CN102042561A - Reflective structure for lamp shade of illuminating lamp and producing method thereof - Google Patents
Reflective structure for lamp shade of illuminating lamp and producing method thereof Download PDFInfo
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- CN102042561A CN102042561A CN 200910110203 CN200910110203A CN102042561A CN 102042561 A CN102042561 A CN 102042561A CN 200910110203 CN200910110203 CN 200910110203 CN 200910110203 A CN200910110203 A CN 200910110203A CN 102042561 A CN102042561 A CN 102042561A
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Abstract
The invention relates to a reflective structure for a lamp shade of an illuminating lamp and a producing method thereof. The reflective structure comprises a reflective structure main body, wherein the reflective structure main body is provided with a reflective layer which is provided with high reflective rate to visible light and is made of metal; the upper surface of the reflective layer is provided with a protecting layer which is made of metal oxide or metal mixture and is capable of absorbing ultraviolet ray, and capable of penetrating through the visible light; and a transition coating layer is further arranged between the reflective structure main body and the reflecting layer. The reflective structure capable of absorbing the ultraviolet rays produced by the invention can absorb the ultraviolet rays emitted by an absorbing light source so as to eliminate the damage of the ultraviolet rays to people and articles so that the staff and the articles are safer. The reflective structure can reach the reflective rate up to 90% to the visible light; and the reflective structure can be used for producing green lighting products which are more personalized.
Description
Technical field
The present invention relates to field of illuminating lamps, relate in particular to a kind of reflective structure that is used for the lighting lampshade and preparation method thereof.
Background technology
In the present light source that lighting adopted, there are some can launch a spot of ultraviolet light or black light.Short time uses such light source not have big influence, if but long-time incognizant being under such light source irradiation, can bring negative effect unavoidably, especially when to some historical relics, textile, when the medical treatment product shine, long ultraviolet irradiation will directly cause these precious article damaged surfaces, make it lose due value gradually.The staff of long-term work under the irradiation of this light fixture healthyly also can be affected.
But the reflective structure of present most of light fixtures adopts rafifinal face or silver-colored face as reflective surface, though this reflective structure can high efficiency reflect visible light, satisfy the requirement of people, but also can reflect simultaneously the aging ultraviolet ray that catalytic action is arranged, human body is had injury effect of article to illuminance of lamp.Therefore, the reflective structure of lighting lampshade haves much room for improvement.
Summary of the invention
The technical problem to be solved in the present invention is, at the above-mentioned defective of prior art, provide a kind of simple in structure, cost is low, can absorb the reflective structure that is used for the lighting lampshade of ultraviolet ray, reflect visible light.
The technical problem that the present invention further will solve is, provides a kind of technology simple, the easy to operate preparation method of reflective structure of lampshade who is used to prepare lighting that can absorb ultraviolet ray, reflect visible light.
The technical solution adopted for the present invention to solve the technical problems is:
Construct a kind of reflective structure that is used for the lighting lampshade, be used to prepare the lampshade of lighting, comprise the reflective structure body with predetermined lampshade shape, wherein, described reflective structure body is provided with by the metal reflector layer that visible light is had high reflecting rate;
Described reflector layer upper surface is provided with by what metal oxide or metal mixture were made can absorb the protective layer that ultraviolet ray also sees through visible light.
Reflective structure of the present invention wherein, also is provided with tie coat between described reflective structure body and the described reflector layer, and described tie coat thickness is 5~30 microns.
Reflective structure of the present invention, wherein, the thickness of described reflector layer is 40~250 nanometers.
Reflective structure of the present invention, wherein, described protective layer is for being coated with layer, and thickness is 40~200 nanometers.
Reflective structure of the present invention, wherein, described protective layer is a coating, thickness is 3~10 microns.
Reflective structure of the present invention, wherein, the metal oxide that is used for preparing described protective layer comprises one or more of ceria, tantalum pentoxide, titanium monoxide, titanium dioxide, yittrium oxide, titanium sesquioxide or five oxidation Tritanium/Trititaniums; Described metal mixture comprises zirconium titanium mixture.
Reflective structure of the present invention, wherein, the metal that is used for preparing described reflector layer comprises one or more of aluminium, silver, gold, chromium and lawrencium.
Reflective structure of the present invention, wherein, described reflective structure body is made by fine aluminium, aluminium alloy, plastic cement, glass or pottery.
A kind of preparation method who is used for the reflective structure of lighting lampshade wherein, may further comprise the steps:
A, employing fine aluminium, aluminium alloy, plastic cement, glass or pottery are made any surface finish, pore-free, carrot-free reflective structure body, and adopt acid solution or alkali lye to clean up;
In B, employing aluminium, silver, gold, chromium and the lawrencium one or more, the thickness that is coated with high reflecting rate at described reflective structure body surface is the reflector layer of 40~250 nanometers;
C, on described reflector layer, be coated with or be coated with to be shaped on and be used to absorb ultraviolet protective layer by what metal oxide or metal mixture were made; described metal oxide comprises one or more in ceria, tantalum pentoxide, titanium monoxide, titanium dioxide, yittrium oxide, titanium sesquioxide or the five oxidation Tritanium/Trititaniums, and described metal mixture comprises zirconium titanium mixture.
Preparation method of the present invention, wherein, further comprising the steps of before the described step B:
B0, good, the thickness of spraying adhesion is 5~30 microns even transition coating on described reflective structure body, and to being coated with the reflective structure body of this tie coat, adopts high temperature drying or ultraviolet curing drying mode to carry out drying processing.
What the present invention prepared can absorb the ultraviolet reflective structure that can be used for the lighting lampshade, can absorb the ultraviolet light that light source sends, thereby eliminates the injury of ultraviolet ray to human body or article, makes staff and article safer.And reflective structure of the present invention can reach more than 90% the reflecting rate of visible light, can utilize it to prepare the green illumination product of hommization more.
Description of drawings
The invention will be further described below in conjunction with drawings and Examples, in the accompanying drawing:
Fig. 1 is the lampshade schematic diagram that adopts the reflective structure of the embodiment of the invention;
Fig. 2 is the enlarged diagram of the reflective structure of A part among Fig. 1.
The specific embodiment
Below in conjunction with diagram, the preferred embodiments of the present invention are described in detail.
The reflective structure that is used for the lighting lampshade of the present invention does not limit the shape of illuminating lamp shade, can be lampshade 10 as shown in Figure 1, can be the lampshade structure of other profiles, as C shape lampshade, circular lampshade, square lampshade, sphere shape lampshade or the like yet.Be mainly used in ultraviolet or black light in the light that absorbs light source 20 emissions that are installed on the lampshade, and reflect visible light.
The reflective structure schematic diagram of the local A of lampshade shown in Fig. 1 10 as shown in Figure 2, it mainly comprises reflective structure body 11, reflector layer 13 and protective layer 14, between reflective structure body 11 and reflector layer 13, also tie coat 12 can be set as required.
Wherein reflective structure body 11 mainly is to be made by the base material that aluminium, aluminium alloy, plastic cement, glass or pottery etc. are convenient to moulding, can earlier this base material be made the shape that needs, and sets gradually tie coat 12, reflector layer 13 and protective layer 14 again on its surface.Because the surface of reflective structure body 11 need apply, therefore should be bright and clean, pore-free, no burr.
It is 5~30 microns tie coat 12 that reflective structure body 11 is provided with homogeneous thickness, and this tie coat 12 is general to adopt priming paint, or the good coating material of other associativity.
Tie coat 12 surfaces are provided with the reflector layer 13 that visible light is had high reflecting rate, mainly make by the good metal of reflective function, wherein metal comprises aluminium, silver, gold, chromium, lawrencium etc., also comprise in aluminium, silver, gold, chromium, the lawrencium at least two kinds alloy, tie coat 12 thickness are generally 40~250 nanometers.
If adhesion is good between reflective structure body and the reflector layer, need not spray or be coated with tie coat 12 between reflective structure body 11 and the reflector layer 13, directly with reflector layer 13 spraying or be coated on reflective structure body 11 surfaces, when adopting glass as base material; Otherwise then needing increases adhesion with priming paint, when adopting fine aluminium, aluminium alloy, plastic cement as base material; During as base material, can select whether to need to be coated with tie coat with pottery according to actual needs.
Reflector layer 13 surfaces are provided with the protective layer 14 that can absorb ultraviolet ray and see through visible light; protective layer 14 can adopt and be coated with layer or coating, when protective layer 14 when being coated with layer, its thickness is 40~200 nanometers; when protective layer 14 was coating, its thickness was 3~10 microns.Protective layer 14 is made by metal oxide or metal mixture; wherein metal oxide comprises one or more in ceria, tantalum pentoxide, titanium monoxide, titanium dioxide, yittrium oxide, titanium sesquioxide or the five oxidation Tritanium/Trititaniums; metal mixture can be a zirconium titanium mixture; above material have have stable high-temperature performance, cheap, absorb ultraviolet ray and do not absorb advantage such as visible light, specific nature is as shown in table 1 below.
Table 1 is used for each material physical property of protective layer
The name of an article | Molecular formula | Fusing point ℃ | Purity (%) | Refractive index | Transparent wave band (u) |
Tantalum pentoxide | Ta 2O 5 | 1800 | 99.99 | 2.3 | 0.35-9 |
Five oxidation Tritanium/Trititaniums | Ti 3O 5 | 1750 | 99.99 | 2.2-2.3 | 0.4-12 |
Titanium sesquioxide | Ti 2O 3 | 1880 | 99.9 | 2.2-2.3 | 0.4-12 |
Titanium monoxide | TiO | 1750 | 99.9 | 2.2-2.3 | 0.4-12 |
Titanium dioxide | TiO 2 | 1800 | 99.99 | 2.3 | 0.36-9 |
Yittrium oxide | Y 2O 3 | 2680 | 99.99 | 1.89 | 0.3-12 |
Ceria | CeO 2 | 2600 | 99.9 | 2.2 | 0.46-11 |
The concrete steps of reflective structure preparation provided by the present invention are as follows:
The first step is made a reflective structure body earlier, and the material of selecting for use can be base materials such as aluminium, aluminium alloy, plastic cement, glass, pottery, because its surface needs plated film, therefore should be bright and clean, and forming defects such as pore-free, no burr.
Second step, according to the pollution condition of reflective structure body in manufacturing process, use correspondingly that cleaning fluid cleans, commonly used have alkali cleaning or a pickling.
The 3rd step, for guaranteeing vacuum evaporation coating quality, spraying one deck tie coat on the reflective structure body surface, be generally priming paint, priming paint and reflective structure body and reflector layer afterwards will all have good adhesion, and need meet the heatproof requirement, and this thickness of crossing coating is generally 5~30 microns, and should apply evenly, its effect has:
1) by priming paint sealing base material, the volatile materials when preventing vacuum coating in the base material is overflowed, and influences coating quality;
2) substrate surface is more coarse, by the priming paint preliminary treatment, can obtain smooth smooth mirror effect;
3) base material that surface polarity is lower adhesive force common and coating is relatively poor, can obtain adherence of coating energy preferably by coating prime lacquer, and improve reflection efficiency;
4) to the relatively poor base material of some heat resistance, priming paint can play the slow effect of heat, and the protection base material exempts from thermal-induced deformation.
The 4th step, the reflective structure body that scribbles priming paint is carried out drying, can select different drying modes according to the kind of priming paint, commonly used have high temperature drying and a ultraviolet curing drying.
The 5th step was coated with the reflector layer that can improve reflecting rate on the tie coat surface, and this reflector layer can be metals such as aluminium, silver, gold, chromium, lawrencium, or their alloy, the thickness of reflector layer preferably between 40 nanometers~250 nanometers, has approached very much easy light leak, and too thick then hot tearing performance is bad.
The 6th step; vacuum is coated with or application one deck can absorb ultraviolet protective layer on the reflecting coating surface; this protective layer can absorb in the ultraviolet metal oxide one or more by ceria, tantalum pentoxide, titanium monoxide, titanium dioxide, yittrium oxide, titanium sesquioxide, five oxidation Tritanium/Trititaniums etc. and make; the physical property of various materials is as shown in table 1; or can absorb ultraviolet metal mixture by some, make as zirconium titanium mixture etc.
The coating that protective layer can be coated with or apply; but single sometimes rete is limited to ultraviolet absorption; weatherability for better ultraviolet ray filtering, raising protective layer; can consider to be coated with or coated with multiple layer; but no matter the number of plies what; its gross thickness generally remains a stationary value, if it is bad to have approached very much the effect of ultraviolet ray filtering, and the too thick reflector efficiency that then influences reflective structure.If be coated with layer, thickness generally is about 40~200 nanometers, if coating, its thickness is about 3~10 microns.
Wherein, reflector layer and protective layer all can be coated with under vacuum condition; with the coating material is that cerium di-oxide layer is an example; concrete operations are; in order to eliminate the moisture that coating materials inflammability impurity and its strong hygroscopicity form, must earlier the base material that scribbles priming paint be toasted or sintering under 800~1100 ℃ high temperature in air, again under vacuum condition; tungsten sheet with 0.4~0.5 millimeters thick is made the evaporation boat, heating evaporation coating material ceria (CeO
2), it is deposited on be gets final product on the about 50 ℃ reflective structure body 18 inches away from evaporation source more than.
Energy provided by the present invention absorbs ultraviolet reflective structure, not only can be used for being prepared into the reflector of light fixture, can also be used for the reflector surface, enumerates two object lessons below and is illustrated.
Embodiment 1
With 1050 fine aluminiums is the substrate preparation reflective structure, earlier 1050 fine aluminiums is spun into 1 millimeters thick, has and need the reflector of shape body; Again the reflector body being carried out degreasing-washing-drying successively handles; With 3.5~4.0kg/cm
2Spray pressure is priming paint, as the commercial Taiwan male CN-885 priming paint that shakes, sprays on the dried reflective structure body, and this coating layer thickness is 7 microns; Again at normal temperatures behind the slow-speed levelling, put into 180 ℃ dry 50~60 minutes of insulating box; Adopting conventional vacuum vapour deposition to be coated with 200 nanometer thickness, purity again is 99.9% aluminium film; Adopt conventional RF ion plating embrane method to be coated with the titanium dioxide diaphragm of 150 nanometer thickness to the aluminium film.
After tested, more than prepared reflective structure can absorb the ultraviolet ray more than 80% in the light source, reflectivity remains on more than 90%.
Embodiment 2
With glass is the substrate preparation reflective structure, earlier glass is pressed into about 2.4 millimeters of thickness, has and need the reflector of shape body, after it was carried out dedusting, cleaning, drying, the purity that is coated with about 200 nanometers of thickness in its surface vacuum evaporation was 99.9% aluminium film, 5 * 10
-6Under the torr vacuum, oxygen partial pressure is by force 5 * 10
-5Torr (wherein, torr is a torr, and 1 torr is equivalent to the pressure of 1 millimeter of mercury) with electron beam heating evaporation five oxidations two titaniums, with the deposition rate of 0.6 nm/sec, is coated with thickness and is 120 millimeters five oxidations, two titanium diaphragms on 250 ℃ aluminium film.
After tested, prepared reflective structure reaches more than 90% absorption of UV, and the reflectivity of reflector remains on more than 92%.
In use, the light that sends from light source is when the outermost protective layer of reflective structure, and ultraviolet light wherein is absorbed, thereby has eliminated the injury of ultraviolet ray to human body and article, makes staff and article safer.Simultaneously, because the thickness of protective layer is suitable, be convenient to a large amount of reflect visible light lines of reflector layer, reflecting rate can reach more than 90%, can guarantee enough illuminances, can be used for preparing the green illumination product of hommization more.
Should be understood that, for those of ordinary skills, can be improved according to the above description or conversion, and all these improvement and conversion all should belong to the protection domain of claims of the present invention.
Claims (10)
1. a reflective structure that is used for the lighting lampshade comprises the reflective structure body, it is characterized in that, described reflective structure body is provided with the reflector layer that is made of metal that visible light is had high reflecting rate;
Described reflector layer surface is provided with by what metal oxide or metal mixture were made can absorb the protective layer that ultraviolet ray also sees through visible light.
2. reflective structure according to claim 1 is characterized in that, also is provided with thickness between described reflective structure body and the described reflector layer and is 5~30 microns tie coat.
3. reflective structure according to claim 2 is characterized in that, described reflector layer thickness is 40~250 nanometers.
4. reflective structure according to claim 3 is characterized in that, described protective layer is for being coated with layer, and thickness is 40~200 nanometers.
5. reflective structure according to claim 4 is characterized in that, described protective layer is a coating, and thickness is 3~10 microns.
6. reflective structure according to claim 1, it is characterized in that the metal oxide that is used for preparing described protective layer comprises one or more of ceria, tantalum pentoxide, titanium monoxide, titanium dioxide, yittrium oxide, titanium sesquioxide or five oxidation Tritanium/Trititaniums; Described metal mixture comprises zirconium titanium mixture.
7. reflective structure according to claim 1 is characterized in that, the metal that is used for preparing described reflector layer comprises one or more of aluminium, silver, gold, chromium and lawrencium.
8. reflective structure according to claim 2 is characterized in that, described reflective structure body is made by aluminium, aluminium alloy, plastic cement, glass or pottery.
9. a preparation method who is used for the reflective structure of lighting lampshade is characterized in that, may further comprise the steps:
A, employing fine aluminium, aluminium alloy, plastic cement, glass or pottery are made any surface finish, pore-free, carrot-free reflective structure body, and adopt acid solution or alkali lye to clean up;
In B, employing aluminium, silver, gold, chromium and the lawrencium one or more, the thickness that is coated with high reflecting rate at described reflective structure body surface is the reflector layer of 40~250 nanometers;
C, on the surface of described reflector layer, be coated with or coat by what metal oxide or metal mixture were made and be used to absorb ultraviolet protective layer; described metal oxide comprises one or more in ceria, tantalum pentoxide, titanium monoxide, titanium dioxide, yittrium oxide, titanium sesquioxide or the five oxidation Tritanium/Trititaniums, and described metal mixture comprises zirconium titanium mixture.
10. the preparation method who is used for the reflective structure of lighting lampshade according to claim 9 is characterized in that, and is further comprising the steps of before the described step B:
B0, good, the thickness of spraying adhesion is 5~30 microns even transition coating on described reflective structure body, and to being coated with the reflective structure body of this tie coat, adopts high temperature drying or ultraviolet curing drying mode to carry out drying processing.
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Cited By (6)
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CN102514295A (en) * | 2011-12-02 | 2012-06-27 | 上海安美特铝业有限公司 | Ultrahigh-reflectivity composite material and preparation method thereof |
CN103032820A (en) * | 2013-01-10 | 2013-04-10 | 严余山 | Production method for reflecting housing of nano-optical energy saving lamp |
CN103075664A (en) * | 2012-12-31 | 2013-05-01 | 深圳市文卓绿色环保科技有限公司 | LED (Light Emitting Diode) ceramic substrate-based lamp and manufacturing method thereof |
CN104676539A (en) * | 2013-12-03 | 2015-06-03 | 苏州承源光电科技有限公司 | Street lamp LED (light-emitting diode) heat sink |
CN110587367A (en) * | 2019-09-29 | 2019-12-20 | 张家港科杰机械装备有限公司 | High efficiency reducing gear box apparatus for producing |
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2009
- 2009-10-21 CN CN 200910110203 patent/CN102042561B/en not_active Expired - Fee Related
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102514295A (en) * | 2011-12-02 | 2012-06-27 | 上海安美特铝业有限公司 | Ultrahigh-reflectivity composite material and preparation method thereof |
CN103075664A (en) * | 2012-12-31 | 2013-05-01 | 深圳市文卓绿色环保科技有限公司 | LED (Light Emitting Diode) ceramic substrate-based lamp and manufacturing method thereof |
CN103032820A (en) * | 2013-01-10 | 2013-04-10 | 严余山 | Production method for reflecting housing of nano-optical energy saving lamp |
CN103032820B (en) * | 2013-01-10 | 2014-01-01 | 严余山 | Production method for reflecting housing of nano-optical energy saving lamp |
CN104676539A (en) * | 2013-12-03 | 2015-06-03 | 苏州承源光电科技有限公司 | Street lamp LED (light-emitting diode) heat sink |
CN110587367A (en) * | 2019-09-29 | 2019-12-20 | 张家港科杰机械装备有限公司 | High efficiency reducing gear box apparatus for producing |
CN112471827A (en) * | 2020-12-04 | 2021-03-12 | 北京三月雨文化传播有限责任公司 | Exhibition device based on 5G application |
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