CN101967199A - Composite modified starch, preparation method and application thereof - Google Patents
Composite modified starch, preparation method and application thereof Download PDFInfo
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- CN101967199A CN101967199A CN2010101192621A CN201010119262A CN101967199A CN 101967199 A CN101967199 A CN 101967199A CN 2010101192621 A CN2010101192621 A CN 2010101192621A CN 201010119262 A CN201010119262 A CN 201010119262A CN 101967199 A CN101967199 A CN 101967199A
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Abstract
The invention provides a preparation method of composite modified starch, comprising: carrying out crosslinking by crosslinker sodium trimetaphosphate; and then esterfying by succinic anhydride. The invention also provides a composite modified starch prepared with the method and application thereof.
Description
Technical field
The application relates to a kind of preparation method of composite modified starch and the composite modified starch that is prepared by this method, and especially, this composite modified starch can be used for foodstuffs industry, the additive of esp meat goods industry.
Background technology
Particularly in the meat product processing, adopt native starch to improve water-retentivity, the weave construction of food as thickening material at food always; Make outward appearance and yield that vehicle and weighting agent improve product.But in some product processing, native starch and single modified starch but can not satisfy some processing requirement.Therefore, people utilize the complex denaturation mode of starch to improve the fundamental characteristics of its molecule, produce to adapt to the composite modified starch that the different foods complete processing requires.Modified starch is to instigate starch and chemical reagent reaction, connects reactive group or make it crosslinked together on molecule, to strengthen the performance of its some aspect, makes its effect in actual applications more outstanding, and working conditions is wideer.At present, the sex change of starch has binary, ternary, quaternary sex change, and main complex denaturation (sex change repeatedly) has crosslinked-esterification starch, etherificate-crosslinked-pre-gelatinized starch, crosslinked-carboxymethyl sex change etc.Such as disclosing a kind of etherificate-crosslinked-pre-gelatinized starch among the Chinese patent CN200310112684.6, with characteristics such as antiacid, the anti-salt that improves starch, freeze-thaw-, cold water Yi Rong, make the finished product can be used as the thickening stabilizer of peracid, high salt, frozen product; The Henan chemical industry, 2006,23 (4), the preparation and the performance study of the crosslinked cassava acetate starch of hexanodioic acid, the 17-19 page or leaf, described and a kind ofly made linking agent with hexanodioic acid, vinyl acetate is made esterifying agent and is prepared crosslinked acetate starch, and the cross-linked esterification starch that obtains has higher viscosity and freeze-thaw stability.
Though for starch multiple sex change mode has been arranged at present, but with the starch after these sex change be used for food particularly hard and nonelastic, the mouthfeel of meat product ubiquity the starch flavor is arranged, organizes many defectives such as coarse, though starch acetic anhydride esterification after crosslinked can obtain to have better performance, as anti-shearing strong, heat-resisting ability, the caking ability height, freeze-thaw stability is good, but acetic anhydride has pungency, unfavorable to HUMAN HEALTH, be not suitable for foodstuffs industry, and products obtained therefrom cost height is unfavorable for wide popularization and application.
Summary of the invention
First purpose of the present invention is to provide that a kind of to adopt the linking agent Trisodium trimetaphosphate to carry out starch crosslinked, and carry out esterification by Succinic anhydried, can obtain having premium properties, composite modified starch, the preparation method of a kind of composite modified starch that its production method is simple, with low cost.
Second purpose of the present invention is to provide a kind of composite modified starch.
The 3rd purpose of the present invention is to provide a kind of purposes of composite modified starch.
Purpose of the present invention is implemented by following technical scheme: a kind of preparation method of composite modified starch, it comprises inhibitor and basic catalyst soluble in water, again to wherein adding starch, adjusting Ph is 10.0-11.5, and heating in water bath obtains starch milk under 40-42 ℃, then add Trisodium trimetaphosphate, reacted 1.5-2.5 hour, be neutralized to weakly alkaline (such as Ph8.0-9.0) with acid afterwards, add Succinic anhydried simultaneously and keep this Ph value reaction, after the Succinic anhydried interpolation finishes, treat that Ph is not after variation, neutralization, washing, drying and crushing is also sieved, and obtains composite modified starch.
In the above-described embodiment, the add-on of inhibitor is the 1%-5% based on starch weight, preferred 2-4%, more preferably 3%, the add-on of basic catalyst is the 0.2%-0.8% based on starch weight, preferred 0.5-0.6%, when with inhibitor and sodium hydroxide when soluble in water the consumption of water be based on starch weight 1.0-1.5 times, preferred 1.2 times.
In an embodiment preferred of the present invention, a kind of preparation method of composite modified starch is provided, it comprises the steps:
1), will be dissolved in respect to inhibitor, the 0.2%-0.8% basic catalyst of starch weight 1%-5% with respect in the about 1.0-1.5 of the starch weight water doubly, fully stir, obtain uniform solution;
2), add starch to above-mentioned solution, mix, regulate the Ph value to 10.0-11.5, heating in water bath obtains starch milk to 40-42 ℃ simultaneously;
3), in above-mentioned starch milk, add linking agent Trisodium trimetaphosphate based on the 0.010%-0.050% of starch weight, keep pH value between 10.0-11.5, reacted 1.5-2.5 hour;
4), be neutralized to PH 8.0-9.0, be cooled to 20-30 ℃ simultaneously with the 9%-11% hydrochloric acid soln;
5), add succinic anhydride esterification based on the 0.3%-0.5% of starch weight, keep pH value to react at 8.0-9.0, after question response is finished, be neutralized to PH 5.5-6.5 with mass percent concentration 9%-11% hydrochloric acid;
6), wash to specific conductivity＜800us/cm PH 5.5-6.5 with softening water; Afterwards, dry, pulverize and sieve, obtain composite modified starch.
In the above-described embodiment, described inhibitor can be sodium sulfate or sodium-chlor, this programme preferably sulfuric acid sodium; Basic catalyst can be sodium hydroxide, potassium hydroxide, calcium hydroxide or yellow soda ash etc. any, preferred sodium hydroxide.
In the above-described embodiment, the add-on of linking agent Trisodium trimetaphosphate is the 0.010%-0.050% based on the starch consumption, preferred 0.020%; The add-on of Succinic anhydried is the 0.3%-0.5% based on the starch consumption, preferred 0.4%.
In this article, described starch can be W-Gum, wheat starch, rye starch, oat starch, tapioca (flour), yam starch, glutinous rice starch, preferred yam starch.
In the technical scheme of second purpose of the present invention, provide a kind of composite modified starch for preparing according to the preparation method of composite modified starch of the present invention.
In the 3rd the purpose technical scheme of the present invention, also provide the purposes of the composite modified starch that preparation in accordance with the present invention prepares,, be used for the thickening material, water-holding agent, vehicle, stablizer of meat product processing etc. especially as foodstuff additive.
If not explanation especially, in the preparation method of composite modified starch of the present invention, the weight that given mass percent is based on the starch that wherein adopts is basic; Described " ative starch " or " native starch " starch that to be the conventional any method that adopts in this area directly obtain from the material of natural origin such as potato class.
The preparation method of composite modified starch of the present invention finishes in a step in the cross-linking starch production technique, and technological design is simple, practical, has reduced production cost, is convenient to promote the use of.And, the present invention reacts by cross-linking of starch, make two or more starch molecules formation spacial framework crosslinked together, reach anti-shearing, the heat-resisting ability that require in the foodstuffs industry, the caking ability height, the purpose that freeze-thaw stability is good, on this basis, add the succinic anhydride esterification agent, make and produce esterified group on the starch molecule simultaneously, thereby improve swelling property, resistance to deterioration and gelation, thereby in foodstuffs industry, have important use.Under the situation that does not increase any equipment, crosslinked, two kinds of denaturation methods of esterification are combined, and adopt specific Succinic anhydried to make esterifying agent, give the composite modified starch that obtains and have better freeze-thaw stability, better good characteristics such as strong, the good water-retaining property of transparency and elasticity, resistance to deterioration, turgidity height.Composite modified starch of the present invention is applied to food particularly in the meat product (such as the intestines based article), has the goods of making homogeneous microstructure exquisiteness, structure is tight, high resilience, tangent plane is smooth, and is fresh and tender agreeable to the taste, many good application characteristics such as water-retentivity is strong when prolonged preservation and deepfreeze.
Description of drawings
Fig. 1 is the Bradley Bender viscograph of the potato ative starch of 5% concentration.
Fig. 2 is the Bradley Bender viscograph by the potato composite modified starch of embodiment 1 experiment condition preparation of 5% concentration.
Fig. 3 is a method for preparing composite modified starch synoptic diagram of the present invention.
Embodiment
Further elaborate the present invention with reference to embodiment below, but it will be appreciated by those skilled in the art that but the present invention is not limited to the method for these embodiment and use.And those skilled in the art can carry out it is equal to replacement, combination, improvement or modification according to description of the invention to the present invention, but these all will comprise within the scope of the invention.
In following embodiment, the succinate Determination on content method of composite modified starch is as follows:
Accurately take by weighing 2.0g (in dry-matter, butt) starch in the 150ml beaker, add the 0.1mol/L HCL solution of 25ml, make its carboxyl become free acidic group, magnetic agitation 30 minutes is filtered with the glass sand core funnel, and is washed till no chlorion with distilled water and (uses AgNO
3Detect), afterwards, be transferred in the 500ml beaker with 300ml distilled water, heating is 10 minutes in boiling water bath, is that indicator is used the titration while hot of 0.1mol/L NaOH standardized solution to terminal with phenolphthalein, and the volume of consumption is V
1
Blank: get ative starch 2.0g (butt) and add the gelatinization of 300ml distilled water in the 500ml beaker, to the phenolphthalein variable color, the volume of consumption is V with 0.1mol/L NaOH standard solution titration
2
Soduxin base content C
M(%)=(V
1-V
2) * C * 0.123 * 100/2.0
In the formula:
C
M: Soduxin base content (%);
C: the concentration of standard solution of sodium hydroxide (mol/L);
V
1: composite modified starch consumes the volume (ml) of standard solution of sodium hydroxide;
V
2: ative starch consumes the volume (ml) of standard solution of sodium hydroxide.
The preparation of embodiment 1 potato composite modified starch
Prepare the potato composite modified starch according to following steps:
1, with 3.0 gram sodium sulfate, 0.2 gram sodium hydroxide is dissolved in the 100 gram softening waters, fully stirs, and obtains uniform solution;
2, add 100 gram potato ative starchs in above-mentioned solution, mix, regulate pH value to 10.0 with the sodium hydroxide solution of mass percent 4%, heating in water bath to 42 ℃ obtains starch milk simultaneously;
3, in above-mentioned starch milk, add 0.05 gram Trisodium trimetaphosphate, keep pH value 10.0 reactions 2.5 hours;
4, with in 10% hydrochloric acid and starch milk pH to 8.0, be cooled to 20 ℃ then;
5, add 0.4 gram succinic anhydride esterification, keep pH value, (finish when Succinic anhydried adds, when treating that pH value no longer changes) question response is finished after 8.0, with in mass percent concentration 10% hydrochloric acid with the starch milk pH value 5.5;
6, wash to specific conductivity＜800us/cm PH 5.5-6.5 with softening water; Filter, filter cake is dry in 50 ℃ of baking ovens, pulverized 100 mesh sieves after, composite modified starch.After measured, C
M=0.53.
The preparation of embodiment 2 cassava composite modified starchs
Prepare the cassava composite modified starch according to following steps:
1, with 5.0 gram sodium-chlor, 0.8 gram potassium hydroxide is dissolved in the 150 gram softening waters, fully stirs, and obtains uniform solution;
2, add 100 gram cassava ative starchs in above-mentioned solution, mix, regulate pH value to 11.5 with the sodium hydroxide solution of mass percent concentration 4%, heating in water bath to 42 ℃ obtains starch milk simultaneously;
3, in above-mentioned starch milk, add 0.03 gram Trisodium trimetaphosphate, keep pH value 11.5 reactions 2.5 hours;
4, with in 10% hydrochloric acid and starch milk pH value to 9.0, be cooled to 30 ℃ then;
5, add the succinic anhydride esterification of 0.5 gram, keep pH value 9.0, after question response is finished, with in the 9%-11% hydrochloric acid and the starch milk pH value 6.5;
6, wash to specific conductivity＜800us/cm PH 5.5-6.5 with softening water; Filter, filter cake is dry in 50 ℃ of baking ovens, pulverized 100 mesh sieves after, composite modified starch.After measured, C
M=0.65.
The preparation of embodiment 3 corn composite modified starchs
Prepare the corn composite modified starch according to following steps:
1, with 1.0 gram sodium sulfate, 0.2 gram sodium hydroxide is dissolved in the 100 gram softening waters, fully stirs, and obtains uniform solution;
2, add 100 gram corn ative starchs in above-mentioned solution, mix, regulate pH value to 11.5 with the sodium hydroxide solution of mass percent concentration 4%, heating in water bath to 42 ℃ obtains starch milk simultaneously;
3, in above-mentioned starch milk, add 0.01 gram Trisodium trimetaphosphate, keep pH value 10.0 reactions 1.5 hours;
4, with in 10% hydrochloric acid and starch milk pH value to 9.0, be cooled to 30 ℃ then;
5, add the succinic anhydride esterification of 0.3 gram, keep pH value, (finish when Succinic anhydried adds, treat that pH value is not when changing) question response is finished after 9.0, with in the mass percent concentration 9%-11% hydrochloric acid with the starch milk pH value 6.5;
6, wash to specific conductivity＜800us/cm with softening water, PH 5.5-6.5 filters, and filter cake is dry in 50 ℃ of baking ovens, pulverized 100 mesh sieves after, composite modified starch.After measured, C
M=0.40.
Claims (10)
1. the preparation method of a composite modified starch, it comprises inhibitor and basic catalyst soluble in water, and to wherein adding starch, adjusting Ph is 10.0-11.5 again, and heating in water bath obtains starch milk under 40-42 ℃, then add Trisodium trimetaphosphate, reacted 1.5-2.5 hour, be neutralized to weakly alkaline with acid afterwards, add Succinic anhydried simultaneously and keep this Ph value reaction, after question response was finished, neutralization, washing, drying and crushing were also sieved, and obtain composite modified starch
2. according to the preparation method of the composite modified starch of claim 1, the add-on of described inhibitor is the 1%-5% based on starch weight, preferred 2-4%, more preferably 3%; The add-on of sodium hydroxide is the 0.2%-0.8% based on starch weight, preferred 0.5-0.6%; The add-on of Trisodium trimetaphosphate is the 0.010%-0.050% based on starch weight, preferred 0.020%; The add-on of Succinic anhydried is the 0.3%-0.5% based on starch weight, preferred 0.4%.
3. according to the preparation method of the composite modified starch of claim 1, it comprises the steps:
1), will be dissolved in respect to inhibitor, the 0.2%-0.8% basic catalyst of starch weight 1%-5% with respect in the about 1.0-1.5 of the starch weight water doubly, fully stir, obtain uniform solution;
2), add starch to above-mentioned solution, mix, regulate the Ph value to 10.0-11.5, heating in water bath obtains starch milk to 40-42 ℃ simultaneously;
3), in above-mentioned starch milk, add linking agent Trisodium trimetaphosphate based on the 0.010%-0.050% of starch weight, keep pH value between 10.0-11.5, reacted 1.5-2.5 hour;
4), be neutralized to PH 8.0-9.0, be cooled to 20-30 ℃ simultaneously with the 9%-11% hydrochloric acid soln;
5), add succinic anhydride esterification based on the 0.3%-0.5% of starch weight, keep pH value to react at 8.0-9.0, after question response is finished, with mass percent concentration be 9%-11% hydrochloric acid be neutralized to PH 5.5-6.5;
6), wash to specific conductivity＜800us/cm PH 5.5-6.5 with softening water; Afterwards, dry, pulverize and sieve, obtain composite modified starch.
4. according to the preparation method of each described composite modified starch among the claim 1-3, wherein said inhibitor is sodium sulfate or sodium-chlor.
5. according to the preparation method of each described composite modified starch among the claim 1-3, wherein basic catalyst is any of sodium hydroxide, potassium hydroxide, calcium hydroxide or yellow soda ash, preferred sodium hydroxide.
6. according to the preparation method of the composite modified starch of claim 3, wherein the add-on of Trisodium trimetaphosphate is based on starch weight 0.020%; The add-on of Succinic anhydried is based on 0.4% of starch weight.
7. according to the preparation method of each described composite modified starch among the claim 1-6
Described starch is selected from W-Gum, wheat starch, rye starch, oat starch, tapioca (flour), yam starch, glutinous rice starch, preferred yam starch.
8. the composite modified starch for preparing according to the preparation method of each described composite modified starch in the claim 1 to 6.
9. the composite modified starch of claim 8 as the purposes of foodstuff additive.
10. according to the purposes of claim 9, wherein said composite modified starch is as thickening material, water-holding agent, vehicle, stablizer in the meat product processing.
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| CN102086233A (en) * | 2010-12-24 | 2011-06-08 | 陈明兴 | Manioc modified starch and production method thereof |
| CN102731663A (en) * | 2011-03-31 | 2012-10-17 | 聚祥(厦门)淀粉有限公司 | Modified starch |
| CN103360500A (en) * | 2013-07-26 | 2013-10-23 | 安徽光明槐祥工贸集团有限公司 | Preparation method of high-purity sweet rice starch |
| CN103687501A (en) * | 2011-07-22 | 2014-03-26 | 味之素株式会社 | Meat quality improver |
| CN104172023A (en) * | 2014-07-15 | 2014-12-03 | 呼和浩特华欧淀粉制品有限公司 | Alum-free potato nutritional vermicelli and preparation method thereof |
| CN104543663A (en) * | 2014-11-28 | 2015-04-29 | 安徽紫山农业科技有限公司 | Corn modified starch |
| CN104872402A (en) * | 2015-05-26 | 2015-09-02 | 成都易创思生物科技有限公司 | Method for preparing coated ferrous sulfate by using acetylate cross-link starch |
| CN105001346A (en) * | 2015-08-26 | 2015-10-28 | 广西梧州市明阳生化科技有限公司 | Production method for esterified modified starch |
| CN107522819A (en) * | 2017-09-15 | 2017-12-29 | 桂林理工大学 | The preparation method of the esterified oxidized tapiocas of high polymer coagulant EA g SA |
| CN109400941A (en) * | 2018-10-24 | 2019-03-01 | 合肥工业大学 | A kind of preparation method of cross-linked wheat porous-starch |
| CN110194854A (en) * | 2019-05-21 | 2019-09-03 | 广西高源淀粉有限公司 | A kind of composite modified starch and preparation method thereof |
| CN110408085A (en) * | 2018-04-27 | 2019-11-05 | 成都仁天医疗器械有限公司 | A kind of radiation resistance cold-storage gel and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102086233B (en) * | 2010-12-24 | 2012-10-03 | 陈明兴 | Manioc modified starch and production method thereof |
| CN102086233A (en) * | 2010-12-24 | 2011-06-08 | 陈明兴 | Manioc modified starch and production method thereof |
| CN102731663B (en) * | 2011-03-31 | 2016-04-06 | 厦门能藏义贸易有限公司 | A kind of modified starch |
| CN102731663A (en) * | 2011-03-31 | 2012-10-17 | 聚祥(厦门)淀粉有限公司 | Modified starch |
| CN103687501A (en) * | 2011-07-22 | 2014-03-26 | 味之素株式会社 | Meat quality improver |
| CN103360500A (en) * | 2013-07-26 | 2013-10-23 | 安徽光明槐祥工贸集团有限公司 | Preparation method of high-purity sweet rice starch |
| CN104172023A (en) * | 2014-07-15 | 2014-12-03 | 呼和浩特华欧淀粉制品有限公司 | Alum-free potato nutritional vermicelli and preparation method thereof |
| CN104543663A (en) * | 2014-11-28 | 2015-04-29 | 安徽紫山农业科技有限公司 | Corn modified starch |
| CN104872402A (en) * | 2015-05-26 | 2015-09-02 | 成都易创思生物科技有限公司 | Method for preparing coated ferrous sulfate by using acetylate cross-link starch |
| CN105001346A (en) * | 2015-08-26 | 2015-10-28 | 广西梧州市明阳生化科技有限公司 | Production method for esterified modified starch |
| CN107522819A (en) * | 2017-09-15 | 2017-12-29 | 桂林理工大学 | The preparation method of the esterified oxidized tapiocas of high polymer coagulant EA g SA |
| CN110408085A (en) * | 2018-04-27 | 2019-11-05 | 成都仁天医疗器械有限公司 | A kind of radiation resistance cold-storage gel and preparation method thereof |
| CN109400941A (en) * | 2018-10-24 | 2019-03-01 | 合肥工业大学 | A kind of preparation method of cross-linked wheat porous-starch |
| CN110194854A (en) * | 2019-05-21 | 2019-09-03 | 广西高源淀粉有限公司 | A kind of composite modified starch and preparation method thereof |
| CN112806555A (en) * | 2021-02-05 | 2021-05-18 | 瑞泰高直生物科技(武汉)有限公司 | Preparation method of special low-calorie salad dressing fat substitute |
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Application publication date: 20110209 |