CN102039699B - Metal foil laminated film and manufacture method thereof - Google Patents

Metal foil laminated film and manufacture method thereof Download PDF

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Publication number
CN102039699B
CN102039699B CN201010286394.3A CN201010286394A CN102039699B CN 102039699 B CN102039699 B CN 102039699B CN 201010286394 A CN201010286394 A CN 201010286394A CN 102039699 B CN102039699 B CN 102039699B
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CN
China
Prior art keywords
metallic substrate
substrate layer
metal
foil laminated
metal foil
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Expired - Fee Related
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CN201010286394.3A
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Chinese (zh)
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CN102039699A (en
Inventor
辛龙承
任基烈
金珍秀
裴娥贤
李坽洙
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Samsung Electronics Co Ltd
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Samsung Electronics Co Ltd
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Publication of CN102039699A publication Critical patent/CN102039699A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/04Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B15/08Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/14Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M1/00Inking and printing with a printer's forme
    • B41M1/12Stencil printing; Silk-screen printing

Abstract

The present invention openly can make outward appearance have metal-like, guarantee that electric wave can present the metal foil laminated film of one and the manufacture method thereof of various appearances pattern through characteristic.Metal foil laminated film can be presented on apparent pattern by adopting metal material to be formed in metallic substrate layer, and stackedly color printing layer and injection article are set and manufacture, or binding metal sheet material in metallic substrate layer, and adopt punch process and be fabricated to one.

Description

Metal foil laminated film and manufacture method thereof
Technical field
The present invention relates to and a kind ofly outward appearance can be made to have metal-like, guarantee that electric wave can present metal foil laminated film and the manufacture method thereof of various appearances pattern through characteristic.
Background technology
Usually, comprise the shells of portable terminal such as mobile phone, PDA, hand-held computer or the decoration panel of household electrical appliance mostly to adopt macromolecular material to carry out injection mo(u)lding to form.In order to add pattern on the surface of these shells or panel, adopt insert-moulding technique or surface screen-printed technology.
In addition, use metal material to present metal-like in appearance, and adopt the methods such as anodic oxidation (anodizing), application, printing, evaporation to form desired pattern.But the technique of processing metallic is comparatively complicated, and causes expense to increase due to the increase of technique number of times, therefore causes manufacturing cost to increase.And, in phone housing, in order to the Signal reception preventing the wave shield effect produced owing to using metal material from causing is bad, plastics are adopted to carry out injection mo(u)lding the definite part at antenna place, so, need to manufacture the assembly structure adopted by the bi-material of metal material and plastics, be therefore difficult to make monolithic case or panel present metal-like, thus be restricted when needs embody various appearances design.
Summary of the invention
The present invention proposes to solve the problem, and its object is to provides one that outward appearance can be made to have metal-like, guarantees that electric wave is through characteristic, and can present metal foil laminated film and the manufacture method thereof of various appearances pattern.
To achieve these goals, comprise according to the metal foil laminated film of the embodiment of the present invention: adopt metal material to form the metallic substrate layer being presented on apparent pattern; The color printing layer formed for presenting color in the background parts except described pattern; For the stacked injection article arranging described metallic substrate layer and injection mo(u)lding.
Further, described injection article is the casting resin layer adopting transparent resin injection mo(u)lding.
Further, the tack coat for bond described metallic substrate layer and described casting resin layer is also comprised.
Further, described color printing layer is formed in the bottom of described casting resin layer.
Further, the surface protection film for the protection of described metallic substrate layer is also comprised.
Further, described color printing layer is formed in the inside of described surface protection film.
Further, the thickness of described casting resin layer is 0.8 ~ 3mm.
Further, described color printing layer is formed in the bottom of described metallic substrate layer, also comprises the tack coat for bond described color printing layer and described casting resin layer.
Further, described metallic substrate layer adopts chemical etching or adopts mechanical stamping process method to form pattern.
Further, described metallic substrate layer by covering translucent printed layers on hyaline membrane, and jointing metal paper tinsel and being formed.
Further, described hyaline membrane is PET (PET; Polyethyleneterephthalate), Merlon (PC; Polycarbonate), acrylonitrile-butadiene-styrene resin (ABS; Acrylonitrile-butadiene-styrene copolymer), polymethyl methacrylate (PMMA; Polymethylmethacrylate) any one in.
Further, any one in described translucent printed layers employing gravure, channel mould, rhynchostome coating machine, silk printrng process obtains color.
Further, described metal forming is through Wire Drawing process.
Further, the thickness of described metal forming is 5 ~ 50 μm,
The material of described metal forming is aluminium (Al), copper (Cu), stainless steel (STS; Stainless steel) in any one.
Further, the metal protective film for the protection of described metal forming is also comprised.
Metal foil laminated film according to the embodiment of the present invention comprises: adopt metal material to form the metallic substrate layer being presented on apparent pattern; For the stacked sheet metal arranging described metallic substrate layer; For the tack coat of bond described metallic substrate layer and described sheet metal.
Further, described metallic substrate layer and described sheet metal are fabricated to one by punch forming.
Further, the material of described sheet metal is any one in aluminium (Al), stainless steel (STS), hot melt galvanized steel plain sheet (GI), plated steel sheet (EGI).
Further, described metallic substrate layer by covering translucent printed layers on hyaline membrane, and jointing metal paper tinsel and being formed.
According to the manufacture method of the metal foil laminated film of the embodiment of the present invention, comprise step: prepare metallic substrate layer; Metallic substrate layer is formed and is presented in apparent pattern; In order to present pattern in the background parts except described pattern, form color printing layer in the side of described metallic substrate layer; Described metallic substrate layer is set in order to stacked, forms injection article by injection mo(u)lding.
Further, described metallic substrate layer covers translucent printed layers by any one adopting in gravure, channel mould, rhynchostome coating machine, silk printrng process on hyaline membrane, and jointing metal paper tinsel and being formed.
Further, described metallic substrate layer adopts chemical etching or adopt mechanical stamping process method to form pattern.
Further, the step formed for the tack coat of bond described metallic substrate layer and described injection article is also comprised.
Further, the step formed for the protection of the surface protection film of described metallic substrate layer is also comprised.
Further, described color printing layer is formed in the inside of described surface protection film.
Further, when described color printing layer is formed in the bottom of described metallic substrate layer, the step of the tack coat formed for bonding described color printing layer and described injection article is also comprised.
According to the manufacture method of the metal foil laminated film of the embodiment of the present invention, comprise step: prepare metallic substrate layer; Described metallic substrate layer adopts metal material formed and be presented in apparent pattern; Surface treatment is carried out to described metallic substrate layer, and coating adhesive and form tack coat; Under state according to described tack coat binding metal sheet material in described metallic substrate layer, adopt punch forming and be fabricated to one.
Further, described metallic substrate layer covers translucent printed layers by adopting gravure technique method or silk printrng process on hyaline membrane, and jointing metal paper tinsel and being formed.
Further, described metallic substrate layer adopts chemical etching or adopt mechanical stamping process method to form pattern.
Further, the step formed for the protection of the surface protection film of described metallic substrate layer is also comprised.
In sum, according to the embodiment of the present invention, the shell of portable terminal or the decoration panel of household electrical appliance can be made to have metal-like, the multiple patterns such as space pattern or plane pattern can be presented simultaneously.
Accompanying drawing explanation
Fig. 1 a represents the schematic diagram according to the metallic substrate layer of the embodiment of the present invention;
Fig. 1 b represents the schematic diagram according to the figuratum metallic substrate layer of the formation of the embodiment of the present invention;
Fig. 2 a to Fig. 2 c represents the schematic diagram forming the process of pattern according to the employing chemical etching of the embodiment of the present invention;
Fig. 3 a to Fig. 3 c represents the schematic diagram forming the process of pattern according to the employing mechanical stamping process method of the embodiment of the present invention;
Fig. 4 a is the schematic diagram representing the structure forming color printing layer in the bottom of the metallic substrate layer according to the embodiment of the present invention;
Fig. 4 b is the schematic diagram representing the structure forming color printing layer on the top of the metallic substrate layer according to the embodiment of the present invention;
Fig. 4 c represents in the bottom of the metallic substrate layer according to the embodiment of the present invention the stacked schematic diagram arranging the structure of metal protective film and color printing layer;
Fig. 4 d represents at the top of the metallic substrate layer according to embodiment of the present invention formation color printing layer and the schematic diagram of the structure of back side formation metal protective film;
Fig. 5 represents in the bottom of the metallic substrate layer according to the embodiment of the present invention the stacked schematic diagram arranging the metal foil laminated film of tack coat, casting resin layer and color printing layer;
Fig. 6 represents in the bottom of the metallic substrate layer according to the embodiment of the present invention the stacked schematic diagram arranging the metal foil laminated film of color printing layer, tack coat and casting resin layer;
Fig. 7 represents to be bonded to sheet metal according to the metallic substrate layer of the embodiment of the present invention and the schematic diagram of the metal foil laminated film adopting mechanical stamping process method to be molded as one;
Fig. 8 is the flow chart of the manufacture method of metal foil laminated film for illustration of the Fig. 5 according to the embodiment of the present invention;
Fig. 9 is the flow chart of the manufacture method of metal foil laminated film for illustration of the Fig. 6 according to the embodiment of the present invention;
Figure 10 is the flow chart of the manufacture method of metal foil laminated film for illustration of the Fig. 7 according to the embodiment of the present invention.
Symbol description: 1,1a is metallic substrate layer, 10 is hyaline membrane, and 11 is translucent printed layers; 12 is metal forming; 13 is groove portion, and 14 is mask, and 15 is adhesive; 16a, 16b are punching press mould frame, 17 is surface protection film; 18,18a, 18b are color printing layer, and 19 is metal protective film, and 20 is tack coat; 30,30a is casting resin layer, and 40 is sheet metal.
Detailed description of the invention
Below, embodiments of the invention are described in detail with reference to accompanying drawing.
Fig. 1 a represents the schematic diagram according to the metallic substrate layer of the embodiment of the present invention, and Fig. 1 b represents the schematic diagram according to the figuratum metallic substrate layer of the formation of the embodiment of the present invention.
As shown in Figure 1a, metallic substrate layer 1 by cover on hyaline membrane 10 in employing gravure (gravure), channel mould (Slot die), kiss painting machine (Kiss coater), silk printrng (silk printing) process any one and obtain the translucent printed layers 11 of color, then engage the metal forming 12 of processing through wire drawing (hairline) and make.Metal forming 12 uses to present metal-like.Now, the reason that Wire Drawing is carried out on surface for metal forming 12 is, in order to present the intrinsic texture that metal material has, and the part through Wire Drawing of metal forming 12 is superimposed with the color of translucent printed layers 11, can present beautiful color sensation.
The material of metal forming 12 can adopt aluminium (Al), copper (Cu), brass, stainless steel (STS; The metal material such as stainlesssteel), the thickness of its metal forming is 5 ~ 50 μm.
PET (PET can be adopted as hyaline membrane 10; Polyethyleneterephthalate), Merlon (PC; Polycarbonate), acrylonitrile-butadiene-styrene resin (ABS; Acrylonitrile-butadiene-styrene copolymer), polymethyl methacrylate (PMMA; Polymethylmethacrylate) etc.
In order to ensure electric wave through characteristic and interpolation pattern, as shown in Figure 1 b, by arranging groove portion 13 in metallic substrate layer 1, form multiple patterns with this.
As this pattern formation method, chemical etching is adopted to form pattern.Such as, as shown in Figure 2 a, in metallic substrate layer 1 bottom, corresponding to groove portion 13 to be formed, arrange etching mask 14, then as shown in Figure 2 b, carry out chemical etching process, now as shown in Figure 2 c, metal forming 12 forms groove portion 13, thus form the pattern of expectation in metallic substrate layer 1.
As another kind of pattern formation method, mechanical stamping process method is adopted to form pattern.Such as, as shown in Figure 3 a, hyaline membrane 10 covers translucent printed layers 11, and engage the metal forming 12 through Wire Drawing at this translucent printed layers 11 bottom coating adhesive 15, prepare metallic substrate layer 1a accordingly.Then, as shown in Figure 3 b, in metallic substrate layer 1a bottom, corresponding to groove portion 13 to be formed, arranging the bottom punching press mould frame 16b for cutting off, and on hyaline membrane 10, arrange passive top punching press mould frame 16a, cutting off necessary part in this case by pressurizeing.After this, if slough the adhesive 15 be folded between translucent printed layers 11 and metal forming 12, then as shown in Figure 3 c, metal platinum 12 forms groove portion 13, thus on metallic substrate layer 1a, form the pattern of expectation.
If form pattern on metallic substrate layer 1,1a, then in order to make the background parts except desired pattern present color, metallic substrate layer 1,1a form color printing layer 18.
As the formation method of color printing layer, can select to adopt a kind of method in the multiple example shown in Fig. 4 a to Fig. 4 d.
The first, as shown in fig. 4 a, adopt hard coat to form surface protection film 17 on the top forming figuratum metallic substrate layer 1, form color printing layer 18 in the bottom of metallic substrate layer 1.Hard coat formation method for the formation of surface protection film 17 can adopt coating polyurethane (PU; And coating ultraviolet (UV polyurethane); Ultraviolet) method etc. of the solid coating of light.Color printing layer formation method can adopt in gravure, channel mould, rhynchostome coating machine, silk printrng process any one.
The second, consider that the region of actual needs print color is the background parts except pattern, therefore as shown in Figure 4 b, on the surface of hyaline membrane 10, can not cover the scope interior formation color printing layer 18a of the part being presented on outside metal forming 12.Hard coat is adopted to form the surface protection film 17 comprising this color printing layer 18a in hyaline membrane 10 outside.Now, the method for the hard coat method of being formationed and formation color printing layer 18a that form surface protection film 17 can adopt Fig. 4 a the method that is suitable for.
3rd, as illustrated in fig. 4 c, forming the bottom covering metal diaphragm 19 of figuratum metallic substrate layer 1, for preventing metal forming 12 damaged when injection mo(u)lding, then forming color printing layer 18b in its underpart.In addition, as Fig. 4 a, hard coat is adopted to form surface protection film 17 on metallic substrate layer 1 top.
4th, as shown in figure 4d, as Fig. 4 b, on the surface of hyaline membrane 10, do not cover the scope interior formation color printing layer 18a of the part being presented in outside metal forming 12.Further, as Fig. 4 c, metal protective film 19 is covered forming the bottom of figuratum metallic substrate layer 1, for preventing the metal forming 12 when injection mo(u)lding damaged.
Above, for giving metal-like and guaranteeing that electric wave is illustrated through characteristic, the operation of pattern that presents expectation simultaneously by forming pattern, but the metal foil laminated film for presenting three-dimensional pattern effect can also be manufactured further.At this, the principle presenting space pattern is, forms injection article by adopting injection mo(u)lding between metallic substrate layer and color printing layer, thus can color sensation be made in appearance more three-dimensional.At this, injection article can adopt transparent resin carry out injection mo(u)lding and form casting resin layer.
With reference to Fig. 5, the figuratum metallic substrate layer 1 of formation adopts hard coat to form surface protection film 17, surface treatment is carried out to the lower surface of metallic substrate layer 1 simultaneously, and coating adhesive and form tack coat 20.
In the bottom of tack coat 20 by forming thicker casting resin layer 30 by transparent resin injection mo(u)lding.After this, color printing layer 18 is formed in casting resin layer 30 bottom.The thickness of casting resin layer 30 is arranged to 0.8 ~ 3mm, but if want to make color sensation more three-dimensional by increasing the spacing between pattern and color printing layer 18 formed according to metal forming 12, then can adjust larger by thickness.
When forming color printing layer 18 in casting resin layer 30 bottom, adopt mixing translucent coating and clear dope, and with the spraying method color of overlapping 1 to 5 degree and the method for printing layer by layer.The thickness of color printing layer 18 is arranged to below 0.1mm, and this thickness also can adjust according to the process conditions such as process efficiency and manufacturing expense.
In addition, when lay stress on make outward appearance present plane pattern time, as shown in Figure 6, metal foil laminated film can be manufactured.That is, the figuratum metallic substrate layer 1 of formation adopts hard coat to form surface protection film 17, form color printing layer 18 in the bottom of metallic substrate layer 1 simultaneously.After this, surface treatment and coating adhesive are carried out to color printing layer 18, thus after forming tack coat 20, adopt resin injection molding, form casting resin layer 30a thus.Now, casting resin layer 30a does not need transparent, colouring resin can be adopted to carry out injection mo(u)lding with this.
Above, adopt injection molding process to manufacture metal foil laminated film, but in addition, mechanical stamping process method can be adopted to manufacture metal foil laminated film, this is described with reference to Fig. 7.
As shown in Figure 7, adopt hard coat to form surface protection film 17 on the top forming figuratum metallic substrate layer 1, simultaneously surface treated metallic substrate layer 1 lower surface coating adhesive and form tack coat 20.After this, sheet metal 40 bonds tack coat 20, and by punch forming one, manufactures metal foil laminated film with this.The material of sheet metal 40 can adopt aluminium (Al), stainless steel (STS), hot melt galvanized steel plain sheet (GI; Galvanized Iron), plated steel sheet (EGI; Electrolytic GalvanizedIron).If so adopt mechanical stamping process method to manufacture metal foil laminated film, then do not need specifically created color printing layer, and the color of sheet metal 40 self determines the color of the background parts beyond pattern substantially.
Fig. 8 is the flow chart of the manufacture method of metal foil laminated film for illustration of the Fig. 5 according to the embodiment of the present invention.
As shown in Figure 8, by covering translucent printed layers 11 on hyaline membrane 10, then engaging the metal forming 12 through Wire Drawing, forming metallic substrate layer 1 (101) with this.The part through Wire Drawing of this metal forming 12 is superimposed with the color of translucent printed layers 11, can present beautiful color sensation.
Then, in order to ensure electric wave through characteristic and interpolation pattern, as shown in Figure 1 b, by arranging groove portion 13 in the bottom of metallic substrate layer 1, thus multiple patterns (102) is formed.In order to form pattern on metal substrate layer 1, as shown in Fig. 2 a to Fig. 2 c, can chemical etching be adopted, or as shown in Fig. 3 a to Fig. 3 c, mechanical stamping process method can be adopted.
Hard coat is adopted to form surface protection film 17 (103) on the top forming figuratum metallic substrate layer 1.Then, surface treatment is carried out to the lower surface of metallic substrate layer 1, and coating adhesive and form tack coat 20 (104).In this tack coat 20 bottom by forming thicker casting resin layer 30 by transparent resin injection mo(u)lding, space pattern (105) can be presented accordingly.The thickness of this casting resin layer 30 is arranged to 0.8 ~ 3mm, makes color sensation more three-dimensional, then can adjust larger by thickness if want by increasing the spacing between pattern and color printing layer 18 formed according to metal forming 12.
Then, form color printing layer 18 in casting resin layer 30 bottom, now by the translucent coating of mixing and clear dope, and carry out printing (106) with the spraying method color that overlap 1 to 5 is spent layer by layer.As shown in Figure 5, through the metal foil laminated film that this technique is obtained, owing to being provided with the casting resin layer 30 with transparent color between metallic substrate layer 1 bottom and color printing layer 18, therefore formed space pattern, can color sensation be made in appearance more three-dimensional.
Fig. 9 is the flow chart of the manufacture method of metal foil laminated film for illustration of the Fig. 6 according to the embodiment of the present invention, and it is for the manufacture of the metal foil laminated film mainly presenting plane pattern in appearance.
By covering translucent printed layers 11 on hyaline membrane 10, then engage the metal forming 12 through Wire Drawing, thus form metallic substrate layer 1 (201).
Then, in order to ensure electric wave through characteristic and interpolation pattern, as shown in Figure 1 b, multiple patterns (202) is formed in metallic substrate layer 1 bottom.Metal substrate layer 1 is formed the method for pattern, as shown in Fig. 2 a to Fig. 2 c, can chemical etching be adopted, or as shown in Fig. 3 a to Fig. 3 c, mechanical stamping process method can be adopted.
Adopt hard coat to form surface protection film 17 on the top forming figuratum metallic substrate layer 1, and form color printing layer 18 (203) in the bottom of metal substrate layer 1.Then, surface treatment is carried out to color printing layer 18, and coating adhesive and form tack coat 20 (204).Then, by being formed casting resin layer 30a (205) by resin injection molding.This casting resin layer 30a does not need transparent, and colouring resin can be adopted to carry out injection mo(u)lding.
Figure 10 is the flow chart of the manufacture method of metal foil laminated film for illustration of the Fig. 7 according to the embodiment of the present invention.
First form metallic substrate layer 1, now same be suitable for as shown in Figures 5 and 6 by covering translucent printed layers 11 on hyaline membrane 10, then engage the technique (301) through the metal forming 12 of Wire Drawing.
Then, in order to add the pattern of expectation, as shown in Fig. 2 a to Fig. 2 c, by adopting chemical etching, or as shown in Fig. 3 a to Fig. 3 c, adopt mechanical stamping process method, thus as shown in Figure 1 b, multiple patterns (302) is formed in the bottom of metallic substrate layer 1.
Then, adopt hard coat to form surface protection film 17 (303) on the top forming figuratum metallic substrate layer 1, and surface treatment is carried out for the lower surface of metallic substrate layer 1, coating adhesive and form tack coat 20 (304).
Then, under the state by the tack coat 20 that bonds on sheet metal 40, through punch forming, mutual generates, manufactures metal foil laminated film (305) with this.The material of sheet metal 40 can adopt aluminium (Al), stainless steel (STS), hot melt galvanized steel plain sheet (GI), plated steel sheet (EGI).If so adopt mechanical stamping process method to manufacture metal foil laminated film, then owing to not needing specifically created color printing layer, therefore can reduce technique number of times, and the color of sheet metal 40 self determines the color of the background parts beyond pattern substantially.

Claims (28)

1. a metal foil laminated film, is characterized in that comprising:
The groove portion making metal material form through metal material self forms the metallic substrate layer being presented on apparent pattern;
The color printing layer formed for presenting color in the background parts except described pattern corresponding to described groove portion;
For the stacked injection article arranging described metallic substrate layer and injection mo(u)lding,
Described metallic substrate layer by covering translucent printed layers on hyaline membrane, and jointing metal paper tinsel and being formed.
2. metal foil laminated film as claimed in claim 1, is characterized in that described injection article is the casting resin layer adopting transparent resin injection mo(u)lding.
3. metal foil laminated film as claimed in claim 2, characterized by further comprising the tack coat for bond described metallic substrate layer and described casting resin layer.
4. metal foil laminated film as claimed in claim 2 or claim 3, is characterized in that described color printing layer is formed in the bottom of described casting resin layer.
5. metal foil laminated film as claimed in claim 1, characterized by further comprising the surface protection film for the protection of described metallic substrate layer.
6. metal foil laminated film as claimed in claim 5, is characterized in that described color printing layer is formed in the inside of described surface protection film.
7. metal foil laminated film as claimed in claim 2, is characterized in that the thickness of described casting resin layer is 0.8 ~ 3mm.
8. metal foil laminated film as claimed in claim 2, is characterized in that described color printing layer is formed in the bottom of described metallic substrate layer,
Also comprise the tack coat for bond described color printing layer and described casting resin layer.
9. metal foil laminated film as claimed in claim 1, is characterized in that described metallic substrate layer adopts chemical etching or adopts mechanical stamping process method to form pattern.
10. metal foil laminated film as claimed in claim 1, is characterized in that described hyaline membrane is any one in PET, Merlon, acrylonitrile-butadiene-styrene resin, polymethyl methacrylate.
11. metal foil laminated films as claimed in claim 1, is characterized in that described translucent printed layers adopts that gravure, channel mould, kiss are coated with, any one in silk printrng process to be to obtain color.
12. metal foil laminated films as claimed in claim 1, is characterized in that described metal forming is through Wire Drawing process.
13. metal foil laminated films as claimed in claim 1, is characterized in that the thickness of described metal forming is 5 ~ 50 μm,
The material of described metal forming is any one in aluminium, copper, stainless steel.
14. metal foil laminated films as claimed in claim 1, characterized by further comprising the metal protective film for the protection of described metal forming.
15. 1 kinds of metal foil laminated films, is characterized in that comprising:
The groove portion making metal material form through metal material self forms the metallic substrate layer being presented on apparent pattern; For the stacked sheet metal arranging described metallic substrate layer;
For the tack coat of bond described metallic substrate layer and described sheet metal,
Described metallic substrate layer by covering translucent printed layers on hyaline membrane, and jointing metal paper tinsel and being formed.
16. metal foil laminated films as claimed in claim 15, is characterized in that described metallic substrate layer and described sheet metal are fabricated to one by punch forming.
17. metal foil laminated films as claimed in claim 15, is characterized in that the material of described sheet metal is any one in aluminium, stainless steel, hot melt galvanized steel plain sheet, plated steel sheet.
The manufacture method of 18. 1 kinds of metal foil laminated films, is characterized in that comprising step:
Prepare by covering translucent printed layers and jointing metal paper tinsel and the metallic substrate layer that formed on hyaline membrane;
Described metallic substrate layer is formed and is presented in apparent pattern, described metallic substrate layer forms pattern by making described metal forming form the groove portion of through described metal forming self;
In order to present pattern in the background parts except described pattern corresponding to described groove portion, form color printing layer in the side of described metallic substrate layer;
Described metallic substrate layer is set in order to stacked, forms injection article by injection mo(u)lding.
The manufacture method of 19. metal foil laminated films as claimed in claim 18, it is characterized in that any one by adopting gravure, channel mould, kiss to be coated with on hyaline membrane, in silk printrng process of described metallic substrate layer covers translucent printed layers, and jointing metal paper tinsel and being formed.
The manufacture method of 20. metal foil laminated films as claimed in claim 18, is characterized in that in described metallic substrate layer, adopting chemical etching or adopting mechanical stamping process method to form pattern.
The manufacture method of 21. metal foil laminated films as claimed in claim 18, characterized by further comprising the step formed for the tack coat of bond described metallic substrate layer and described injection article.
The manufacture method of 22. metal foil laminated films as claimed in claim 18, characterized by further comprising the step formed for the protection of the surface protection film of described metallic substrate layer.
The manufacture method of 23. metal foil laminated films as claimed in claim 22, is characterized in that described color printing layer is formed in the inside of described surface protection film.
The manufacture method of 24. metal foil laminated films as claimed in claim 18, is characterized in that when described color printing layer is formed in the bottom of described metallic substrate layer, also comprises the step of the tack coat formed for bonding described color printing layer and described injection article.
The manufacture method of 25. 1 kinds of metal foil laminated films, is characterized in that comprising step:
Prepare by covering translucent printed layers and jointing metal paper tinsel and the metallic substrate layer that formed on hyaline membrane;
Described metallic substrate layer adopts metal forming formed and be presented in apparent pattern, described metallic substrate layer forms pattern by making described metal forming form the groove portion of through described metal forming self;
Surface treatment is carried out to described metallic substrate layer, and coating adhesive and form tack coat;
Under state according to described tack coat binding metal sheet material in described metallic substrate layer, adopt punch forming and be fabricated to one.
The manufacture method of 26. metal foil laminated films as claimed in claim 25, is characterized in that described metallic substrate layer covers translucent printed layers by adopting gravure technique method or silk printrng process on hyaline membrane, and jointing metal paper tinsel and being formed.
The manufacture method of 27. metal foil laminated films as claimed in claim 25, is characterized in that described metallic substrate layer adopting chemical etching or adopting mechanical stamping process method to form pattern.
The manufacture method of 28. metal foil laminated films as claimed in claim 25, characterized by further comprising the step formed for the protection of the surface protection film of described metallic substrate layer.
CN201010286394.3A 2009-10-13 2010-09-15 Metal foil laminated film and manufacture method thereof Expired - Fee Related CN102039699B (en)

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KR1020090097235A KR20110040094A (en) 2009-10-13 2009-10-13 Metal foil clad film and method for making the same
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