CN102092986B - Additive of adhesive mortar for polystyrene insulation board - Google Patents
Additive of adhesive mortar for polystyrene insulation board Download PDFInfo
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- CN102092986B CN102092986B CN 201010573167 CN201010573167A CN102092986B CN 102092986 B CN102092986 B CN 102092986B CN 201010573167 CN201010573167 CN 201010573167 CN 201010573167 A CN201010573167 A CN 201010573167A CN 102092986 B CN102092986 B CN 102092986B
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- additive
- adhesive mortar
- thermal insulation
- insulation plate
- vinyl polymer
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Abstract
The invention provides an additive of adhesive mortar which is suitable for sticking a polystyrene insulation board to the outer wall of a building. The additive comprises the following components in percentage by weight: 0.5 to 40 percent of vinyl polymer, 1.0 to 5.0 percent of coupling agent, 45 to 80 percent of anti-caking filler and 10 to 20 percent of solvent or plasticizer. In the additive, the vinyl polymer with a similar property to the polystyrene insulation board is taken as adhesive resin, and is compounded with a certain amount of coupling agent which can be reacted with the vinyl polymer as well as inorganic materials such as cement, sand and the like simultaneously, so that the adhesive mortar comprising the additive can be well stuck to the polystyrene insulation board and a concrete wall face. The adhesive mortar comprising the additive has high bonding intensity, high water resistance, cost lowered by about 25 to 45 percent compared with that of the conventional adhesive mortar into which rubber powder or emulsion is added, and a good market prospect.
Description
Technical field
The present invention relates to a kind of additive, relate in particular to a kind of additive of adhesive mortar, more specifically relate to a kind of additive that is suitable for the adhesive mortar that skin paste polystyrene warming plate uses.
Background technology
At present, energy-saving and emission-reduction have become the common recognition of the whole society, and it is the guarantee that makes up Sustainable development society.Improve constantly along with what environment protection and save energy were required, the thermal insulation technology of architectural exterior-protecting construction has become one of important building energy conservation approach of China.In the multiple body of wall complex heat-preservation technology of at present having developed, be a kind of important method of wall thermal insulating at external wall paste polystyrene warming plate.Because XPS is an organic materials; Ordinary mortar and its bond effect are poor; The existing adhesive mortar that is used for skin paste polystyrene plate; Generally be to improve its cohesive force in interpolation rubber powder or emulsion in the conventional cement mortar of ether of cellulose modification, the rubber powder that adopts usually is ethene-vinyl acetate rubber powder, vinylformic acid rubber powder or sbr powder, and emulsion is ethene-vinyl acetate emulsion or ACRYLIC EMULSION.XPS comprises eps plate (EPS plate) and extrusion moulding type polystyrene plate (XPS plate); Be used to paste the adhesive mortar of EPS plate; The addition of rubber powder or emulsion generally is the 2%-3.5% of sand-cement slurry weight; And being used to paste the adhesive mortar of density than higher XPS plate, the addition of rubber powder or emulsion generally is more than 5% of sand-cement slurry weight; Price like pectin powder and emulsion is pressed 20 yuan of/kilogram calculating; The mortar of one ton of EPS plate that is used to bond only rubber powder or emulsion just needs 400-700 unit; Add 400 yuan of cement, sand and ether of cellulose; The cost of one ton of adhesive mortar just needs 800-1100 unit, and the adhesive mortar of one ton of XPS plate that is used to bond reaches more than 1400 yuan especially.Because the price of rubber powder or emulsion is higher and the addition in adhesive mortar is not low, causes it in the cost structure of adhesive mortar, to account for more than 50%, the adhesive mortar price that therefore is used for the paste polystyrene plate is always high; In addition, be added with the adhesive mortar of rubber powder or emulsion, poor water resistance, under the environment of humidity, its cohesive strength receives very big influence.
Summary of the invention
For overcoming the problem of above existence, the purpose of this invention is to provide a kind of additive of polystyrene thermal insulation plate adhesive mortar, the addition of this additive is few, and can make the adhesive mortar that contains this additive have the water tolerance that high cohesive strength is become reconciled.
For realizing above purpose, the additive of polystyrene thermal insulation plate adhesive mortar of the present invention comprises following each component and weight proportion:
Above-mentioned anti-caking filler adopts following particle diameter and grating:
Particle diameter＜1 micron 8-23% weight ratio
Particle diameter＞50 micron 77-92% weight ratio.
The preferred SE of above-mentioned vinyl polymer, Z 150PH, PS, Vilaterm or vinyl resin.
When vinyl polymer is Z 150PH, Vilaterm or vinyl resin, the weight proportion optimal ethylene based polyalcohol 20-40% of above-mentioned each component of additive, coupling agent 3-5%, anti-caking filler 45-60%, solvent or softening agent 10-20%.
When vinyl polymer is SE or PS, the weight proportion optimal ethylene based polyalcohol 0.5-20% of above-mentioned each component of additive, coupling agent 1-3%, anti-caking filler 60-85%, solvent or softening agent 10-20%.
In order to make the better and inorganic materials bonding of adhesive mortar ability, above-mentioned coupling agent preferred silane coupling agent or titanate coupling agent.
The preferred silicon ash of the anti-caking filler of above-mentioned particle diameter＜1 micron, SiO2 that this silicon ash produces when being smelting ferrosilicon and industrial silicon and Si gas and the rapid oxidation of airborne oxygen and condensation and a kind of ultra-fine siliceous powder body material that forms.
The preferred water-ground limestone of anti-caking filler and/or the flyash of above-mentioned particle diameter＞50 micron.
The preferred toluene of above-mentioned solvent, YLENE or vinyl acetate.
The preferred hexanodioic acid Ucar 35 of above-mentioned softening agent, Witcizer 300 or DOP.
The additive of polystyrene thermal insulation plate adhesive mortar of the present invention, its prescription has following advantage:
1, adhesive mortar additive of the present invention; Select for use the akin vinyl polymer of character and polystyrene thermal insulation plate as tacky resin; Making itself and XPS have good interface combines; Be equipped with simultaneously a certain amount of not only can with the vinyl polymer reaction but also can with the coupling agent of inorganic materials reactions such as cement, sand, the adhesive mortar that contains this additive can finely be pasted with XPS, can finely paste again with concrete wall surface; And through reacting the good stability of polymkeric substance in water that forms with coupling agent, the heat insulation system water tolerance that the XPS of being pasted by this adhesive mortar constitutes is greatly improved.
2, through adding a certain amount of anti-caking filler, vinyl polymer and coupling agent can better be distributed in the mortar, guarantee that adhesive mortar has uniform cohesive force.
3, through adding certain amount of solvent or softening agent, increase the plasticity and the flowability of polymkeric substance, make additive more easily, mixed with mortar more equably.
4, additive of the present invention, cohesive strength is high, and addition is few, can reduce the cost of XPS adhesive mortar greatly.
Embodiment
Embodiment 1
1, the prescription of additive and preparation
Prescription: Z 150PH 30%
Vinyl acetate 18%
Silane coupling agent 4%
Silicon ash 5%
Flyash 10%
Water-ground limestone 33%
Preparation: press above-mentioned weight ratio, each component is stirred is mixed with Powdered additive.
2, adhesive mortar preparation
Ratio in mortar weight 1% joins above-mentioned additive in the sand-cement slurry of ether of cellulose modification, is mixed with adhesive mortar.
3, cohesive force test
According to the cohesive strength of JG149-2003 " expanded polystyrene external insulating system for thinly plastered external wall " test adhesive mortar and polystyrene thermal insulation plate (EPS), the result is following:
Embodiment 2
1, the prescription of additive and preparation
Prescription: Vilaterm 3%
DOP 12%
Silane coupling agent 1%
Silicon ash 8%
Flyash 8%
Water-ground limestone 68%
Preparation: press above-mentioned weight ratio, each component is stirred is mixed with Powdered additive.
2, adhesive mortar preparation
Ratio in mortar weight 2.5% joins above-mentioned additive in the sand-cement slurry of ether of cellulose modification, is mixed with adhesive mortar.
3, cohesive force test
According to the cohesive strength of JG149-2003 " expanded polystyrene external insulating system for thinly plastered external wall " test adhesive mortar and polystyrene thermal insulation plate (XPS), the result is following:
Embodiment 3
1, the prescription of additive and preparation
Prescription: Vilaterm 20%
Hexanodioic acid Ucar 35 15%
Titanate coupling agent 1%
Silicon ash 14%
Flyash 8%
Water-ground limestone 42%
Preparation: press above-mentioned weight ratio, each component is stirred is mixed with Powdered additive.
2, adhesive mortar preparation
Ratio in mortar weight 0.8% joins above-mentioned additive in the sand-cement slurry of ether of cellulose modification, is mixed with adhesive mortar.
3, cohesive force test
According to the cohesive strength of JG149-2003 " expanded polystyrene external insulating system for thinly plastered external wall " test adhesive mortar and polystyrene thermal insulation plate (EPS), the result is following:
Can find out by above embodiment; Stickup for eps plate (EPS plate); Additive of the present invention addition in mortar is 0.8%, 1% o'clock; The cohesive strength of adhesive mortar and EPS plate is high, and after soak 7 sky and water, has still reached the JG149-2203 standard-required of 100% destruction EPS plate; For the stickup of extrudability XPS (XPS plate), additive of the present invention addition in mortar is 2.5% o'clock, and the cohesive strength of adhesive mortar and XPS plate is high, and after soak 7 sky and water, has still reached the JG149-2203 standard-required that destroys the XPS plate.If the price of additive of the present invention is by 20 yuan/kilogram, for the stickup of EPS plate, if addition is by 1%; One ton of adhesive mortar needs 200 yuan of additives of the present invention; Add 400 yuan of cement, sand, ether of cellulose, cost is 600 yuan, has reduced 25-45% than existing adhesive mortar price (800-1100 unit) of adding rubber powder or emulsion; Greatly reduce the price of XPS adhesive mortar, have good market outlook.
Claims (9)
1. the additive of a polystyrene thermal insulation plate adhesive mortar comprises following each component and weight proportion:
Wherein anti-caking filler adopts following particle diameter and grating:
Particle diameter＜1 micron 8-23% weight ratio
Particle diameter＞50 micron 77-92% weight ratio.
2. according to the said polystyrene thermal insulation plate adhesive mortar of claim 1 additive, it is characterized in that: said vinyl polymer is SE, Z 150PH, PS or Vilaterm.
3. according to the said polystyrene thermal insulation plate adhesive mortar of claim 2 additive; It is characterized in that: when vinyl polymer is Z 150PH or Vilaterm; The weight proportion of said each component of additive is vinyl polymer 20-40%, coupling agent 3-5%, anti-caking filler 45-60%, solvent or softening agent 10-20%.
4. according to the said polystyrene thermal insulation plate adhesive mortar of claim 2 additive; It is characterized in that: when vinyl polymer is SE or PS; The weight proportion of said each component of additive is vinyl polymer 0.5-20%, coupling agent 1-3%, anti-caking filler 60%, solvent or softening agent 10-20%.
5. according to claim 3 or 4 said polystyrene thermal insulation plate adhesive mortar additives, it is characterized in that: said coupling agent is silane coupling agent or titanate coupling agent.
6. according to claim 3 or 4 said polystyrene thermal insulation plate adhesive mortar additives, it is characterized in that: the anti-caking filler of said particle diameter＜1 micron is the silicon ash.
7. according to claim 3 or 4 said polystyrene thermal insulation plate adhesive mortar additives, it is characterized in that: the anti-caking filler of said particle diameter＞50 micron is water-ground limestone and/or flyash.
8. according to claim 3 or 4 said polystyrene thermal insulation plate adhesive mortar additives, it is characterized in that: said solvent is toluene, YLENE or vinyl acetate.
9. according to claim 3 or 4 said polystyrene thermal insulation plate adhesive mortar additives, it is characterized in that: said softening agent is hexanodioic acid Ucar 35, Witcizer 300 or DOP.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010573167 CN102092986B (en) | 2010-11-25 | 2010-11-25 | Additive of adhesive mortar for polystyrene insulation board |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010573167 CN102092986B (en) | 2010-11-25 | 2010-11-25 | Additive of adhesive mortar for polystyrene insulation board |
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| CN102092986A CN102092986A (en) | 2011-06-15 |
| CN102092986B true CN102092986B (en) | 2012-12-12 |
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| CN 201010573167 Active CN102092986B (en) | 2010-11-25 | 2010-11-25 | Additive of adhesive mortar for polystyrene insulation board |
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Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102992691B (en) * | 2012-12-20 | 2014-08-13 | 江南大学 | Additive for adhesive mortar of polystyrene heat-insulating plate and preparation method for same |
| CN105585292A (en) * | 2014-11-17 | 2016-05-18 | 天津禹神节能保温材料有限公司 | Adhesive mortar for external wall heat insulation |
| CN113150353B (en) * | 2021-04-29 | 2023-03-17 | 北京工业大学 | Preparation method of extruded polystyrene thermal insulation material/mortar covalent bonding system |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101205443A (en) * | 2007-12-05 | 2008-06-25 | 李旭东 | Adhesives for exterior wall insulation decorative boards |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004292613A (en) * | 2003-03-26 | 2004-10-21 | Sekisui Chem Co Ltd | Method for producing curable composition, curable composition, sealing material and adhesive |
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Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101205443A (en) * | 2007-12-05 | 2008-06-25 | 李旭东 | Adhesives for exterior wall insulation decorative boards |
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| Title |
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| JP特开2004-292613A 2004.10.21 |
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| CN102092986A (en) | 2011-06-15 |
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Address after: 515041 A, international commercial building, No. 106 Jinsha Road, Guangdong, Shantou, China 24B Applicant after: Guangdong Longhu Sci.&Tech. Company Limited Address before: 515041 A, international commercial building, No. 106 Jinsha Road, Guangdong, Shantou, China 24B Applicant before: Shantou SEZ Longhu S&T Co., Ltd. |
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