CN102002887A - Treating fluid for special medium - Google Patents

Treating fluid for special medium Download PDF

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Publication number
CN102002887A
CN102002887A CN 201010258671 CN201010258671A CN102002887A CN 102002887 A CN102002887 A CN 102002887A CN 201010258671 CN201010258671 CN 201010258671 CN 201010258671 A CN201010258671 A CN 201010258671A CN 102002887 A CN102002887 A CN 102002887A
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Prior art keywords
weight
ether
treatment fluid
special media
paper
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CN 201010258671
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CN102002887B (en
Inventor
洪华星
刘金德
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FORTUNA IMATEK Co Ltd
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FORTUNA IMATEK Co Ltd
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Priority to CN 201010258671 priority Critical patent/CN102002887B/en
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Abstract

The invention relates to treating fluid for a special medium, which is characterized by being prepared from the following components in percentage by weight: 1-20 percent of electrolyte with high valence state, 5-30 percent of solvent, 0.05-1 percent of surface active agent, 0.1-1 percent of pH regulator, 1-10 percent of high molecular substance with enhanced brightness, 0.01-1 percent of preservative and the balance of deionized water. The treating fluid of the invention mainly treats mediums mainly comprising decorative paper, rice paper, gouache paper, art paper, cotton fiber, and the like with poor coloring capability, and printing pictures which are treated by the treating fluid, and the color density of a treated printed picture is obviously improved compared with the pictures which are not treated by the treating fluid.

Description

A kind of treatment fluid that is used for special media
Technical field
The present invention relates to print the treatment fluid of special media, can increase substantially color saturation and the brightness to the medium of pigment, dyestuff water-based ink printed.
Background technology
Develop rapidly along with ink-jet technology, the use of base material is also more and more wider, people are more and more higher to the printing effect of various media, especially be applied to the medium of industrial use, comprise artistic paper, canvas, rice paper, gouache paper, facing paper, fibrous material etc., but because the shower nozzle of ink-jet is high especially to the stability of pigment and dyestuff, and ink-jet is that a kind of cost is lower, beautiful in colour, the colour print mode that can print on demand, the water-soluble ink-jet ink is generally by water, one or more water miscible auxiliary agents of water miscible dyestuff or pigment and one or more surfactants are formed, so the viscosity of ink and colorant concentration can be very not high, so marking ink permeates in paper on the bigger crude fibre medium in slit easily, thereby make the color vivid client's of not reaching demand inadequately, and use into chromatic effect preferably the medium price be more than 10 times of generic media, this is difficult to satisfy client's cost requirement again, therefore a kind of treatment fluid is provided, as long as do some processing on the special media surface, the pattern color density that makes printing has and promotes significantly that thereby to reach the client very low again to the cost that the demand of color increases simultaneously, and it is also very convenient to operate.
Summary of the invention
The object of the present invention is to provide a kind of treatment fluid that is used for the big bad crude fibre medium of quality of hole.
Above-mentioned purpose of the present invention reaches by the following technical programs:
A kind of treatment fluid that is used for special media (the big bad crude fibre medium of quality of hole) is characterized in that comprising following proportioning component:
The high valence state electrolyte of 1-20 weight %;
The solvent of 5-30 weight %;
The surfactant of 0.05-1%;
0.1-1 the PH conditioning agent of weight %;
1-10 weight % increases the brightness polymer substance;
0.01-0.5 the preservative agent of weight %;
Its surplus is a deionized water.
A kind of optimal technical scheme is characterized in that: described high valence state electrolyte is calcium chloride, calcium nitrate, magnesium chloride, magnesium nitrate, magnesium sulfate, frerrous chloride, iron chloride, ferrous nitrate, ferric nitrate, copper chloride, copper nitrate, zinc chloride or zinc sulfate.
A kind of optimal technical scheme is characterized in that: the electrolytical proportioning of described high valence state is 3-10 weight %.A kind of optimal technical scheme, it is characterized in that: described solvent is trimethylolpropane, ethylene glycol, glycerine, 1,3-butanediol, 1,5 pentanediols, 1,6 hexylene glycols, 2-methyl 2,4 pentanediols, Macrogol 200, PEG400, Macrogol 600, diethylene glycol, triethylene glycol, diethylene glycol dimethyl ether, diethylene glycol ether, diethylene glycol dimethyl ether, EGME, glycol propyl ether, butyl glycol ether, diethylene glycol butyl ether, dipropylene glycol ether, n-formyl sarcolysine base pyrrolidones or alpha-pyrrolidone.
A kind of optimal technical scheme is characterized in that described PH conditioning agent is monomethyl amine, dimethylamine, trimethylamine, N, N-dimethylethanolamine, methylethanolamine, a carbinolamine, dimethanolamine, trimethanolamine or triethanolamine.
A kind of optimal technical scheme is characterized in that: the proportioning of described PH conditioning agent is 0.3-0.8 weight %.
A kind of optimal technical scheme is characterized in that described surfactant is alkyl diphenyl base oxide disulfonate, dioctyl sulfosuccinate, alkylphenol polyoxyethylene, fatty alcohol-polyoxyethylene ether, block polyether and EO/PO copolymer, isomery alcohol polyoxyethylene ether or secondary alcohol polyoxyethylene ether, polyether modified siloxane, polyether-modified dimethyl silicone polymer.
A kind of optimal technical scheme is characterized in that: the proportioning of described surfactant is 0.05-0.5 weight %.
A kind of optimal technical scheme is characterized in that described preservative agent is: proxelGXL, glutaraldehyde, benzoic acid and Sodium Benzoate, methyl p-hydroxybenzoate, ethyl p-hydroxybenzoate, P-hydroxybenzoic acid third fat or parahydroxybenzoate butyl.
A kind of optimal technical scheme, the proportioning that it is characterized in that described preservative agent are 0.1-0.3 weight %.
A kind of optimal technical scheme is characterized in that described increase brightness polymer substance is PVA05-88, PVAl7-88, PVA-124, PEG4000, PEG6000, PEG10000 or PEG20000.
A kind of optimal technical scheme, the proportioning that it is characterized in that described increase brightness polymer substance are 2-5 weight %.
Beneficial effect:
Treatment fluid of the present invention is mainly handled the relatively poor medium of quality ability (mainly containing facing paper, rice paper, gouache paper, artistic paper, cotton fiber etc.), and printing picture after treatment has obvious lifting than the color density of not handling.The present invention will be further described below by the specific embodiment, but and do not mean that limiting the scope of the invention.
The specific embodiment
Embodiment 1
The proportioning of media processes liquid of the present invention is as follows:
8.0 the zinc sulfate of weight %
20.0 the Macrogol 600 of weight %
20.0 the trimethylolpropane of weight %
5.0 the PVP-K30 of weight %
0.02 is the polyether modified siloxane class surfactant B YK604 of weight % (available from BYK company? what is its standard name? with be which must be corresponding in front the technical scheme?Down together)
0.3 the triethanolamine of weight %
0.1 the preservative agent PROXEL GXL of weight %
Its surplus is that all the other deionized waters of deionized water are supplied.
Embodiment 2
Its proportioning of media processes liquid of the present invention is as follows:
8.0 the calcium nitrate of weight %
40.0 the diethylene glycol dimethyl ether of weight %
3.0 the PVA15-99 of weight %
0.02 the isomery of weight % alcohol polyethenoxy ether class surfactant 465 (available from aerochemistry companies)
0.3 the dimethylethanolamine of weight %
0.1 1 of weight %, the 5-glutaraldehyde
Its surplus is a deionized water.
All the other deionized waters are supplied
Embodiment 3
Its proportioning of media processes liquid of the present invention is as follows:
8.0 the zinc chloride of weight %
20.0 the ethylene glycol of weight %
20.0 weight % diethylene glycol dimethyl ether
5.0 the PVP-K30 of weight %
0.02 the polyether modified siloxane class surfactant B YK604 (available from BYK company) of weight %
0.3 the triethanolamine of weight %
0.1 the preservative agent PROXEL GXL of weight %
Its surplus is that all the other deionized waters of deionized water are supplied.
Embodiment 4
Its proportioning of media processes liquid of the present invention is as follows:
8.0 the magnesium nitrate of weight %
20.0 the diethylene glycol butyl ether of weight %
20.0 the alpha-pyrrolidone of weight %
3.0 the PVA of weight %
0.02 the block polyether of weight % and EO/PO copolymer analog surfactant 15-S-9 (available from Gutian, Nanjing company)
0.3 the dimethanolamine of weight %
0.1 the Sodium Benzoate of weight %
Its surplus is that all the other deionized waters of deionized water are supplied.
Embodiment 5
Its proportioning of media processes liquid of the present invention is as follows:
8.0 the calcium nitrate of weight %
40.0 the EGME of weight %
3.0 the PVA17-88 of weight %
0.02 the isomery of weight % alcohol polyethenoxy ether class surfactant 465 (available from aerochemistry companies)
0.3 the triethanolamine of weight %
0.1 the PROXEL GXL of weight %
Its surplus is a deionized water.
Embodiment 6
Its proportioning of media processes liquid of the present invention is as follows:
9.0 the calcium chloride of weight %
30.0 1,6 hexylene glycol of weight %
3.0 the PEG6000 of weight %
0.02 the polyether modified siloxane class surfactant B YK345 (available from BYK company) of weight %
0.3 the monoethanolamine of weight %
0.1 the ethyl p-hydroxybenzoate of weight %
Its surplus is a deionized water.
Embodiment 7
Its proportioning of media processes liquid of the present invention is as follows:
8.0 the magnesium chloride of weight %
30.0 2-methyl 2,4 pentanediols of weight %
3.0 the PEG10000 of weight %
0.02 the polyether modified siloxane class surfactant B YK348 (available from BYK company) of weight %
0.3 the dimethylethanolamine of weight %
0.1 the PROXEL GXL of weight %
Its surplus is a deionized water.
Embodiment 8
Its proportioning of media processes liquid of the present invention is as follows:
8.0 the iron chloride of weight %
30.0 the triethylene glycol of weight %
3.0 the PVA-124 of weight %
0.02 the polyether modified siloxane class surfactant B YK348 (available from BYK company) of weight %
0.3 the dimethylamine of weight %
0.1 P-hydroxybenzoic acid third fat of weight %
Its surplus is a deionized water.
Embodiment 9
Its proportioning of media processes liquid of the present invention is as follows:
9.0 the ferric nitrate of weight %
25.0 weight %'s, 5 pentanediols
1.0 the PEG20000 of weight %
0.02 the polyether modified siloxane class surfactant B YK348 (available from BYK company) of weight %
0.3 the N of weight %, the N-dimethylethanolamine
0.1 the bactericide BIT of weight % (1, the 2-benzisothiazole-3-ketone) (? standard name)
Its surplus is a deionized water.
Embodiment 10
Its proportioning of media processes liquid of the present invention is as follows:
9.0 the magnesium nitrate of weight %
20.0 the 1,3 butylene glycol of weight %
1.0 the PEG6000 of weight %
0.02 the polyether modified siloxane class surfactant B YK346 (available from BYK company) of weight %
0.3 the N of weight %, the N-dimethylethanolamine
0.1 the glutaraldehyde of weight %
Its surplus is a deionized water.
Embodiment 11
Its proportioning of media processes liquid of the present invention is as follows:
9.0 the magnesium chloride of weight %
20.0 the glycol propyl ether of weight %
1.0 the PEG4000 of weight %
0.02 the polyether modified siloxane class surfactant B YK346 (available from BYK company) of weight %
0.3 the N of weight %, the N-dimethylethanolamine
0.1 the benzoic acid of weight % and Sodium Benzoate
Its surplus is a deionized water.
Its proportioning of media processes liquid of the present invention is as follows:
The preparation method: according to above proportioning with solid earlier and water mix stir treat solid dissolving fully after, interpolation surfactant, PH conditioning agent=preservative agent fully stir and become clarification until solution and get final product.
Operating procedure: will prepare treatment fluid and be placed in the air pump airbrush, it is vaporific that adjusting air pump air pressure makes ejection liquid, fog-like liquid is sprayed onto on the medium to be processed, and being drying regime after handling can directly print, and directly printing effect is the same with the spray back for printing effect after placement a period of time.
Printing the contrast picture with conventional method shows: treated liquid is handled the back printing effect and is obviously promoted.

Claims (8)

1. treatment fluid that is used for special media is characterized in that comprising following proportioning component:
The high valence state electrolyte of 1-20 weight %;
5-30 weight % solvent;
0.05-1 weight % surfactant;
0.1-1 weight %PH conditioning agent;
1-10 weight % increases the brightness polymer substance;
0.01-1 weight % preservative agent;
Its surplus is a deionized water.
2. the treatment fluid that is used for special media according to claim 1 is characterized in that: described special media is facing paper, artistic paper, rice paper, wallpaper, nonwoven fabric or gouache paper.
3. the treatment fluid that is used for special media according to claim 1 is characterized in that: described high valence state electrolyte is calcium chloride, calcium nitrate, magnesium chloride, magnesium nitrate, magnesium sulfate, frerrous chloride, iron chloride, ferrous nitrate, ferric nitrate, copper chloride, copper nitrate, zinc chloride or zinc sulfate.
4. the treatment fluid that is used for special media according to claim 1, it is characterized in that: described solvent is trimethylolpropane, ethylene glycol, glycerine, 1,3-butanediol, 1,5 pentanediols, 1,6 hexylene glycols, 2-methyl 2,4 pentanediols, Macrogol 200, PEG400, Macrogol 600, diethylene glycol, triethylene glycol, diethylene glycol dimethyl ether, diethylene glycol ether, diethylene glycol dimethyl ether, EGME, glycol propyl ether, butyl glycol ether, diethylene glycol butyl ether, dipropylene glycol ether, n-formyl sarcolysine base pyrrolidones or alpha-pyrrolidone.
5. the treatment fluid that is used for special media according to claim 1 is characterized in that: described surfactant is alkyl diphenyl base oxide disulfonate, dioctyl sulfosuccinate, alkylphenol polyoxyethylene, fatty alcohol-polyoxyethylene ether, block polyether and EO/PO copolymer, isomery alcohol polyoxyethylene ether or secondary alcohol polyoxyethylene ether, polyether modified siloxane, polyether-modified dimethyl silicone polymer.
6. the treatment fluid that is used for special media according to claim 1, it is characterized in that: described PH conditioning agent is monomethyl amine, dimethylamine, trimethylamine, N, the N-dimethylethanolamine, methylethanolamine, a carbinolamine, dimethanolamine, trimethanolamine or triethanolamine.
7. the treatment fluid that is used for special media according to claim 1 is characterized in that: described increase brightness polymer substance is PVA05-88, PVA17-88, PVA-124, PEG4000, PEG6000, PEG10000 or PEG20000.
8. the treatment fluid that is used for special media according to claim 1 is characterized in that: described preservative agent is proxelGXL, glutaraldehyde, BIT, benzoic acid and Sodium Benzoate, methyl p-hydroxybenzoate, ethyl p-hydroxybenzoate, P-hydroxybenzoic acid third fat or parahydroxybenzoate butyl.
CN 201010258671 2010-08-20 2010-08-20 Treating fluid for decoration paper, artistic paper, xuan paper, wall paper, non-woven fabric or gouache paper Active CN102002887B (en)

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Application Number Priority Date Filing Date Title
CN 201010258671 CN102002887B (en) 2010-08-20 2010-08-20 Treating fluid for decoration paper, artistic paper, xuan paper, wall paper, non-woven fabric or gouache paper

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102230297A (en) * 2011-06-13 2011-11-02 东北林业大学 Plant paper pulp fiber modifying agent and modifying method using same, and filter paper and preparation method thereof
CN103276623A (en) * 2013-05-22 2013-09-04 李燕芹 Album page optimizing agent and preparing method thereof
CN103526639A (en) * 2012-07-03 2014-01-22 金东纸业(江苏)股份有限公司 Lubricating agent and paint made by using same
CN110028841A (en) * 2019-05-18 2019-07-19 北京联创佳艺影像新材料技术有限公司 A kind of ink improving digital printing clear-cut margin degree

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1323367A (en) * 1998-10-15 2001-11-21 宝洁公司 Soft tissue paper
CN1875150A (en) * 2003-10-27 2006-12-06 巴斯福股份公司 Method of making a paper coating using a blend of a vinyl aromatic-acrylic polymer dispersion with a vinyl aromatic-diene polymer dispersion

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1323367A (en) * 1998-10-15 2001-11-21 宝洁公司 Soft tissue paper
CN1875150A (en) * 2003-10-27 2006-12-06 巴斯福股份公司 Method of making a paper coating using a blend of a vinyl aromatic-acrylic polymer dispersion with a vinyl aromatic-diene polymer dispersion

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102230297A (en) * 2011-06-13 2011-11-02 东北林业大学 Plant paper pulp fiber modifying agent and modifying method using same, and filter paper and preparation method thereof
CN102230297B (en) * 2011-06-13 2013-01-09 东北林业大学 Plant paper pulp fiber modifying method, and filter paper and preparation method thereof
CN103526639A (en) * 2012-07-03 2014-01-22 金东纸业(江苏)股份有限公司 Lubricating agent and paint made by using same
CN103526639B (en) * 2012-07-03 2016-01-27 金东纸业(江苏)股份有限公司 Lubricant and apply the coating of this lubricant
CN103276623A (en) * 2013-05-22 2013-09-04 李燕芹 Album page optimizing agent and preparing method thereof
CN103276623B (en) * 2013-05-22 2016-02-17 李燕芹 An a kind of album of paintings or calligraphy optimizes agent and preparation method
CN110028841A (en) * 2019-05-18 2019-07-19 北京联创佳艺影像新材料技术有限公司 A kind of ink improving digital printing clear-cut margin degree

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PE01 Entry into force of the registration of the contract for pledge of patent right

Denomination of invention: Treating fluid for decoration paper, artistic paper, xuan paper, wall paper, non-woven fabric or gouache paper

Effective date of registration: 20160513

Granted publication date: 20130320

Pledgee: Haidian Beijing science and technology enterprise financing Company limited by guarantee

Pledgor: Fortuna Imatek Co., Ltd.

Registration number: 2016990000386

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PC01 Cancellation of the registration of the contract for pledge of patent right
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Date of cancellation: 20170510

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Pledgee: Haidian Beijing science and technology enterprise financing Company limited by guarantee

Pledgor: Fortuna Imatek Co., Ltd.

Registration number: 2016990000386

PE01 Entry into force of the registration of the contract for pledge of patent right
PE01 Entry into force of the registration of the contract for pledge of patent right

Denomination of invention: Treating fluid for decoration paper, artistic paper, xuan paper, wall paper, non-woven fabric or gouache paper

Effective date of registration: 20170510

Granted publication date: 20130320

Pledgee: Haidian Beijing science and technology enterprise financing Company limited by guarantee

Pledgor: Fortuna Imatek Co., Ltd.

Registration number: 2017990000396

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Date of cancellation: 20190429

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Pledgee: Haidian Beijing science and technology enterprise financing Company limited by guarantee

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Registration number: 2017990000396