CN101993148A - Sequencing-batch membrane bioreactor - Google Patents
Sequencing-batch membrane bioreactor Download PDFInfo
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- CN101993148A CN101993148A CN 201010591596 CN201010591596A CN101993148A CN 101993148 A CN101993148 A CN 101993148A CN 201010591596 CN201010591596 CN 201010591596 CN 201010591596 A CN201010591596 A CN 201010591596A CN 101993148 A CN101993148 A CN 101993148A
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Abstract
The invention discloses a sequencing-batch membrane bioreactor which relates to a membrane bioreactor. The invention aims to solve the problems of complexity device, sludge loss, long enrichment culture time and strict requirement on environment in the existing enrichment culture of anaerobic ammoxidation bacteria. A water inlet tank is communicated with a water inlet at the top of a cylindrical organic glass barrel through a water inlet pump; a first relay controls the on-off state of the water inlet pump; the outer layer of the cylindrical organic glass barrel is provided with a concentric water bath ring which is arranged on a magnetic stirrer; a second relay controls the on-off state of the magnetic stirrer; a fiber web, a filler, a filler bracket and a magnetic rotor with blades are arranged in the cylindrical organic glass barrel; the magnetic rotor with blades is arranged on the bottom of the cylindrical organic glass barrel; the filler bracket is arranged on the bottom of the cylindrical organic glass barrel; the filler is arranged on the filler bracket; the fiber web is arranged on the filler; and the water outlet at the bottom of the cylindrical organic glass barrel is communicated with a water outlet tank through a water outlet pump. The invention is used for processing nitrogenous sewage.
Description
Technical field
The present invention relates to a kind of membrane bioreactor.
Background technology
At present, other many countries of the China and the world generally adopt aerobic means such as the various sewage of Wastewater Treated by Activated Sludge Process, though aerobic process can reach treatment effect preferably, but still have a series of problems: 1, energy consumption height: aerobic process needs sewage is carried out oxygenation, needs to consume a large amount of electric energy.It is estimated, a Sewage Plant that adopts traditional activated sludge process, 75% of overall running cost expends on electric energy, and the burden on still energy-conservation economically is all heavier; 2, sludge yield height: the productive rate of aerobic microbiological is generally up to 0.2-0.6kgVSS/kgCOD, therefore need dewater to mud, subsequent disposal such as security landfill or burning, increased the cost of sewage disposal; 3, add organic carbon source: need additional carbon for the insufficient waste water of some carbon sources, increased operational and administrative expenses; 4, management is inconvenient: the infrastructure investment of aerobic process is bigger, and the operational management inconvenience, is not suitable for developing the cities and towns and the rural area that fall behind relatively and uses.
Anaerobic ammonia oxidation process can be saved 60% running cost than traditional technology, has therefore begun the industrial experimentation research that anaerobic ammonia oxidation process is handled nitrogenous effluent abroad.The enrichment culture anaerobic ammonia oxidizing bacteria is the key of successful Application anaerobic ammonia oxidation process.At present, the reactor that is used for the enrichment culture of anaerobic ammonia oxidizing bacteria mainly contains sequencing batch activated sludge treatment system SBR, up flow anaerobic sludge blanket reactor UASB, membrane bioreactor MBR etc.The main drawback that the reactor of these several enrichment culture exists is as follows:
1, SBR, UASB may cause sludge loss.These two kinds of reactors utilize the settling property of mud self to carry out mud-water separation, therefore may not produce sludge loss when the sedimentation function of Anammox mud is good.Because the growth cycle of anaerobic ammonia oxidizing bacteria is long, sludge loss can cause enrichment culture long, even the enrichment failure.
2, built-in MBR changes the membrane module problem.Though built-in MBR has solved the sludge loss problem, but frequent replacing membrane module may destroy the environment of the strictly anaerobic of anaerobic ammonia oxidizing bacteria needs.In addition, should not form microbial film in the MBR reactor, and existing studies confirm that, microbial film is to keep the slowly good carrier of growth bacterial classification such as anaerobic ammonia oxidizing bacteria.
In addition, because anaerobic ammonia oxidizing bacteria is relatively strict to environment requirement, and is poor to the resistibility of poor environment, also has a certain distance from the application of actual engineering, therefore it is strong to demand developing a kind of adaptability urgently, can overcome the novel anaerobic ammonia oxidation reactor of above-mentioned shortcoming simultaneously.
Summary of the invention
The purpose of this invention is to provide a kind of sequencing batch membrane bioreactor, with the long problem that reaches the environmental requirement strictness of device complexity, sludge loss, anaerobic ammonoxidation bacterium concentrating incubation time that solves present enrichment anaerobic ammonia oxidizing bacteria.
The present invention solves the problems of the technologies described above the technical scheme of taking to be: described reactor comprises inlet chest, intake pump, magnetic stirring apparatus, the magnetic force rotor of band blade, go out water pump, water tank, very first time relay, second time relay, the water-bath ring, cylindrical synthetic glass tube, fibrous reticulum, filler, filler support, the heating rod and the 3rd time relay, inlet chest is communicated with by the water-in of intake pump with cylindrical synthetic glass tube top, the switch of first rly. control intake pump, cylindrical synthetic glass tube skin is concentric water-bath ring, the water-bath ring is arranged on the magnetic stirring apparatus, the switch of second rly. control magnetic stirring apparatus, be provided with fibrous reticulum in the cylindrical synthetic glass tube, filler, the magnetic force rotor of filler support and band blade, the magnetic force rotor of band blade is located at the bottom of cylindrical synthetic glass tube, filler support is placed on the bottom of cylindrical synthetic glass tube and is positioned at the top of the magnetic force rotor of band blade, filler support is provided with filler, filler is provided with fibrous reticulum, the water outlet of cylindrical synthetic glass tube bottom is communicated with water tank by going out water pump, the 3rd rly. is controlled out the switch of water pump, is provided with heating rod in the water-bath ring.
The present invention has following beneficial effect: apparatus of the present invention are simple in structure, and workflow is simple, and are easy to operate, can save settling tank and reflux; Good effect of separating solid from liquid, effluent quality is good, can realize mixing fully at inside reactor by the magnetic force rotor of band blade, be that ideal staticly settles during precipitation, the water content of the sludge microbe in the microbial film is low, and the aged microbial film volume that peels off is bigger, and settling property is good; Operation is flexible, can regulate each processing parameter according to the water quality situation, effectively prevents sludge bulking, anti impulsion load; Microbial film hangs on the carrier, and the residence time and dwell time of sewage are irrelevant, helps long microbial growth generation time such as anaerobic ammonia oxidizing bacteria, and the enrichment culture time is short, and the excess sludge generation is few.
Description of drawings
Fig. 1 is an one-piece construction synoptic diagram of the present invention, and Fig. 2 is the variation synoptic diagram that contains the ammonia nitrogen mass concentration in the present invention behind the stop different time in the sewage, wherein
For sewage before handling contains the mass concentration of ammonia nitrogen,
Contain the mass concentration of ammonia nitrogen for handling back sewage,
Ammonia-N removal rate in the sewage during for processing, Fig. 3 is the variation synoptic diagram that contains the nitrite nitrogen mass concentration in the present invention behind the stop different time in the sewage, wherein
For sewage before handling contains the nitrous mass concentration,
Contain the nitrous mass concentration for handling back sewage,
Nitrous clearance in the sewage during for processing, Fig. 4 are the variation synoptic diagram that contains the nitric nitrogen mass concentration in the present invention behind the stop different time in the sewage, wherein
For sewage before handling contains the mass concentration of nitric nitrogen,
For handling the mass concentration that back sewage contains nitric nitrogen, Fig. 5 is the variation synoptic diagram that contains total nitrogen concentration in the present invention behind the stop different time in the sewage, wherein
For sewage before handling contains the mass concentration of total nitrogen,
For handling the mass concentration that back sewage contains total nitrogen, Fig. 6 is the structural representation of filler support 9-3.
Embodiment
Embodiment one: present embodiment is described in conjunction with Fig. 1 and Fig. 6, the reactor of present embodiment comprises inlet chest 1, intake pump 2, magnetic stirring apparatus 3, the magnetic force rotor 3-1 of band blade, go out water pump 4, water tank 5, very first time rly. 6, second time relay 7, water-bath ring 8, cylindrical synthetic glass tube 9, fibrous reticulum 9-1, filler 9-2, filler support 9-3, the heating rod 11 and the 3rd time relay 12, inlet chest 1 is communicated with the water-in at cylindrical synthetic glass tube 9 tops by intake pump 2, the switch of first rly., 6 control intake pumps 2, cylindrical synthetic glass tube 9 skins are concentric water-bath ring 8, water-bath ring 8 is arranged on the magnetic stirring apparatus 3, the switch of second rly., 7 control magnetic stirring apparatuss 3, be provided with fibrous reticulum 9-1 in the cylindrical synthetic glass tube 9, filler 9-2, the magnetic force rotor 3-1 of filler support 9-3 and band blade, the magnetic force rotor 3-1 of band blade is located at the bottom of cylindrical synthetic glass tube 9, filler support 9-3 is placed on the bottom of cylindrical synthetic glass tube 9 and is positioned at the magnetic force rotor 3-1 top of band blade, filler support 9-3 is provided with filler 9-2, filler 9-2 is provided with fibrous reticulum 9-1, the water outlet of cylindrical synthetic glass tube 9 bottoms is communicated with water tank 5 by going out water pump 4, the 3rd rly. 12 is controlled out the switch of water pump 4, is provided with heating rod 11 in the water-bath ring 8.
The present invention disposes of sewage effect referring to Fig. 2-Fig. 5.Reactor of the present invention utilizes sequencing batch membrane bioreactor to realize the short distance nitration-anaerobic ammoxidation autotrophic denitrification.The enrichment culture time is short: reactor advanced the operation about two months, reached steady state substantially, and ammonia nitrogen and nitrite nitrogen are almost removed with 1: 1 ratio, and the loss of total nitrogen reaches about 68%, and tangible Anammox phenomenon is arranged.Other reactor enrichment culture times are compared with it generally at 6 to 42 months, have shortened start time greatly; Not strict to environmental requirement: the microbial film of formation plays the vital role of separated by spaces aerobic ammonia-oxidizing bacteria and anaerobic ammonia oxidizing bacteria.The microbial film internal layer is mainly anaerobic ammonia oxidizing bacteria, and skin is aerobic ammonia-oxidizing bacteria and the symbiotic system of a spot of heterotrophic bacterium.In actual motion, outer bacterium consumes dissolved oxygen and the organism of introducing accidentally in the reactor, thereby is the good living environment of anaerobic ammonia oxidizing bacteria creation of internal layer.Therefore, SBBR can allow the existence of a spot of oxygen on a small quantity, does not influence the steady running of system.
Embodiment two: in conjunction with Fig. 1 present embodiment is described, the reactor of present embodiment also comprises dissolved oxygen meter 10, and the test lead of dissolved oxygen meter 10 is located in the filler 9-2, and this structure is used for the temperature dissolved oxygen is carried out periodic monitor.Other compositions and annexation are identical with embodiment one.
Embodiment three: present embodiment is described in conjunction with Fig. 1, distance H between the bottom face of the filler 9-2 of present embodiment and the bottom face of cylindrical synthetic glass tube 9 is 1/4 of a cylindrical synthetic glass tube 9, and filler 2 used raw materials are high density polyethylene(HDPE), a material and No. two material.The ratio of weight and number of high density polyethylene(HDPE), a material and No. two material is 25: 3-5: 3.5-5.5, wherein expect for No. one to be made of the compound particles of waste stone dust, coke powder, slag powders, iron powder and high density polyethylene(HDPE), the ratio of weight and number of waste stone dust, coke powder, slag powders, iron powder and high density polyethylene(HDPE) is 18-19.6: 1.5-1.8: 1.14-2: 0.36-0.6: 51-54; No. two fillers are made of be cut powder, talcum powder, iron powder and high density polyethylene blend particle of ore deposit, and the ratio of weight and number of ore deposit quarrel powder, talcum powder, iron powder and high density polyethylene(HDPE) is 11.35-12.75: 14-15: 2.15-2.25: 45-47.5.Other compositions and annexation are identical with embodiment one.
Embodiment four: in conjunction with Fig. 1 present embodiment is described, the unit grain of the filler 9-2 of present embodiment is an annular, and the external diameter of each unit grain is 10mm, and this structure is easy to form microbial film.Other compositions and annexation are identical with embodiment one.
Principle of work: the synthetic wastewater that inlet chest is 1 li rises in the circular synthetic glass bucket interior 9 through intake pump 2,9 internal contamination things fully contact with filler 9-2 under magnetic stirring apparatus 3 effects with filler 9-2 in circular synthetic glass bucket, form microbial film, organic pollutant obtains degraded gradually and removes under biomembranous effect, after reacting completely, second time relay, 7 control magnetic stirring apparatuss 3, staticly settle, go out water pump 4 then and will handle the waste water of post precipitation and be extracted into water tank 5, finish the whole service process.Wherein intake, stir, precipitation, water outlet be by very first time rly. 6, second time relay 7 and the 3rd time relay 12 are accurately controlled separately.Outside water-bath ring makes temperature maintenance at 35 degree by heating rod 11.
Claims (4)
1. sequencing batch membrane bioreactor, it is characterized in that described reactor comprises inlet chest (1), intake pump (2), magnetic stirring apparatus (3), the magnetic force rotor (3-1) of band blade, go out water pump (4), water tank (5), very first time rly. (6), second time relay (7), water-bath ring (8), cylindrical synthetic glass tube (9), fibrous reticulum (9-1), filler (9-2), filler support (9-3), the heating rod (11) and the 3rd time relay (12), inlet chest (1) is communicated with the water-in at cylindrical synthetic glass tube (9) top by intake pump (2), the switch of first rly. (6) control intake pump (2), cylindrical synthetic glass tube (9) skin is a concentric water-bath ring (8), water-bath ring (8) is arranged on the magnetic stirring apparatus (3), the switch of second rly. (7) control magnetic stirring apparatus (3), be provided with fibrous reticulum (9-1) in the cylindrical synthetic glass tube (9), filler (9-2), the magnetic force rotor (3-1) of filler support (9-3) and band blade, the magnetic force rotor (3-1) of band blade is located at the bottom of cylindrical synthetic glass tube (9), filler support (9-3) is placed on the bottom of cylindrical synthetic glass tube (9) and is positioned at magnetic force rotor (3-1) top of band blade, filler support (9-3) is provided with filler (9-2), filler (9-2) is provided with fibrous reticulum (9-1), the water outlet of cylindrical synthetic glass tube (9) bottom is communicated with water tank 5 by going out water pump 4, the 3rd rly. 12 is controlled out the switch of water pump 4, is provided with heating rod 11 in the water-bath ring 8.
2. according to the described sequencing batch membrane bioreactor of claim 1, it is characterized in that described reactor also comprises dissolved oxygen meter (10), the probe of dissolved oxygen meter (10) is located in the filler (9-2).
3. according to claim 1 or 2 described sequencing batch membrane bioreactors, it is characterized in that the distance (H) between the bottom face of the bottom face of described filler (9-2) and cylindrical synthetic glass tube (9) is 1/4 of cylindrical synthetic glass tube (9).
4. according to claim 1 or 2 described sequencing batch membrane bioreactors, it is characterized in that the unit grain of described filler (9-2) is annular, the external diameter of each unit grain is 10mm.
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105645664A (en) * | 2014-11-14 | 2016-06-08 | 重庆大学 | A constructing method of an autotrophic denitrification system for low-concentration ammonia nitrogen sewage |
CN105776526A (en) * | 2016-03-25 | 2016-07-20 | 中国海洋大学 | Anaerobic membrane bioreactor |
CN105925478A (en) * | 2016-06-20 | 2016-09-07 | 同济大学 | Rapid enrichment culture device for anaerobic ammonium oxidation bacteria |
CN107117703A (en) * | 2017-05-12 | 2017-09-01 | 北京建筑大学 | A kind of control sequencing batch membrane bioreactor in real time |
CN107129040A (en) * | 2016-02-29 | 2017-09-05 | 鞍钢股份有限公司 | A kind of method and device for extending sequencing batch membrane bioreactor film service life |
CN109354218A (en) * | 2018-12-27 | 2019-02-19 | 大连海洋大学 | A kind of use for laboratory graphite oxide aerogel biofilm reactor |
Citations (3)
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CN2600437Y (en) * | 2003-01-22 | 2004-01-21 | 胡龙兴 | Order group type bio-membrane reactor system |
WO2004011377A2 (en) * | 2002-07-26 | 2004-02-05 | The Regents Of The University Of California | Treatment of wastewater by biological and membrane separation technologies |
CN1927739A (en) * | 2006-08-29 | 2007-03-14 | 湖南大学 | Operation mode and apparatus of short distance nitration-anaerobic ammoxidation batched biomembrane denitrogenation |
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2010
- 2010-12-16 CN CN2010105915969A patent/CN101993148B/en not_active Expired - Fee Related
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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WO2004011377A2 (en) * | 2002-07-26 | 2004-02-05 | The Regents Of The University Of California | Treatment of wastewater by biological and membrane separation technologies |
CN2600437Y (en) * | 2003-01-22 | 2004-01-21 | 胡龙兴 | Order group type bio-membrane reactor system |
CN1927739A (en) * | 2006-08-29 | 2007-03-14 | 湖南大学 | Operation mode and apparatus of short distance nitration-anaerobic ammoxidation batched biomembrane denitrogenation |
Non-Patent Citations (1)
Title |
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《工业用水与废水》 20021231 王亚宜等 "序批式生物膜(SBBR)法和SBR法的对比研究" 4-6 1-4 第33卷, 第6期 2 * |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105645664A (en) * | 2014-11-14 | 2016-06-08 | 重庆大学 | A constructing method of an autotrophic denitrification system for low-concentration ammonia nitrogen sewage |
CN107129040A (en) * | 2016-02-29 | 2017-09-05 | 鞍钢股份有限公司 | A kind of method and device for extending sequencing batch membrane bioreactor film service life |
CN105776526A (en) * | 2016-03-25 | 2016-07-20 | 中国海洋大学 | Anaerobic membrane bioreactor |
CN105925478A (en) * | 2016-06-20 | 2016-09-07 | 同济大学 | Rapid enrichment culture device for anaerobic ammonium oxidation bacteria |
CN105925478B (en) * | 2016-06-20 | 2018-06-05 | 同济大学 | A kind of anaerobic ammonia oxidizing bacteria fast enriching culture apparatus |
CN107117703A (en) * | 2017-05-12 | 2017-09-01 | 北京建筑大学 | A kind of control sequencing batch membrane bioreactor in real time |
CN109354218A (en) * | 2018-12-27 | 2019-02-19 | 大连海洋大学 | A kind of use for laboratory graphite oxide aerogel biofilm reactor |
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