CN102012033B - Combustion treatment method for carbonyl nickel-containing waste gas - Google Patents

Combustion treatment method for carbonyl nickel-containing waste gas Download PDF

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Publication number
CN102012033B
CN102012033B CN2010105611802A CN201010561180A CN102012033B CN 102012033 B CN102012033 B CN 102012033B CN 2010105611802 A CN2010105611802 A CN 2010105611802A CN 201010561180 A CN201010561180 A CN 201010561180A CN 102012033 B CN102012033 B CN 102012033B
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China
Prior art keywords
waste gas
carbonyl nickel
air
inlet pipe
sleeve pipe
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CN2010105611802A
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CN102012033A (en
Inventor
王芳镇
肖冬明
刘军位
李朝平
寇宗质
刘俊
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Jinchuan Group Nickel Cobalt Co ltd
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Jinchuan Group Co Ltd
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Abstract

The invention discloses a combustion treatment method for carbonyl nickel-containing waste gas and relates to improvement of a combustion treatment method for the carbonyl nickel-containing waste gas generated in the carbonyl metallurgical production process. The method is characterized in that: by utilizing the Venturi principle of fluid for the combustion treatment of the carbonyl nickel-containing waste gas, a sleeve is arranged on an air inlet pipe of an incinerator; and a compressed air inlet pipe is arranged at the front end of the sleeve; therefore, the temperature of an exhaust pipe is reduced, and the distribution of the waste gas and air is realized. The method comprises the following steps of: opening a compressed air valve to introduce air into the sleeve, and opening a carbonyl nickel-containing waste gas inlet valve to perform mixed flow distribution combustion. By utilizing the Venturi principle of fluid, mixed flow distribution is performed before the waste gas is combusted, a negative pressure area is formed at the waste gas inlet, the rate for decomposing the carbonyl nickel in the waste gas at the air inlet to form nickel plating is delayed and the continuous treatment time of the waste gas is prolonged; therefore, the process of combusting the waste gas is continuously and stably performed, and the aim of timely disinfection is fulfilled.

Description

A kind of burn processing method that contains carbonyl nickel waste gas
Technical field
A kind of burn processing method that contains carbonyl nickel waste gas relates to the improvement of the burn processing method that contains carbonyl nickel waste gas that produces in a kind of carbonylation metallurgical production process.
Background technology
In carbonylation metallurgical production process, can produce the waste gas that contains a small amount of carbonyl compound, these waste gas must could outer be discharged in the atmosphere after the disinfection.At present, in carbonylation metallurgical production process, be to adopt waste gas is input to carry out burning disposal in the incinerator; In burning process; Carbonyl nickel in the waste gas can decompose at the incinerator air inlet, forms nickel plating, gradually air inlet is stopped up; The burned waste gas process can not normally be carried out, hinder the normal tissues of production process to carry out.
Summary of the invention
The object of the invention is exactly the deficiency that exists to above-mentioned prior art; Provide a kind of and can solve incinerator air inlet nickel plating blockage problem in the burning process effectively; Make the burned waste gas process continuously, carry out for a long time; The waste gas disinfection that will produce in time will producing ensures that production process contains the burn processing method of carbonyl nickel waste gas normally.
The objective of the invention is to realize through following technical scheme.
A kind of burn processing method that contains carbonyl nickel waste gas; Its burn processing process adopts and will contain carbonyl nickel waste gas and feed the mode that incinerator burns and carry out; The carbonyl nickel waste gas that contains that it is characterized in that burn processing is the venturi principle that utilizes fluid, on the incinerator air inlet pipe, increases sleeve pipe, is provided with compressed air inlet pipe at the sleeve pipe front end; Both realize cooling exhaust pipe temperature, realized waste gas and air distribution again; At first open the compressed air valve and in sleeve pipe, blast earlier air, open again and contain carbonyl nickel waste gas air intake valve, carry out mixed flow distribution burning.
A kind of burn processing method that contains carbonyl nickel waste gas of the present invention is characterized in that the port of export that on the incinerator air inlet pipe, increases sleeve pipe exceeds incinerator air inlet pipe pipe port of export length 8~20cm.
A kind of burn processing method that contains carbonyl nickel waste gas of the present invention, it is characterized in that blasting air mass flow is 1: 1~3: 1 with the volume ratio that contains the carbonyl nickel exhaust gas flow.
Method of the present invention is utilized the venturi principle of fluid, before burned waste gas, carries out the mixed flow distribution; Form negative pressuren zone at waste gas inlet; Flame is away from waste gas inlet in the burning process, and the carbonyl nickel in the slow exhaust gas is separated the speed that forms nickel plating in air inlet punishment, increases the waste gas continuous processing time; Make the burned waste gas process continuously, stable carrying out, realize the purpose of in time disinfecting.
The specific embodiment
A kind of burn processing method that contains carbonyl nickel waste gas; Its burn processing process adopts and will contain carbonyl nickel waste gas and feed the mode that incinerator burns and carry out; Containing carbonyl nickel waste gas is the venturi principle that utilizes fluid, on the incinerator air inlet pipe, increases sleeve pipe, is provided with compressed air inlet pipe at the sleeve pipe front end; Both realize cooling exhaust pipe temperature, realized waste gas and air distribution again.At first open the compressed air valve and in sleeve pipe, blast air, open again and contain carbonyl nickel waste gas air intake valve, carry out mixed flow distribution burning.
Embodiment 1
When the exhaust inlet pipe external diameter was 159mm, installing length additional at the exhaust inlet pipe place was 3000mm, and external diameter is the carbon steel sleeve pipe of 219mm; It is 8cm that the sleeve pipe outlet exceeds air inlet outlet length; Clay seals sleeve pipe and air inlet pipe joint, after the igniting of incinerator oil-burning machine, opens air compressor earlier; Open the waste gas air intake valve again, exhaust gas flow is 300m 3/ h, the control compressor flowrate is 300m 3/ h, move 7200h continuously after air inlet begin to occur the nickel plating clogging.
Embodiment 2
When the exhaust inlet pipe external diameter was 159mm, installing length additional at the exhaust inlet pipe place was 3000mm, and external diameter is the carbon steel sleeve pipe of 219mm; It is 15cm that the sleeve pipe outlet exceeds air inlet outlet length; Clay seals sleeve pipe and air inlet pipe joint, after the igniting of incinerator oil-burning machine, opens air compressor earlier; Open the waste gas air intake valve again, exhaust gas flow is 300m 3/ h, the control compressor flowrate is 300m 3/ h, move 9600h continuously after air inlet begin to occur the nickel plating clogging.
Embodiment 3
When the exhaust inlet pipe external diameter was 159mm, installing length additional at the exhaust inlet pipe place was 3000mm, and external diameter is the carbon steel sleeve pipe of 219mm; It is 15cm that the sleeve pipe outlet exceeds air inlet outlet length; Clay seals sleeve pipe and air inlet pipe joint, after the igniting of incinerator oil-burning machine, opens air compressor earlier; Open the waste gas air intake valve again, exhaust gas flow is 300m 3/ h, the control compressor flowrate is 600m 3/ h, move 7200h continuously after air inlet begin to occur the nickel plating clogging.
Embodiment 4
When the exhaust inlet pipe external diameter was 159mm, installing length additional at the exhaust inlet pipe place was 3000mm.External diameter is the carbon steel sleeve pipe of 219mm, and it is 20cm that the sleeve pipe outlet exceeds air inlet outlet length, and clay seals sleeve pipe and air inlet pipe joint, after the igniting of incinerator oil-burning machine, opens air compressor earlier, opens the waste gas air intake valve again, and exhaust gas flow is 300m 3/ h, the control compressor flowrate is 900m 3/ h, move 14400h continuously after air inlet begin to occur the nickel plating clogging.

Claims (3)

1. burn processing method that contains carbonyl nickel waste gas; Its burn processing process adopts and will contain carbonyl nickel waste gas and feed the mode that incinerator burns and carry out; The carbonyl nickel waste gas that contains that it is characterized in that burn processing is the venturi principle that utilizes fluid, on the incinerator exhaust inlet pipe, increases sleeve pipe, is provided with compressed air inlet pipe at the sleeve pipe front end; Both realize the cooling exhaust intake manifold temperature, realized waste gas and air distribution again; At first open the compressed air valve and in sleeve pipe, blast air, open again and contain carbonyl nickel waste gas air intake valve, carry out mixed flow distribution burning.
2. a kind of burn processing method that contains carbonyl nickel waste gas according to claim 1 is characterized in that the port of export that on the incinerator exhaust inlet pipe, increases sleeve pipe exceeds incinerator exhaust inlet pipe pipe port of export length 8~20cm.
3. a kind of burn processing method that contains carbonyl nickel waste gas according to claim 1, it is characterized in that blasting air mass flow is 1: 1~3: 1 with the volume ratio that contains the carbonyl nickel exhaust gas flow.
CN2010105611802A 2010-11-23 2010-11-23 Combustion treatment method for carbonyl nickel-containing waste gas Active CN102012033B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2010105611802A CN102012033B (en) 2010-11-23 2010-11-23 Combustion treatment method for carbonyl nickel-containing waste gas

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Application Number Priority Date Filing Date Title
CN2010105611802A CN102012033B (en) 2010-11-23 2010-11-23 Combustion treatment method for carbonyl nickel-containing waste gas

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CN102012033A CN102012033A (en) 2011-04-13
CN102012033B true CN102012033B (en) 2012-05-30

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0285485A1 (en) * 1987-03-18 1988-10-05 L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Method and device for destroying toxic gaseous effluents
CN2404005Y (en) * 1999-12-22 2000-11-01 中国科学院山西煤炭化学研究所 Incinerator for treating combustable waste gas
CN1818101A (en) * 2006-03-17 2006-08-16 金川集团有限公司 Method for recovering metallic elements from mixed gas containing carbonyl substances
CN2926832Y (en) * 2006-04-29 2007-07-25 中国石油化工股份有限公司 Waste-gas gun for incinerator

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63113207A (en) * 1986-10-30 1988-05-18 Kawasaki Steel Corp Exhaust heat recovery type burner
JP2003322314A (en) * 2002-04-30 2003-11-14 Toho Gas Co Ltd Burner

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0285485A1 (en) * 1987-03-18 1988-10-05 L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Method and device for destroying toxic gaseous effluents
CN2404005Y (en) * 1999-12-22 2000-11-01 中国科学院山西煤炭化学研究所 Incinerator for treating combustable waste gas
CN1818101A (en) * 2006-03-17 2006-08-16 金川集团有限公司 Method for recovering metallic elements from mixed gas containing carbonyl substances
CN2926832Y (en) * 2006-04-29 2007-07-25 中国石油化工股份有限公司 Waste-gas gun for incinerator

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
JP昭63-113207A 1988.05.18
JP特开2003-322314A 2003.11.14
李侬等.羰基镍生产中的事故风险及预防对策.《工业安全与防尘》.1998,(第8期),第22~26页. *

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Owner name: JINCHUAN GROUP CO., LTD.

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Address after: 737103 Jinchuan Road, Gansu, China, No. 98, No.

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Patentee before: Jinchuan Group Co.,Ltd.

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Address after: 737100 No. 2 Lanzhou Road, Beijing Road Street, Jinchuan District, Jinchang City, Gansu Province

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Address before: 737103 No. 98, Jinchuan Road, Jinchang, Gansu

Patentee before: JINCHUAN GROUP Co.,Ltd.

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