Rare earth-silanization treating agent and compound method thereof before the metallic cathode electrophoresis
Technical field
The present invention relates to the metallic surface silanization process field, be specifically related to preceding rare earth-silanization treating agent of a kind of metallic cathode electrophoresis and compound method thereof.
Background technology
It is to be that staple is carried out the surface-treated process to metal with the organosilane aqueous solution that metallic surface silanization is handled.The silylanization processing is compared with conventional phosphatizing has following a plurality of advantage: no harmful heavy metal ion, and not phosphorous, need not to heat.The silane treatment process does not produce sediment, and the treatment time is short, controls easy.Treatment step is few, can save table and transfer operation, and tank liquor is reusable.Effectively improve the sticking power of paint to base material.But multiple base materials such as collineation processing iron plate, galvanized sheet, aluminium sheet.But with regard to present domestic technique, not very ripe, especially in the selection of silane and auxiliary agent, also have a lot of not enough places.
Metallic surface silanization is handled and to be had broad application prospects, but the silane film that prior art became exists that corrosion resistance is strong, film forming is inhomogeneous, do not possess perhaps defective such as " selfreparing " poor performance of " selfreparing " performance, has limited its development.
Summary of the invention
The invention provides preceding rare earth-silanization treating agent of a kind of metallic cathode electrophoresis and compound method thereof.Adopting rare earth-silanization treating agent of the present invention to carry out metallic surface silanization handles; Form silane-silicon-molybdenum heteropoly acid Rare Earth Lanthanum hybridized film in the metallic surface; The silane of gained-silicon-molybdenum heteropoly acid Rare Earth Lanthanum hybridized film, corrosion resistance is strong, film forming is fine and close evenly, sticking power is good, " selfreparing " performance is good.
The technical scheme that the present invention adopts is following:
Rare earth-silanization treating agent before the metallic cathode electrophoresis, it is characterized in that: the weight of each component of constitutive material of its every liter treatment agent is:
The compound method of rare earth-silanization treating agent is characterized in that before the described metallic cathode electrophoresis, specifically may further comprise the steps:
(1) it is even ethanol to be added deionized water for stirring;
(2) silane coupling agent KH-560 is joined during ethanol that step (1) prepares dissolves, stir, and the PH=4-6 of regulator solution, make solution 1;
(3) Sodium orthomolybdate and water glass are dissolved in the deionized water respectively, and mix, behind the re-adjustment PH=2-3, again lanthanum acetate is added wherein dissolving mixing, make solution 2;
(4) solution 1 is mixed with solution 2, add isomery alcohol polyoxyethylene poly-oxygen propylene aether and EDTA Disodium, fully stir and constant volume the PH=4-6 of last regulator solution;
(5) leave standstill hydrolysis 24 hours under the mixing solutions room temperature, get final product.
The compound method of rare earth-silanization treating agent before the described metallic cathode electrophoresis is characterized in that: the pH value that comes regulator solution in the solution process for preparation with acetate or ammoniacal liquor.
Beneficial effect of the present invention:
Adopting rare earth-silanization treating agent of the present invention to carry out metallic surface silanization handles; Form silane-silicon-molybdenum heteropoly acid Rare Earth Lanthanum hybridized film in the metallic surface; The silane of gained-silicon-molybdenum heteropoly acid Rare Earth Lanthanum hybridized film, corrosion resistance is strong, film forming is fine and close evenly, sticking power is good, " selfreparing " performance is good.
Embodiment
Prepare the preceding rare earth-silanization treating agent of 1 liter of metallic cathode electrophoresis, the weight of its each component of constitutive material is:
The compound method of rare earth-silanization treating agent before the described metallic cathode electrophoresis specifically may further comprise the steps:
(1) it is even ethanol to be added deionized water for stirring;
(2) silane coupling agent KH-560 is joined during ethanol that step (1) prepares dissolves, stir, and the PH=4-6 of regulator solution, make solution 1;
(3) Sodium orthomolybdate and water glass are dissolved in the deionized water respectively, and mix, behind the re-adjustment PH=2-3, again lanthanum acetate is added wherein dissolving mixing, make solution 2;
(4) solution 1 is mixed with solution 2, add isomery alcohol polyoxyethylene poly-oxygen propylene aether and EDTA Disodium, fully stir and constant volume the PH=4-6 of last regulator solution;
(5) leave standstill hydrolysis 24 hours under the mixing solutions room temperature, get final product.