composite coating paint and preparation method thereof |
CN101760115A (en) * | 2009-11-30 | 2010-06-30 | 北方涂料工业研究设计院 | Preparation method of low shrink air dry vinyl ester heavy-duty anti-corrosive paint |
Non-Patent Citations (1)
Title |
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JP特开昭49-39621A 1974.04.13 |
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