CN102080226A - Phosphorization solution - Google Patents

Phosphorization solution Download PDF

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Publication number
CN102080226A
CN102080226A CN2009103107137A CN200910310713A CN102080226A CN 102080226 A CN102080226 A CN 102080226A CN 2009103107137 A CN2009103107137 A CN 2009103107137A CN 200910310713 A CN200910310713 A CN 200910310713A CN 102080226 A CN102080226 A CN 102080226A
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CN
China
Prior art keywords
parts
phosphatization liquid
tetraacetic acid
edta
nitrate
Prior art date
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Pending
Application number
CN2009103107137A
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Chinese (zh)
Inventor
刘玉平
田继超
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
TIANJIN TIANGANG SPECIAL PETROLEUM PIPE MANUFACTURE CO Ltd
Original Assignee
TIANJIN TIANGANG SPECIAL PETROLEUM PIPE MANUFACTURE CO Ltd
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Application filed by TIANJIN TIANGANG SPECIAL PETROLEUM PIPE MANUFACTURE CO Ltd filed Critical TIANJIN TIANGANG SPECIAL PETROLEUM PIPE MANUFACTURE CO Ltd
Priority to CN2009103107137A priority Critical patent/CN102080226A/en
Publication of CN102080226A publication Critical patent/CN102080226A/en
Pending legal-status Critical Current

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Abstract

The invention provides a phosphorization solution. The phosphorization solution mainly consists of the following components in parts by weight in each unit volume: 40 parts of ferromanganese dihydrogen phosphate, 120 parts of zinc nitrate, 50 parts of manganese nitrate and 1 to 2 parts of ethylene diamine tetraacetic acid. The phosphorization solution is used for corrosion protection treatment of steel and iron pieces, enhances the bonding force between a coating film layer and a workpiece, improves the corrosion resistance of a coating on the surface of the workpiece after coating, and accords with the requirements of markets.

Description

A kind of phosphatization liquid
Technical field
The present invention relates to the surface chemistry technical field, especially a kind of phosphatization liquid.
Background technology
Phosphating process before the assemblings such as steel pipe is in order to protect internal and external threads to assemble not thread gluing, to guarantee the internal thread non-corrosive, improving impact resistance.The phosphatization liquid that can get better plays important effect for the quality-guarantee of products such as steel pipe.
Summary of the invention
Technical problem to be solved by this invention is to provide a kind of phosphatization liquid.
For solving the problems of the technologies described above, technical scheme of the present invention is:
A kind of phosphatization liquid mainly is made up of phosphate dihydrogen manganese molysite, zinc nitrate, manganous nitrate and ethylenediamine tetraacetic acid (EDTA), by 40 parts in phosphate dihydrogen manganese molysite, 120 parts of zinc nitrates, 50 parts of manganous nitrates, ethylenediamine tetraacetic acid (EDTA) 1-2 part in its parts by weight per unit volume.
Preferably, above-mentioned phosphatization liquid is by 40 parts in phosphate dihydrogen manganese molysite, 120 parts of zinc nitrates, 50 parts of manganous nitrates, 1.5 parts of ethylenediamine tetraacetic acid (EDTA)s in its parts by weight per unit volume.
The collocation method of above-mentioned phosphatization liquid, concrete steps stir promptly for after by above-mentioned parts by weight phosphate dihydrogen manganese molysite, zinc nitrate, manganous nitrate and ethylenediamine tetraacetic acid (EDTA) being dissolved respectively.
Preferably, the collocation method of above-mentioned phosphatization liquid, the solution solvent temperature is 40-50 ℃.
Beneficial effect of the present invention:
Above-mentioned phosphatization liquid is used for the anti-corrosion protective treatment of steel part, strengthens bonding force between application rete and workpiece, improves the solidity to corrosion of surface coating after the application, meets the demand in market.
Embodiment
Below in conjunction with specific embodiment technical scheme of the present invention is further described.
Embodiment 1
A kind of phosphatization liquid, component is as follows:
Figure B2009103107137D0000011
Embodiment 2
A kind of phosphatization liquid, component is as follows:
Figure B2009103107137D0000021
Embodiment 3
A kind of phosphatization liquid, component is as follows:
Figure B2009103107137D0000022
The collocation method of the described phosphatization liquid of the foregoing description 1-3, concrete steps stir promptly for after according to the above ratio phosphate dihydrogen manganese molysite, zinc nitrate, manganous nitrate and ethylenediamine tetraacetic acid (EDTA) being dissolved respectively.In addition, the solution solvent temperature can be controlled in 40-50 ℃ with accelerate dissolution.
The described phosphatization liquid of the foregoing description 1-3, using method is:
The water (distilled water or deionized water) that adds 2/3 volume in the phosphatization groove adds fully dissolving in the phosphatization groove with above-mentioned phosphatization liquid, stirs and can use.
In addition, solution temperature can be heated to 40-50 ℃ with accelerate dissolution, and can be according to using needs to add water to the respective specified volume.
Need boil 0.5-1 hour before adding the phosphating solution work that water configures, add some again through oil removing and the clean iron filings of pickling, carry out " iron filings processing ", to increase the ferrous ion in the solution, iron filings can carry out the phosphatization of pickling-washing-more repeatedly, color up to phosphating solution becomes stable brown-green or pale brown look, can produce.
Above-mentioned detailed description of this a kind of phosphatization liquid being carried out with reference to embodiment; be illustrative rather than determinate; can list several embodiment according to institute's limited range,, should belong within protection scope of the present invention therefore in the variation and the modification that do not break away under the general plotting of the present invention.

Claims (4)

1. phosphatization liquid, it is characterized in that: mainly form, by 40 parts in phosphate dihydrogen manganese molysite, 120 parts of zinc nitrates, 50 parts of manganous nitrates, ethylenediamine tetraacetic acid (EDTA) 1-2 part in its parts by weight per unit volume by phosphate dihydrogen manganese molysite, zinc nitrate, manganous nitrate and ethylenediamine tetraacetic acid (EDTA).
2. a kind of phosphatization liquid according to claim 1 is characterized in that: by 40 parts in phosphate dihydrogen manganese molysite, 120 parts of zinc nitrates, 50 parts of manganous nitrates, 1.5 parts of ethylenediamine tetraacetic acid (EDTA)s in its parts by weight per unit volume.
3. the collocation method of the described phosphatization liquid of claim 1-2 is characterized in that: concrete steps stir promptly for after by above-mentioned parts by weight phosphate dihydrogen manganese molysite, zinc nitrate, manganous nitrate and ethylenediamine tetraacetic acid (EDTA) being dissolved respectively.
4. the collocation method of root phosphatization liquid according to claim 4, the solution solvent temperature is 40-50 ℃.
CN2009103107137A 2009-12-01 2009-12-01 Phosphorization solution Pending CN102080226A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2009103107137A CN102080226A (en) 2009-12-01 2009-12-01 Phosphorization solution

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2009103107137A CN102080226A (en) 2009-12-01 2009-12-01 Phosphorization solution

Publications (1)

Publication Number Publication Date
CN102080226A true CN102080226A (en) 2011-06-01

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CN (1) CN102080226A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102367573A (en) * 2011-10-19 2012-03-07 中航力源液压股份有限公司 Precise composite phosphating tank solution and phosphating technology thereof
CN102851657A (en) * 2012-08-31 2013-01-02 成都天马铁路轴承有限公司 Phosphatization method for preventing generation of corrosion pits in railway antifriction bearing ring
CN104357818A (en) * 2014-11-14 2015-02-18 无锡伊佩克科技有限公司 Composition for steel phosphating and preparation method thereof
CN104962893A (en) * 2015-06-30 2015-10-07 大连碧城环保科技股份有限公司 Environmental phosphating solution

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102367573A (en) * 2011-10-19 2012-03-07 中航力源液压股份有限公司 Precise composite phosphating tank solution and phosphating technology thereof
CN102367573B (en) * 2011-10-19 2013-07-17 中航力源液压股份有限公司 Precise composite phosphating tank solution and phosphating technology thereof
CN102851657A (en) * 2012-08-31 2013-01-02 成都天马铁路轴承有限公司 Phosphatization method for preventing generation of corrosion pits in railway antifriction bearing ring
CN104357818A (en) * 2014-11-14 2015-02-18 无锡伊佩克科技有限公司 Composition for steel phosphating and preparation method thereof
CN104962893A (en) * 2015-06-30 2015-10-07 大连碧城环保科技股份有限公司 Environmental phosphating solution

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Application publication date: 20110601