CN102093834A - Non-halogen fire-retardant adhesive - Google Patents
Non-halogen fire-retardant adhesive Download PDFInfo
- Publication number
- CN102093834A CN102093834A CN2009101889021A CN200910188902A CN102093834A CN 102093834 A CN102093834 A CN 102093834A CN 2009101889021 A CN2009101889021 A CN 2009101889021A CN 200910188902 A CN200910188902 A CN 200910188902A CN 102093834 A CN102093834 A CN 102093834A
- Authority
- CN
- China
- Prior art keywords
- tackiness agent
- halogen
- retardant
- fire
- flame retardant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Insulated Conductors (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention provides a non-halogen fire-retardant adhesive. The non-halogen fire-retardant adhesive can be used for manufacturing flat cables and comprises the following components: (A) polyester resin, (B) a nitrogen-containing organic fire retardant and (C) an inorganic filler. The formed fire-retardant adhesive or the formed fire-retardant adhesive film can keep high adhesiveness and can realize the fire retardance equal to that of a halogen fire retardant.
Description
Technical field
The present invention is about a kind of non-halogen fire retardant tackiness agent, especially in regard to a kind of non-halogen fire retardant tackiness agent that is used on inflammableness article, cable or the electronic product.
Background technology
Look about we around, with people live closely bound up household electrical appliances, office automated machine, electronic motor, material of construction, automotive material and daily living article etc., all is inflammable material a lot; In order to improve the quality of living and to ensure life security, have only by means of flame retardant resistance tackiness agent and flame-retarded technology thereof and improve properties of materials, reduce the possibility that material combustion is stretched, reduce the generation of fire, so the exploitation of flame retardant resistance tackiness agent and be utilized as a critical ring.Flame retardant resistance tackiness agent on the market is according to whether halogen-containing halogen-containing class and the non-halogen of being divided into:
1, halogen-containing class
The halogen fire-retardancy tackiness agent that contains that uses mainly is chlorine and two kinds of compounds of bromine at present, contain the halogen fire-retardancy tackiness agent and have a good effect fire-retardant, for example brominated bisphenol a type epoxy resin only need be done a spot of interpolation in macromolecular material, can reach flame retardant effect; Yet contain the halogen fire-retardancy tackiness agent and can produce corrodibility and toxic hydrogen halide, and the amount of being fuming is big, and burning the time may produce harmful carcinogenic poison gas such as halogenation dioxin or halogenation furans, so electronics of European Union's legislation, motor device instruction (Directiveon " Waste Electrical; among the Electronic Equipment (WEEE) "), for electronics, the restriction of objectionable impurities in the motor device (Restriction of Hazardous Substances (RoHS) in EEE) provides against and uses poly-bromination biphenyl (Polybrominated biphenyl (PBB)), poly-bromination biphenyl ether bromine-containing compounds such as (Polybrominated diphenyl ethers (PBDE)).
2, non-halogen
Non-halogen be meant the cl content that integral material comprises that uses as exploitation less than 900ppm and bromine content less than 900ppm.And the Halogen material is is mainly researched and developed according to following four notions at present: (1) flame retardant resistance need meet the UL94-V0 standard; (2) do not contain halogen; (3) do not contain antimony element; And (4) do not contain red phosphorus.Wherein, though antimony and red phosphorus are to replace halogen to become the flame retardant resistance tackiness agent and select preferably, antimony has carcinogenic danger.In addition, existing at present patent discloses the flame retardant resistance tackiness agent of phosphorus-containing groups, as United States Patent (USP) the 6th, 291, and No. the 490474th, No. 627 and Taiwan patent announcement etc.Yet, though the phosphor-containing flame-proof tackiness agent can effectively replace the halogen fire retardant tackiness agent, because of phosphorus can hydrolysis cause the excellent oxidation in rivers and creeks, another environmental issue of deriving, simultaneously, itself has ignition quality red phosphorus, easily causes danger.Therefore, antimony and red phosphorus have become the chemical substance of avoiding on the market using on the flame retardant resistance tackiness agent at present.
Summary of the invention
The object of the present invention is to provide a kind of non-halogen fire retardant tackiness agent, the basic resin of using the lower vibrin of water absorbability to use as the flame retardant resistance tackiness agent uses nitrogenous organic fire-retardants such as containing trimeric cyanamide as fire retardant, and inorganic filler.
For achieving the above object, the invention provides a kind of non-halogen fire retardant tackiness agent, it is characterized by and contain following (A), (B), (C) composition: (A) vibrin; (B) contain the organic fire-retardant of nitrogen; And (C) inorganic filler.Again, the invention provides a kind of non-halogen fire retardant adhesive film, it is characterized by and on the insulativity base material film, be provided with the flame retardant resistance adhesive coating that this fire retardant constitutes.In addition, non-halogen fire retardant adhesive film provided by the invention is applicable to the making of flat cable, it is characterized by with this flame retardant resistance adhesive film electric conductor is covered.
Non-halogen fire retardant tackiness agent of the present invention contains following (A), (B), (C) composition: the vibrin that (A) contains 40～60 weight percents; (B) contain the nitrogenous organic fire-retardant of 35～50 weight percents; (C) contain the inorganic filler of 1～20 weight percent.In non-halogen fire retardant tackiness agent of the present invention, the vibrin of composition (A) is as adhesion composition and film forming component.The vibrin of this type is by sour composition, (for example can enumerate by sour composition, terephthalic acid, m-phthalic acid, two benzene dicarboxylic acids, hexanodioic acid, contain the polyvalent carboxylic acid, pentanedioic acid, trimellitic acid, sulfoisophthalic acid sodium of phosphoric acid residue etc. in sebacic acid, the molecule) with the glycols composition (for example, ethylene glycol, 1,4-butyleneglycol, 1,4-bicyclohexane dimethanol, 1, the trishydroxymethyl propyl alcohol that 4-hexanaphthene dihydroxymethyl, Diethylene Glycol, dihydroxyphenyl propane and oxyethane addition reaction go out etc.) formed vibrin.Wherein, be preferably saturated polyester resin.
Composition (A) is a vibrin, be preferably saturated polyester resin, be more preferred from polyethylene terephthalate, be applied to the making of flat cable at the flame retardant resistance tackiness agent, the heat-blocking energy that composition (A) tool is good, glass tansition temperature (Tg temperature) is preferably between 0～100 ℃, and is and more appropriate between 0～70 ℃.
Composition (B) is a non-halogen flame retardant for nitrogenous organic fire-retardant, nitrogenous organic fire-retardant as this composition (B), can enumerate trimeric cyanamide (cyanogen urine triamide), trimeric cyanamide diamide (cyanurodiamide), trimeric cyanamide monoamide (cyanogen urine monoamide), melam and (be estimated as (3,5-(NH2) C3N3) NH), melamine cyanurate (condenses of trimeric cyanamide and cyanuric acid), melamine resin, high guanamine, at least a kind or its combination in the melamine derivatives such as benzo guanamine, acetyl guanamine etc.; By the viewpoints such as dispersiveness, Combination and tackiness to vibrin, wherein, it is preferable using trimeric cyanamide, melamine cyanurate or benzo guanamine, is more preferred from melamine cyanurate.
Composition (C) is an inorganic filler, obtains well balanced as flame retardant resistance that makes the flame retardant resistance tackiness agent and clinging power.This type of inorganic filler includes, glass fibre, carbon fiber, mica, titanium dioxide, silicon-dioxide, talcum powder, high territory, how at least a kind or its combination in the rice clay etc.Wherein, titanium dioxide and silicon-dioxide are preferable.
The usage quantity of the nitrogenous organic fire-retardant of composition (B), if then can't obtain sufficient flame retardant effect with quantity not sufficient, consumption is crossed and can be caused adhesion strength insufficient at most, compare the vibrin of 40～60 component in percentage by weight (A), be preferably in the nitrogenous organic fire-retardant of 35～50 weight percents.
The usage quantity of the inorganic filler of composition (C), then can't obtain sufficient additive effect with quantity not sufficient, consumption is crossed and can be caused clinging power to reduce at most, compare the vibrin of 40～60 component in percentage by weight (A) and the nitrogenous organic fire-retardant of 35～50 weight percent compositions (B), be preferably in the inorganic filler of 1～20 weight percent.
Non-halogen fire retardant tackiness agent therefore provided by the invention is formed part, comprises the vibrin of (A) 40～60 weight percents; (B) the nitrogenous organic fire-retardant of 35～50 weight percents; (C) inorganic filler of 1～20 weight percent.And preferable composition part being comprises the vibrin of (A) 45～55 weight percents; (B) the nitrogenous organic fire-retardant of 40～45 weight percents; (C) inorganic filler of 2～15 weight percents.
And if the inorganic filler of composition of the present invention (C) is a silicon-dioxide, the present invention forms a part following expression:
Non-halogen fire retardant tackiness agent provided by the invention is formed part, comprises the vibrin of (A) 40～60 weight percents; (B) the nitrogenous organic fire-retardant of 35～50 weight percents; (C) silicon-dioxide of 1～15 weight percent.And preferable composition part being comprises the vibrin of (A) 45～55 weight percents; (B) the nitrogenous organic fire-retardant of 40～45 weight percents; (C) silicon-dioxide of 2～10 weight percents.
And if the inorganic filler of composition of the present invention (C), mix with these two inorganic filler of silicon-dioxide, titanium dioxide and to use, the present invention forms a part following expression:
Non-halogen fire retardant tackiness agent provided by the invention is formed part, comprises the vibrin of (A) 40～60 weight percents; (B) the nitrogenous organic fire-retardant of 35～50 weight percents; (C1) silicon-dioxide of 2～10 weight percents, (C2) titanium dioxide of 3～15 weight percents.And preferable composition part being comprises the vibrin of (A) 45～55 weight percents; (B) the nitrogenous organic fire-retardant of 40～45 weight percents; (C1) silicon-dioxide of 2～8 weight percents, (C2) titanium dioxide of 3～10 weight percents.
Non-halogen fire retardant tackiness agent of the present invention can be used with forms such as solution, pasty state and particulate state.
Non-halogen fire retardant adhesive film provided by the invention has the flame retardant resistance adhesive coating that aforementioned non-halogen fire retardant tackiness agent is constituted and is arranged at structure on the insulativity base material film.Therefore, this flame retardant resistance adhesive film can be realized the flame retardant resistance adhesive film of the flame retardant resistance that is equal to mutually with halogen flame.Though the thickness of flame retardant resistance adhesive film is different different because of the application target of flame retardant resistance adhesive film, usually between 10～100 μ m.The insulativity base material film can be enumerated polyethylene terephthalate film, poly (ethylene naphthalate) film, polyimide film, polyphenylene sulfide film, polyoxytrimethylene film, polyethylene film, polypropylene screen and polyamide membrane etc.Flame retardant resistance adhesive film of the present invention, form the mode of flame retardant resistance adhesive film after in addition dry on the insulativity base material film that can be by the organic solvent that will contain aforementioned flame retardant resistance tackiness agent of the present invention (for example toluene) solution coat in polyethylene terephthalate etc., or be the flame retardant resistance tackiness agent to be melt extruded on the insulativity base material film and film forming mode is made.
Non-halogen fire retardant adhesive film provided by the invention can use as a kind of surface protection film of electric conductor, and is particularly suitable when making flat cable.For example, after flat cable was arranged in parallel a plurality of conductors, the mode laminated in addition up and down by the flame retardant resistance adhesive film from conductor was made.At this, tackiness is not enough at normal temperatures because of the existence of fire retardant for the flame retardant resistance adhesive film, so when laminated, can be heated to legal manufacturing of thermosphere of the roller of 80～200 ℃ of scopes by use.
Beneficial effect of the present invention: non-halogen fire retardant tackiness agent provided by the invention, the basic resin of using the lower vibrin of water absorbability to use as the flame retardant resistance tackiness agent, use contains nitrogenous organic fire-retardants such as trimeric cyanamide as fire retardant, and inorganic filler, the flame retardant resistance tackiness agent or the adhesive film of the making that is applicable to flat cable of non-halogen flame retardant can be kept good clinging power and can realize that with halogen be the flame retardant resistance that fire retardant is equal to mutually simultaneously.
Embodiment
Technique means and the effect thereof taked for further setting forth the present invention are described in detail below in conjunction with embodiments of the invention 1-4 and comparative example.
The preparation of flame retardant resistance tackiness agent:
With the amount of preparation shown in the table 1, with polyethylene terephthalate, the solvent that constitutes with butanone 75g and toluene 300g is dissolved, and is added into fire retardant and inorganic filler in this solution, mixes the flame retardant resistance tackiness agent that is modulated into the solution shape after stirring.
Embodiment 1
Get the 45g polyethylene terephthalate, the solvent that constitutes with butanone 75g and toluene 300g is dissolved, add 45g melamine cyanurate (Melamine Cyanurate) in this solution, 2g silicon-dioxide and 8g titanium dioxide mix the flame retardant resistance tackiness agent that is modulated into the solution shape after stirring.
Embodiment 2
Get the 20g polyethylene terephthalate, the solvent that constitutes with butanone 75g and toluene 300g is dissolved, add 70g melamine cyanurate (Melamine Cyanurate) in this solution, 2g silicon-dioxide and 8g titanium dioxide mix the flame retardant resistance tackiness agent that is modulated into the solution shape after stirring.
Embodiment 3
Get the 70g polyethylene terephthalate, the solvent that constitutes with butanone 75g and toluene 300g is dissolved, add 20g melamine cyanurate (Melamine Cyanurate) in this solution, 2g silicon-dioxide and 8g titanium dioxide mix the flame retardant resistance tackiness agent that is modulated into the solution shape after stirring.
Embodiment 4
Get the 45g polyethylene terephthalate, the solvent that constitutes with butanone 75g and toluene 300g is dissolved, add 45g melamine cyanurate (Melamine Cyanurate) and 10g silicon-dioxide in this solution, mix the flame retardant resistance tackiness agent that is modulated into the solution shape after stirring.
Comparative example
The preparation of existing flame retardant resistance tackiness agent (control group):
Get the 45g polyethylene terephthalate, the solvent that constitutes with butanone 75g and toluene 300g is dissolved, add the poly-bromination biphenyl (Polybrominated biphenyl (PBB)) of 30g in this solution, the 15g ANTIMONY TRIOXIDE SB 203 99.8 PCT, 2g silicon-dioxide and 8g titanium dioxide mix the flame retardant resistance tackiness agent that is modulated into the solution shape after stirring.
The preparation of table 1 flame retardant resistance tackiness agent
Annotate:
1.%: be weight percentage
2.-: for not adding
The making of flame retardant resistance adhesive film:
Utilize spreading rod to coat on the thick polyester film of 25 μ m the flame retardant resistance tackiness agent of solution shape, put into drying oven and make butanone and toluene volatilization back form flame retardant resistance adhesive coating (thickness 40 μ m).Can obtain the flame retardant resistance adhesive film whereby.
The making of flat cable:
Be ready to 2 and be cut into both aforementioned flame retardant resistance adhesive films that makes of measured length, a plurality of straight angle conductors (tinned straight angle copper cash) that on the flame retardant resistance adhesive film of a slice with line thickness are 50 μ m therein are arranged in parallel, after placing the flame retardant resistance adhesive film of another sheet then above it, by making it by being heated to the mode of 2 rollers of 150 ℃, two adhesive films are fitted mutually, be made into flat cable.
(test example)
At the flame retardant resistance tackiness agent of embodiment 1～4 and comparative example, as described below, carry out test relevant for flame retardant resistance and clinging power.The result who is obtained is represented with table 2.
The flame retardant resistance test
Carry out the combustion experiment test with UL-SUB758-VW1 institute testing method:
1. test mode:
After sample and burning things which may cause a fire disaster are all prepared according to aforementioned standard and are adjusted, with burning things which may cause a fire disaster according to predetermined distance and angle near sample 15 seconds, leave after 15 seconds, so repeat 5 times, yet, if still do not disappear after the flame on the sample is leaving burning things which may cause a fire disaster, the combustion testing of this sample writes off, but this failure scenario allows to be tested once again.Above testing method should be carried out at least 5 samples.
2. basis for estimation:
In 25 times combustion testing at least altogether, all samples is after leaving burning things which may cause a fire disaster, and the flame on its body should extinguish in 60 seconds, otherwise write off.During burning, sample is blown or has combustionmaterial to break away from various reasons such as body drops and cause dried cotton burning, writes off.Be fixed on the test label on the sample, the part of afterfire or blackout must be less than 25% after tested, otherwise writes off.
Be evaluated as during the occasion of test result and the identical flame retardant resistance of halogen-containing flame retardant (comparative example) " zero ", the more halogen-containing difference as a result of flame retardant resistance but do not influence and use the problem of going up then with " △ ", on using, have problem then to represent with " X ".(tester table is along the crystal-clear system MODEL-1220S/1220HS of enterprise)
The clinging power test
Flame retardant resistance adhesive film and metallic conductor are passed between two rubber wheels, fit with 175 degree temperature and 1M/Min speed, utilize puller system to make conductor and flame retardant resistance adhesive film peel off its clinging power of test with 180 degree, when its clinging power during greater than 0.5kg/cm par be " zero " expression, when its clinging power during between 0.2～0.5kg/cm par be " △ " expression, par is " X " expression when its clinging power reaches 0.2kg/cm.(the system SB-A1 of tester table brightness in morning Electric Machine Co., Ltd)
The test result of table 2 flame retardant resistance and clinging power
| Flame retardant resistance tackiness agent prescription | Flame retardant resistance | Clinging power |
| Embodiment 1 | ○ | ○ |
| Embodiment 2 | ○ | X |
| Embodiment 3 | X | ○ |
| Embodiment 4 | ○ | ○ |
| Comparative example | ○ | ○ |
Annotate 1: be evaluated as during the occasion of as shown in table 2 and the identical flame retardant resistance of halogen-containing flame retardant (comparative example) " zero ", the more halogen-containing difference as a result of flame retardant resistance but do not influence and use the problem of going up then with " △ ", as having problem then to represent in the use with " X ".
Annotate 2: as shown in table 2ly be evaluated as " zero " expression during greater than 0.5kg/cm when its clinging power,, when its clinging power does not reach 0.2kg/cm, be evaluated as " X " and represent when its clinging power is evaluated as " △ " expression during between 0.2～0.5kg/cm.
(result of invention)
Can learn that by table 1 the flame retardant resistance tackiness agent among embodiment 1 and the embodiment 4 demonstrates and has excellent flame-retardant performance and clinging power, and the flame retardant resistance that is equal to mutually of realization and halogen flame.
Embodiment 2 makes its clinging power not reach the use standard because of the composition of flame retardant resistance tackiness agent divides polyethylene terephthalate (PET) content less.
Embodiment 3 makes its flame retardant resistance very inabundant because of the composition of flame retardant resistance tackiness agent divides melamine cyanurate content less.
In sum, use the flame retardant resistance tackiness agent of the comparative example of halogen flame in the past, can't solve the problem of its combustion gases.(practicality on the industry), can be kept good clinging power and can realize that with halogen be the flame retardant resistance that fire retardant is equal to mutually simultaneously at the flame retardant resistance tackiness agent or the adhesive film of the making that is applicable to flat cable of using non-halogen flame retardant according to the present invention.
The above for the person of ordinary skill of the art, can make other various corresponding changes and distortion according to technical scheme of the present invention and technical conceive, and all these changes and distortion all should belong to the protection domain of claim of the present invention.
Claims (10)
1. a non-halogen fire retardant tackiness agent is characterized in that, comprising: (A) vibrin of 40～60 weight percents; (B) the nitrogenous organic fire-retardant of 35～50 weight percents; Reach (C) inorganic filler of 1～20 weight percent.
2. non-halogen fire retardant tackiness agent as claimed in claim 1, it is characterized in that the nitrogenous organic fire-retardant of composition (B) is selected from least a kind or its combination in trimeric cyanamide, trimeric cyanamide diamide, trimeric cyanamide monoamide, melam, melamine cyanurate, melamine resin and the melamine derivative.
3. non-halogen fire retardant tackiness agent as claimed in claim 1, it is characterized in that composition (C) inorganic filler is selected from glass fibre, carbon fiber, mica, titanium dioxide, silicon-dioxide, talcum powder, high territory, how at least a kind or its combination in the rice clay.
4. non-halogen fire retardant tackiness agent as claimed in claim 1 is characterized in that, comprising: (A) vibrin of 45～55 weight percents; (B) the nitrogenous organic fire-retardant of 40～45 weight percents; Reach (C) inorganic filler of 2～15 weight percents.
5. non-halogen fire retardant tackiness agent as claimed in claim 4 is characterized in that, composition (A) vibrin is a saturated polyester resin.
6. non-halogen fire retardant tackiness agent as claimed in claim 5 is characterized in that, composition (A) saturated polyester resin is a polyethylene terephthalate.
7. non-halogen fire retardant tackiness agent as claimed in claim 6 is characterized in that, the nitrogenous organic fire-retardant of composition (B) is a melamine cyanurate.
8. non-halogen fire retardant tackiness agent as claimed in claim 6 is characterized in that, the nitrogenous organic fire-retardant of composition (B) is a melamine cyanurate, and composition (C) inorganic filler is a silicon-dioxide.
9. non-halogen fire retardant tackiness agent as claimed in claim 6 is characterized in that, the nitrogenous organic fire-retardant of composition (B) is a melamine cyanurate, and composition (C) inorganic filler is a titanium dioxide.
10. as each described non-halogen fire retardant tackiness agent in the claim 1 to 9, it is characterized in that this non-halogen fire retardant tackiness agent is used for flat cable.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009101889021A CN102093834A (en) | 2009-12-11 | 2009-12-11 | Non-halogen fire-retardant adhesive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009101889021A CN102093834A (en) | 2009-12-11 | 2009-12-11 | Non-halogen fire-retardant adhesive |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102093834A true CN102093834A (en) | 2011-06-15 |
Family
ID=44127103
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2009101889021A Pending CN102093834A (en) | 2009-12-11 | 2009-12-11 | Non-halogen fire-retardant adhesive |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102093834A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106009556A (en) * | 2016-08-10 | 2016-10-12 | 安徽省宁国天成电工有限公司 | Polyethylene glycol terephthalate plastic film used for heating cable |
-
2009
- 2009-12-11 CN CN2009101889021A patent/CN102093834A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106009556A (en) * | 2016-08-10 | 2016-10-12 | 安徽省宁国天成电工有限公司 | Polyethylene glycol terephthalate plastic film used for heating cable |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Khan et al. | A durable, flexible, large‐area, flame‐retardant, early fire warning sensor with built‐in patterned electrodes | |
| Vahabi et al. | Effects of ageing on the fire behaviour of flame‐retarded polymers: A review | |
| AU658550B2 (en) | Intumescent coating and method of manufacture | |
| US20080302544A1 (en) | Fire barrier fabric and related fire protective systems | |
| JP2008285804A (en) | Flame-retardant metal-coated fabric and gasket for shielding electromagnetic wave by using the same | |
| Zhao et al. | Flame retardancy and thermal degradation properties of polypropylene/wood flour composite modified with aluminum hypophosphite/melamine cyanurate | |
| CN107286563A (en) | A kind of expansion type flame retardant and its preparation and application for ABS electric switch outer covers | |
| CN103232635A (en) | Synergetic intumescent flame-retardant polypropylene composite material and preparation method thereof | |
| CN101070426A (en) | Glass-fiber reinforced fire-retardant polyamide resin composition | |
| KR100898418B1 (en) | The fire retardant adhesive compositon and the production method thereof | |
| CN105733253A (en) | Halogen-free flame-retardant high-temperature-resistant nylon composite | |
| CN101085859A (en) | Thermoplastic resin composition with excellent flame retardancy and impact resistance | |
| JP6782067B2 (en) | Organic materials as fireproof and flame retardant synergists | |
| JP5478609B2 (en) | Resin composition for heat resistant wires and heat resistant wires | |
| CN109735913A (en) | A kind of fire-retardant combination and preparation method thereof, artificial grass filaments, artificial grassplot back glue and chinampa | |
| CN102276979A (en) | Polyamide/phosphate glass flame-retardant material and preparation method thereof | |
| Li et al. | Improving the fire performance of structural insulated panel core materials with intumescent flame-retardant epoxy resin adhesive | |
| Lyu et al. | Thermal stability, flame retardance, and mechanical properties of polyamide 66 modified by a nitrogen–phosphorous reacting flame retardant | |
| CN100484993C (en) | Halogen-free flame-proof antistatic modified polypropylene composition useable in electric appliance casing | |
| Fang et al. | Preparation and properties of PA@ PANI conductive and flame retardant functional polyester fabric without droplet | |
| CN102093834A (en) | Non-halogen fire-retardant adhesive | |
| CN1204220C (en) | Flame-retardant adhesive flame-retardant adhesive film made using same, and flat cable | |
| CN104130505B (en) | Halogen-free flame-retardant crosslinked polypropylene as well as preparation method and application thereof | |
| KR101872019B1 (en) | Flame retardant resin composition | |
| CN103160113B (en) | A kind of antimicrobial halogen-free flame PET/PA6 alloy material and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20110615 |