CN1021256C - Ph meter - Google Patents
Ph meter Download PDFInfo
- Publication number
- CN1021256C CN1021256C CN 90106980 CN90106980A CN1021256C CN 1021256 C CN1021256 C CN 1021256C CN 90106980 CN90106980 CN 90106980 CN 90106980 A CN90106980 A CN 90106980A CN 1021256 C CN1021256 C CN 1021256C
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- CN
- China
- Prior art keywords
- analog
- microcomputer
- output
- digital converter
- amplifier
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000005259 measurement Methods 0.000 claims description 14
- 238000006243 chemical reaction Methods 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 3
- 238000012545 processing Methods 0.000 claims description 2
- 230000008023 solidification Effects 0.000 claims 1
- 239000007853 buffer solution Substances 0.000 abstract description 11
- 239000000243 solution Substances 0.000 abstract description 7
- 230000008901 benefit Effects 0.000 abstract description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 230000006870 function Effects 0.000 description 8
- 230000003321 amplification Effects 0.000 description 4
- 238000003199 nucleic acid amplification method Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 239000004065 semiconductor Substances 0.000 description 3
- 238000013461 design Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 230000008520 organization Effects 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 238000004164 analytical calibration Methods 0.000 description 1
- 238000009529 body temperature measurement Methods 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 238000013016 damping Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000001139 pH measurement Methods 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- IWZKICVEHNUQTL-UHFFFAOYSA-M potassium hydrogen phthalate Chemical compound [K+].OC(=O)C1=CC=CC=C1C([O-])=O IWZKICVEHNUQTL-UHFFFAOYSA-M 0.000 description 1
- JMTCDHVHZSGGJA-UHFFFAOYSA-M potassium hydrogenoxalate Chemical compound [K+].OC(=O)C([O-])=O JMTCDHVHZSGGJA-UHFFFAOYSA-M 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
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- Investigating Or Analyzing Materials By The Use Of Electric Means (AREA)
Abstract
The present invention relates to an instrument for measuring solution acidity. The instrument is mainly characterized in that through the only two operation keys, the electrode potential (mV), the solution pH value, the temperature and other parameters can be measured, and the automatic compensation of the temperature, electrodes and a standard buffer solution can be realized. The eight work states of eight light emitting diode indicating instruments are used in the instrument of the present invention. The present invention has the advantages of intelligence, high precision, simple structure, stable and reliable work, convenient operation, low manufacture cost, and convenient popularization and application.
Description
The invention belongs to the surveying instrument to solution acidity (pH value).
The pH meter of measuring solution acidity is widely used in fields such as chemical industry, medical treatment, biology, environmental protection.Intelligent pH meter is the upgraded product of traditional pH meter.The system controlled by computer metering circuit is sampled to temperature and pH electrode potential, tries to achieve correction factor with numerical evaluation again and compensates automatically.Saved manual temperature compensation, electrode slope and three regulator potentiometers of demarcation, made that instrument calibration process and measurement are comparatively convenient, and automatic spell-checking facility is arranged.The instrument that prior art can be measured pH value and band microcomputer has two classes: a class is to survey the pH value, claims pH meter; Another kind of title ionometer can also be measured multivalent ion concentration except that can measuring the pH value.But pH meter is usually with the keyswitch more than four, at least tens of ionometer buttons, operating switch is many, reliability is low, complex structure, the cost height, and during ion instrumentation pH value, the standard buffer solution pH value of calibration is input to numerical value in the instrument by keyboard after needing manually to table look-up according to solution temperature, inconvenient operation, Olin Corp (ORION RESEARCH INCORPORATED) 811 type pH meters for example, but its potential electrode current potential, the pH value, temperature, electrode conversion ratio (slope), but the function switch of regular use has adopted the many thumbwheel switches in contact, shorter than single contact switch life, poor reliability; And this instrument adopts two single chip microcomputers, and respectively electrode potential and temperature is sampled with two analog to digital converters (ADC), and is with this circuit structure complexity, with high costs.
The purpose of the invention is to manufacture and design a kind of employing a slice single chip microcomputer and a small amount of peripheral circuit, and the pH meter of two operation push-buttons is only arranged, and it can finish the function that prior art need adopt a plurality of operating switchs, complicated circuit to realize.Reduce button and make that instrument reliability improves, circuit structure is simple, easy to operate.
The main contents of the invention organization plan: the current potential of the pH electrode that will contact 1 output with solution through impedance transformer 2 and amplifier 3,4 output voltages to analog switch 7; The current signal of temperature sensor 5 outputs is also sent into analog switch 7 through amplifier 6; Only need then by two buttons 11,12 of operation, single chip microcomputer circuit 9 need to select the parameter (comprising mv value, pH value, temperature) of test to measure by the specific program control analog switch of finishing 7.Convert simulating signal to digital signal through analog to digital converter 8, again the binary-coded decimal of converter output is changed and numerical evaluation through single chip microcomputer, and with scan mode test result is presented on the charactron 12, for the stable case of the duty of instrument and the data of surveying by function and status displays 13 demonstrations.The present invention adopts 8 kinds of duties of 8 LEDs (13b) indicating instrument.
The organization plan that invention will be further ex-plained with reference to the appended drawings creates:
Fig. 1 is the general structure block scheme of the invention pH meter.Fig. 2 is a multichannel analog to digital converter basic circuit diagram.Fig. 3 is a single chip microcomputer basic structure synoptic diagram.Symbolic significance is among the figure: the 1-pH electrode, the 2-impedance transformer, the 3-amplifier, the 4-amplifier, the 5-semiconductor temperature sensor, the 6-amplifier, the 7-analog switch, the 8-analog to digital converter, 9-single chip microcomputer circuit, wherein 9a is 8031CPU, 9b is latch 74LS373,9c is read-only memory 2732EPROM, 9d is EingangsAusgangsSchnittstelle 8255A able to programme, the 10-function key, 11-is provided with key, the 12-nixie display, wherein 12a is driving circuit 74LS06,12b is four seven segment digital tubes, 13-function and status displays, wherein 13a is 3-8 code translator 74LS138,13b is eight LED light emitting diodes, the NPN triode that 13c shows for the promotion state, 13d is a LED light emitting diode.
As shown in Figure 1, the current potential of pH electrode 1 output is given analog switch 7 through impedance transformer 2, amplifier 3 and the voltage of the different requirements of the amplifier 4 various test parameters of output; The current signal of semiconductor temperature sensor 5 outputs also is input to analog switch 7 through amplifier 6.Making 8031 single-chip microcomputers, 9 follow procedures require to control analog switch 7 through function key 10 or operation that key 11 is set measures to select the parameter of being surveyed, convert simulating signal to digital signal through analog to digital converter 8, binary-coded decimal with analog to digital converter output carries out data processing through single-chip microcomputer 9 again, and the result is presented on 4 LED charactron 12b, but by the stable case of function and status displays 13 indicating instrument duties and measurement data with scan mode.
According to shown in Figure 2, can clearly demonstrate the circuit theory of multichannel analog to digital converter.The current potential of pH electrode 1 output is earlier through impedance transformer 2(CA3140 high resistance operating amplifier) output potential is resolution 1mV shelves signals, be input to operational amplifier (LM747) 3 and 4 respectively by the voltage of impedance transformer output and carry out voltage amplification, measure grade signal as resolution 0.1mV shelves and pH value and import analog converter 7(CD4051 respectively) 14 pin and 13 pin.Semiconductor temperature sensor 5(AD590) Shu Chu current signal is through I/V converter 6(LM741 operational amplifier) as temperature measurement signal, this signal is transported to 15 pin of analog switch 7.1.5 pin of analog switch 7 connect reference voltage, 2.4 pin ground connection, as the normal voltage of self check analog to digital converter input.Analog switch 7 is subjected to single-chip microcomputer 9a(8031) P
1.5, P
1.6And P
1.7The control of pin can be selected the measurement of pH, 0.1mV, 1mV and all parameters of temperature, analog switch 7 and a slice high-precision adc 8(5G1443) be connected, can realize the measurement of multiple parameters.
The full journey of the work of analog to digital converter 8 is ± 1999mV that resolution is ± 1mV.The enlargement factor of impedance transformer 2 is 1, thus from its output the direct input analog-to-digital converter 8 of voltage, its measurement range is ± 1999 ± 1mV; And amplifier 3 voltage amplification factors are 10 times, so its measurement range becomes ± 199.9 ± 0.1mV; About 4 times of amplifier 4 voltage amplification factors.Measure the pH value for the dynamic range that makes full use of this analog to digital converter, the analog-to-digital conversion definition of pH value reaches ± 0.005pH.I/V converter 6 output voltages are 10mV/ ℃, and its measurement range is limited by temperature sensor, and we adopt 0～100 ℃ of the temperature range that is fit to the pH electrode at present, and resolution is 0.1 ℃.
The key character of this instrument adopts two operating keys, wherein key 10 for function key, be used for conversion and select each test parameter etc.: comprise that (this instrument has pH for the demarcation of clock, electrode potential (mV) measurement, temperature survey, electrode slope and corresponding various standard buffer solutions and measurement
2, pH
4, pH
7And pH, four kinds of standard buffer solutions) have eight kinds of duties, by eight corresponding states of LED light emitting diode indication; Another key 11 claims key is set, and is used to be provided with clock, manual temperature compensation setting, manually temperature value setting during temperature compensation, and to certain selected standard buffer solution a bit or two-point calibration start and delete a certain point of having calibrated.
Above-mentioned standard buffer solution pH value temperature influence, this instrument adopts four kinds of standard pH buffer solution, is 0.05M four potassium binoxalate, 0.05M Potassium Hydrogen Phthalate, 0.025M mixed phosphate and 0.01M borax.These four kinds of buffer solution are corresponding to pH
2, pH
4, pH
7And pH, four scaling points, the user can choose one or both buffer solution arbitrarily and calibrate, and claims also a bit or two-point calibration that the pH value and the variation of temperature relation of damping fluid all deposit in the microcomputer.When calibration,, revise the pH value of selected standard buffer solution automatically by microcomputer according to the survey solution temperature.
As shown in Figure 3, microcomputer 9 adopts the chip of MCS51 series, and it is by single-chip microcomputer (8031) 9a, latch (74LS373) 9b, reservoir EPROM(2732) compositions such as 9c and programmable interface chip (PIO8255A) 9d.Micro-architecture is simply compact, the P by 8255 and 8031
1Required IO interface such as the existing multichannel analog to digital conversion control of cause for gossip, keyboard interface, demonstration output interface.All softwares (about 3.8KB) are solidificated in EPROM(2732 4KB capacity) in the 9c.Obtain digital signal from analog to digital converter 8, after single-chip data is handled, pass through 8255 A mouth and last half C mouth, promote LED charactron 12b display result through driver (74LS06) 12a again.8255 B mouth links to each other with analog to digital converter (5G14433) 8.8255 times half C mouth is used for function and state demonstration by 13a, 13b, 13c and 13d, wherein three output to code translator (74LS138) 13a, light 8 LED13b respectively and indicate Instrument working state at that time, also has one by a NPN triode 13c amplification, drive LED13d indication measurement stable case as a result, after display result is stable, promptly lighted, reliable results this moment is described.Button 10,11 is connected the P of single-chip microcomputer 8031
1.0And P
1.1Pin.
The microcomputer that this instrument adopts is take the MCS51 series monolithic of high integration as core, in addition new foreign circuit design. Make this product have simple in structure, hardware component is few, cost is low, the characteristics of reliable operation. Adopt a slice high precision analogue converter ic to measure mV, pH value and temperature, take full advantage of analog-digital converter dynamic range measurement pH value, make the accuracy of instrument height, the operation scheme of two keys of employing is finished the auto-compensation of parameter measurement and temperature, electrode and standard buffer solution, makes instrumentation very convenient. According to the invention scheme made that function is strong, intelligent, easy to operate, working stability, with low cost, pH meter that precision is high.
Claims (2)
1, a kind of acidometer that is used to measure solution, feature of the present invention is: mainly form by PH electrode, impedance transformer, amplifier, temperature sensor, analog switch, microcomputer, two operation push-buttons, analog to digital converter and displays, its mutual connecting relation be the current potential of PH electrode (1) output that will contact with solution through impedance transformer (2) and amplifier (3), (4) output voltage to analog switch (7); The current signal of temperature sensor (5) output is also sent into analog switch (7) through amplifier (6); Then by operating the function key (10) that is connected with microcomputer (9) or key (11) being set, microcomputer follow procedure requirement control analog switch (7) is measured to select the parameter of being surveyed, convert simulating signal to digital signal through analog to digital converter (8), the binary-coded decimal of output carries out data processing through microcomputer (9), and with scan mode the result is presented on 4 LED charactrons (12b), by the stable case of function and status displays (13) indicating instrument duty and measurement data.
2, the acidometer of measurement solution according to claim 1, it is characterized in that microcomputer is by single-chip microcomputer 8031(9a), latch 74LS373(9b), reservoir EPROM2732(9c) and programmable interface chip PIO8255A(9d) institute form P by 8255 and 8031
1The existing multichannel analog to digital conversion control of cause for gossip, keyboard interface and demonstration output interface, all software solidifications are at EPROM(9c) in, from analog to digital converter (8) output digital signal, after handling, passes through single-chip data 8255 A mouth and last half C mouth, again through driver 74LS06(12a) promotion LED charactron (12b) display result, 8255 B mouth and analog to digital converter 5G14433(8) link to each other, three of 8255 second C mouths output to code translator 74LS138(13a), light 8 LED(13b respectively) indicate Instrument working state at that time, foot has one and amplify to drive a LED(13d by a NPN triode (13c)) indication measurement stable case as a result, button (10), (11) be connected to the P of single-chip microcomputer 8031
1.0And P
1.1Pin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 90106980 CN1021256C (en) | 1990-08-11 | 1990-08-11 | Ph meter |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 90106980 CN1021256C (en) | 1990-08-11 | 1990-08-11 | Ph meter |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1059032A CN1059032A (en) | 1992-02-26 |
| CN1021256C true CN1021256C (en) | 1993-06-16 |
Family
ID=4880356
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 90106980 Expired - Fee Related CN1021256C (en) | 1990-08-11 | 1990-08-11 | Ph meter |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1021256C (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102006032905A1 (en) * | 2006-04-28 | 2007-10-31 | Endress + Hauser Conducta Gesellschaft für Mess- und Regeltechnik mbH + Co. KG | Sensor e.g. optical sensor, calibrating and/or adjusting method, involves designing evaluation electronics so that signal produced by sensor is not changeable, where sensor is adjusted at place other than subsequent measuring point |
| CN102706947B (en) * | 2012-06-21 | 2014-03-12 | 中国计量学院 | Portable pH instrument |
| CN113933350B (en) * | 2021-09-30 | 2023-12-22 | 深圳市中金岭南有色金属股份有限公司凡口铅锌矿 | Pulp pH value detection method and device and computer readable storage medium |
| CN113933351B (en) * | 2021-09-30 | 2023-12-22 | 深圳市中金岭南有色金属股份有限公司凡口铅锌矿 | Pulp pH value detection method and device and computer readable storage medium |
-
1990
- 1990-08-11 CN CN 90106980 patent/CN1021256C/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN1059032A (en) | 1992-02-26 |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |