CN102126772A - Electroabsorption desalting regeneration system and regeneration method - Google Patents
Electroabsorption desalting regeneration system and regeneration method Download PDFInfo
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- CN102126772A CN102126772A CN 201110075134 CN201110075134A CN102126772A CN 102126772 A CN102126772 A CN 102126772A CN 201110075134 CN201110075134 CN 201110075134 CN 201110075134 A CN201110075134 A CN 201110075134A CN 102126772 A CN102126772 A CN 102126772A
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Abstract
The invention discloses an electroadsorption desalting regeneration system and an electroadsorption desalting regeneration method, which relate to the field of sewage treatment and are used for solving the problem of a relative poor regeneration effect of an electroadsorption module in the prior art. The system comprises an electroadsorption module to be regenerated, an acid water tank for storing acid liquor, an acid-washing short connected regeneration unit for washing the electroadsorption module by using the acid liquor in the acid water tank, an acid discharging unit for discharging the acid liquor generated after the washing of the acid-washing short connected regeneration unit, a water tank for storing water, a regeneration washing unit for washing the electroadsorption module by using the water stored in the water tank, and a drainage unit for draining the water generated after the washing of the regeneration washing unit. The method comprises the following steps of: performing acid-washing regeneration; discharging the acid liquor; performing regeneration washing; and draining the water. In the invention, an acid-washing regeneration process is added, so that positive ions on a group of the electroadsorption module can be completely displaced to fulfill the aim of complete regeneration.
Description
Technical field
The present invention relates to sewage treatment area, particularly relate to a kind of electro-adsorption demineralization regeneration system rapidly and renovation process.
Background technology
Along with development economic and society, the human on the one hand demand and the requirement of quality to water is more and more higher, and on the other hand, scope and degree that water pollutes are also increasing.
The electro-adsorption demineralization technology is as a kind of water technology, and its total technical process is divided into 3 parts, and workflow, short circuit leave standstill flow process, short circuit regeneration flow process.Workflow is to make electrode of opposite sheet logical positive negative electricity in position in the module, utilizes the potential difference between the electrode slice to adsorb the interior zwitterion of former water, reaches the purpose that purifies former water, and at this moment, the pH value is lower near the anodal electrode slice, shows acid; The pH value is higher near the electrode slice of negative pole, shows alkalescence.The water outlet of electro-adsorption module promptly is the product water of electro-adsorption demineralization system in this process; It is with electrode slice positive and negative electrode short circuit that short circuit leaves standstill flow process, because the electromotive force of absorption zwitterion disappears, zwitterion meeting desorption is in module channels; Short circuit regeneration flow process is that water is gone out the electro-adsorption module with desorption in the short circuit process to the whole ions in the passage, makes it to obtain regeneration.
Use existing electro-adsorption system process, find through secular actual motion, significantly decrease, trace it to its cause with the desalination rate that begins to compare the electro-adsorption module, along with electrode lengthening duration of service, the surface has produced the acidic-group that has ion-exchange in a large number.This kind group has the function of similar ion-exchange, that is: electrode slice is placed the lower solution of pH value, the positively charged ion generation permutoid reaction of hydrogen ion energy and the absorption of electrode surface group in the solution, hydrogen ion is adsorbed by electrode slice, and the cation concn of bulk solution raises; Again electrode slice is inserted the pH value in the neutral salts solution, the hydrogen ion of electrode surface group absorption again can with the positively charged ion generation permutoid reaction in the solution, positively charged ion is adsorbed by the electrode slice group, the pH value reduction of solution.This behavior shows in the module routine, during work, shows acid because electrode slice is anodal that is:, the pH value is lower, and the positively charged ion that adsorbs on the electrode slice group can be exchanged in the original solution by hydrogen ion, and the cation concn of original solution is raise, go out water concentration and raise, influence clearance.And in regenerative process, solution is neutral near the electrode slice, and the positively charged ion in the solution can come back on the electrode slice positively charged ion by the exchange of the hydrogen ion on the electrode slice group, influences regeneration effect.Formed the process of adsorbing---desorption---absorption contrary with the electro-adsorption module.Cause electro-adsorption module adsorption efficiency to descend.
Summary of the invention
The invention provides a kind of electro-adsorption demineralization regeneration system rapidly and renovation process, in order to solve the relatively poor problem of electro-adsorption module regeneration effect of prior art.
System of the present invention comprises: treat regenerated electro-adsorption module; The sour water case is used to store acid solution; Pickling short circuit regeneration unit is used for cleaning above-mentioned electro-adsorption module with the acid solution of sour water case storage; The acid discharge unit is used to discharge the acid solution that is produced after pickling short circuit regeneration unit cleans; Water tank is used for storage of water; Regeneration flushing unit is used for washing above-mentioned electro-adsorption module with the water of water tank storage; Drainage cell is used to discharge the water that is produced after regeneration flushing unit flushing.
Further, also comprise: timing unit is used to control the duration that regeneration flushing unit washes above-mentioned electro-adsorption module.
Further, also comprise: acid solution reclaims the unit, is used to reclaim the residue acid solution that discharge the acid discharge unit.
Further, also comprise: water reclaims the unit, is used to reclaim the water that drainage cell is discharged.
Method of the present invention comprises the following steps: pickling regenerated step: the electro-adsorption module of cleaning the electro-adsorption demineralization system with acid solution; The step of acid discharge: discharge the acid solution that is produced through above-mentioned pickling regeneration step; The step of regeneration flushing: the electro-adsorption module of washing described electro-adsorption demineralization system with water; The step of draining: discharge the water that is produced through above-mentioned regeneration rinse step.
Further, in described regeneration rinse step, the electro-adsorption module of described electro-adsorption demineralization system is washed with default duration.
Further, also comprise the step that reclaims acid solution: reclaim the residue acid solution that described acid discharge step is discharged.
Further, the step that also comprises recycle-water: reclaim the water that described drain step is discharged.
Beneficial effect of the present invention is as follows:
In the existing electro-adsorption module reclaiming process, owing to do not have pickling this process of regenerating, so the positively charged ion that adsorbs on the electro-adsorption module can not cement out fully.The present invention has increased the pickling regenerative process, therefore the positively charged ion on the group of electro-adsorption module can be cemented out fully, reaches thorough regenerated purpose.As seen, the present invention can guarantee the long-term continous-stable operation of electro-adsorption demineralization system.
Description of drawings
Fig. 1 is the system architecture synoptic diagram of the embodiment of the invention;
Fig. 2 is the system architecture synoptic diagram of another embodiment of the present invention;
Fig. 3 is the method steps schema of the embodiment of the invention;
Fig. 4 is the method steps schema of another embodiment of the present invention.
Embodiment
Regeneration effect for the electro-adsorption module that promotes the electro-adsorption demineralization system, after the short circuit process in the prior art (after being the positive and negative electrode short circuit, positive pole is emitted negatively charged ion, negative pole is emitted positively charged ion, the negative ions of electro-adsorption process absorption is discharged in the bulk solution), the invention provides a kind of embodiment of electro-adsorption demineralization regeneration system rapidly, referring to shown in Figure 1, it comprises:
Treat regenerated electro-adsorption module 101.
Pickling short circuit regeneration unit 103, be used for acid solution feeding electro-adsorption module 101 with the certain pH value of sour water case 102 storages, hydrogen ion in the acid solution gets off the cation replacement on the electrode surface group, make electrode surface group absorption hydrogen ion, cation concn in the acid solution is raise, reach the purpose of regeneration electro-adsorption module 101 electrodes.
The acid solution that is produced after for some time, is discharged in acid discharge unit 104 after pickling short circuit regeneration unit 103 cleans.
In specific implementation, can realize pouring into, discharging of acid solution by motor-mount pump or other modes.
As seen, present embodiment has increased sour water case 102, pickling short circuit regeneration unit 103 and acid discharge unit 104 at least with respect to prior art, has promptly increased the process of pickling.Therefore, reached the purpose that promotes electro-adsorption module regeneration effect, seen for details above-mentioned.
Further, for the electro-adsorption module of long term operation, two kinds of effects can appear during work.The one, the electro-adsorption effect: former water is by between the positive and negative electrode of electro-adsorption module, and wherein negatively charged ion is adsorbed by positive pole, and positively charged ion is adsorbed by negative pole.This process makes former water desalination, reaches the purification purpose.Because the regeneration effect of electro-adsorption module of the present invention is better, so the desalination rate is high than prior art.Another kind of effect is: hydrogen ion on the positive and negative electrode sheet group of electro-adsorption module and the positively charged ion generation exchange interaction in the former water; group absorption positively charged ion; hydrogen ion is displaced to former acidity of water is increased, the basicity neutralization in common meeting of this part acidity of increase and the water.This process can be removed anhydrate middle-jiao yang, function of the spleen and stomach ion and basicity, reaches the purpose of purification.Owing to after the acid cleaning process, attached a large amount of hydrogen ions on the electro-adsorption module electrodes, therefore cationic exchange interaction (promptly adsorbing cationic effect) in above-mentioned hydrogen ion and the former water, and acid-base neutralisation effect all than prior art for well.
To sum up, present embodiment can guarantee the operation of the long-term continous-stable of electro-adsorption demineralization system.
The present invention also provides another embodiment of a kind of electro-adsorption demineralization regeneration system rapidly, referring to shown in Figure 2, comprising:
Treat regenerated electro-adsorption module 201.
Sour water case 202 is used to store acid solution.
Pickling short circuit regeneration unit 203, be used for acid solution feeding electro-adsorption module 201 with the certain pH value of sour water case 202 storages, hydrogen ion in the acid solution gets off the cation replacement on the electrode surface group, make electrode surface group absorption hydrogen ion, cation concn in the acid solution is raise, reach the purpose of regeneration electro-adsorption module 201 electrodes.
The acid solution that is produced after for some time, is discharged in acid discharge unit 204 after pickling short circuit regeneration unit 203 cleans.
Water tank 205 is used for storage of water.
Regeneration flushing unit 206, mode by the concentration diffusion, water with water tank 205 storage washes above-mentioned electro-adsorption module 201, and short circuit process and pickling short circuit this two ions that the stage bears again of regenerating are gone out electro-adsorption module 201, reaches the purpose of thorough regeneration electro-adsorption module 201.
Drainage cell 207 is used to discharge the water that is produced after 206 flushings of regeneration flushing unit.
Timing unit 208 is used to control the duration that the 206 pairs of above-mentioned electro-adsorption modules 201 in regeneration flushing unit are washed.
Acid solution reclaims unit 209, is used to reclaim the residue acid solution that discharge acid discharge unit 204.
Water reclaims unit 210, is used to reclaim the water that drainage cell 207 is discharged.
In specific implementation, can realize pouring into, discharging of acid solution by motor-mount pump or other modes.Can pass through PLC (Programmable Logic Controller, programmable logic controller) or timer etc. realizes regularly.
As seen, present embodiment has increased sour water case 202, pickling short circuit regeneration unit 203 and acid discharge unit 204 at least with respect to prior art, has promptly increased the process of pickling; And timing unit 208, acid solution recovery unit 209 and water reclaim unit 210.Therefore, reached the purpose that promotes electro-adsorption module regeneration effect, seen for details above-mentioned.
Further, for the electro-adsorption module of long term operation, two kinds of effects can appear during work.The one, the electro-adsorption effect: former water is by between the positive and negative electrode of electro-adsorption module, and wherein negatively charged ion is adsorbed by positive pole, and positively charged ion is adsorbed by negative pole.This process makes former water desalination, reaches the purification purpose.Because the regeneration effect of electro-adsorption module of the present invention is better, so the desalination rate is high than prior art.Another kind of effect is: hydrogen ion on the positive and negative electrode sheet group of electro-adsorption module and the positively charged ion generation exchange interaction in the former water; group absorption positively charged ion; hydrogen ion is displaced to former acidity of water is increased, the basicity neutralization in common meeting of this part acidity of increase and the water.This process can be removed anhydrate middle-jiao yang, function of the spleen and stomach ion and basicity, reaches the purpose of purification.Owing to after the acid cleaning process, attached a large amount of hydrogen ions on the electro-adsorption module electrodes, therefore cationic exchange interaction (promptly adsorbing cationic effect) in above-mentioned hydrogen ion and the former water, and acid-base neutralisation effect all than prior art for well.
Further, control can be optimized regeneration effect to the duration of electro-adsorption module flushing, and water consumption.Reclaim the residue acid solution and the water of discharging, so that recycling economizes on resources.
To sum up, present embodiment can guarantee the operation of the long-term continous-stable of electro-adsorption demineralization system.
The present invention also provides a kind of embodiment of electro-adsorption demineralization renovation process, referring to shown in Figure 3, comprises the following steps:
S301, the electro-adsorption module of cleaning the electro-adsorption demineralization system with acid solution.
Concrete, acid solution with certain pH value feeds in the electro-adsorption module, and the hydrogen ion in the acid solution gets off the cation replacement on the electrode surface group, makes electrode surface group absorption hydrogen ion, cation concn in the acid solution is raise, reach the purpose of regeneration electro-adsorption module electrodes.
S302, after for some time, discharge through pickling regeneration and clean the acid solution that is produced.
S303, with the electro-adsorption module of water flushing electro-adsorption demineralization system.
Concrete, by the mode of concentration diffusion,, short circuit process and pickling short circuit this two ions that the stage bears again of regenerating are gone out the electro-adsorption module with water flushing electro-adsorption module, reach the purpose of thorough regeneration electro-adsorption module.
The water that S304, discharge are produced through the regeneration flushing.
In specific implementation, can realize pouring into, discharging of acid solution by motor-mount pump or other modes.
As seen, present embodiment has increased step S301 and S302 at least with respect to prior art, has promptly increased the process of pickling.Therefore, reached the purpose that promotes electro-adsorption module regeneration effect, seen for details above-mentioned.
Further, for the electro-adsorption module of long term operation, two kinds of effects can appear during work.The one, the electro-adsorption effect: former water is by between the positive and negative electrode of electro-adsorption module, and wherein negatively charged ion is adsorbed by positive pole, and positively charged ion is adsorbed by negative pole.This process makes former water desalination, reaches the purification purpose.Because the regeneration effect of electro-adsorption module of the present invention is better, so the desalination rate is high than prior art.Another kind of effect is: hydrogen ion on the positive and negative electrode sheet group of electro-adsorption module and the positively charged ion generation exchange interaction in the former water; group absorption positively charged ion; hydrogen ion is displaced to former acidity of water is increased, the basicity neutralization in common meeting of this part acidity of increase and the water.This process can be removed anhydrate middle-jiao yang, function of the spleen and stomach ion and basicity, reaches the purpose of purification.Owing to after the acid cleaning process, attached a large amount of hydrogen ions on the electro-adsorption module electrodes, therefore cationic exchange interaction (promptly adsorbing cationic effect) in above-mentioned hydrogen ion and the former water, and acid-base neutralisation effect all than prior art for well.
To sum up, present embodiment can guarantee the operation of the long-term continous-stable of electro-adsorption demineralization system.
The present invention also provides another embodiment of a kind of electro-adsorption demineralization renovation process, referring to shown in Figure 4, comprises the following steps:
S401, the electro-adsorption module of cleaning the electro-adsorption demineralization system with acid solution.
Concrete, acid solution with certain pH value feeds in the electro-adsorption module, and the hydrogen ion in the acid solution gets off the cation replacement on the electrode surface group, makes electrode surface group absorption hydrogen ion, cation concn in the acid solution is raise, reach the purpose of regeneration electro-adsorption module electrodes.
S402, after for some time, discharge through pickling regeneration and clean the acid solution that is produced.
The residue acid solution that S403, recovery are discharged.
S404, with the electro-adsorption module of water flushing electro-adsorption demineralization system.
Concrete, by the mode of concentration diffusion, the electro-adsorption module is washed with default duration water.Short circuit process and pickling short circuit this two ions that the stage bears again of regenerating are gone out the electro-adsorption module, reach the purpose of thorough regeneration electro-adsorption module.
The water that S405, discharge are produced through the regeneration flushing.
The water that S406, recovery are discharged.
In specific implementation, can realize pouring into, discharging of acid solution by motor-mount pump or other modes.Can realize regularly by PLC or timer etc.
As seen, present embodiment has increased S401, S402 at least with respect to prior art, has promptly increased the process of pickling; And the timing content among step S403, the S404, and S406.Therefore, reached the purpose that promotes electro-adsorption module regeneration effect, seen for details above-mentioned.
Further, for the electro-adsorption module of long term operation, two kinds of effects can appear during work.The one, the electro-adsorption effect: former water is by between the positive and negative electrode of electro-adsorption module, and wherein negatively charged ion is adsorbed by positive pole, and positively charged ion is adsorbed by negative pole.This process makes former water desalination, reaches the purification purpose.Because the regeneration effect of electro-adsorption module of the present invention is better, so the desalination rate is high than prior art.Another kind of effect is: hydrogen ion on the positive and negative electrode sheet group of electro-adsorption module and the positively charged ion generation exchange interaction in the former water; group absorption positively charged ion; hydrogen ion is displaced to former acidity of water is increased, the basicity neutralization in common meeting of this part acidity of increase and the water.This process can be removed anhydrate middle-jiao yang, function of the spleen and stomach ion and basicity, reaches the purpose of purification.Owing to after the acid cleaning process, attached a large amount of hydrogen ions on the electro-adsorption module electrodes, therefore cationic exchange interaction (promptly adsorbing cationic effect) in above-mentioned hydrogen ion and the former water, and acid-base neutralisation effect all than prior art for well.
Further, control can be optimized regeneration effect to the duration of electro-adsorption module flushing, and water consumption.Reclaim the residue acid solution and the water of discharging, so that recycling economizes on resources.
To sum up, present embodiment can guarantee the operation of the long-term continous-stable of electro-adsorption demineralization system.
Can know that with the system actual motion the present invention is more thorough to the regeneration of electro-adsorption module by experiment.Do not taking before this technology, electro-adsorption module desalting efficiency descends significantly, removes decrease in efficiency 10% in 3 months, adopts technology of the present invention, and after system moved 6 months continuously, the clearance of electro-adsorption module was not seen obvious decline.
Obviously, those skilled in the art can carry out various changes and modification and not break away from the spirit and scope of the present invention the present invention, for example: increased another regeneration flushing process before acid cleaning process, again for example: increase pickling number of times etc.Like this, if of the present invention these are revised and modification belongs within the scope of claim of the present invention and equivalent technologies thereof, then the present invention also is intended to comprise these changes and modification interior.
Claims (8)
1. electro-adsorption demineralization regeneration system rapidly comprises: treat regenerated electro-adsorption module, it is characterized in that, also comprise:
The sour water case is used to store acid solution;
Pickling short circuit regeneration unit is used for cleaning above-mentioned electro-adsorption module with the acid solution of sour water case storage;
The acid discharge unit is used to discharge the acid solution that is produced after pickling short circuit regeneration unit cleans;
Water tank is used for storage of water;
Regeneration flushing unit is used for washing above-mentioned electro-adsorption module with the water of water tank storage;
Drainage cell is used to discharge the water that is produced after regeneration flushing unit flushing.
2. electro-adsorption demineralization regeneration system rapidly as claimed in claim 1 is characterized in that, also comprises:
Timing unit is used to control the duration that regeneration flushing unit washes above-mentioned electro-adsorption module.
3. electro-adsorption demineralization regeneration system rapidly as claimed in claim 1 is characterized in that, also comprises:
Acid solution reclaims the unit, is used to reclaim the residue acid solution that discharge the acid discharge unit.
4. electro-adsorption demineralization regeneration system rapidly as claimed in claim 1 is characterized in that, also comprises:
Water reclaims the unit, is used to reclaim the water that drainage cell is discharged.
5. an electro-adsorption demineralization renovation process is characterized in that, comprises the following steps:
Pickling regenerated step: the electro-adsorption module of cleaning the electro-adsorption demineralization system with acid solution;
The step of acid discharge: discharge the acid solution that is produced through above-mentioned pickling regeneration step;
The step of regeneration flushing: the electro-adsorption module of washing described electro-adsorption demineralization system with water;
The step of draining: discharge the water that is produced through above-mentioned regeneration rinse step.
6. electro-adsorption demineralization renovation process as claimed in claim 5 is characterized in that, in described regeneration rinse step, with default duration the electro-adsorption module of described electro-adsorption demineralization system is washed.
7. electro-adsorption demineralization renovation process as claimed in claim 5 is characterized in that, also comprises the step that reclaims acid solution: the residue acid solution that reclaims the step discharge of described acid discharge.
8. electro-adsorption demineralization renovation process as claimed in claim 5 is characterized in that, also comprises the step of recycle-water: the water that reclaims the step discharge of described draining.
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CN102603040A (en) * | 2012-03-30 | 2012-07-25 | 中国石油化工股份有限公司 | Processing method for electro-adsorption demineralized water |
CN106673276A (en) * | 2017-03-13 | 2017-05-17 | 盐城工学院 | Apparatus for treating high-salinity wastewater jointly by photoelectric catalytic oxidation and electric adsorption |
CN106830453A (en) * | 2017-03-13 | 2017-06-13 | 盐城工学院 | The method and apparatus of photoelectrocatalysioxidization oxidization Electro Sorb collaboration treatment high-salt wastewater |
CN110395828A (en) * | 2019-08-28 | 2019-11-01 | 宝钢工程技术集团有限公司 | A kind of cold rolling wastewater desalting system and method |
CN114275858A (en) * | 2022-01-27 | 2022-04-05 | 中国华能集团清洁能源技术研究院有限公司 | Plug flow type electrolytic descaling system and method |
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CN114275858A (en) * | 2022-01-27 | 2022-04-05 | 中国华能集团清洁能源技术研究院有限公司 | Plug flow type electrolytic descaling system and method |
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