CN102127381A - Traceless adhesive, and traceless free sticker prepared from same - Google Patents
Traceless adhesive, and traceless free sticker prepared from same Download PDFInfo
- Publication number
- CN102127381A CN102127381A CN 201010238723 CN201010238723A CN102127381A CN 102127381 A CN102127381 A CN 102127381A CN 201010238723 CN201010238723 CN 201010238723 CN 201010238723 A CN201010238723 A CN 201010238723A CN 102127381 A CN102127381 A CN 102127381A
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- rubberizing
- layer
- weight part
- laminating layer
- traceless
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Abstract
The invention discloses a traceless adhesive for preparing a traceless free sticker, and a free sticker prepared from the same. The adhesive disclosed by the invention comprises a product prepared by stirring and dispersing a mixture of 16 parts (by weight) of SEBS elastomer, 45-55 parts of white oil, 10-16 parts of titanium white and 1-3 parts of nano activated calcium carbonate at 150-160 DEG C for at least 30 minutes. The sticker disclosed by the invention can be used repeatedly, and can be moved and attached to any other position at any time, thereby achieving the goals of energy saving and environmental protection. The sticker disclosed by the invention can be used on a large-area adhesive pattern, and has the effects of water resistance, oil resistance and dust prevention. After being taken down, the sticker does not leave any trace, and can maintain the original clean surface.
Description
Technical field
The present invention relates to a kind of rubberizing, especially a kind ofly can be used for preparing the rubberizing that seamless random attaching is share product.
Background technology
The laminating type of rubberizing in the market has three kinds, and a kind of is bonding with double faced adhesive tape, and another kind is that glue is bonding, and also having a kind of is that sucked type is bonding.But no matter adopt double faced adhesive tape bonding or glue is bonding, all can only disposablely use, can not move after bonding heavily stickingly, be difficult to recycling.And the bonding circular magnetic chuck that can only use of sucked type, area is little, and use range is narrow.
Summary of the invention
For addressing the above problem, first purpose of the present invention has been to provide a kind of and has can be used for preparing seamless random attaching and share the rubberizing of product, comprise laminating layer of rubberizing and preparation method thereof, and this seamless random attaching share that product can be repeatedly used and suitable big area is bonding.
Second purpose of the present invention is to provide a kind of and is repeatedly used and suitable big area adherent applying articles for use.
For realizing first purpose, rubberizing provided by the present invention comprises the product that is prepared by following preparation method: with the mixture of 16 parts of (weight part) SEBS elastomericss, 45-55 part white oil, 10-16 part titanium dioxide, 1-3 part nm-class active calcium carbonate dispersed with stirring at least 30 minutes and the product that obtains under 150-160 ℃ condition.Preferably, described mixture is under 150-160 ℃ condition dispersed with stirring 30-60 minute.Preferably, also contain at least a in 10-16 part (weight part) jelly wax, 1-3 part white oil tackifier, the 1-3 part polyester resin in the described mixture.Jelly wax, white oil tackifier, polyester resin can significantly further improve the adsorptive power of rubberizing.Above-mentioned various material all can obtain on market.
Rubberizing provided by the present invention has certain softness, and it is ridden on the burnishing surface, can get rid of rubberizing and be reached purpose near vacuum by the air between the veneer, thereby utilize barometric point to be adsorbed on the burnishing surface and do not come off.
The present invention also provides a kind of laminating layer that comprises above-mentioned rubberizing, and described laminating layer also comprises a PET film, and wherein, described rubberizing is being bonded on the described PET film by spraying under 150-160 ℃ the condition.Preferably, described laminating layer also comprises by pressing and sticks to interleaving paper on the rubberizing face of laminating layer.This interleaving paper can be protected the rubberizing face of laminating layer, and making it not be infected with dust or dirt etc. influences the applying effect.
For realizing second purpose, applying articles for use provided by the present invention comprise:
(1) the aforesaid laminating layer that comprises rubberizing; With
(2) be fixed on the subsides thing layer of PET pellicular front one side of laminating layer.
Described subsides thing layer can be hook, distich, pattern, direction board etc.Pasting the thing layer can be fixed on the laminating layer by measures such as glue stickups.Described subsides thing layer can have multilayer, for example, at the side elder generation fixed pattern layer of the PET of laminating layer pellicular front, and then fixes a hook again on patterned layer.
Applying articles for use of the present invention can be repeatedly used, and it is bonding to move to other position at any time, can reach the purpose of energy-conserving and environment-protective.Use the applying articles for use of rubberizing provided by the present invention, can use, also have waterproof, grease proofing dustproof effect in addition at large-area bonding patterns.Do not stay the glue trace after the applying articles for use take off, keep original clean face.Applicable to any smooth burnishing surface, for example glass, ceramic tile, plastic product, oil-base paint face wall and woodwork etc.If the laminating layer of applying articles for use is infected with dust or dirt accidentally, available clear water or soft detergents clean, and dry up with cold wind and to re-use.
Description of drawings
Fig. 1 is the synoptic diagram according to the Traceless hook of a specific embodiment of the present invention;
Fig. 2 is the right view of Traceless hook shown in Figure 1;
Fig. 3 is the partial enlarged drawing of the A part of Traceless hook shown in Figure 2;
Fig. 4 is the exploded view of the each several part of Traceless hook shown in Figure 1.
Embodiment
More specifically, as a specific embodiment of the present invention, rubberizing of the present invention can prepare by the following method: with 16 parts of (weight part) SEBS, 45-55 part white oil, 10-16 part titanium dioxide, 10-16 part jelly wax, 1-3 part white oil tackifier, 1-3 part polyester resin, 1-3 part nm-class active calcium carbonate blending dispersion at least 20 minutes at normal temperatures, so that each component thorough mixing and interpenetrating, then with mixture dispersed with stirring at least 30 minutes and product of obtaining under 160 ℃ condition.Preferably, described mixture is under 160 ℃ condition dispersed with stirring 30-60 minute.
As another embodiment of the present invention, laminating layer of the present invention can prepare by the following method: rubberizing of the present invention under 150-160 ℃ condition, is sprayed to rubberizing on the PET film by the pressure effect.Because the temperature of rubberizing is higher, the rubberizing of spraying directly secure adhesion to the PET film.Those skilled in the art can determine the quantity for spray of rubberizing, the coating thickness of rubberizing etc. according to actual needs.The rubberizing that is sprayed into the PET film can be cooled off under physical environment, and those skilled in the art also can carry out cutting according to actual needs to obtain needed size.The rubberizing face of laminating layer can carry out pressing with the smooth interleaving paper of smooth surface, to reach the purpose of protection rubberizing face.
As another embodiment of the present invention, laminating layer of the present invention can interfix to form applying articles for use of the present invention with subsides thing layer, fixed form for example is, bookbinding bonding with glue or the like fixed form commonly used, and those skilled in the art can freely select fixed form as required.
As illustrated in fig. 1 and 2, be an embodiment of applying articles for use of the present invention, paste thing layer 2 and be adhesively fixed on laminating layer 1 by glue.Figure 4 shows that the exploded view of embodiment shown in Figure 1, wherein paste thing layer 2 and forms by hook 3 and shaft collar 8, what hook 3 and shaft collar 8 can be for one, also can split, still link up with 3 and be fixed on the shaft collar 8.As shown in Figure 3 and Figure 4, laminating layer 1 is made up of patterned layer 4, PET transparent thin film layer 5, sticking adhesive layer 6 and separator paper layer 7.Sticking adhesive layer 6 is bonded to PET transparent thin film layer 5 and forms by rubberizing is sprayed under 160 ℃ temperature.Patterned layer 4 is optionally, mainly is for needs attractive in appearance, and patterned layer is fixed on the PET thin film layer 5 in glue adherent mode.Sticking adhesive layer 6 conforms on the separator paper layer 7 by the mode of pressing, and separator paper layer 7 mainly plays the effect of protector glue-line 6.During use, tear separator paper layer 7,, the applying articles for use are adsorbed on the smooth flat by sticking adhesive layer 6, for example glass, wall etc. by the mode of pressing.
The weight proportion of various raw materials is as follows:
Soft bullet glue material powder (SEBS) (16.95%)
White oil (stone ore oil) (50.85%)
Titanium dioxide (13.55%)
Jelly cured (13.55%)
White oil tackifier (1.7%)
Polyester resin (1.7%)
Nm-class active calcium carbonate (1.7%)
At normal temperatures, above-mentioned materials is mixed; Disperse mutually or infiltration between the various materials so that make.Subsequently in reactor with the mixture heating up to 160 that obtains ℃, and beginning dispersed with stirring 30 minutes, thus obtain the product rubberizing of homogeneous component.
The rubberizing of above-mentioned acquisition under 160 ℃ temperature, is sprayed on the clear PET film by spray gun because the temperature of rubberizing is higher, the rubberizing of spraying directly secure adhesion to the PET film, thereby the formation laminating layer.Can adopt modes such as glue stickup to fix a patterned layer on the PET pellicular front of laminating layer.The rubberizing face of laminating layer can adopt the mode of pressing to adsorb a separator paper layer, with protection rubberizing face.
Hook, distich, random attaching, variable color coloured picture random attaching can be adopted glue adherent mode be fixed to PET pellicular front one side of laminating layer subsequently,, then be fixed on the pattern, share product thereby form non-scar plaster as also having patterned layer on the PET thin film layer.
During use, only need tear separator paper layer, laminating layer is ridden on the burnishing surface, get rid of rubberizing and reached purpose, thereby utilize barometric point that the applying articles for use are adsorbed on the burnishing surface and do not come off near vacuum by the air between the veneer.
The weight proportion of various raw materials is as follows:
Soft bullet glue material powder (SEBS) (16%)
White oil (stone ore oil) (50%)
Titanium dioxide (16%)
Jelly cured (16%)
Nm-class active calcium carbonate (2%)
At normal temperatures, above-mentioned materials is mixed; Disperse mutually or infiltration between the various materials so that make.Subsequently in reactor with the mixture heating up to 150 that obtains ℃, and beginning dispersed with stirring 60 minutes, thus obtain the product rubberizing of homogeneous component.
The rubberizing of above-mentioned acquisition under 160 ℃ temperature, is sprayed on the clear PET film by spray gun because the temperature of rubberizing is higher, the rubberizing of spraying directly secure adhesion to the PET film, thereby the formation laminating layer.Can adopt modes such as glue stickup to fix a patterned layer on the PET pellicular front of laminating layer.The rubberizing face of laminating layer can adopt the mode of pressing to adsorb a separator paper layer, with protection rubberizing face.
Can adopt glue adherent mode to be fixed to PET pellicular front one side of laminating layer hook, distich, random attaching, variable color coloured picture random attaching subsequently,, then be fixed on the pattern, share product thereby form non-scar plaster as on the PET thin film layer pattern being arranged.
During use, only need tear separator paper layer, laminating layer is ridden on the burnishing surface, get rid of rubberizing and reached purpose, thereby utilize barometric point that the applying articles for use are adsorbed on the burnishing surface and do not come off near vacuum by the air between the veneer.
The weight proportion of various raw materials is as follows:
Soft bullet glue material powder (SEBS) (19%)
White oil (stone ore oil) (60%)
Titanium dioxide (19%)
Nm-class active calcium carbonate (2%)
At normal temperatures, above-mentioned materials is mixed; Disperse mutually or infiltration between the various materials so that make.Subsequently in reactor with the mixture heating up to 160 that obtains ℃, and beginning dispersed with stirring 40 minutes, thus obtain the product rubberizing of homogeneous component.
The rubberizing of above-mentioned acquisition under 160 ℃ temperature, is sprayed on the clear PET film by spray gun because the temperature of rubberizing is higher, the rubberizing of spraying directly secure adhesion to the PET film, thereby the formation laminating layer.Can adopt modes such as glue stickup to fix a patterned layer on the PET pellicular front of laminating layer.The rubberizing face of laminating layer can adopt the mode of pressing to adsorb a separator paper layer, with protection rubberizing face.
Can adopt glue adherent mode to be fixed to PET pellicular front one side of laminating layer hook, distich, random attaching, variable color coloured picture random attaching subsequently,, then be fixed on the pattern, share product thereby form non-scar plaster as on the PET thin film layer pattern being arranged.
During use, only need tear separator paper layer, laminating layer is ridden on the burnishing surface, get rid of rubberizing and reached purpose, thereby utilize barometric point that the applying articles for use are adsorbed on the burnishing surface and do not come off near vacuum by the air between the veneer.
The weight proportion of various raw materials is as follows:
Soft bullet glue material powder (SEBS) (16%)
White oil (stone ore oil) (50%)
Titanium dioxide (14%)
Jelly cured (14%)
White oil tackifier (3%)
Nm-class active calcium carbonate (3%)
At normal temperatures, above-mentioned materials is mixed; Disperse mutually or infiltration between the various materials so that make.Subsequently in reactor with the mixture heating up to 160 that obtains ℃, and beginning dispersed with stirring 30 minutes, thus obtain the product rubberizing of homogeneous component.
The rubberizing of above-mentioned acquisition under 160 ℃ temperature, is sprayed on the clear PET film by spray gun because the temperature of rubberizing is higher, the rubberizing of spraying directly secure adhesion to the PET film, thereby the formation laminating layer.Can adopt modes such as glue stickup to fix a patterned layer on the PET pellicular front of laminating layer.The rubberizing face of laminating layer can adopt the mode of pressing to adsorb a separator paper layer, with protection rubberizing face.
Hook, distich, random attaching, variable color coloured picture random attaching can be adopted glue adherent mode be fixed to PET pellicular front one side of laminating layer subsequently,, then be fixed on the pattern, share product thereby form non-scar plaster as also having patterned layer on the PET thin film layer.
During use, only need tear separator paper layer, laminating layer is ridden on the burnishing surface, get rid of rubberizing and reached purpose, thereby utilize barometric point that the applying articles for use are adsorbed on the burnishing surface and do not come off near vacuum by the air between the veneer.
The weight proportion of various raw materials is as follows:
Soft bullet glue material powder (SEBS) (16%)
White oil (stone ore oil) (50%)
Titanium dioxide (14%)
Jelly cured (14%)
Polyester resin (3%)
Nm-class active calcium carbonate (3%)
At normal temperatures, above-mentioned materials is mixed; Disperse mutually or infiltration between the various materials so that make.Subsequently in reactor with the mixture heating up to 160 that obtains ℃, and beginning dispersed with stirring 30 minutes, thus obtain the product rubberizing of homogeneous component.
The rubberizing of above-mentioned acquisition under 160 ℃ temperature, is sprayed on the clear PET film by spray gun because the temperature of rubberizing is higher, the rubberizing of spraying directly secure adhesion to the PET film, thereby the formation laminating layer.Can adopt modes such as glue stickup to fix a patterned layer on the PET pellicular front of laminating layer.The rubberizing face of laminating layer can adopt the mode of pressing to adsorb a separator paper layer, with protection rubberizing face.
Hook, distich, random attaching, variable color coloured picture random attaching can be adopted glue adherent mode be fixed to PET pellicular front one side of laminating layer subsequently,, then be fixed on the pattern, share product thereby form non-scar plaster as also having patterned layer on the PET thin film layer.
During use, only need tear separator paper layer, laminating layer is ridden on the burnishing surface, get rid of rubberizing and reached purpose, thereby utilize barometric point that the applying articles for use are adsorbed on the burnishing surface and do not come off near vacuum by the air between the veneer.
Claims (9)
1. rubberizing comprises the product that is prepared by following preparation method: with the mixture of 16 parts of (weight part) SEBS elastomericss, 45-55 part (weight part) white oil, 10-16 part (weight part) titanium dioxide, 1-3 part (weight part) nm-class active calcium carbonate dispersed with stirring at least 30 minutes and the product that obtains under 150-160 ℃ condition.
2. rubberizing according to claim 1 is characterized in that, among the described preparation method, and described mixture under 150-160 ℃ condition dispersed with stirring 30-60 minute.
3. rubberizing according to claim 1 is characterized in that, is stirred also to contain at least a in 10-16 part (weight part) jelly wax, 1-3 part (weight part) white oil tackifier, 1-3 part (weight part) polyester resin in the described mixture of dispersive.
4. laminating layer, comprise a sticking adhesive layer and the PET film formed by arbitrary described rubberizing among the claim 1-3, wherein, described rubberizing forms the sticking adhesive layer that is compounded on the PET film being bonded to by spraying under 150-160 ℃ the condition on the described PET film.
5. laminating layer according to claim 4 is characterized in that, also comprises a separator paper layer, thereby described separator paper layer sticks on the rubberizing face under the barometric point effect with the air of removing between separator paper layer and the rubberizing by riding in the rubberizing.
6. applying articles for use comprise:
(1) as claim 4 or 5 described laminating layer; With
(2) be fixed on the subsides thing layer of PET pellicular front one side of laminating layer.
7. applying articles for use according to claim 6 is characterized in that, described subsides thing layer is hook, distich, pattern or direction board.
8. applying articles for use according to claim 6 is characterized in that, described subsides thing layer is made up of pattern on the PET film that is fixed on laminating layer and the hook that is fixed on the described pattern.
9. according to arbitrary described applying articles for use among the claim 6-8, it is characterized in that described fixed form is for to fix by the glue bonding method.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010102387237A CN102127381B (en) | 2010-07-28 | 2010-07-28 | Traceless adhesive, and traceless free sticker prepared from same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010102387237A CN102127381B (en) | 2010-07-28 | 2010-07-28 | Traceless adhesive, and traceless free sticker prepared from same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102127381A true CN102127381A (en) | 2011-07-20 |
| CN102127381B CN102127381B (en) | 2012-08-15 |
Family
ID=44265658
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2010102387237A Active CN102127381B (en) | 2010-07-28 | 2010-07-28 | Traceless adhesive, and traceless free sticker prepared from same |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102127381B (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104616591A (en) * | 2015-01-10 | 2015-05-13 | 东莞市想联实业投资有限公司 | Anti-counterfeit label and manufacturing method thereof |
| CN105131852A (en) * | 2015-09-09 | 2015-12-09 | 王涛 | Removable traceless glue and manufacturing process thereof |
| CN105462522A (en) * | 2015-12-18 | 2016-04-06 | 宁波市怡达胶粘制品有限公司 | Adhesive for hook and hook comprising adhesive and application thereof |
| WO2017155644A1 (en) | 2016-03-10 | 2017-09-14 | 3M Innovative Properties Company | Oil resistant adhesive |
| CN109648936A (en) * | 2017-10-12 | 2019-04-19 | 张继援 | A kind of repeated adhering diaphragm |
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| CN1587340A (en) * | 2004-07-09 | 2005-03-02 | 清华大学 | High heat conductive fixed phase change heat storage material suitable for large scale industrial production |
| CN1907575A (en) * | 2006-08-16 | 2007-02-07 | 南京金亚铝箔包装有限公司 | Fabrication method of aluminum foil for hairdressing |
| CN201424451Y (en) * | 2009-06-11 | 2010-03-17 | 上海彩尚实业有限公司 | Sticking film for sticking corner |
| CN101730728A (en) * | 2007-06-29 | 2010-06-09 | 博斯蒂克股份公司 | But the HMPSA that is used for the self-adhesive label of unsticking |
| CN101772556A (en) * | 2007-08-03 | 2010-07-07 | 琳得科株式会社 | Easily attachable adhesive sheet and method for producing the same |
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2010
- 2010-07-28 CN CN2010102387237A patent/CN102127381B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1587340A (en) * | 2004-07-09 | 2005-03-02 | 清华大学 | High heat conductive fixed phase change heat storage material suitable for large scale industrial production |
| CN1907575A (en) * | 2006-08-16 | 2007-02-07 | 南京金亚铝箔包装有限公司 | Fabrication method of aluminum foil for hairdressing |
| CN101730728A (en) * | 2007-06-29 | 2010-06-09 | 博斯蒂克股份公司 | But the HMPSA that is used for the self-adhesive label of unsticking |
| CN101772556A (en) * | 2007-08-03 | 2010-07-07 | 琳得科株式会社 | Easily attachable adhesive sheet and method for producing the same |
| CN201424451Y (en) * | 2009-06-11 | 2010-03-17 | 上海彩尚实业有限公司 | Sticking film for sticking corner |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104616591A (en) * | 2015-01-10 | 2015-05-13 | 东莞市想联实业投资有限公司 | Anti-counterfeit label and manufacturing method thereof |
| CN104616591B (en) * | 2015-01-10 | 2019-01-01 | 东莞市想联实业投资有限公司 | A kind of antifalsification label and preparation method thereof |
| CN105131852A (en) * | 2015-09-09 | 2015-12-09 | 王涛 | Removable traceless glue and manufacturing process thereof |
| CN105462522A (en) * | 2015-12-18 | 2016-04-06 | 宁波市怡达胶粘制品有限公司 | Adhesive for hook and hook comprising adhesive and application thereof |
| CN105462522B (en) * | 2015-12-18 | 2017-06-27 | 宁波市怡达胶粘制品有限公司 | A kind of hook adhesive and the hook comprising the adhesive and its application |
| WO2017155644A1 (en) | 2016-03-10 | 2017-09-14 | 3M Innovative Properties Company | Oil resistant adhesive |
| US10947423B2 (en) | 2016-03-10 | 2021-03-16 | 3M Innovative Properties Company | Oil resistant adhesive |
| CN109648936A (en) * | 2017-10-12 | 2019-04-19 | 张继援 | A kind of repeated adhering diaphragm |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102127381B (en) | 2012-08-15 |
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