CN102087177A - Absorption solution and method for recognizing smoke smell - Google Patents

Absorption solution and method for recognizing smoke smell Download PDF

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Publication number
CN102087177A
CN102087177A CN 201010558590 CN201010558590A CN102087177A CN 102087177 A CN102087177 A CN 102087177A CN 201010558590 CN201010558590 CN 201010558590 CN 201010558590 A CN201010558590 A CN 201010558590A CN 102087177 A CN102087177 A CN 102087177A
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flue gas
absorption liquid
electronic tongue
weight
smoke
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CN102087177B (en
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李智宇
刘强
肖作兵
冒德寿
田怀香
冯涛
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Hongta Tobacco Group Co Ltd
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Hongta Tobacco Group Co Ltd
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Abstract

The invention provides an absorption solution which comprises sodium carboxy methyl cellulose, sorbitol, KCl and NaCl and is prepared from deionized water or ultrapure water. By taking the total amount of the absorption solution as the reference, the sodium carboxy methyl cellulose accounts for 0.5-1.5wt%, the sorbitol accounts for 2-4wt%, the KCl accounts for 0.1-0.14wt%, and the NaCl accounts for 0.7-1wt%. The invention also provides a method for recognizing smoke smell, comprising the following steps of: (1) collecting smoke: smoking by a smoking machine, collecting smoke released from the smoking machine by a smoke catcher via the absorption solution provided by the invention, and obtaining a mixture containing smoke, wherein each ml of mixture contains 0.04-0.3g of smoke released by burning cigarettes; and (2) detecting: putting the mixture containing the smoke into an electronic tongue detection device, moistening and cleaning an electronic tongue sensor by a moistening and cleaning agent, and reading numbers. The electronic tongue provided by the invention can accurately and objectively reflect the smell of the smoke when the electronic tongue is used for measuring the smell of the smoke.

Description

A kind of absorption liquid and a kind of method of discerning the flue gas taste
Technical field
The present invention relates to a kind of absorption liquid and a kind of method of discerning the flue gas taste.
Background technology
One of basic impression of the taste of flue gas is cigarette consumption person, so it is one of important indicator that influences cigarette quality and decision consumer hobby.And the planting environment of tobacco, processing technology and flavoring and casing technology etc. all have the influence of outbalance to cigarette quality, and are significant with the stable aspect that keeps product to the discriminating of tobacco brand or kind.For a long time, the evaluation of cigarette quality is mainly depended on sensory evaluation, yet because the difference of physiology such as the person of smokeing panel test is individual, sex and experience and psychology, the enough reliabilities of expression shortage of, sense of reality objective to taste; In evaluation procedure, need organize a large amount of personnel to be evaluated in addition, can't realize fast detecting.In addition, the tobacco of smokeing panel test in a large number, also very big to the able-bodied danger of the person of smokeing panel test, therefore make up and do not rely on the objective of the person's of smokeing panel test subjective judgement and detection system accurately, be a urgent and significant task.
In recent years, along with development of science and technology, particularly sensor is in the research of chemical field in recent years, and the detector that some are novel such as electronic tongue and Electronic Nose etc. begin to apply in the check of food flavor substances.2000, France Alpha MOS instrument company has released first commercialization electronic tongue Astree in the world, this electronic tongue can identify acid, sweet, bitter, salty taste more accurately, and provides the composition that its quantitative concentration can be used for analyzing fruit juice raw material.
At home and abroad, see about much more comparatively the utilization electronic tongue detects in Study on Flavor such as tealeaves and drinks, wherein Wu Jian etc. has done a kind of green tea Classification Study based on the electronic tongue technology, green tea is analyzed in the major component of the cyclic voltammetric signal of copper electrode, obtained distinguishing preferably effect.Liyama (2003) etc. utilizes taste sensor and glucose sensor array that the quality of sake is detected, this taste sensor array is made up of eight lipid membrane electrodes, utilize principal component analysis (PCA) to carry out pattern-recognition and dimensionality reduction, demonstrate the signal graph of bidimensional at last, represent titratable acidity and pol content respectively, had very big correlativity between the signal value output of electronic tongue and titratable acidity, the pol.
Yet the relevant research of electronic tongue aspect the identification of smoke of tobacco primary taste yet there are no report at home and abroad.
Summary of the invention
For set up do not rely on the objective of the person's of smokeing panel test subjective judgement and accurately detection system the smell road in the flue gas is discerned, one aspect of the present invention provides a kind of absorption liquid, wherein, this absorption liquid contains sodium carboxymethyl cellulose, sorbierite, KCl and NaCl, and with deionized water or ultrapure water preparation; General assembly (TW) with this absorption liquid is a benchmark, and the content of described sodium carboxymethyl cellulose is 0.5-1.5 weight %, and the content of described sorbierite is 2-4 weight %, and the content of described KCl is 0.1-0.14 weight %, and the content of described NaCl is 0.7-1 weight %.
The present invention also provides a kind of method of discerning the flue gas taste on the other hand, and wherein, this method comprises the steps:
(1) collects flue gas: carry out smoking with smoking machine, collect the flue gas at place that described smoking machine discharges with Fume collector and by the described absorption liquid of claim 1-3, acquisition contains the potpourri of flue gas, and wherein, every milliliter of this potpourri contains the flue gas that the burning of 0.04-0.3 gram cigarette is discharged;
(2) detect: the described potpourri that contains flue gas as in the electronic tongue pick-up unit, is used rinse agent rinse electronic tongue sensor, reading.
Experimental result shows when the method that adopts absorption liquid provided by the present invention and electronic tongue detects the taste of flue gas, the result who obtains is consistent with the result of existing taste by the person's of smokeing panel test evaluation of flue gas, but deviation is littler, approximately differ 10 times, thereby the taste that adopts the method for absorption liquid provided by the invention and electronic tongue to detect flue gas more can reflect the taste of flue gas accurately, objectively.
The method of identification flue gas taste provided by the invention is a kind of detection technique based on electronic tongue five tastes sensor, be that artificial intelligence machine is applied to once completely newly attempting in the identification of cigarette smoke primary taste, its purpose and meaning are to improve more effectively cigarette smoke primary taste objective evaluation result's accuracy, for artificial sensory evaluating smoking provides more objective and accurate reference frame, for the identification field that progressively artificial intelligence machine is applied to the cigarette smoke primary taste lays the foundation.
Embodiment
The invention provides a kind of absorption liquid, wherein, this absorption liquid contains sodium carboxymethyl cellulose, sorbierite, KCl and NaCl, and with deionized water or ultrapure water preparation; General assembly (TW) with this absorption liquid is a benchmark, and the content of described sodium carboxymethyl cellulose is 0.5-1.5 weight %, and the content of described sorbierite is 2-4 weight %, and the content of described KCl is 0.1-0.14 weight %, and the content of described NaCl is 0.7-1 weight %.
A kind of preferred embodiment in, this absorption liquid also contains the MgCl of 0.005-0.02 weight % 2, the CaCl of 0.005-0.0202 weight % 2, the KH of 0.01-0.1 weight % 2PO 4Adopt the absorption liquid of this prescription in the electronic tongue detection method, the result of detection is more accurate.
When flue gas did not detect after absorption at once, this absorption liquid preferably also contained 4 * 10 -4-8 * 10 -3The NaN of weight % 3, more preferably contain 4 * 10 -4-8 * 10 -4The NaN of weight % 3, go bad to prevent the potpourri that contains flue gas, influence testing result.
Absorption liquid provided by the invention can be used for the electronic tongue detection technique, is particularly useful for discerning in the detection technique of flue gas taste.
On the other hand, the invention provides a kind of method of discerning the flue gas taste, wherein, this method comprises the steps:
(1) collects flue gas: carry out smoking with smoking machine, collect the flue gas at place that described smoking machine discharges with Fume collector and by the described absorption liquid of claim 1-3, acquisition contains the potpourri of flue gas, and wherein, every milliliter of this potpourri contains the flue gas that the burning of 0.04-0.3 gram cigarette is discharged;
(2) detect: the described potpourri that contains flue gas as in the electronic tongue pick-up unit, is used rinse agent rinse electronic tongue sensor, reading.
A kind of preferred embodiment in, the described potpourri that contains flue gas contains the flue gas that the burning of 0.1-0.3 gram cigarette is discharged, the flue gas that 0.2-0.3 gram cigarette burning is more preferably discharged, the result of Jian Ceing is more accurate like this.
In detection method provided by the invention, described Fume collector can be the Fume collector of any model, and the flue gas that captures can be full flue gas or main flume.But a kind of preferred embodiment in, described Fume collector is a CO Module RM20H type, described flue gas is full flue gas.
Described smoking machine does not have special requirement when smoking, but a kind of preferred embodiment in, described smoking machine carries out smoking according to the ISO3308 defined terms.
In the method for identification flue gas taste provided by the invention, can adopt rinse liquid all in this area, but a kind of preferred embodiment in, described rinse liquid is deionized water or ultrapure water.
Although in detection method provided by the invention, described electronic tongue pick-up unit can be the electronic tongue device of this area any kind, a kind of preferred embodiment in, described electronic tongue device is α-ASTREE type.α-ASTREE electronic tongue pick-up unit (French Alpha MOS company) detects, and the five tastes sensor of this instrument is to be made by the silicon transistor that organism covers, and is furnished with 7 sensors (SRS, STS, SWS, BRS, SPS, UMS, GPS) on this device,
Ag/AgCl is as contrast electrode, and each sensor has different molecular films, can produce selective adsorption to different taste compound, and the variation of chemical reagent and ion is converted into electric signal, and then the data model that change in electric is become can explain.
When the potpourri that obtains to contain flue gas not being detected at once, preferred embodiment be that the potpourri that will obtain to contain flue gas places 0-5 ℃ environment to seal preservation, to prevent the leakage of rotten and flue gas.
The present invention is described by the following examples, adopts the brand of cigarette that Yuxi is arranged in an embodiment, red plum, horse bezoar, Marlboro, classics 100, their abbreviation is respectively YX, HM, MB, WBL, JD100.
Embodiment 1
Absorption liquid prescription 1: sodium carboxymethyl cellulose 10 grams, sorbierite 30 grams, KCl 1.2 grams, NaCl 8.5 grams are settled to 1 liter with ultrapure water.
Rinse liquid: ultrapure water.
Cigarette: Yuxi, red plum, horse bezoar, Marlboro, classical 100.
The flow process of electronic tongue device cigarette smoke taste: according to the ISO3308 defined terms above-mentioned five kinds of cigarette are aspirated with CO Module RM20H type smoking machine, 20 cigarettes of every kind of cigarette smoking (being equivalent to 18 grams), employing captures flue gas with 80 milliliters of above-mentioned absorption liquids with the cold trap trapping device of smoking machine configuration, capture all cigarettes of every kind of cigarette and prop up the flue gas that is discharged, obtain to contain the potpourri of flue gas.Inhale and finish, bottleneck sealing, absorption liquid sealing stored refrigerated;
The electronic tongue device is carried out steps such as self check, diagnosis and rectification, select for use the hydrochloric acid of 0.01M that sensor is calibrated, have reliability and stability with the data of guaranteeing to collect.
Each sample is got the above-mentioned potpourri that contains flue gas of 20ml and is poured in the special-purpose sample bottle of α-ASTREE electronic tongue pick-up unit electronic tongue, cleans with the sensor of deionized water to electronic tongue before mensuration, at room temperature carries out data acquisition.The time of each image data is 120 seconds, and getting the 120th second the empirical value in stable back is operational data, each sample duplicate measurements 4 times.
The flue gas of five kinds of cigarettes measured value size on each road sensor on the electronic tongue is as shown in table 1.
The actual measurement response of the main flume taste of five kinds of cigarettes of table 1 on the five tastes sensor on the electronic tongue
Figure BSA00000360562000051
In the gained data:
The red plum that records and the bitter taste relative standard deviation of Marlboro are high slightly, but (SD<30) all in allowed limits, video data result's reappearance is better.
Can to obtain following relative size relation as shown in table 2 by the gained result being carried out the grand computing of electronic tongue statistical software.
The relative response of the main flume taste of five kinds of cigarettes of table 2 on the five tastes sensor on the electronic tongue
Figure BSA00000360562000061
Be compared as follows according to the taste power of response five kinds of cigarettes:
Tart flavour: red plum>classics 100>Yuxi>horse bezoar>Marlboro
Sweet taste: red plum>classics 100>Yuxi>Marlboro>horse bezoar
Bitter taste: Marlboro>Yuxi>horse bezoar>classics 100>red plum
Saline taste: Yuxi>horse bezoar>classics 100>red plum>Marlboro
Embodiment 2
Absorption liquid prescription 2: sodium carboxymethyl cellulose 15 grams, sorbierite 20 grams, KCl 1.0 grams, NaCl 1.0 grams, MgCl 26H 2O 0.05 gram, anhydrous CaCl 20.101 gram, KH 2PO 40.35 gram, NaN 34.2 milligram is settled to 1 liter with deionized water.
Rinse liquid: deionized water.
Cigarette: Yuxi, red plum, horse bezoar, Marlboro, classical 100.
The flow process of electronic tongue device cigarette smoke taste: according to the ISO3308 defined terms above-mentioned five kinds of cigarette are aspirated with CO Module RM20H type smoking machine, 10 cigarettes of every kind of cigarette smoking (being equivalent to 9 grams), employing captures flue gas with 80 milliliters of above-mentioned absorption liquids with the cold trap trapping device of smoking machine configuration, capture the flue gas that all cigarettes of every kind of cigarette prop up, obtain to contain the potpourri of flue gas.
The electronic tongue device is carried out steps such as self check, diagnosis and rectification, select for use the hydrochloric acid of 0.01M that sensor is calibrated, have reliability and stability with the data of guaranteeing to collect.
Each sample is got the above-mentioned potpourri that contains flue gas of 20ml and is poured in the special-purpose sample bottle of α-ASTREE electronic tongue pick-up unit electronic tongue, cleans with the sensor of deionized water to electronic tongue in mensuration, at room temperature carries out data acquisition.The time of each image data is 120 seconds, and getting the 120th second the empirical value in stable back is operational data, each sample duplicate measurements 4 times.
The flue gas of five kinds of cigarettes measured value size on each road sensor on the electronic tongue is as shown in table 3.
The actual measurement response of the main flume taste of five kinds of cigarettes of table 3 on the five tastes sensor on the electronic tongue
Figure BSA00000360562000071
By the gained result being carried out the grand computing of electronic tongue statistical software, it is as shown in table 4 to obtain following relative size relation.
The relative response of the main flume taste of five kinds of cigarettes of table 4 on the five tastes sensor on the electronic tongue
Figure BSA00000360562000081
Be compared as follows according to the taste power of response five kinds of cigarettes:
Tart flavour: red plum>classics 100>Yuxi>horse bezoar>Marlboro
Sweet taste: red plum>classics 100>Yuxi>Marlboro>horse bezoar
Bitter taste: Marlboro>Yuxi>horse bezoar>classics 100>red plum
Saline taste: Yuxi>horse bezoar>classics 100>red plum>Marlboro
Embodiment 3
Absorption liquid prescription 3: sodium carboxymethyl cellulose 5 grams, sorbierite 40 grams, KCl 1.4 grams, NaCl 0.7 gram, MgCl 26H 2O 0.2 gram, anhydrous CaCl 20.05 gram, KH 2PO 41 gram, NaN 38 milligrams, be settled to 1 liter with deionized water.
Rinse liquid: deionized water.
Cigarette: Yuxi, red plum, horse bezoar, Marlboro, classical 100.
The flow process of electronic tongue device cigarette smoke taste: according to the ISO3308 defined terms five kinds of cigarette are aspirated with CO Module RM20H type smoking machine, 15 cigarettes of every kind of cigarette smoking (being equivalent to 13.5 grams), employing captures flue gas with 80 milliliters of above-mentioned absorption liquids with the cold trap trapping device of smoking machine configuration, capture the flue gas that all cigarettes of every kind of cigarette prop up, obtain to contain the potpourri of flue gas.
The electronic tongue device is carried out steps such as self check, diagnosis and rectification, select for use the hydrochloric acid of 0.01M that sensor is calibrated, have reliability and stability with the data of guaranteeing to collect.
Each sample is got the above-mentioned potpourri that contains flue gas of 20ml and is poured in the special-purpose sample bottle of α-ASTREE electronic tongue pick-up unit electronic tongue, cleans with the sensor of deionized water to electronic tongue in mensuration, at room temperature carries out data acquisition.The time of each image data is 120 seconds, and getting the 120th second the empirical value in stable back is operational data, each sample duplicate measurements 4 times.
The flue gas of five kinds of cigarettes measured value size on each road sensor on the electronic tongue is as shown in table 5.
The actual measurement response of the main flume taste of five kinds of cigarettes of table 5 on the five tastes sensor on the electronic tongue
Figure BSA00000360562000091
By the gained result is carried out grand computing, it is as shown in table 6 to obtain following relative size relation.
The relative response of the main flume taste of five kinds of cigarettes of table 6 on the five tastes sensor on the electronic tongue
Figure BSA00000360562000092
Be compared as follows according to the taste power of response five kinds of cigarettes:
Tart flavour: red plum>classics 100>Yuxi>horse bezoar>Marlboro
Sweet taste: red plum>classics 100>Yuxi>Marlboro>horse bezoar
Bitter taste: Marlboro>Yuxi>horse bezoar>classics 100>red plum
Saline taste: Yuxi>horse bezoar>classics 100>red plum>Marlboro
Embodiment 4
Absorption liquid prescription 4: sodium carboxymethyl cellulose 10 grams, sorbierite 30 grams, KCl 1.4 grams, NaCl 0.85 gram, MgCl 26H 2O 0.1 gram, anhydrous CaCl 20.202 gram, KH 2PO 40.001 gram is settled to 1 liter with deionized water.
Rinse liquid: deionized water.
Cigarette: Yuxi, red plum, horse bezoar, Marlboro, classical 100.
The flow process of electronic tongue device cigarette smoke taste: according to the ISO3308 defined terms five kinds of cigarette are aspirated with CO Module RM20H type smoking machine, 20 cigarettes of every kind of cigarette smoking (being equivalent to 18 grams), employing captures flue gas with 80 milliliters of above-mentioned absorption liquids with the cold trap trapping device of smoking machine configuration, capture the flue gas that all cigarettes of every kind of cigarette prop up, obtain to contain the potpourri of flue gas.
The electronic tongue device is carried out steps such as self check, diagnosis and rectification, select for use the hydrochloric acid of 0.01M that sensor is calibrated, have reliability and stability with the data of guaranteeing to collect.
Each sample is got the above-mentioned potpourri that contains flue gas of 20ml and is poured in the special-purpose sample bottle of α-ASTREE electronic tongue pick-up unit electronic tongue, cleans with the sensor of deionized water to electronic tongue in mensuration, at room temperature carries out data acquisition.The time of each image data is 120 seconds, and getting the 120th second the empirical value in stable back is operational data, each sample duplicate measurements 4 times.
The flue gas of five kinds of cigarettes measured value size on each road sensor on the electronic tongue is as shown in table 7.
The actual measurement response of the main flume taste of five kinds of cigarettes of table 7 on the five tastes sensor on the electronic tongue
Figure BSA00000360562000101
By the gained result is carried out grand computing, it is as shown in table 8 to obtain following relative size relation.
The relative response of the main flume taste of five kinds of cigarettes of table 8 on the five tastes sensor on the electronic tongue
Figure BSA00000360562000111
Be compared as follows according to the taste power of response five kinds of cigarettes:
Tart flavour: red plum>classics 100>Yuxi>horse bezoar>Marlboro
Sweet taste: red plum>classics 100>Yuxi>Marlboro>horse bezoar
Bitter taste: Marlboro>Yuxi>horse bezoar>classics 100>red plum
Saline taste: Yuxi>horse bezoar>classics 100>red plum>Marlboro
The artificial smoking result of four kinds of basic taste sensations of five kinds of cigarette
From the effect of human body when smokeing panel test as can be seen, comprehensively weigh the inherent quality of cigarette, must adopt " the whole method of smokeing panel test that circulates " just can obtain correct, objective conclusion.
Choose a kind of mark post cigarette (is mark post with red plum) earlier, the group of smokeing panel test (8 members) smokes panel test simultaneously to the mark post cigarette and confers the marking of mark post cigarette on basic taste sensation, through after reunification, again the sample cigarette that will estimate is evaluated marking.The marking foundation is for to carry out as following table 9 cigarette aesthetic quality standards of grading.
The sensory evaluation scores standard of four kinds of basic taste sensations of table 9 cigarette
Figure BSA00000360562000112
Figure BSA00000360562000121
Indicate: I level (9-7): strong (wherein 9 minutes extremely strong, 8 minutes strong, 7 minutes stronger);
II level (6-4): in (wherein strong in 6 minutes, in 5 minutes, weak in 4 minutes);
III level (3-1): weak (wherein 3 minutes a little less than, a little less than in the of 2 minutes, 1 split pole is weak);
The sense organ of four kinds of basic taste sensations of five kinds of brand cigarettes of table 10 gets submeter
Tart flavour: red plum>classics 100>Yuxi>horse bezoar>Marlboro
Sweet taste: red plum>classics 100>Yuxi>Marlboro>horse bezoar
Bitter taste: Marlboro>Yuxi>horse bezoar>classics 100>red plum
Saline taste: Yuxi>horse bezoar>classics 100>red plum>Marlboro
Experimental result shows: when adopting absorption liquid provided by the invention to adopt the method for electronic tongue to detect the taste of flue gas, the result of acquisition is consistent with the result of existing taste by the person's of smokeing panel test evaluation of flue gas; Yet the deviation that adopts electronic tongue method testing result of the present invention approximately differs 10 times well below smoke panel test resulting result's deviation of artificial sense.Therefore, the method that electronic tongue method provided by the invention detects the cigarette smoke taste not only can obtain correct result, and the gained result is more objective credible.

Claims (10)

1. an absorption liquid is characterized in that, this absorption liquid contains sodium carboxymethyl cellulose, sorbierite, KCl and NaCl, and with deionized water or ultrapure water preparation; General assembly (TW) with this absorption liquid is a benchmark, and the content of described sodium carboxymethyl cellulose is 0.5-1.5 weight %, and the content of described sorbierite is 2-4 weight %, and the content of described KCl is 0.1-0.14 weight %, and the content of described NaCl is 0.7-1 weight %.
2. absorption liquid according to claim 1, wherein, this absorption liquid also contains: the general assembly (TW) with this absorption liquid is a benchmark, the MgCl of 0.005-0.02 weight % 2, the CaCl of 0.005-0.0202 weight % 2, the KH of 0.01-0.1 weight % 2PO 4
3. absorption liquid according to claim 1 and 2, wherein, this absorption liquid also contains, and is benchmark with the general assembly (TW) of this absorption liquid, and 4 * 10 -4-8 * 10 -3The NaN of weight % 3
4. according to the application of any described absorption liquid among the claim 1-3 in identification flue gas taste.
5. a method of discerning the flue gas taste is characterized in that, this method comprises the steps:
(1) collects flue gas: carry out smoking with smoking machine, collect the flue gas that described smoking machine discharges with Fume collector and by the described absorption liquid of claim 1-3, acquisition contains the potpourri of flue gas, and wherein, every milliliter of this potpourri contains the flue gas that the burning of 0.04-0.3 gram cigarette is discharged;
(2) detect: the described potpourri that contains flue gas as in the electronic tongue pick-up unit, is used rinse agent rinse electronic tongue sensor, reading.
6. method according to claim 5, wherein, described Fume collector is a CO Module RM20H type, described flue gas is full flue gas.
7. method according to claim 5, wherein, described smoking machine carries out smoking according to the ISO3308 defined terms.
8. method according to claim 5, wherein, described rinse liquid is deionized water or ultrapure water.
9. method according to claim 5, wherein, described electronic tongue pick-up unit is α-ASTREE type.
10. method according to claim 5 wherein, places 0-5 ℃ environment to seal preservation in this potpourri after obtaining to contain the potpourri of flue gas.
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Publication number Priority date Publication date Assignee Title
CN114324760A (en) * 2021-12-29 2022-04-12 山东和富工程检测有限公司 Building materials product smell release testing arrangement

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CN1298096A (en) * 2000-12-08 2001-06-06 南京大学 Microwave spectrophotometric process for the fast detection of nitrosamine and nitroxide content in tobacco
CN101876651A (en) * 2010-07-02 2010-11-03 中国烟草总公司郑州烟草研究院 Method for measuring main carbonyl compounds in main stream cigarette smoke

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114324760A (en) * 2021-12-29 2022-04-12 山东和富工程检测有限公司 Building materials product smell release testing arrangement
CN114324760B (en) * 2021-12-29 2023-07-21 山东和富工程检测有限公司 Odor release testing device for building material products

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