CN102086337A - High-performance impact-resistance steel structure paint - Google Patents

High-performance impact-resistance steel structure paint Download PDF

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Publication number
CN102086337A
CN102086337A CN 201010608861 CN201010608861A CN102086337A CN 102086337 A CN102086337 A CN 102086337A CN 201010608861 CN201010608861 CN 201010608861 CN 201010608861 A CN201010608861 A CN 201010608861A CN 102086337 A CN102086337 A CN 102086337A
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component
epoxy
performance impact
resisting steel
steel structural
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CN102086337B (en
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张鹏珍
丁武斌
方军锋
李明
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Shanghai Hilong Shine New Material Co., Ltd.
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SHANGHAI HILONG SHINE NEW MATERIAL CO Ltd
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Abstract

The invention relates to the field of coating technology in chemical technology, in particular to high-performance impact-resistance steel structure paint, which comprises a component A and a component B, wherein the component A and the component B are used in combination according to the mass ratio of the component A to the component B of (3-5):1. In the invention, dimer acid addition modified toughened epoxy resin is added with potassium hexatitanate whisker with a tunnel-like structure and phenolic aldehyde modified amine is used as a curing agent, so the paint has high mechanical performance, chemical performance and high impact resistance; besides high anticorrosion performance, the 200-micrometer-thick coating on carbon steel plate can resist 200kg.cm impact; a coating process is safe and exerts fewer influences on the environment; and the damage rate of coated steel pipes in a transport process is greatly reduced, supplementary coating or recoating times are reduced, labor and materials are saved, cost is lowered and construction efficiency is improved.

Description

The high-performance impact resisting steel structural paint
Technical field
The present invention relates to the technical field of coatings of chemical industry technology, specifically, relate to the development of high-performance impact resisting steel structural paint.
Background technology
Steel construction coating is a kind of in the numerous paint, and it is applicable to pipeline and bridge, power equipment, rack and the etch-proof protections of all kinds of chemical industry equipment such as sewage, seawater, service water, oil transportation, gas transmission, is with a wide range of applications.But, finish the steel construction of outer wall coating in transportation with existing steel construction coating, because will be through lifting, automotive, or processes such as shipment, sea-freight, can be subjected in various degree collision, damage, therefore, present most coated steel structure all needs to carry out coating or overcoating after arriving the point of destination, this has not only wasted great amount of manpower and material resources, has improved cost, also can influence the progress of construction.
At present, main open source literature about stamping enamel has: Chinese patent CN 101580670A discloses " a kind of impact-resistant primer coating ", and the weight percent of this coating each component is: titanium dioxide slurry 52~62, n-butyl ether terpolycyantoamino-formaldehyde resin 5~7, sticking power promotor 2~4, elastic resin 5~7, propyl carbinol 2~5, ethyl acetate 4~6, conductive agent 0.5~1, dimethylbenzene 2~4, saturated polyester resin 14~24; Being formulated as of its titanium dioxide slurry: titanium dioxide 54, saturated polyester resin 36, dimethylbenzene 1, ethylene glycol ether acetate 2, solvent oil 2, dispersion agent 2.5, organobentonite 2.5.Chinese patent CN 101245208A discloses " compound zinc-rich paint of a kind of Shockproof corrosion resistant nano and preparation method thereof ", and this coating A component is formed massfraction and is: in the silicic acid of modulus 3~5-and sodium silicate solution 63%~85%, benzene emulsion or organosilicon crylic acid latex 10%~30%, zeopan inorganic gel 1%~5%, tensio-active agent FC80 0.1%~0.5%, BD-800 multifunctional assistant 0.1%~0.5%, BD-710 defoamer 0%~1%.Chinese patent CN 1197823A discloses " a kind of coating composition of shock-resistant wearing and tearing and preparation method thereof " and coated goods, it comprises (A) and has the aliphatic ester group of a plurality of reactive functional groups or the polymerization or the oligomeric composition of aliphatic ether, its reactive functional group degree is 2~5, equivalent weight is 150~750, and the compound that (B) contains a plurality of groups that can react with the reactive functional groups on the composition (A).
The stamping enamel of above-mentioned patent disclosure can satisfy the requirement of general impact resistance, be basically 45 microns following impact strengths greater than 50cmkg, mainly be applicable to aspects such as medical device, automobile.And steel construction is in transportation and hoisting process, and the external force that coating is subjected to is far longer than 50cmkg, and that the impact strength data of testing on general tinplate and carbon steel sheet will be big with respect to the impact strength data of steel construction (as steel pipe) material test piece is many.Therefore, develop the higher steel construction coating of a kind of impact resistance is the thing that steel construction manufacturer and anticorrosion manufacturer are concerned about always.
Summary of the invention
The objective of the invention is to overcome the deficiencies in the prior art, a kind of high impact-resistant is provided, steel construction coating with good chemicals-resistant corrosive nature and mechanical property, its protection against corrosion and shock resistance should be more excellent than currently available products, and the consume of steel construction coating in transportation after applying with it should obviously reduce.
For achieving the above object, the technical scheme taked of the present invention is:
A kind of high-performance impact resisting steel structural paint is characterized in that, comprises A component and B component, and the mass percent of two kinds of component raw material compositions is:
The A component:
Resins, epoxy 20.0~40.0%;
Resins, epoxy 1 5.0~10.0%;
Toughened resin 5.0~15.0%;
Thinner 10.0~30.0%;
Dispersion agent 0.1~0.3%;
Defoamer 0.2~0.5%;
Flow agent 0.3~0.8%;
Aerosil 0.5~2.5%;
Potassium titanate crystal whisker 1.0~4.0%;
Polynite 0.5~5.0%;
Titanium dioxide 10.0~25.0%;
Talcum powder 5.0~15.0%;
Carbon black 0.01~1.00%;
The B component:
Phenol aldehyde modified epoxy curing agent 5.0~15.0%;
Described A component and B component are used by mass ratio A:B=3~5:1.
The mass percent that described A component raw material is formed is preferably:
Resins, epoxy 25.0~36.0%;
Resins, epoxy 1 5.5~9.5%;
Toughened resin 6.0~12.0%;
Thinner 12.0%~25.0%;
Dispersion agent 0.15%~0.25%;
Defoamer 0.25%~0.35%;
Flow agent 0.35%~0.65%;
Aerosil 0.6%~1.5%;
Potassium titanate crystal whisker 1.5%~3.0%;
Polynite 1.0~4.0%;
Titanium dioxide 12.0%~20.0%;
Talcum powder 6.0%~12.0%;
Carbon black 0.02%~0.08%;
The mass percent that described B component raw material is formed is preferably:
Phenol aldehyde modified epoxy curing agent 8.0~12%.
Optionally, described Resins, epoxy is one or both in E-20 Resins, epoxy, the rubber modified epoxy resin.
Optionally, one or both in described toughened resin be the dimeracid addition modification Resins, epoxy, CTBN modified epoxy and the diglycidyl ether epoxy resin.
Optionally, the described thinner mixed diluent that is dimethylbenzene, propyl carbinol, pimelinketone.
Optionally, described dispersion agent is a BMC V2 salt unsaturated carboxylic acid.
Optionally, described defoamer is the fluorine-containing type siloxane defoamer of BMC 806.
Optionally, described flow agent is a BMC 1091S type siloxane flow agent.
Optionally, described potassium titanate crystal whisker is crystal whisker of hexa potassium titanate (K 2O6TiO 2) and/or the modified Nano polynite in one or both.
Optionally, the described solidifying agent phenol aldehyde modified amine epoxy curing agent that is Ka Delai.
The positively effect of high-performance impact resisting steel structural paint of the present invention is:
(1) Resins, epoxy of employing dimeracid addition modification, in CTBN modified epoxy and the diglycidyl ether epoxy resin one or both are as filmogen, add and to have the crystal whisker of hexa potassium titanate of tunnel-like structures and/or in the modified Nano polynite one or both as the shock resistance filler, adopt phenol aldehyde modified amine as solidifying agent, make this coating have favorable mechanical performance, chemical property and high shock resistance, except that good Corrosion Protection, the coating of 150 micron thickness on the carbon steel sheet can be more than the anti-200kg.cm impact;
(2) coating processes safety, little to the influence of environment;
(3) the coating loss percentage of steel construction in transportation of finishing coating reduced greatly, reduce coating or overcoating, save the man power and material, reduce cost, improve operating efficiency.
Embodiment
Below provide the embodiment of high-performance impact resisting steel structural paint of the present invention, provide 3 embodiment.But should be pointed out that enforcement of the present invention is not limited to following embodiment.
Embodiment 1The preparation of high-performance impact resisting steel structural paint
(1) proportioning raw materials
Comprise A component and B component, the mass percent of two kinds of component raw material compositions is:
The A component:
Resins, epoxy 28.00% adopts the product of HongChang Electronic Materials Co., Ltd or Yue Hua company of China Petrochemical Industry;
Resins, epoxy 1 8.00% adopts the product of Shenzhen Jia Dida chemical industry company limited;
Toughened resin 7.50%, group provides by the oceanic rise petroleum industry;
Thinner 22.65% adopts commercially available conventional material;
Dispersion agent 0.25% adopts two products that moisten chemical company;
Defoamer 0.34% adopts two products that moisten chemical company;
Flow agent 0.58% adopts two products that moisten chemical company;
Aerosil 0.80% adopts commercially available conventional material;
Potassium titanate crystal whisker 2.00%, group provides by the oceanic rise petroleum industry;
Polynite 2.00%, group provides by the oceanic rise petroleum industry;
Titanium dioxide 9.00% adopts the titanium white R-902 product of E.I.Du Pont Company;
Talcum powder 9.00% adopts the product of marine origin mining industry company limited;
Carbon black 0.03% adopts commercially available conventional material;
The B component:
Phenol aldehyde modified epoxy curing agent: 9.85%, adopt the product of Ka Delai company;
When coating uses A component and B component are used by mass ratio A:B=9.15:1.
A component and B component are stirred by proportioning, it are sprayed onto on the carbon steel sheet and intercepting steel pipe test plate (panel) of sandblast with the airless spraying method, treat completely solidified after, as the model of filming aFor performance evaluation.
(2) preparation method
Above-described high-performance impact resisting steel structural paint, its concrete preparation process comprises:
(1) prepares raw material
Prepare raw material by the mass percent that above-mentioned A component and B component raw material are formed;
(2) batching and dispersion
The mass percent of forming by A component raw material adds raw material in the scuffing of cylinder bore, starts the dispersion machine stirring at low speed, adds raw material while stirring, and raw material is after finish, (1000 to change/min) disperse 30min, to obtain dispersive A component compound at a high speed;
(3) grind
The A component compound that step (2) is scattered is put into sand mill and is carried out sand milling, and fineness reaches below 40 microns; The B component need not to grind;
(4) filter and package
The A component compound that sand milling is good is put into the finished product still, opens stirrer and stirs, and connects filtering net in the exit, carries out the packing of product while filtering, and A component and B component be packing separately.
Embodiment 2The preparation of high-performance impact resisting steel structural paint
(1) proportioning raw materials:
Comprise A component and B component, the mass percent of two kinds of component raw material compositions is:
The A component:
Resins, epoxy 30.00%;
Resins, epoxy 1 6.00%;
Toughened resin 6.00%;
Thinner 21.20%;
Dispersion agent 0.22%;
Defoamer 0.30%;
Flow agent 0.52%;
Aerosil 0.90%;
Potassium titanate crystal whisker 2.30%;
Polynite 3.00%;
Titanium dioxide 13.00%;
Talcum powder 6.53%;
Carbon black 0.03%;
The B component:
Phenol aldehyde modified epoxy curing agent 10.00%;
(source of above raw material is with embodiment 1)
When coating uses A component and B component are used by mass ratio A:B=9.00:1.
A component and B component are stirred by proportioning, it are sprayed onto on the carbon steel sheet and intercepting steel pipe test plate (panel) of sandblast with the airless spraying method, treat completely solidified after, as the model of filming bFor performance evaluation.
(2) preparation method (with embodiment 1).
Embodiment 3The preparation of high-performance impact resisting steel structural paint
(1) proportioning raw materials:
Comprise A component and B component, the mass percent of two kinds of component raw material compositions is:
The A component:
Resins, epoxy 25.00%;
Resins, epoxy 1 9.00%;
Toughened resin 9.00%;
Thinner 20.00%;
Dispersion agent 0.20%;
Defoamer 0.20%;
Flow agent 0.50%;
Aerosil 0.60%;
Potassium titanate crystal whisker 2.00%;
Polynite 1.00%;
Titanium dioxide 14.00%;
Talcum powder 8.73%;
Carbon black 0.05%;
The B component:
Phenol aldehyde modified epoxy curing agent: 9.72%;
(source of above raw material is with embodiment 1)
When coating uses with A component and B component by mass ratio A:B=9. 29:1 is used.
A component and B component are stirred by proportioning, it are sprayed onto on the carbon steel sheet and intercepting steel pipe test plate (panel) of sandblast with the airless spraying method, treat completely solidified after, as the model of filming cFor performance evaluation.
(2) preparation method (with embodiment 1).
The model performance of filming of the high-performance impact resisting steel structural paint of embodiment 1-3 preparation sees Table 1:
Table 1. is coated with lamina membranacea performance evaluation
Has superpower impact resistance from above test-results high-performance impact resisting steel structural paint of the present invention as can be seen than general protective system.
The high-performance impact resisting steel structural paint of embodiment 1-3 preparation and the performance index of coating are for seeing Table 2:
The performance index of table 2. coating and coating
Figure 166516DEST_PATH_IMAGE002
?。

Claims (10)

1. a high-performance impact resisting steel structural paint is characterized in that, comprises A component and B component, and the mass percent of two kinds of component raw material compositions is:
The A component:
Resins, epoxy 20.0~40.0%;
Resins, epoxy 1 5.0~10.0%;
Toughened resin 5.0~15.0%;
Thinner 10.0~30.0%;
Dispersion agent 0.1~0.3%;
Defoamer 0.2~0.5%;
Flow agent 0.3~0.8%;
Aerosil 0.5~2.5%;
Potassium titanate crystal whisker 1.0~4.0%;
Polynite 0.5~5.0%;
Titanium dioxide 10.0~25.0%;
Talcum powder 5.0~15.0%;
Carbon black 0.01~1.00%;
The B component:
Phenol aldehyde modified epoxy curing agent 5.0~15.0%;
Described A component and B component are used by mass ratio A:B=3~5:1.
2. according to right 1 described a kind of high-performance impact resisting steel structural paint, it is characterized in that the mass percent that described A component raw material is formed is:
Resins, epoxy 25.0~36.0%;
Resins, epoxy 1 5.5~9.5%;
Toughened resin 6.0~12.0%;
Thinner 12.0%~25.0%;
Dispersion agent 0.15%~0.25%;
Defoamer 0.25%~0.35%;
Flow agent 0.35%~0.65%;
Aerosil 0.6%~1.5%;
Potassium titanate crystal whisker 1.5%~3.0%;
Polynite 1.0~4.0%;
Titanium dioxide 12.0%~20.0%;
Talcum powder 6.0%~12.0%;
Carbon black 0.02%~0.08%;
The mass percent that described B component raw material is formed is:
Phenol aldehyde modified epoxy curing agent 8.0~12%.
3. according to right 1 or 2 described a kind of high-performance impact resisting steel structural paints, it is characterized in that optional, described Resins, epoxy is one or both in E-20 Resins, epoxy, the rubber modified epoxy resin.
4. according to right 1 or 2 described a kind of high-performance impact resisting steel structural paints, it is characterized in that one or both in the Resins, epoxy that optional, described toughened resin is the dimeracid addition modification, CTBN modified epoxy and the diglycidyl ether epoxy resin.
5. according to right 1 or 2 described a kind of high-performance impact resisting steel structural paints, it is characterized in that optional, described thinner is the mixed diluent of dimethylbenzene, propyl carbinol, pimelinketone.
6. according to right 1 or 2 described a kind of high-performance impact resisting steel structural paints, it is characterized in that optional, described dispersion agent is a BMC V2 salt unsaturated carboxylic acid.
7. according to right 1 or 2 described a kind of high-performance impact resisting steel structural paints, it is characterized in that optional, described defoamer is the fluorine-containing type siloxane defoamer of BMC 806.
8. according to right 1 or 2 described a kind of high-performance impact resisting steel structural paints, it is characterized in that optional, described flow agent is a BMC 1091S type siloxane flow agent.
9. according to right 1 or 2 described a kind of high-performance impact resisting steel structural paints, it is characterized in that optional, described potassium titanate crystal whisker is K 2O6TiO 2And/or in the modified Nano polynite one or both.
10. according to right 1 or 2 described a kind of high-performance impact resisting steel structural paints, it is characterized in that optional, described solidifying agent is the phenol aldehyde modified amine epoxy curing agent of Ka Delai.
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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103694853A (en) * 2013-12-13 2014-04-02 天津科瑞达涂料化工有限公司 Car oil tank inner-wall paint as well as preparation method and application thereof
CN103834141A (en) * 2014-01-15 2014-06-04 江苏华联电力器材有限公司 Insulating material for bus and preparation method thereof
CN105969061A (en) * 2016-06-17 2016-09-28 安庆市虹泰新材料有限责任公司 Method for preparing dimer acid/SiO2/epoxy resin composite paint
CN105969165A (en) * 2016-07-13 2016-09-28 蚌埠市正园电子科技有限公司 Impact-resistant water-based polyester coating and preparation method thereof
CN106010103A (en) * 2016-06-17 2016-10-12 安庆市虹泰新材料有限责任公司 Preparation method of dimer acid and SiO2 nanoparticle modified epoxy resin paint
CN106118379A (en) * 2016-06-17 2016-11-16 安庆市虹泰新材料有限责任公司 A kind of dimeric dibasic acid/SiO2the preparation method of/epoxy resin ternary coating
CN106337440A (en) * 2016-09-20 2017-01-18 蓝色海洋(天津)工程技术有限公司 Prefabricated pipeline overhaul well with corrosion prevention function
CN106867342A (en) * 2017-03-07 2017-06-20 沈阳宣伯新材料科技有限公司 The steel structure aqueous metallic paint of heavy antisepsis
CN107201136A (en) * 2017-05-19 2017-09-26 浙江帝恒实业有限公司 A kind of epoxide terrace and preparation method thereof, construction technology
CN108300149A (en) * 2017-09-18 2018-07-20 河北清华发展研究院 It is a kind of that there is wear-resisting epoxy coating and preparation method thereof

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CN101284969A (en) * 2007-04-14 2008-10-15 厦门双瑞船舶涂料有限公司 Solvent-free epoxy coal tar heavy duty anticorrosive coating and preparation process thereof
CN101619189A (en) * 2009-07-16 2010-01-06 青岛红树林投资有限公司 Underwater solventless epoxy anti-corrosive coating and preparation method thereof

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EP0774476A1 (en) * 1995-06-06 1997-05-21 Nof Corporation Thermosetting composition, method of finish coating, and coated articles
CN101284969A (en) * 2007-04-14 2008-10-15 厦门双瑞船舶涂料有限公司 Solvent-free epoxy coal tar heavy duty anticorrosive coating and preparation process thereof
CN101619189A (en) * 2009-07-16 2010-01-06 青岛红树林投资有限公司 Underwater solventless epoxy anti-corrosive coating and preparation method thereof

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103694853A (en) * 2013-12-13 2014-04-02 天津科瑞达涂料化工有限公司 Car oil tank inner-wall paint as well as preparation method and application thereof
CN103694853B (en) * 2013-12-13 2016-01-20 天津科瑞达涂料化工有限公司 Car oil tank inner-wall paint and preparation method thereof and application
CN103834141A (en) * 2014-01-15 2014-06-04 江苏华联电力器材有限公司 Insulating material for bus and preparation method thereof
CN103834141B (en) * 2014-01-15 2016-08-17 江苏华联电力器材有限公司 A kind of insulant for bus and preparation method thereof
CN106010103A (en) * 2016-06-17 2016-10-12 安庆市虹泰新材料有限责任公司 Preparation method of dimer acid and SiO2 nanoparticle modified epoxy resin paint
CN105969061A (en) * 2016-06-17 2016-09-28 安庆市虹泰新材料有限责任公司 Method for preparing dimer acid/SiO2/epoxy resin composite paint
CN106118379A (en) * 2016-06-17 2016-11-16 安庆市虹泰新材料有限责任公司 A kind of dimeric dibasic acid/SiO2the preparation method of/epoxy resin ternary coating
CN105969165A (en) * 2016-07-13 2016-09-28 蚌埠市正园电子科技有限公司 Impact-resistant water-based polyester coating and preparation method thereof
CN106337440A (en) * 2016-09-20 2017-01-18 蓝色海洋(天津)工程技术有限公司 Prefabricated pipeline overhaul well with corrosion prevention function
CN106337440B (en) * 2016-09-20 2020-01-24 蓝色海洋(天津)工程技术有限公司 Prefabricated type pipeline manhole with anticorrosive function
CN106867342A (en) * 2017-03-07 2017-06-20 沈阳宣伯新材料科技有限公司 The steel structure aqueous metallic paint of heavy antisepsis
CN107201136A (en) * 2017-05-19 2017-09-26 浙江帝恒实业有限公司 A kind of epoxide terrace and preparation method thereof, construction technology
CN108300149A (en) * 2017-09-18 2018-07-20 河北清华发展研究院 It is a kind of that there is wear-resisting epoxy coating and preparation method thereof

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