CN102010575B - Environmental-friendly human pipeline casting filler and preparation method thereof - Google Patents
Environmental-friendly human pipeline casting filler and preparation method thereof Download PDFInfo
- Publication number
- CN102010575B CN102010575B CN201010274655XA CN201010274655A CN102010575B CN 102010575 B CN102010575 B CN 102010575B CN 201010274655X A CN201010274655X A CN 201010274655XA CN 201010274655 A CN201010274655 A CN 201010274655A CN 102010575 B CN102010575 B CN 102010575B
- Authority
- CN
- China
- Prior art keywords
- epoxy resin
- weighting agent
- filler
- parts
- perfusion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Epoxy Resins (AREA)
Abstract
The invention relates to an environmental-friendly human pipeline casting filler and a preparation method thereof. The filler is prepared from the following compositions in parts by weight: 100 parts of CYD-128(E-51) epoxy, 15ml of epoxy high performance toughening modifier RF-400, 5 parts of 2, 4, 6 tri(dimethylamino methyl) phenol (DMP-30), 0.3-0.5 part of epoxy defoamer and 45-50 parts of modified alicyclic amine epoxy curing agent ZY-1618. The invention has the advantages of easy preparation, convenient operation, finishing by once perfusion, good filler fluidity, little perfusion resistance, vigorous and plump forming, fineness, beauty, small shrinkage factor, environmental protection, no toxicity, very strong support force of a casting trunk and good flexibility of a branch.
Description
Technical field
The present invention relates to the human anatomy cast technique.
Technical background
Along with developing by leaps and bounds of chemical industry, the human anatomy cast technique is also developed rapidly, and many different properties casting mold weighting agents continue to bring out out.Domestic casting mold weighting agent commonly used has following several kinds at present: self-solidifying denture base material, chlorinated polyvinyl chloride, epoxy resin, ABS etc., but in actual application, various weighting agents all have its relative merits.For example the self-solidifying denture base material has advantages such as moulding is full, anchorage force is strong, but setting time is short, moulding sample surface irregularity, and snappiness is poor; Chlorinated polyvinyl chloride has advantages such as snappiness is good, moulding is attractive in appearance, but needs repeatedly after-teeming, anchorage force not strong, is prone to make the casting mold distortion.Epoxy resin has that physical strength height, shrinking percentage are low, good stability, processing characteristics are good etc., is widely used in the fields such as cast, embedding and coating, tackiness agent and matrices of composite material of electronic material.Utilize its characteristic that it is used for human pipeline perfusion, the moulding sample has that anchorage force is strong, shrinking percentage is low, meticulous attractive in appearance, has certain snappiness simultaneously, is more satisfactory casting mold weighting agent.
Summary of the invention
The present invention seeks to through epoxy resin is carried out modification; To increase its flowability and snappiness; Make it to become a kind of good physical and chemical properties, resistance to acids and bases is strong, existing good snappiness, the novel environment friendly filler for canal cast of human body and the compound method thereof of the anchorage force that tool is stronger again.
The object of the invention is realized by following technical scheme:
Weighting agent of the present invention is by the preparation of following volume ratio: CYD-128 (E-51) type epoxy resin is that 100 parts, epoxy resin high-performance plasticized modifier RF-40015ml, 2,4,6 three (dimethylamino methyl) phenol (DMP-30) are 5 parts, epoxy resin skimmer 0.3-0.5 part, modification aliphatic cyclic amine epoxy curing agent ZY-161845-50 part.
Preparing novel environment friendly filler for canal cast of human body method of the present invention is:
1. extract 100mlCYD-128 (E-51) type epoxy resin with syringe and inject the 400ml beaker,
Extract RF-40015ml and epoxy resin skimmer 0.3-0.5ml respectively and inject beaker, fully stir;
2. add an amount of fat-soluble pigment, decide according to the perfusion pipeline is different, artery adds redness, and vein adds blueness, and tracheae adds white or colourless, and common hepatic duct adds green, fully stirs 5-10 minute;
3. add DMP-305ml and ZY-161845-50ml respectively after fully stirring; After continuing to stir 5 minutes; Then the pintle of syringe is extracted out, poured weighting agent of the present invention into syringe, refill pintle; Air in the exhaustjet device slowly is injected into weighting agent in the pipeline through the intubate pressurization.
The related reagent of weighting agent of the present invention is explained as follows:
CYD-128 (E-51) epoxy resin product oxirane value is high, low, the lighter color of viscosity, has good flowability.
RF-400 is the epoxy resin high-performance plasticized modifier, is again good reactive thinner.Have good toughness reinforcing performance and reactive behavior, can improve the physical and mechanical properties such as shock-resistant, compression, cracking resistance and cohesive strength of epoxy resin cured product significantly.In the present invention's preparation, not only effectively increase the snappiness of CYD-128 epoxy resin, also reduce the viscosity of CYD-128 epoxy resin effectively, increase the flowability of weighting agent of the present invention, be convenient to perfusion.
2,4,6-three (dimethylamino methyl) phenol is called for short DMP-30, and molecular formula is C15H27N30, is the efficient promotor of epoxy curing agent, can reduce weighting agent solidification value of the present invention effectively, shorten set time (solidifying fully behind the 2h), improves solidification rate.
The epoxy resin skimmer can be eliminated rapidly when weighting agent stirs and produce bubble, helps reducing the weighting agent surface tension, the resistance when reducing weighting agent perfusion pipeline effectively.Simultaneously weighting agent there is wetting action, is difficult for producing " flake " or " cavity ".
Special construction in the ZY-1618 solidifying agent molecule can be under normal temperature or coldcondition plays crosslinking reaction with epoxy resin fully, and does not produce by product, and is nontoxic, cohesiveness, snappiness, the insulativity of excellence arranged, water-fast, resistance to chemical attack.
The present invention has following advantage:
1. preparation is easy, instant joining, easy and simple to handle.Once perfusion can be accomplished, and does not need after-teeming, pours into and can prepare (preparing in the 5min) immediately when not enough.
2. RF-400 both can increase CYD-128 epoxy resin snappiness efficiently, also can dilute epoxy resin, reduced the viscosity of CYD-128 epoxy resin, increased the flowability of weighting agent of the present invention, was convenient to perfusion.
3. when the weighting agent mixed solution stirs, add skimmer, can eliminate producing bubble when stirring rapidly, help reducing the weighting agent surface tension, the resistance when reducing weighting agent perfusion pipeline effectively.Simultaneously weighting agent there is wetting action, is difficult for producing " flake " or " cavity ".
4. DMP-30 can reduce weighting agent solidification value of the present invention effectively, shorten set time (solidifying fully behind the 2h), helps keeping the pipeline original appearance, is difficult for making casting mold to produce distortion.
5. weighting agent good fluidity, little, the moulding of perfusion resistance full full, meticulous attractive in appearance, shrinking percentage is little, and trunk has very strong anchorage force and the good snappiness of ramose.
6. weighting agent has environment-protecting asepsis property, and comprehensive cost is low.
That casting mold sample of the present invention can be medical teaching, the research and production medical practice provides is clear, truly, morphology is dissected foundation intuitively.Also study for tumor vessel distributes simultaneously, three-dimensional operation etc. provides technical support.
Embodiment
Embodiments of the invention are accomplished by following steps:
1, wash and leave standstill:
Get fresh adult or children's (comprising infant and fetus) material (after death 6h in), artery with (or) vein selects suitable bore intubate, at the intubate place with 5% Sodium Citrate saline water flushing pipe repeatedly, till the vein outflow is than clear liquid.Then sample is positioned over the washbasin of filling clear water, floats 6-12h in water, extract 8-10% Superlysoform to each intubate place perfusion with the 50ml syringe again, make sample fully fixing, put into clear water at last and leave standstill 12-24h.
2, preparation novel environment friendly filler for canal cast of human body of the present invention:
According to above-mentioned casting mold weighting agent CYD-128: RF-400: DMP-30: skimmer: ZY-1618=100: 15: 5: 0.5: the weighting agent of 45 ratios preparation appropriate amount and add an amount of pigment and stir and to pour into.
3, perfusion:
During the perfusion blood vessel, before perfusion, repeatedly extract air in certain amount and in blood vessel, pour into, make the interior excess liquid of blood vessel exosmose the resistance when helping reducing perfusion with the 50ml plastic injector.Simultaneously can check out whether blood vessel has the gas leakage point, if there is timely usefulness " 502 " glue to seal.Then the pintle of syringe is extracted out, poured weighting agent of the present invention into syringe, refill pintle, the gas in the exhaustjet device slowly is injected into weighting agent in the blood vessel through intubate.The filling degree of close observation sample periphery and the phenomenon that whether leaks outside are controlled dabbling amount with the feel resistance during perfusion, obviously feel should stop immediately when resistance is very big perfusion.At last, clamp each mouth of pipe, extract syringe, sample is put into clear water 12--18h, make the abundant hardened forming of weighting agent, be sure not to move easily or change its attitude with mosquito forceps.
During the perfusion tracheae, because weighting agent is easy in tiny segmental bronchus and alveolar, so in filling process, general resistance is little, can answer each lobe of the lung filling degree of close observation and surface thereof white dot whether to occur simultaneously first quick and back slow.If the white dot that part is dispersed in occurs, then answer decrement, along with increasing of spot; And when feeling that obviously resistance increases; Should stop perfusion immediately, cause local adhesion sclerosis agglomerating, influence post-processed work such as burn into pruning in order to avoid too much weighting agent gets into alveolar space.
4, post-processed work:
The back sample that will harden is put into 25% dense HCL solution (sample that needs to keep bone is then put into 20%KOH solution) corrosion.Waiting to corrode the back takes the circumstances into consideration flushing, prunes.Then casting mold is placed the H of 5%-10%
2O
2Behind the solution soaking bleaching 6h, with the bottled preservation of formalin solution.
Claims (2)
1. environment-friendly type filler for canal cast of human body is characterized in that: by following volume ratio preparation: CYD-128 type epoxy resin is that 100ml, epoxy resin high-performance plasticized modifier RF-400 15ml, 2,4,6-three (dimethylamino methyl) phenol are 5ml, epoxy resin skimmer 0.3-0.5ml, modification aliphatic cyclic amine epoxy curing agent ZY-1618 45-50ml.
2. the compound method of environment-friendly type filler for canal cast of human body is characterized in that: may further comprise the steps:
1., extract 100mlCYD-128 type epoxy resin with syringe and inject the 400ml beaker, extract RF-400 15ml and epoxy resin skimmer 0.3-0.5ml respectively and inject beaker, fully stirring;
2., add an amount of fat-soluble pigment, decide according to the perfusion pipeline is different, artery adds redness, vein adds blueness, tracheae adds white or colourless, common hepatic duct adds green, fully stirs 5-10 minute;
3., fully add DMP-30 5ml and ZY-1618 45-50ml respectively after the stirring; After continuing to stir 5 minutes; Then the pintle of syringe is extracted out, poured weighting agent into syringe, refill pintle; Air in the exhaustjet device slowly is injected into weighting agent in the pipeline through the intubate pressurization.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010274655XA CN102010575B (en) | 2010-09-07 | 2010-09-07 | Environmental-friendly human pipeline casting filler and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010274655XA CN102010575B (en) | 2010-09-07 | 2010-09-07 | Environmental-friendly human pipeline casting filler and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102010575A CN102010575A (en) | 2011-04-13 |
| CN102010575B true CN102010575B (en) | 2012-07-25 |
Family
ID=43840914
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201010274655XA Expired - Fee Related CN102010575B (en) | 2010-09-07 | 2010-09-07 | Environmental-friendly human pipeline casting filler and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102010575B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109049459A (en) * | 2018-07-09 | 2018-12-21 | 张家港市德仁科教仪器设备有限公司 | A kind of foot perivascular nerves sample embedding method and model |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102391617B (en) * | 2011-07-28 | 2013-02-27 | 黄海龙 | Human body canal cast filler and preparation method thereof |
| CN104269096B (en) * | 2014-09-19 | 2018-08-10 | 黄海龙 | The construction method of digital virtual fetus systemic arterial system |
| CN104497485B (en) * | 2014-12-18 | 2017-06-16 | 黄海龙 | A kind of cadaver sample angiogram filler and preparation method thereof |
| CN109166432A (en) * | 2018-07-13 | 2019-01-08 | 河南中博健康科技有限公司 | Blood vessel casting specimen embedding and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1687227A (en) * | 2005-04-25 | 2005-10-26 | 黄海龙 | Filler for canal cast of human body and method of preparation |
| CN101003663A (en) * | 2006-12-30 | 2007-07-25 | 南京师范大学 | Cast agent for blood vessel of no-solvent type epoxy resin |
-
2010
- 2010-09-07 CN CN201010274655XA patent/CN102010575B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1687227A (en) * | 2005-04-25 | 2005-10-26 | 黄海龙 | Filler for canal cast of human body and method of preparation |
| CN101003663A (en) * | 2006-12-30 | 2007-07-25 | 南京师范大学 | Cast agent for blood vessel of no-solvent type epoxy resin |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109049459A (en) * | 2018-07-09 | 2018-12-21 | 张家港市德仁科教仪器设备有限公司 | A kind of foot perivascular nerves sample embedding method and model |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102010575A (en) | 2011-04-13 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102010575B (en) | Environmental-friendly human pipeline casting filler and preparation method thereof | |
| CN108299599B (en) | Acrylic acid salt aqueous solution grouting material and preparation method thereof | |
| CN101885592B (en) | Mold material and preparation method and application thereof | |
| CN100569854C (en) | Small biological sample preparing process with transparant water soluble resin | |
| CN110183185A (en) | Foam concrete | |
| CN105001591B (en) | Ionic liquid toughening type pentaerythritol acrolein resin and curing method thereof | |
| CN103965715A (en) | Water-based glass coating | |
| CN104448713B (en) | A kind of open cell type heat conductivity epoxy radicals composite porous material and preparation method thereof and application | |
| CN105061670A (en) | Low-contraction acrylic acid ester vacuum infiltration agent used for sealed reinforcement | |
| CN104357010A (en) | Low-shrinkage acrylic ester type vacuum impregnation agent for sealing reinforcement | |
| CN103183945A (en) | Modified unsaturated polyester resin and preparation method thereof | |
| CN103299985A (en) | Cantharias specimen and making method thereof | |
| CN101585958B (en) | Composition and method for preparing artificial gem | |
| CN110156373A (en) | Concrete retarder and its preparation method and application | |
| CN109777117A (en) | A kind of add-on type silica gel for turning over fine decorative pattern mold processed, preparation method and applications | |
| CN105924565B (en) | Modified super absorbent polymer and preparation method thereof and the application in cement-based material | |
| CN107262666B (en) | Composite modified waterglass and preparation method thereof for water-glass sand | |
| CN102391617B (en) | Human body canal cast filler and preparation method thereof | |
| CN107312482A (en) | Bullion makes the pouring procedure of epoxy resin AB glue | |
| CN110105024A (en) | Normal concrete | |
| CN108084667B (en) | A kind of modified microcrystalline cellulose enhancing soybean oil based resin composite material and preparation method | |
| CN106391997A (en) | Preparation method of yttrium oxide composite paint for investment casting of titanium alloy | |
| CN109575522A (en) | A kind of epoxy resin is composite porous and its preparation method and application | |
| CN106110399B (en) | A kind of 3D printing method of multicomponent composite hydrogel | |
| CN1650705A (en) | Manufacturing technique of biomass full body bone structural connection blood vessel casting mould specimen |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20120725 Termination date: 20130907 |