CN102094205A - Phosphorus-free oil removing powder and phosphorus-free oil removing process - Google Patents
Phosphorus-free oil removing powder and phosphorus-free oil removing process Download PDFInfo
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- CN102094205A CN102094205A CN 201010600354 CN201010600354A CN102094205A CN 102094205 A CN102094205 A CN 102094205A CN 201010600354 CN201010600354 CN 201010600354 CN 201010600354 A CN201010600354 A CN 201010600354A CN 102094205 A CN102094205 A CN 102094205A
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Abstract
The invention discloses phosphorus-free oil removing powder, which comprises the following raw materials in part by mass: 10 to 25 parts of sodium hydroxide, 20 to 32 parts of sodium carbonate, 20 to 35 parts of phosphorus-free builder, 5 to 10 parts of sodium sulfate, 1 to 5 parts of sodium citrate, 1 to 5 parts of sodium gluconate and 6 to 12 parts of surfactant. A phosphorus-free oil removing process using the phosphorus-free oil removing powder comprises the following steps of: preparing cleaning solution from the phosphorus-free oil removing powder and water, and adding into a cleaning tank, wherein the pH of the cleaning solution is 12.5 to 13.5; and putting a workpiece into the cleaning solution, soaking and cleaning. Phosphorus-free oil removing liquid prepared from the phosphorus-free oil removing powder does not contain phosphorus, is environmental-friendly, has a cleaning effect superior to that of the conventional pretreatment oil removing process, and has longer service life; and the generated wastewater is easier to treat.
Description
Technical field
The present invention relates to without phosphorus oil-bound distemper and the without phosphorus oil removing process of removing.
Background technology
Because phosphoric acid salt has sequestering power, wash-aid effect preferably, it is widely used in fields such as traditional industry after being re-dubbed clean-out system as a kind of washing assistant and tensio-active agent etc.Yet, because it is phosphorous in this kind clean-out system, after it is discharged away as waste water, can make body eutrophication, cause waterplant such as algae to breed in a large number, and the aerobic repiration of plant materials will consume oxygen a large amount of in the water, and the hydrocoles anoxic is caused death and produce a series of natural disaster (the blue-green algae incident that repeatedly breaks out as Taihu Lake, Jiangsu, Chaohu, Anhui, Dian Chi, Yunnan etc., and global marine red tide phenomenon etc.), badly influenced human safe drinking water.
Since the nineties in last century, more and more enterprises begins to research and develop without phosphorus clean-out system, the exploitation of the without phosphorus clean-out system of electroplating industry pre-treatment then starts from late nineteen nineties, yet, the phosphate builders because the builder as substitute for phosphate that is adopted can't match in excellence or beauty on over-all propertieies such as wash-aid effect, sequestering power, flush away is not so still there is to replace fully the pre-electroplating treatment product of phosphorous hydrochlorate oil removing powder so far.
Summary of the invention
The purpose of this invention is to provide a kind of without phosphorus oil-bound distemper and without phosphorus oil removing process of removing.
The technical solution used in the present invention is:
A kind of without phosphorus except that oil-bound distemper, comprise the raw material of following mass parts: 10～25 parts sodium hydroxide, 20～30 parts yellow soda ash, 20～35 parts non-phosphorus builder, 5～10 parts of sodium sulfate, 1～5 part of Trisodium Citrate, 1～5 part of Sunmorl N 60S, 6～12 parts of tensio-active agents.
Non-phosphorus builder is at least a in C2～8 carboxylic acids, the siliceous carboxyl acid modified thing in C2～8, toxilic acid/acrylic copolymer, the molecular sieve.
Tensio-active agent is at least a in sodium lauryl sulphate, Sodium dodecylbenzene sulfonate, alkyl diphenyl base oxide stilbene-4,4'-bis-(1-azo-3, 4-dihydroxy-benzene)-2,2'-disulfonate, C10～16 fat alcohol ethoxyl compounds, C12～15 secondary alcohol ethoxy compounds, the fatty alcohol-polyoxyethylene ether.
The described without phosphorus without phosphorus oil removing process that removes oil-bound distemper may further comprise the steps:
1) remove oil-bound distemper and water is mixed with scavenging solution with without phosphorus, join in the rinse bath, the pH of scavenging solution is 12.5～13.5;
2) workpiece is placed the scavenging solution soaking and washing.
The without phosphorus concentration of removing oil-bound distemper is 45～55g/L.
The soaking and washing time is 1～5min.
The temperature of scavenging solution is 50～70 ℃.
The surface-area of workpiece and the volume ratio of scavenging solution are 110～130dm
2: 1L.
The invention has the beneficial effects as follows: this without phosphorus without phosphorus degreasing fluid except that the oil-bound distemper preparation is not phosphorous, environmentally friendly, and cleaning performance is better than conventional pre-treatment oil removing process, and the work-ing life of degreasing fluid is more lasting, and the easier processing of waste water that produces.
Embodiment
A kind of without phosphorus oil removing process may further comprise the steps:
1) the without phosphorus oil-bound distemper that removes is mixed with the scavenging solution that concentration is 45～55g/L, joins in the rinse bath, the pH of scavenging solution is 12.5～13.5, and the temperature of adjusting scavenging solution is 50～70 ℃.
2) workpiece is placed scavenging solution soaking and washing 1～5min, the long-pending volume ratio with scavenging solution of workpiece surface is 110～130dm
2: 1L.
Below in conjunction with embodiment prescription of the present invention is described further:
Embodiment 1:
The without phosphorus table 1 composed as follows that removes oil-bound distemper:
Table 1: the without phosphorus composition that removes oil-bound distemper
| Raw material | Mass parts |
| Sodium hydroxide | 12 |
| Yellow soda ash | 25 |
| The carboxyl acid modified thing in siliceous C2～8 | 20 |
| Sodium sulfate | 8 |
| Trisodium Citrate | 3 |
| Sunmorl N 60S | 5 |
| Sodium lauryl sulphate | 2 |
| Alkyl diphenyl base oxide stilbene-4,4'-bis-(1-azo-3, 4-dihydroxy-benzene)-2,2'-disulfonate | 2 |
| The C12 fat alcohol ethoxyl compound | 6 |
A kind of without phosphorus oil removing process may further comprise the steps:
1) the without phosphorus oil-bound distemper that removes is mixed with the scavenging solution that concentration is 45g/L with water, joins in the rinse bath, the pH of scavenging solution is 12.5～13.5, and the temperature of adjustment scavenging solution is 55 ℃.
2) workpiece is placed scavenging solution soaking and washing 1min, the long-pending volume ratio with scavenging solution of workpiece surface is 110～130dm
2: 1L.
Oil removal efficiency reaches 99%, adopts the moisture film test method(s) to estimate degreasing effect, forms uniform moisture film on it, water-break-free splitting, and the test piece degreasing is clean.
Embodiment 2:
The without phosphorus table 2 composed as follows that removes oil-bound distemper:
Table 2: the without phosphorus composition that removes oil-bound distemper
| Raw material | Mass parts |
| Sodium hydroxide | 10 |
| Yellow soda ash | 30 |
| Toxilic acid/acrylic copolymer | 28 |
| Sodium sulfate | 5 |
| Trisodium Citrate | 1 |
| Sunmorl N 60S | 4 |
| Sodium dodecylbenzene sulfonate | 5 |
| Fatty alcohol-polyoxyethylene ether | 7 |
A kind of without phosphorus oil removing process may further comprise the steps:
1) the without phosphorus oil-bound distemper that removes is mixed with the scavenging solution that concentration is 55g/L with water, joins in the rinse bath, the pH of scavenging solution is 12.5～13.5, and the temperature of adjustment scavenging solution is 50 ℃.
2) workpiece is placed scavenging solution soaking and washing 5min, the long-pending volume ratio with scavenging solution of workpiece surface is 110～130dm
2: 1L.
Oil removal efficiency reaches 98.8%, adopts the moisture film test method(s) to estimate degreasing effect, forms uniform moisture film on it, water-break-free splitting, and the test piece degreasing is clean.
Embodiment 3:
The without phosphorus table 3 composed as follows that removes oil-bound distemper:
Table 3: the without phosphorus composition that removes oil-bound distemper
| Raw material | Mass parts |
| Sodium hydroxide | 25 |
| Yellow soda ash | 20 |
| Toxilic acid/acrylic copolymer | 18 |
| Ammonium acetate | 10 |
| Sodium sulfate | 10 |
| Trisodium Citrate | 4 |
| Sunmorl N 60S | 1 |
| Alkyl diphenyl base oxide stilbene-4,4'-bis-(1-azo-3, 4-dihydroxy-benzene)-2,2'-disulfonate | 2 |
| Fatty alcohol-polyoxyethylene ether | 6 |
A kind of without phosphorus oil removing process may further comprise the steps:
1) the without phosphorus oil-bound distemper that removes is mixed with the scavenging solution that concentration is 50g/L with water, joins in the rinse bath, the pH that adjusts scavenging solution is 12.5～13.5, and the temperature of adjustment scavenging solution is 65 ℃.
2) workpiece is placed scavenging solution soaking and washing 2min, the long-pending volume ratio with scavenging solution of workpiece surface is 110～130dm
2: 1L.
Oil removal efficiency reaches 99.8%, adopts the moisture film test method(s) to estimate degreasing effect, forms uniform moisture film on it, water-break-free splitting, and the test piece degreasing is clean.
Embodiment 4:
The without phosphorus table 4 composed as follows that removes oil-bound distemper:
Table 4: the without phosphorus composition that removes oil-bound distemper
| Raw material | Mass parts |
| Sodium hydroxide | 20 |
| Yellow soda ash | 27 |
| The carboxylic acid trimethylsilyl group | 35 |
| Sodium sulfate | 9 |
| Trisodium Citrate | 5 |
| Sunmorl N 60S | 5 |
| The C12 fat alcohol ethoxyl compound | 3 |
| The C15 fat alcohol ethoxyl compound | 3 |
A kind of without phosphorus oil removing process may further comprise the steps:
1) the without phosphorus oil-bound distemper that removes is mixed with the scavenging solution that concentration is 48g/L with water, joins in the rinse bath, the pH that adjusts scavenging solution is 12.5～13.5, and the temperature of adjustment scavenging solution is 70 ℃.
2) workpiece is placed scavenging solution soaking and washing 4min, the long-pending volume ratio with scavenging solution of workpiece surface is 110～130dm
2: 1L.
Oil removal efficiency reaches 99.9%, adopts the moisture film test method(s) to estimate degreasing effect, forms uniform moisture film on it, water-break-free splitting, and the test piece degreasing is clean.
Embodiment 5:
The without phosphorus table 5 composed as follows that removes oil-bound distemper:
Table 5: the without phosphorus composition that removes oil-bound distemper
| Raw material | Mass parts |
| Sodium hydroxide | 18 |
| Yellow soda ash | 32 |
| Metasilicate pentahydrate sodium | 24 |
| Sodium sulfate | 8 |
| Trisodium Citrate | 3 |
| Sunmorl N 60S | 2 |
| Molecular sieve | 4 |
| Sodium lauryl sulphate | 4 |
| Sodium dodecylbenzene sulfonate | 2 |
| The C12 fat alcohol ethoxyl compound | 2 |
A kind of without phosphorus oil removing process may further comprise the steps:
1) the without phosphorus oil-bound distemper that removes is mixed with the scavenging solution that concentration is 52g/L with water, joins in the rinse bath, the pH that adjusts scavenging solution is 12.5～13.5, and the temperature of adjustment scavenging solution is 66 ℃.
2) workpiece is placed scavenging solution soaking and washing 2min, the long-pending volume ratio with scavenging solution of workpiece surface is 110～130dm
2: 1L.
Oil removal efficiency reaches 99.5%, adopts the moisture film test method(s) to estimate degreasing effect, forms uniform moisture film on it, water-break-free splitting, and the test piece degreasing is clean.
Oil removal efficiency of the present invention all on 98.8%, has high oil removal efficiency, adopts the moisture film test method(s) to estimate degreasing effect, forms uniform moisture film on it, water-break-free splitting, and the test piece degreasing is clean. Cleaning performance is better than conventional pre-treatment oil removing process, because without phosphorus degreasing fluid is not phosphorous, environmentally friendly, and the easier processing of the waste water of generation.
Claims (8)
1. without phosphorus oil-bound distemper that removes comprises the raw material of following mass parts: 10～25 parts sodium hydroxide, 20～32 parts yellow soda ash, 20～35 parts non-phosphorus builder, 5～10 parts of sodium sulfate, 1～5 part of Trisodium Citrate, 1～5 part of Sunmorl N 60S, 6～12 parts of tensio-active agents.
2. a kind of without phosphorus oil-bound distemper that removes according to claim 1 is characterized in that: non-phosphorus builder is at least a in C2～8 carboxylate salts, siliceous C2～8 carboxylate salt modifiers, the toxilic acid/acrylic copolymer sodium salt.
3. a kind of without phosphorus oil-bound distemper that removes according to claim 1 is characterized in that: tensio-active agent is at least a in sodium lauryl sulphate, Sodium dodecylbenzene sulfonate, alkyl diphenyl base oxide stilbene-4,4'-bis-(1-azo-3, 4-dihydroxy-benzene)-2,2'-disulfonate, C10～16 fat alcohol ethoxyl compounds, C12～15 secondary alcohol ethoxy compounds, fatty alcohol-polyoxyethylene ether, the molecular sieve.
4. use any described without phosphorus without phosphorus oil removing process that removes oil-bound distemper of claim 1～3, may further comprise the steps:
1) the without phosphorus oil-bound distemper that removes is mixed with scavenging solution with water, joins in the rinse bath, the pH of adjustment scavenging solution is 12.5～13.5;
2) workpiece is placed the scavenging solution soaking and washing.
5. a kind of without phosphorus oil removing process according to claim 4 is characterized in that: the without phosphorus concentration of removing oil-bound distemper is 45～55g/L.
6. a kind of without phosphorus oil removing process according to claim 4 is characterized in that: the soaking and washing time is 1～5min.
7. a kind of without phosphorus oil removing process according to claim 4 is characterized in that: the temperature of scavenging solution is 50～70 ℃.
8. a kind of without phosphorus oil removing process according to claim 4 is characterized in that: the surface-area of workpiece and the volume ratio of scavenging solution are 110～130dm
2: 1L.
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| CN2010106003541A CN102094205B (en) | 2010-12-22 | 2010-12-22 | Phosphorus-free oil removing powder and phosphorus-free oil removing process |
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|---|---|---|---|
| CN2010106003541A CN102094205B (en) | 2010-12-22 | 2010-12-22 | Phosphorus-free oil removing powder and phosphorus-free oil removing process |
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| CN102094205A true CN102094205A (en) | 2011-06-15 |
| CN102094205B CN102094205B (en) | 2012-06-20 |
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Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102492952A (en) * | 2011-11-18 | 2012-06-13 | 东莞市东辉贸易有限公司 | Phosphorus-free degreasing powder, production process and phosphorus-free degreasing process thereof |
| CN102534636A (en) * | 2011-10-31 | 2012-07-04 | 武汉钢实硅钢协力表面处理有限公司 | Phosphate-free degreasing fluid composition for cold-rolled sheets before galvanizing, and preparation method for composition |
| CN103103547A (en) * | 2013-02-27 | 2013-05-15 | 杨东佑 | Non-phosphorus environment-friendly metal degreasing agent, and production method and usage method thereof |
| CN103290423A (en) * | 2013-06-22 | 2013-09-11 | 兰溪市卓越电子有限公司 | Powerful electroplating oil removal method |
| CN103882460A (en) * | 2014-04-18 | 2014-06-25 | 北京中科创新科技发展中心 | Degreasing and derusting two-in-one purifying liquid |
| CN104087990A (en) * | 2014-06-17 | 2014-10-08 | 宁国新博能电子有限公司 | Chemical treatment liquid used for nickel plating of copper wire |
| CN104313615A (en) * | 2014-11-10 | 2015-01-28 | 湖北德美科技有限公司 | Environment friendly low-foam skimmed powder for cleaning metal surfaces and preparation method thereof |
| CN104694946A (en) * | 2015-03-13 | 2015-06-10 | 武汉钢铁(集团)公司 | Phosphorus-free degreaser |
| CN105238568A (en) * | 2015-11-10 | 2016-01-13 | 荆门市拓达科技有限公司 | Non-phosphorus oil removing powder |
| CN105483726A (en) * | 2015-11-30 | 2016-04-13 | 武汉奥克特种化学有限公司 | Efficient low-foam normal-temperature phosphorous-free oil removing liquid |
| CN106498421A (en) * | 2016-09-23 | 2017-03-15 | 佛山市海明威生态科技有限公司 | A kind of environmentally friendly double-component efficient cryogenic degreasing agent product and its production technology |
| CN106929871A (en) * | 2017-02-17 | 2017-07-07 | 上海蔚来汽车有限公司 | A kind of automobile component surface treatment grease removing composition |
| CN107099805A (en) * | 2017-03-10 | 2017-08-29 | 广东华普科技股份有限公司 | Without phosphorus degreasing powder |
| CN107740122A (en) * | 2017-10-19 | 2018-02-27 | 江门市濠成化工科技有限公司 | A kind of degreasing powder for metal surface and preparation method thereof |
| CN111575754A (en) * | 2019-06-13 | 2020-08-25 | 胡云亮 | Environment-friendly synchronous wax and oil removing cleaning agent before plating |
| CN114592188A (en) * | 2022-03-10 | 2022-06-07 | 常州市春雷浩宇环保科技有限公司 | Vitrification process |
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| CN102534636A (en) * | 2011-10-31 | 2012-07-04 | 武汉钢实硅钢协力表面处理有限公司 | Phosphate-free degreasing fluid composition for cold-rolled sheets before galvanizing, and preparation method for composition |
| CN102492952B (en) * | 2011-11-18 | 2014-02-19 | 东莞市东辉贸易有限公司 | Phosphorus-free degreasing powder, production process and phosphorus-free degreasing process thereof |
| CN102492952A (en) * | 2011-11-18 | 2012-06-13 | 东莞市东辉贸易有限公司 | Phosphorus-free degreasing powder, production process and phosphorus-free degreasing process thereof |
| CN103103547B (en) * | 2013-02-27 | 2016-09-21 | 杨东佑 | Phosphateless environmentally friendly degreasing agent for metal, production method and using method |
| CN103103547A (en) * | 2013-02-27 | 2013-05-15 | 杨东佑 | Non-phosphorus environment-friendly metal degreasing agent, and production method and usage method thereof |
| CN103290423A (en) * | 2013-06-22 | 2013-09-11 | 兰溪市卓越电子有限公司 | Powerful electroplating oil removal method |
| CN103882460A (en) * | 2014-04-18 | 2014-06-25 | 北京中科创新科技发展中心 | Degreasing and derusting two-in-one purifying liquid |
| CN104087990A (en) * | 2014-06-17 | 2014-10-08 | 宁国新博能电子有限公司 | Chemical treatment liquid used for nickel plating of copper wire |
| CN104313615A (en) * | 2014-11-10 | 2015-01-28 | 湖北德美科技有限公司 | Environment friendly low-foam skimmed powder for cleaning metal surfaces and preparation method thereof |
| CN104694946A (en) * | 2015-03-13 | 2015-06-10 | 武汉钢铁(集团)公司 | Phosphorus-free degreaser |
| CN105238568A (en) * | 2015-11-10 | 2016-01-13 | 荆门市拓达科技有限公司 | Non-phosphorus oil removing powder |
| CN105483726A (en) * | 2015-11-30 | 2016-04-13 | 武汉奥克特种化学有限公司 | Efficient low-foam normal-temperature phosphorous-free oil removing liquid |
| CN106498421A (en) * | 2016-09-23 | 2017-03-15 | 佛山市海明威生态科技有限公司 | A kind of environmentally friendly double-component efficient cryogenic degreasing agent product and its production technology |
| CN106929871A (en) * | 2017-02-17 | 2017-07-07 | 上海蔚来汽车有限公司 | A kind of automobile component surface treatment grease removing composition |
| CN107099805A (en) * | 2017-03-10 | 2017-08-29 | 广东华普科技股份有限公司 | Without phosphorus degreasing powder |
| CN107740122A (en) * | 2017-10-19 | 2018-02-27 | 江门市濠成化工科技有限公司 | A kind of degreasing powder for metal surface and preparation method thereof |
| CN111575754A (en) * | 2019-06-13 | 2020-08-25 | 胡云亮 | Environment-friendly synchronous wax and oil removing cleaning agent before plating |
| CN114592188A (en) * | 2022-03-10 | 2022-06-07 | 常州市春雷浩宇环保科技有限公司 | Vitrification process |
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Address after: 510663 6 research road, Science City, hi tech Industrial Development Zone, Guangdong, Guangzhou Patentee after: Guangzhou Light Industry Research Institute of Limited by Share Ltd Address before: 510663 6 research road, Science City, hi tech Industrial Development Zone, Guangdong, Guangzhou Patentee before: Guangzhou Etsing Plating Industry Science Technology Research Institute |
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