CN101981210A - Device for stirring molten metal - Google Patents

Device for stirring molten metal Download PDF

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Publication number
CN101981210A
CN101981210A CN2010800013317A CN201080001331A CN101981210A CN 101981210 A CN101981210 A CN 101981210A CN 2010800013317 A CN2010800013317 A CN 2010800013317A CN 201080001331 A CN201080001331 A CN 201080001331A CN 101981210 A CN101981210 A CN 101981210A
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CN
China
Prior art keywords
molten metal
stirring body
agitating vane
slot part
path slot
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CN2010800013317A
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Chinese (zh)
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CN101981210B (en
Inventor
永留朝郎
内田富大
堤英气
打田龙彦
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Mitsui Mining and Smelting Co Ltd
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Mitsui Mining and Smelting Co Ltd
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Priority claimed from JP2009036158A external-priority patent/JP5032521B2/en
Priority claimed from JP2009067815A external-priority patent/JP4672067B2/en
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Publication of CN101981210A publication Critical patent/CN101981210A/en
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B9/00General processes of refining or remelting of metals; Apparatus for electroslag or arc remelting of metals
    • C22B9/05Refining by treating with gases, e.g. gas flushing also refining by means of a material generating gas in situ
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/10Supplying or treating molten metal
    • B22D11/11Treating the molten metal
    • B22D11/116Refining the metal
    • B22D11/117Refining the metal by treating with gases
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B21/00Obtaining aluminium
    • C22B21/06Obtaining aluminium refining
    • C22B21/064Obtaining aluminium refining using inert or reactive gases
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D27/00Stirring devices for molten material

Abstract

Provided is a device for stirring a molten metal whereby bubbles formed by blowing a gas can be miniaturized and uniformized. A device (1) for stirring a molten metal equipped with a stirring blade (2) which is attached to the front end of a tubular shaft (3) and in which grooves (22) for the passage of a blown gas are formed radially on the bottom face (2a) thereof, characterized in that the ratio of the projected bottom area of the grooves (22) to the projected bottom area of the stirring blade (2) is adjusted to 0.20 to 0.60. The stirring blade (2) can be shaped into a disc form and the ratio of the radius of the disc to the length of the grooves (22) can be adjusted to 0.5 to 0.9.

Description

The molten metal stirring body
Technical field
The present invention relates to be used to carry out the molten metal stirring body that the degassing of molten metals such as aluminium is handled.
Background technology
The degassing of aluminium or aluminium alloy etc. is for example handled by being blown into argon gas, nitrogen etc. on one side in the molten metals such as aluminium and is blown into gas and utilizes molten metal to carry out with the stirring body stirring molten metal on one side.By carrying out this processing, can be captured in and be blown in the gas and remove dissolving in obnoxious flavoures such as hydrogen in the molten metal or small inclusion.
In order to improve the effect that the degassing is handled, need to improve the stirring efficiency of molten metal, make be blown into molten metal to be blown into gas fine and form size uniformly and diffuse to each place in the molten metal.
In following patent documentation 1~5, disclose the molten metal stirring body that is provided with radial slot in the bottom surface of agitating vane, and put down in writing the technology that shearing action that the rare gas element by radial slot produces by the rotation by agitating vane is segmented.
In following patent documentation 6,7, disclose and be the molten metal stirring body that is provided with jut radially in the bottom surface of agitating vane, and put down in writing the situation of utilizing jut the bubble chopping to be made its miniaturization.
In following patent documentation 8, disclose and be provided with the molten metal stirring body that many cross sections are the groove of triangular shape in the bottom surface of agitating vane, and put down in writing and utilized groove to produce eddy current, thereby molten metal has been stirred and made the technology of bubble sectionalization.
Patent documentation 1: the real fair 7-23098 communique (claim 1, Fig. 2 etc.) of Japan
Patent documentation 2: the real flat 3-91161 communique (Fig. 2 etc.) of opening of Japan
Patent documentation 3: the real fair 7-53804 communique (Fig. 2 etc.) of Japan
Patent documentation 4: real No. 2504800 communiques (Fig. 3 etc.) of stepping on of Japan
Patent documentation 5: Japanese kokai publication hei 7-55365 communique (Fig. 2 etc.)
Patent documentation 6: TOHKEMY 2001-59122 communique (claim 1, Fig. 1 etc.)
Patent documentation 7: TOHKEMY 2003-130557 communique (Fig. 2 etc.)
Patent documentation 8: TOHKEMY 2003-328046 communique (claim 1, Fig. 2 etc.)
As mentioned above, need make bubble miniaturization and the homogenizing in molten metal that is blown into gas.
Use in the stirring body at the molten metal that above-mentioned patent documentation 1~5 is put down in writing, the bubble that radial slot is flow through in existence spilt before arriving peripheral part, the bubble in big footpath is dispersed to the situation in the molten metal.
And, use in the stirring body at the molten metal that above-mentioned patent documentation 6,7 is put down in writing, owing to utilize jut that bubble is shredded, even if therefore the size of bubble miniaturization bubble is also inhomogeneous, in addition, use in the stirring body, utilize eddy current to make the bubble miniaturization at the molten metal that above-mentioned patent documentation 8 is put down in writing, but, be difficult to the size adjustment of bubble even.
Above-mentioned situation can cause the decline of degassing performance, and the result causes the bubble of metal products residual, and produces substandard product.
Summary of the invention
Therefore, the object of the present invention is to provide and a kind ofly can make the bubble miniaturization that is blown into gas and the molten metal stirring body of homogenizing.
Molten metal of the present invention is arranged on the tip of the axis with stirring body with agitating vane, described agitating vane is formed with for the radial path slot part that is blown into gas flow in bottom surface sections, it is characterized in that the projection floorage of described path slot part part is 0.20~0.60 with the ratio of the projection floorage of agitating vane part.
For molten metal stirring body of the present invention, form predetermined scope by ratio with the shadow area of agitating vane and the shadow area of path slot part, can make the bubble miniaturization and the homogenizing that are blown into gas.
Description of drawings
Fig. 1 is the stereographic map of the molten metal of an embodiment of the invention with stirring body.
Fig. 2 is the upward view of stirring body shown in Figure 1.
Fig. 3 is the sectional view of the agitating vane part of stirring body shown in Figure 1.
Fig. 4 is the local amplification stereogram that the bottom surface side of stirring body shown in Figure 1 is shown.
Fig. 5 is the figure that the agitating vane projection floorage partly of stirring body shown in Figure 1 is shown with oblique line.
Fig. 6 is the figure that the path slot part projection floorage partly of stirring body shown in Figure 1 is shown with oblique line.
Fig. 7 is the stereographic map of the molten metal of other embodiments of the present invention with stirring body.
Fig. 8 is the upward view of stirring body shown in Figure 7.
Fig. 9 is the side-view of stirring body shown in Figure 7.
Figure 10 is the side-view in a variation of slot part shown in the stirring body shown in Figure 7.
Figure 11 is the side-view in other variation of slot part shown in the stirring body shown in Figure 7.
Figure 12 is the local amplification inclinating view of stirring body shown in Figure 7.
Figure 13 is the sectional view of stirring body shown in Figure 7.
Figure 14 is the local amplification stereogram of stirring body shown in Figure 7.
Figure 15 is the figure that the path slot part projection floorage partly of stirring body shown in Figure 7 is shown with oblique line.
Figure 16 illustrates the shape of the molten metal of embodiment 15~23 and comparative example 10~13 with stirring body, (a) is upward view, (b) is the sectional view along the X-X line.
Embodiment
Below, the molten metal of an embodiment of the invention is described with stirring body.In addition, scope of the present invention is not limited to this embodiment.
Shown in Fig. 1 waits, the molten metal of an embodiment of the invention with stirring body 1 by fixing agitating vane 2 and spools 3 integratedly such as fastening or bonding.
Agitating vane 2 and axle 3 can be that pottery, silicon carbide system pottery, carbon ceramics, charcoal etc. form by silicon nitride series pottery, Sai Long (sialon), more particularly, can form by following pottery etc.: utilize sintering aid that alpha-silicon nitride powders is carried out sintering and the silicon nitride series pottery or the grand system of the match pottery that obtain; The silicon carbide system pottery that carborundum sintered body that obtains by utilizing sintering aid that silicon carbide powder is carried out sintering or the silicon nitride combined silicon carbide sintered compact that contains the silicon carbide more than the 70 weight % etc. form; And mix charcoal, silicon carbide, norbide etc. to make sintered compact and the carbon ceramics that obtains.
Shown in Fig. 2 or Fig. 3 etc., agitating vane 2 forms discoid, the terminal part of axle 3 can be fixed in the circular hole at the center of being located at agitating vane 2, be formed with the reservoir 21 that is used to store the circular concavity that is blown into gas at the bottom surface sections 2a of agitating vane 2, and, be formed with for being blown into the radial path slot part 22 that gas passes through, be formed with notch part 23 with proper spacing at the peripheral part 2b of agitating vane 2.
Agitating vane 2 there is no particular determination, and diameter forms 120mm~300mm, is preferably 170mm~230mm, and thickness forms 10mm~35mm, is preferably 20mm~30mm.
Shown in Fig. 1 or Fig. 2 etc., reservoir 21 is spaces that rounded shape depression that the interior perimembranous 2c by the bottom surface 3a of axle 3 and agitating vane 2 surrounds forms, and forms the gas that is blown into that can store from axle 3 ejections.
Reservoir 21 there is no particular determination, and diameter forms 40mm~80mm, is preferably 50mm~70mm, and the degree of depth forms 6mm~15mm, is preferably 8mm~12mm.
Interior perimembranous 2c preferred vertical ground forms or is formed obliquely in the mode that narrows down towards the below, by such formation, is blown into gas and is difficult to overflow from reservoir 21.
Shown in Fig. 1~4 grades, path slot part 22 the bottom surface sections 2a of agitating vane 2 be formed with radially a plurality of, this path slot part 22 is all side openings end 22a in interior perimembranous 2c forms, form outer circumferential side open end 22b at the peripheral part 2b of agitating vane 2, thereby this path slot part 22 forms with reservoir 21 and links to each other with peripheral part 2b, the bubble that is blown into gas that is stored in reservoir 21 can be sent the peripheral part 2b side to agitating vane 2.
The shape of path slot part 22 there is no particular determination, can form that cross section square shape, cross section are circular-arc, section triangle shape etc.
The projection floorage of path slot part 22 parts (the oblique line part of Fig. 6) is 0.20~0.60, is preferably 0.30~0.50 that with the ratio of the projection floorage (the oblique line part of Fig. 5) of agitating vane 2 parts the length of path slot part 22 is 0.5~0.9, is preferably 0.6~0.8 with the ratio of the radius of agitating vane 2.
In addition, the projection floorage of so-called agitating vane 2 parts is meant the bottom surface sections 2a of agitating vane 2 and the projection floorage that axle 3 bottom surface 3a adds part together.
Path slot part 22 can with width outward perimembranous 2b broaden gradually or the mode that narrows down forms taper, in this case, the width of outer circumferential side open end 22b is 0.5~6.0, is preferably 0.8~2.0 with the ratio of the width of interior all side openings end 22a.
The degree of depth of path slot part 22 is 0.3~3.0, is preferably 0.5~1.5 with the ratio of the width of outer circumferential side open end 22b.
Notch part 23 is configured between each slot part 22 of peripheral part 2b of agitating vane 2, forms by square-shaped otch.
Notch part 23 there is no particular determination, and width forms 6mm~10mm, is preferably 7mm~9mm, and depth forms 6mm~14mm, is preferably 8mm~12mm.
Shown in Fig. 1 or Fig. 2 etc., axle 3 forms and has the cylindric of bottom surface 3a, and inside forms for the vent passage that is blown into gas flow, is formed with the gas vent 31 that ejection is blown into the circle of gas in the approximate centre of bottom surface 3a.
The molten metal of Xing Chenging can make the bubble after miniaturization and the big or small homogenizing be dispersed in the molten metal with stirring body 1 by this way, therefore can improve the efficient that the degassing is handled.
And, be under the situation of above-mentioned pottery in the material that makes stirring body, in order to form the stirring body of resistance to sudden heating and excellent in wear resistance, be preferably formed and be following mode.
The molten metal that is formed by pottery that other modes have been shown in Fig. 7~15 is with stirring body 4.
Shown in Fig. 7~9 grades, agitating vane 5 forms the umbrella shape shape of central part protuberance, and the end of axial region 6 can be fixed in the circular hole of the approximate centre of being located at agitating vane.Peripheral part 5a at agitating vane 5 is formed with notch part 51, is formed with taper portion 52 and path slot part 53 at the bottom surface sections 5b of agitating vane 5.
From taking into account the viewpoint of stirring efficiency and resistance to sudden heating, wall thickness (the size t among Figure 13 of the interior perimembranous 5c side of agitating vane 5 i) be preferably formed 4.0%~9.0% ratio for diameter, be preferably formed 5.0%~8.0% ratio into diameter especially, and, be preferably formed wall thickness (the size t among Fig. 9 into peripheral part 5a side o) 0.9~2.0 times, to be preferably formed especially be 1.1~1.6 times.
Specifically, the diameter of agitating vane 5 is preferably formed to 120mm~300mm, be preferably formed especially and be 170mm~230mm, the wall thickness of interior perimembranous 5c is preferably formed to 7mm~21mm, be preferably formed especially and be that 9mm~18mm, the wall thickness of peripheral part 5b are preferably formed to 6mm~16mm, are preferably formed especially and are 8mm~12mm.
In addition, said wall thickness is meant the wall thickness of removing the position in addition, position that is formed with path slot part 53 among the present invention.
Shown in Fig. 8 or Figure 12 etc., notch part 51 becomes square shape at the peripheral part 5a of agitating vane 5 with the proper spacing notch shape, and two bight 51a, the 51a of the inboard of this notch part 51 (axial region 6 sides) form the fillet shape.
Shown in Fig. 8 or Figure 13 etc., taper portion 52 is formed near the central authorities of bottom surface sections 5b, in section, form from the end side of axial region 6 towards below skewed towards outside expansion gradually.
Shown in Fig. 8,9 or 14 etc., path slot part 53 forms the groove that the cross section is a semicircle shape, and bottom surface sections 5b with from taper portion 52 toward the outer side by each notch part 51 between and the mode that extends through peripheral part 5a be formed with radially a plurality of.
At this moment, the projection floorage of path slot part 53 parts becomes the part shown in the oblique line part of Figure 15.
In addition,, be not limited thereto, also can form the path slot part 53a of cross section square shape shown in Figure 10 or path slot part 53b of cross section U word shape shown in Figure 11 etc. though path slot part 53 forms the cross section semicircle shape.
As shown in figure 13, axial region 6 forms has the cylindric of bottom 6a endways, is provided with circular hole in the approximate centre of bottom 6a, and this hole is blown into gas and sprays from gas vent 61 by the inside of axial region 6a as gas vent 61.The private side of the bottom 6a of axial region 6 forms the curved surface 62 that is hemispherical depression in the mode towards gas ejection ports 61 constrictions.
For this molten metal with stirring body 4, because agitating vane 5 is formed the umbrella shape shape and the wall thickness of interior perimembranous 5c is defined in predetermined scope, so the resistance to sudden heating excellence, also be difficult to break even if use repeatedly, and, owing to form by pottery, so wearability is also excellent.
Embodiment
Below, according to embodiment the present invention is carried out more specific description.But scope of the present invention is not limited to this embodiment.
(test 1)
As embodiment 1~14 and comparative example 1~9, form shape as shown in table 1, the molten metal stirring body of material, and use each stirring body to measure degassing performance.
<degassing performance 〉
It is in 730 ℃ the molten aluminum of 600kg that stirring body is immersed in melt temperature, the rotating speed that makes stirring body is 600rpm, feed argon gas as being blown into gas with 30L/min, under this state, make stirring body work and the processing that outgases, and make the molten metal after the degassing is handled flow into mold, the cross section state of the foundry goods that visual observation obtains.If the state that does not have a pore for " ◎ ", establish the state that almost do not have pore (not in-problem degree aspect practical) for " zero ", establish the state that there is pore (in-problem degree aspect practical) for " △ " and estimate.
[table 1]
Figure BPA00001232846400071
Than 1: the projection floorage of path slot part part and the ratio of agitating vane projection floorage partly
Than 2: the length of path slot part part and the ratio of the radius of agitating vane
Than 3: the ratio of outer circumferential side open end groove width and interior all side openings end groove width
Than 4: the ratio of the degree of depth of path slot part and the groove width of outer circumferential side open end
(result)
Embodiment 1~14 is the state that does not have the state of pore or almost do not have pore, is good result.Comparative example 1~9 has all produced pore, is bad result.
From this result as can be seen, shown in embodiment 1~14, if the ratio of the projection floorage of path slot part part and the projection floorage of agitating vane part is 0.25~0.55 scope, then is the evaluation of " zero " or " ◎ ", is the stirring body with good degassing performance.
And, shown in comparative example 1~9, below 0.17 or under the situation more than 0.61, then be the evaluation of " △ " at the ratio of the shadow area of path slot part part and the projection floorage of agitating vane part, can confirm not outgas fully.
Owing to these reasons, think under the projection floorage of path slot part part with respect to the projection floorage of agitating vane part is the situation of 0.20~0.60 scope, to form stirring body with good degassing performance.
(test 2)
As the stirring body of embodiment 15~23 and comparative example 10~13, form the stirring body of shape shown in Figure 16.Such formation as shown in table 2 such as the interior perimembranous of agitating vane and the wall thickness of peripheral part, diameter, the following formation of shape of taper portion, notch part, path slot part.
Taper portion
Length: with respect to diameter is 12%
Highly: 8mm
Notch part
Width: with respect to diameter is 10%
The degree of depth: with respect to diameter is 10%
Two jiaos of R:4mm
The path slot part
Width: with respect to diameter is 5%
The degree of depth: the wall thickness with respect to peripheral part is 50%
The projection floorage of path slot part part is with respect to the ratio of the projection floorage of agitating vane part: 0.34
Use the stirring body of embodiment 15~23 and comparative example 10~13 to carry out following resistance to sudden heating test.Its result shown in the following table 2.
[table 2]
Figure BPA00001232846400081
Than perimembranous wall thickness/periphery wall wall thickness in the 5=
Than perimembranous wall thickness/diameter * 100 in the 6=
Material
A silicon nitride series pottery
B silicon carbide system pottery
The grand system of C match pottery
The D carbon ceramics
(resistance to sudden heating test)
Not carrying out preheating just is immersed in embodiment 15~23 and comparative example 10~13 from normal temperature (about 20 ℃) and is adjusted into the molten aluminum of certain temperature and kept 5 minutes.Then stirring body is extracted out from molten aluminum and cooled off in atmosphere, Visual Confirmation has flawless, and utilizes following metewand to judge.
◎: postcooling does not have crackle yet in 800 ℃ the molten aluminum even if be immersed in.
Zero: be immersed in that postcooling does not have crackle in 750 ℃ the molten aluminum, if but be immersed in postcooling in 800 ℃ the molten aluminum then have crackle.
△: be immersed in that postcooling does not have crackle in 700 ℃ the molten aluminum, if but be immersed in postcooling in 750 ℃ the molten aluminum then have crackle.
*: be immersed in that also there is crackle in postcooling in 700 ℃ the molten aluminum.
(result)
Embodiment 15~23 is not cracking more than 750 ℃ in the resistance to sudden heating test.Comparative example 10~13 all cracks at 750 ℃ in the resistance to sudden heating test, and comparative example 13 also cracks at 700 ℃.
Like this, according to the result of comparative example 10,11,, therefore think that about 0.9~2.0 is suitable when of ratio (interior perimembranous wall thickness/peripheral part wall thickness) resistance to sudden heating decline when being 0.7 and 2.2 of interior perimembranous wall thickness with the peripheral part wall thickness.
And according to the result of comparative example 12,13, resistance to sudden heating descends when interior perimembranous wall thickness and diameter ratio are 3.0% and 10%, and the perimembranous wall thickness is about 4.0%~9.0% to be suitable with respect to the ratio of diameter in therefore thinking.

Claims (11)

1. molten metal stirring body, this molten metal is arranged on the tip of the axis with stirring body with agitating vane, and described agitating vane is formed with the radial path slot part that is blown into gas in bottom surface sections, and described molten metal is characterised in that with stirring body,
The projection floorage of path slot part part is 0.20~0.60 with the ratio of the projection floorage of agitating vane part.
2. molten metal stirring body according to claim 1, wherein,
Agitating vane forms discoid, and the ratio of the length of described path slot part and the radius of agitating vane is 0.5~0.9.
3. molten metal stirring body according to claim 1 and 2, wherein,
The width of the outer circumferential side open end of described path slot part is 0.5~6.0 with the ratio of the width of interior all side openings end.
4. according to each the described molten metal stirring body in the claim 1~3, wherein,
The degree of depth of described path slot part is 0.3~3.0 with the ratio of the width of the outer circumferential side open end of this path slot part.
5. according to each the described molten metal stirring body in the claim 1~4, wherein,
Be provided with the notch part of square shape with proper spacing at the peripheral part of agitating vane.
6. according to each the described molten metal stirring body in the claim 1~5, wherein,
The material of agitating vane is the grand system of silicon nitride series pottery, match pottery, silicon carbide system pottery, carbon ceramics, charcoal.
7. molten metal stirring body according to claim 6, wherein,
Agitating vane forms the umbrella shape shape, and the interior perimembranous wall thickness of agitating vane forms 4.0%~9.0% thickness of diameter, and the interior perimembranous wall thickness of agitating vane is 0.9~2.0 with the ratio of peripheral part wall thickness.
8. molten metal stirring body according to claim 7 is characterized in that,
The bottom surface sections of agitating vane be formed with from the end side of axial region towards below the taper portion of expansion gradually.
9. according to claim 7 or 8 described molten metal stirring bodies, wherein,
Be provided with the notch part of square shape at the peripheral part of agitating vane with proper spacing, and two bights of the inboard of this notch part form circular-arc.
10. according to each the described molten metal stirring body in the claim 7~9, wherein,
The path slot part forms cross section semicircle shape, cross section U word shape or cross section square shape.
11. according to each the described molten metal stirring body in the claim 7~10, wherein,
Approximate centre in the bottom of axial region is provided with gas ejection ports, and makes the inner recess of this bottom become hemispherical.
CN201080001331.7A 2009-02-19 2010-01-25 Device for stirring molten metal Active CN101981210B (en)

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JP2009036158A JP5032521B2 (en) 2009-02-19 2009-02-19 Stirrer for molten metal
JP2009-036158 2009-02-19
JP2009067815A JP4672067B2 (en) 2009-03-19 2009-03-19 Stirrer for molten metal
JP2009-067815 2009-03-19
PCT/JP2010/000388 WO2010095360A1 (en) 2009-02-19 2010-01-25 Device for stirring molten metal

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CN106735048A (en) * 2016-12-22 2017-05-31 重庆昌跃机电制造有限公司 A kind of aluminium alloy crankshaft-link rod die casting production line
CN106735048B (en) * 2016-12-22 2018-09-11 重庆昌跃机电制造有限公司 A kind of aluminium alloy crankshaft-link rod die casting production line
WO2019204986A1 (en) * 2018-04-24 2019-10-31 安徽阿尔泰克铝业材料科技有限公司 Molten aluminum holding furnace provided with purification system and molten aluminum temperature detection method therefor

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