CN102056667B - 制造结晶金属硅酸盐的方法 - Google Patents

制造结晶金属硅酸盐的方法 Download PDF

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Publication number
CN102056667B
CN102056667B CN2009801210818A CN200980121081A CN102056667B CN 102056667 B CN102056667 B CN 102056667B CN 2009801210818 A CN2009801210818 A CN 2009801210818A CN 200980121081 A CN200980121081 A CN 200980121081A CN 102056667 B CN102056667 B CN 102056667B
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metal silicate
mfi
heu
maz
mfs
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CN102056667A (zh
Inventor
梅廷·布鲁特
皮埃尔·雅各布斯
德尔菲因·米诺克斯
尼科莱·内斯特伦科
让-皮埃尔·达思
桑德·范唐克
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Total Petrochemicals Research Feluy SA
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Total Petrochemicals Research Feluy SA
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/005—Silicates, i.e. so-called metallosilicalites or metallozeosilites
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/023—Preparation of physical mixtures or intergrowth products of zeolites chosen from group C01B39/04 or two or more of groups C01B39/14 - C01B39/48
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/36—Pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C01B39/38—Type ZSM-5
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/36—Pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C01B39/38—Type ZSM-5
    • C01B39/40—Type ZSM-5 using at least one organic template directing agent
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
    • C07C2/862—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms
    • C07C2/864—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms the non-hydrocarbon is an alcohol
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
    • C10G29/20—Organic compounds not containing metal atoms
    • C10G29/205—Organic compounds not containing metal atoms by reaction with hydrocarbons added to the hydrocarbon oil
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/60—Synthesis on support
    • B01J2229/62—Synthesis on support in or on other molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/70—Catalyst aspects
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN2009801210818A 2008-06-06 2009-02-24 制造结晶金属硅酸盐的方法 Expired - Fee Related CN102056667B (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
EP08157768A EP2130585A1 (en) 2008-06-06 2008-06-06 Process for making crystalline metallosilicates
EP08157768.6 2008-06-06
EP09150781.4 2009-01-16
EP09150781 2009-01-16
PCT/EP2009/052169 WO2009146954A1 (en) 2008-06-06 2009-02-24 Process for making crystalline metallosilicates

Publications (2)

Publication Number Publication Date
CN102056667A CN102056667A (zh) 2011-05-11
CN102056667B true CN102056667B (zh) 2013-11-06

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US (1) US20110201861A1 (enExample)
EP (1) EP2300160B1 (enExample)
JP (1) JP5588973B2 (enExample)
KR (1) KR101290542B1 (enExample)
CN (1) CN102056667B (enExample)
WO (1) WO2009146954A1 (enExample)
ZA (1) ZA201008078B (enExample)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2698854A1 (en) * 2007-09-10 2009-03-19 Shell Internationale Research Maatschappij B.V. Zsm-5, its preparation and use in ethylbenzene dealkylation
US8440166B1 (en) * 2010-03-24 2013-05-14 University Of Puerto Rico Method of synthesizing a novel absorbent titanosilicate material (UPRM-5)
KR20130017165A (ko) * 2011-08-10 2013-02-20 서강대학교산학협력단 제올라이트 코어/실리카 제올라이트 쉘 복합체, 그의 제조 방법 및 그의 촉매적 용도
KR101663121B1 (ko) 2012-03-30 2016-10-06 제이엑스 에네루기 가부시키가이샤 실리케이트 피복 ＭＦＩ형 제올라이트와 그 제조 방법 및 그것을 이용한 ｐ-크실렌의 제조 방법
CN103664490B (zh) * 2012-09-05 2016-04-13 中国石油化工股份有限公司 甲苯甲醇烷基化的方法
US9186659B2 (en) * 2014-01-09 2015-11-17 King Fahd University Of Petroleum And Minerals Controlled growth of MTT zeolite by microwave-assisted hydrothermal synthesis
CN107349954B (zh) * 2017-07-05 2020-10-09 江南大学 一种合成气直接制备芳香族化合物的多级纳米反应器催化剂及其制备与应用
KR102655710B1 (ko) * 2019-02-20 2024-04-09 주식회사 엘지화학 층상 실리케이트 합성방법 및 이로부터 합성된 층상 실리케이트
US10843930B1 (en) * 2019-11-13 2020-11-24 Saudi Arabian Oil Company Systems and methods for synthesis of ZSM-22 zeolite
CN114247466B (zh) * 2021-12-02 2022-12-20 厦门大学 一种处理VOCs的低温等离子体协同催化剂及其制备方法和应用

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5354719A (en) * 1993-05-03 1994-10-11 Intevep, S.A. Method of manufacturing metallosilicates
CN101124160A (zh) * 2004-11-26 2008-02-13 道达尔法国公司 沸石材料及其制备和应用

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4203869A (en) * 1976-09-24 1980-05-20 Mobil Oil Corporation ZSM-5 Containing aluminum-free shells on its surface
US4377502A (en) * 1979-12-26 1983-03-22 Standard Oil Company (Indiana) Synthesis of crystalline aluminosilicate molecular sieves
US4394251A (en) * 1981-04-28 1983-07-19 Chevron Research Company Hydrocarbon conversion with crystalline silicate particle having an aluminum-containing outer shell
US4851605A (en) * 1984-07-13 1989-07-25 Exxon Research & Engineering Co. Process for synthesizing a zeolite catalyst on a pH controlled sodium free basis
DE3919098A1 (de) * 1989-06-10 1990-12-13 Vaw Ver Aluminium Werke Ag Verfahren zur herstellung von kristallinen und zeolithischen alumosilikaten
US5670130A (en) * 1989-08-09 1997-09-23 Exxon Chemical Patents Inc. (Ecpi) Zeolite L preparation
DE4120847A1 (de) * 1991-06-25 1993-01-14 Vaw Ver Aluminium Werke Ag Kristallines, zeolithanaloges gallosilicat und verfahren zu dessen herstellung
EP1044068A1 (en) * 1997-12-03 2000-10-18 Exxon Chemical Patents Inc. Catalyst comprising a zeolite partially coated with a second zeolite, its use for hydrocarbon conversion
US6843977B2 (en) * 2000-05-25 2005-01-18 Board Of Trustees Of Michigan State University Ultrastable porous aluminosilicate structures and compositions derived therefrom

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5354719A (en) * 1993-05-03 1994-10-11 Intevep, S.A. Method of manufacturing metallosilicates
CN101124160A (zh) * 2004-11-26 2008-02-13 道达尔法国公司 沸石材料及其制备和应用

Also Published As

Publication number Publication date
CN102056667A (zh) 2011-05-11
EP2300160B1 (en) 2015-12-23
KR20110014628A (ko) 2011-02-11
ZA201008078B (en) 2011-07-27
WO2009146954A1 (en) 2009-12-10
JP5588973B2 (ja) 2014-09-10
JP2011523619A (ja) 2011-08-18
US20110201861A1 (en) 2011-08-18
KR101290542B1 (ko) 2013-07-31
EP2300160A1 (en) 2011-03-30

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Owner name: TOTAL PETROCHEMICALS RESEARCH FELUY

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