CN102134388A - Thermoplastic elastomer to be adhered on polyamide materials - Google Patents
Thermoplastic elastomer to be adhered on polyamide materials Download PDFInfo
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- CN102134388A CN102134388A CN2010106118314A CN201010611831A CN102134388A CN 102134388 A CN102134388 A CN 102134388A CN 2010106118314 A CN2010106118314 A CN 2010106118314A CN 201010611831 A CN201010611831 A CN 201010611831A CN 102134388 A CN102134388 A CN 102134388A
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Abstract
The invention relates to a thermoplastic elastomer to be adhered on polyamide materials, comprising the following components in percentage by weight: 3-8 percent of maleic anhydride grafted hydride styrene elastomer, 20-25 percent of hydride styrene elastomer, 3-7 percent of polyamide, 30-45 percent of polyurethane elastomer, 0.1-0.4 percent of ultraviolet absorber, 0.1-0.4 percent of antioxidant, 30-45 percent of mineral extender oil and 5-20 percent of inorganic nano fillers. Therefore, the thermoplastic elastomer has good handfeel, high comfortableness, meets the requirement on environmental protection, and can also play the function of shock absorption.
Description
Be used for penetrating sticking thermoplastic elastomer with the polyamide material.
Technical field
The present invention relates to a kind of being used for penetrates sticking thermoplastic elastomer with the polyamide material.
Background technology
The existing material that is used to make high-grade garden instrument and electronic product is generally made by the polyvinyl chloride elastomerics.The polyvinyl chloride true qualities are that little yellow is translucent, and are glossy.Transparency is better than polyethylene, polypropylene, is worse than polystyrene, with the auxiliary dosage difference, is divided into soft, rigid polyvinyl chloride, and soft goods is gentle and tough, and feel is sticking, and the hardness of boardy product is higher than new LDPE (film grade), and is lower than polypropylene, albinism can occur at the flexion place.Yet poor, the no cushioning effect of its feel of product by polyvinyl chloride is made does not meet environmental protection requirement.
Summary of the invention
The technical problem to be solved in the present invention provides a kind of good hand touch, comfort level height, meets environmental protection requirement, can also play cushioning effect be used for penetrate sticking thermoplastic elastomer with the polyamide material.The present invention is achieved through the following technical solutions:
A kind of being used for of the present invention penetrated sticking thermoplastic elastomer with the polyamide material, comprises maleic anhydride graft hydrogenated styrene elastomerics, hydrogenated styrene elastomerics, polymeric amide, polyurethane elastomer, UV light absorber, antioxidant, mineral-filled oil, inorganic nano-filler; Wherein, to account for weight percent be that to account for weight percent be that to account for weight percent be that to account for weight percent be that to account for weight percent be that to account for weight percent be that to account for weight percent be that to account for weight percent be 5%-20% for 30%-45%, inorganic nano-filler for 0.1%-0.4%, mineral-filled oil for 0.1%-0.4%, antioxidant for 30%-45%, UV light absorber for 3%-7%, polyurethane elastomer for 20%-25%, polymeric amide for 3%-8%, hydrogenated styrene elastomerics to maleic anhydride graft hydrogenated styrene elastomerics.
As improvement, wherein, maleic anhydride graft hydrogenated styrene elastomerics accounts for that weight percent is 8%, the hydrogenated styrene elastomerics accounts for that weight percent is 23.8%, polymeric amide accounts for that weight percent is 3%, polyurethane elastomer accounts for that weight percent is 32%, UV light absorber accounts for that weight percent is 0.1%, antioxidant accounts for that weight percent is 0.1%, mineral-filled oil accounts for that weight percent is 30%, to account for weight percent be 6% to inorganic nano-filler.
As improvement, wherein, maleic anhydride graft hydrogenated styrene elastomerics accounts for that weight percent is 5%, the hydrogenated styrene elastomerics accounts for that weight percent is 22%, polymeric amide accounts for that weight percent is 4%, polyurethane elastomer accounts for that weight percent is 30.5%, UV light absorber accounts for that weight percent is 0.2%, antioxidant accounts for that weight percent is 0.3%, mineral-filled oil accounts for that weight percent is 32%, to account for weight percent be 6% to inorganic nano-filler.
As improvement, wherein, maleic anhydride graft hydrogenated styrene elastomerics accounts for that weight percent is 3%, the hydrogenated styrene elastomerics accounts for that weight percent is 22%, polymeric amide accounts for that weight percent is 4.2%, polyurethane elastomer accounts for that weight percent is 32%, UV light absorber accounts for that weight percent is 0.4%, antioxidant accounts for that weight percent is 0.4%, mineral-filled oil accounts for that weight percent is 31%, to account for weight percent be 7% to inorganic nano-filler.
As improvement, described hydrogenated styrene elastomerics is SEBS, SEBS is to be end segment with the polystyrene, the ethylene-butene copolymer that obtains with the polyhutadiene hydrogenation is the triblock copolymer of middle elastomeric block, SEBS does not contain unsaturated double-bond, therefore have satisfactory stability and ageing resistance, model that the present invention adopts is one or any mixed multiple among SEBS G1650, SEBS G1651, SEBS G6933, SEBS 4033, the SEBS 4055.
As improvement, described antioxidant is anti-oxidant 1010 and anti-oxidant 168 mixtures by 1:1～2 mixed.
As improvement, described mineral-filled oil is paraffin-base alkanes oil, and its flash-point is more than 200 ℃, and under 25 ℃, viscosity is 15～20Cps.
As improvement, described inorganic nano-filler is a kind of in the above talcum powder of number 5000 orders, barium sulfate, lime carbonate, the mica powder.
A kind of being used for of the present invention penetrated sticking thermoplastic elastomer with the polyamide material, owing to comprise maleic anhydride graft hydrogenated styrene elastomerics, hydrogenated styrene elastomerics, polymeric amide, polyurethane elastomer, UV light absorber, antioxidant, mineral-filled oil, inorganic nano-filler, the elastomerics that can replace polyvinyl chloride to make, therefore, it has good hand touch, comfort level height, meet environmental protection requirement, can also play the benefit of cushioning effect.
Embodiment
A kind of being used for of the present invention penetrated sticking thermoplastic elastomer with the polyamide material, comprises maleic anhydride graft hydrogenated styrene elastomerics, hydrogenated styrene elastomerics, polymeric amide, polyurethane elastomer, UV light absorber, antioxidant, mineral-filled oil, inorganic nano-filler; Wherein, to account for weight percent be that to account for weight percent be that to account for weight percent be that to account for weight percent be that to account for weight percent be that to account for weight percent be that to account for weight percent be that to account for weight percent be 5%-20% for 30%-45%, inorganic nano-filler for 0.1%-0.4%, mineral-filled oil for 0.1%-0.4%, antioxidant for 30%-45%, UV light absorber for 3%-7%, polyurethane elastomer for 20%-25%, polymeric amide for 3%-8%, hydrogenated styrene elastomerics to maleic anhydride graft hydrogenated styrene elastomerics.Therefore, it has good hand touch, comfort level height, meets environmental protection requirement, can also play the benefit of cushioning effect.
Embodiment one: wherein, maleic anhydride graft hydrogenated styrene elastomerics accounts for that weight percent is 8%, the hydrogenated styrene elastomerics accounts for that weight percent is 23.8%, polymeric amide accounts for that weight percent is 3%, polyurethane elastomer accounts for that weight percent is 32%, UV light absorber accounts for that weight percent is 0.1%, antioxidant accounts for that weight percent is 0.1%, mineral-filled oil accounts for that weight percent is 30%, to account for weight percent be 6% to inorganic nano-filler.
Embodiment two: wherein, maleic anhydride graft hydrogenated styrene elastomerics accounts for that weight percent is 5%, the hydrogenated styrene elastomerics accounts for that weight percent is 22%, polymeric amide accounts for that weight percent is 4%, polyurethane elastomer accounts for that weight percent is 30.5%, UV light absorber accounts for that weight percent is 0.2%, antioxidant accounts for that weight percent is 0.3%, mineral-filled oil accounts for that weight percent is 32%, to account for weight percent be 6% to inorganic nano-filler.
Embodiment three: wherein, maleic anhydride graft hydrogenated styrene elastomerics accounts for that weight percent is 3%, the hydrogenated styrene elastomerics accounts for that weight percent is 22%, polymeric amide accounts for that weight percent is 4.2%, polyurethane elastomer accounts for that weight percent is 32%, UV light absorber accounts for that weight percent is 0.4%, antioxidant accounts for that weight percent is 0.4%, mineral-filled oil accounts for that weight percent is 31%, to account for weight percent be 7% to inorganic nano-filler.
In the foregoing description, described hydrogenated styrene elastomerics is SEBS, SEBS is to be end segment with the polystyrene, the ethylene-butene copolymer that obtains with the polyhutadiene hydrogenation is the triblock copolymer of middle elastomeric block, SEBS does not contain unsaturated double-bond, therefore have satisfactory stability and ageing resistance, model that the present invention adopts is one or any mixed multiple among SEBS G1650, SEBS G1651, SEBS G6933, SEBS 4033, the SEBS 4055.Described antioxidant is anti-oxidant 1010 and anti-oxidant 168 mixtures by 1:1～2 mixed.Described mineral-filled oil is paraffin-base alkanes oil, and its flash-point is more than 200 ℃, and under 25 ℃, viscosity is 15～20Cps.Described inorganic nano-filler is a kind of in the above talcum powder of number 5000 orders, barium sulfate, lime carbonate, the mica powder.
The mixture of mixed.A kind of being used for of the present invention penetrated sticking thermoplastic elastomer with the polyamide material, owing to comprise maleic anhydride graft hydrogenated styrene elastomerics, hydrogenated styrene elastomerics, polymeric amide, polyurethane elastomer, UV light absorber, antioxidant, mineral-filled oil, inorganic nano-filler, the elastomerics that can replace polyvinyl chloride to make, therefore, it has good hand touch, comfort level height, meet environmental protection requirement, can also play the benefit of cushioning effect.
Claims (8)
1. one kind is used for penetrating sticking thermoplastic elastomer with the polyamide material, comprises maleic anhydride graft hydrogenated styrene elastomerics, hydrogenated styrene elastomerics, polymeric amide, polyurethane elastomer, UV light absorber, antioxidant, mineral-filled oil, inorganic nano-filler; Wherein, to account for weight percent be that to account for weight percent be that to account for weight percent be that to account for weight percent be that to account for weight percent be that to account for weight percent be that to account for weight percent be that to account for weight percent be 5%-20% for 30%-45%, inorganic nano-filler for 0.1%-0.4%, mineral-filled oil for 0.1%-0.4%, antioxidant for 30%-45%, UV light absorber for 3%-7%, polyurethane elastomer for 20%-25%, polymeric amide for 3%-8%, hydrogenated styrene elastomerics to maleic anhydride graft hydrogenated styrene elastomerics.
2. according to claim 1 being used for penetrated sticking thermoplastic elastomer with the polyamide material, it is characterized in that: wherein, maleic anhydride graft hydrogenated styrene elastomerics accounts for that weight percent is 8%, the hydrogenated styrene elastomerics accounts for that weight percent is 23.8%, polymeric amide accounts for that weight percent is 3%, polyurethane elastomer accounts for that weight percent is 32%, UV light absorber accounts for that weight percent is 0.1%, antioxidant accounts for that weight percent is 0.1%, mineral-filled oil accounts for that weight percent is 30%, to account for weight percent be 6% to inorganic nano-filler.
3. according to claim 1 being used for penetrated sticking thermoplastic elastomer with the polyamide material, it is characterized in that: wherein, maleic anhydride graft hydrogenated styrene elastomerics accounts for that weight percent is 5%, the hydrogenated styrene elastomerics accounts for that weight percent is 22%, polymeric amide accounts for that weight percent is 4%, polyurethane elastomer accounts for that weight percent is 30.5%, UV light absorber accounts for that weight percent is 0.2%, antioxidant accounts for that weight percent is 0.3%, mineral-filled oil accounts for that weight percent is 32%, to account for weight percent be 6% to inorganic nano-filler.
4. according to claim 1 being used for penetrated sticking thermoplastic elastomer with the polyamide material, it is characterized in that: wherein, maleic anhydride graft hydrogenated styrene elastomerics accounts for that weight percent is 3%, the hydrogenated styrene elastomerics accounts for that weight percent is 22%, polymeric amide accounts for that weight percent is 4.2%, polyurethane elastomer accounts for that weight percent is 32%, UV light absorber accounts for that weight percent is 0.4%, antioxidant accounts for that weight percent is 0.4%, mineral-filled oil accounts for that weight percent is 31%, to account for weight percent be 7% to inorganic nano-filler.
5. according to claim 1 being used for penetrated sticking thermoplastic elastomer with the polyamide material, it is characterized in that: described hydrogenated styrene elastomerics is SEBS, SEBS is to be end segment with the polystyrene, the ethylene-butene copolymer that obtains with the polyhutadiene hydrogenation is the triblock copolymer of middle elastomeric block, SEBS does not contain unsaturated double-bond, therefore have satisfactory stability and ageing resistance, model that the present invention adopts is one or any mixed multiple among SEBS G1650, SEBS G1651, SEBS G6933, SEBS 4033, the SEBS 4055.
6. according to claim 1 being used for penetrated sticking thermoplastic elastomer with the polyamide material, it is characterized in that: described antioxidant is anti-oxidant 1010 and anti-oxidant 168 mixtures by 1:1～2 mixed.
7. according to claim 1 being used for penetrated sticking thermoplastic elastomer with the polyamide material, it is characterized in that: described mineral-filled oil is paraffin-base alkanes oil, and its flash-point is more than 200 ℃, and under 25 ℃, viscosity is 15～20Cps.
8. according to claim 1 being used for penetrated sticking thermoplastic elastomer with the polyamide material, it is characterized in that: described inorganic nano-filler is a kind of in the above talcum powder of number 5000 orders, barium sulfate, lime carbonate, the mica powder.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010106118314A CN102134388A (en) | 2010-12-29 | 2010-12-29 | Thermoplastic elastomer to be adhered on polyamide materials |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010106118314A CN102134388A (en) | 2010-12-29 | 2010-12-29 | Thermoplastic elastomer to be adhered on polyamide materials |
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| CN102134388A true CN102134388A (en) | 2011-07-27 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111391275A (en) * | 2020-05-20 | 2020-07-10 | 东莞市山普科技有限公司 | Production process of modified TPE material and modified TPE material |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101747576A (en) * | 2008-12-22 | 2010-06-23 | 上海日之升新技术发展有限公司 | Thermoplastic elastomer composition for bonding PA and preparation method thereof |
| CN101760001A (en) * | 2008-12-19 | 2010-06-30 | 上海日之升新技术发展有限公司 | Thermoplastic elastomer composition for bonding ABS and preparation method thereof |
| CN101845195A (en) * | 2010-05-07 | 2010-09-29 | 浙江俊尔新材料有限公司 | Wear-resistant thermoplastic elastomer and preparation method thereof |
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- 2010-12-29 CN CN2010106118314A patent/CN102134388A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101760001A (en) * | 2008-12-19 | 2010-06-30 | 上海日之升新技术发展有限公司 | Thermoplastic elastomer composition for bonding ABS and preparation method thereof |
| CN101747576A (en) * | 2008-12-22 | 2010-06-23 | 上海日之升新技术发展有限公司 | Thermoplastic elastomer composition for bonding PA and preparation method thereof |
| CN101845195A (en) * | 2010-05-07 | 2010-09-29 | 浙江俊尔新材料有限公司 | Wear-resistant thermoplastic elastomer and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111391275A (en) * | 2020-05-20 | 2020-07-10 | 东莞市山普科技有限公司 | Production process of modified TPE material and modified TPE material |
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Application publication date: 20110727 |