CN101955865A - Shell cleanser for leather and preparation method thereof - Google Patents
Shell cleanser for leather and preparation method thereof Download PDFInfo
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- CN101955865A CN101955865A CN2010102951982A CN201010295198A CN101955865A CN 101955865 A CN101955865 A CN 101955865A CN 2010102951982 A CN2010102951982 A CN 2010102951982A CN 201010295198 A CN201010295198 A CN 201010295198A CN 101955865 A CN101955865 A CN 101955865A
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Abstract
The invention discloses a shell cleanser for leather and a preparation method thereof. The shell cleanser consists of the following components in part by weight: 35 to 45 parts of low-mesh shell power of between 80 and 150 meshes, 30 to 40 parts of high-mesh shell powder of between 200 and 300 meshes, 8 to 15 parts of oxidized microcrystalline wax, 1 to 3 parts of sodium dodecyl benzene sulfonate, 2 to 10 parts of soap powder, 0.1 to 0.5 part of Nipagin ester, 0. 5 to 1 part of simethicone, 1 to 5 parts of essence, and 10 to 20 parts of deionized water. The cleanser has the advantages of strong cleansing capability, stable performance, sterilization and mould proofness, leather protection, simple process and leather scrape resistance, and is suitable for cleaning and maintenance of leather products.
Description
Technical field
The invention belongs to chemically cleaning articles for use technical field, concrete, relate to a kind of leather type shell scrubbing powder and preparation method thereof.
Background technology
Leather and goods thereof are in the variation of using with the time, and aging cracking slowly is coated with the rete deepening of can fading, and anti-water and mildew-resistant ability will in time be maintained.Leather and goods maintenance thereof are very complicated, comprise cleaning, stuffing, fixation, glazing, feel degree, moisture-resistant WATER REPELLENT etc., and the layman is difficult to grasp these.Along with China's constant development of economy, living standards of the people improve constantly, leather and goods thereof are as requisite articles for use in the modern life, for people's lives bring great convenience, but general user lacks the understanding to leather and goods necessity thereof, the blind area that often causes the maintenance of leather and goods thereof.Organic substances such as process hides and goods rich in proteins, fat in the preservation process, are subjected to the microorganism invasion easily, and leather that is processed into and goods thereof owing to introduce the fatting agent of producing with natural fats and oils in a large number, have just become the hotbed of microbial reproduction; Simultaneously, the porousness of leather structure and polar structure make its easy moisture absorption and are acid, and these have constituted leather and the mouldy primary condition of goods thereof.It is not ideal to have the mould inhibitor treatment effect that is used for leather and goods thereof now, has only Compositional type mould inhibitor composite synergistic.The maintenance of the cleaning of leather and goods thereof is a necessary link, and selecting easy to use, high-efficiency low-toxicity, blast to increase scrubbing powder gentle, fungus and mildew resistance is the main flow direction that novel stain remover is studied.Now, the solid-state scrubbing powder that is specifically designed to cleaning leather and goods thereof does not also have appearance, though liquid detergents a multitude of names, its product is many with traditional technology production, and complex process, the restriction that costs an arm and a leg are popularized.Chinese patent 86102134 has been announced a kind of sanitising agent that is used for leatherware, is component suddenly with rosin, pure white oil, lead naphthenate or naphthenic acid, and along with the variation of environmental protection requirement, lead salt should be tried one's best need not.Chinese patent 91109941.7, announced a kind of leather brightening agent for washing, component oil siloxanes, wetting Agent for Printing Inks, tensio-active agent, mould inhibitor, it biases toward leather polishing, rather than integrate decontamination, sterilization, increase gentle, environmental protection, be added with the just more rare of tint retention.
Summary of the invention
The objective of the invention is in order to overcome the deficiency that above-mentioned prior art exists, a kind of simple and quick, fungus and mildew resistance, recovery snappiness are provided, and have feel as the silk and leather type shell scrubbing powder of natural gloss and preparation method thereof.
For achieving the above object, the technical scheme taked of the present invention is; This leather type shell scrubbing powder is to be made by the raw material of following weight part:
35～45 parts of the low order oyster shell whitings of 80～150 purposes
30～40 parts of the high order oyster shell whitings of 200～300 purposes
1～3 part of 8～15 parts of Sodium dodecylbenzene sulfonate of oxidized microcrystalline wax
0.1～0.5 part of 2～10 parts of nipagin esters of soap powder
10～20 parts of 1～5 part of deionized waters of 0.5～1 part of essence of dimethyl silicone oil;
It is standby that pretreated shell is ground into two kinds of other oyster shell whitings of level of high and low order on request; Oxidized microcrystalline wax and Sodium dodecylbenzene sulfonate composition mixture 60～90 ℃ of following heated and stirred 20～30 minutes, add dimethyl silicone oil and deionized water then, 60～90 ℃ of following heated and stirred 20～40 minutes, make emulsified microcrystalline wax; In proportion oyster shell whiting is mixed with various raw materials of soap powder, nipagin esters, essence after the pulverization process, after 10～20 minutes, emulsified microcrystalline wax is carried out thermospray, under heating condition not, stir and be cooled to normal temperature then 30～60 ℃ of heated and stirred, product.
Described nipagin esters comprises one or more in Tegosept M, ethyl p-hydroxybenzoate, propylben, Tegosept B, Tegosept E monooctyl ester and soluble metyl hydroxybenzoate, nipagin A sodium, soluble propylhydroxybenzoate, nipabutyl sodium and the compound sodium nipagin esters.
Described soap powder, nipagin esters and essence are to be not less than 100 purpose meals.
The preparation method of leather type shell scrubbing powder, this leather type shell scrubbing powder is made up of the raw material of following weight part: 35～45 parts of the low order oyster shell whitings of 80～150 purposes, 30～40 parts of the high order oyster shell whitings of 200～300 purposes, 8～15 parts of oxidized microcrystalline waxs, 1～3 part of Sodium dodecylbenzene sulfonate, 2～10 parts of soap powder, 0.1～0.5 part of nipagin esters, dimethyl silicone oil 0.5～1,1～5 part in essence, 10～20 parts of deionized waters;
The preparation method:
(1) shell is cleaned with clear water earlier, washs with the NaOH or the KOH aqueous solution soaking of 0.1% concentration then, with dirt and the residual slough of removing shell surface;
(2) will wash with alkali cleaning after shell be ground into 80～150 orders and two kinds of other oyster shell whitings of level of 200～300 purposes with pulverizer;
(3) oyster shell whiting that step (2) is made is dry under 40～100 ℃ of temperature, to remove the entrained crystal water of oyster shell whiting;
What (4) soap powder, nipagin esters and essence are obtained after the pulverization process separately is not less than 100 purpose meals;
(5) in proportion with oxidized microcrystalline wax, the Sodium dodecylbenzene sulfonate composition mixture 60～90 ℃ of following heated and stirred 20～30 minutes, adds dimethyl silicone oil and deionized water then, 60～90 ℃ of following heated and stirred 20～40 minutes, makes emulsified microcrystalline wax;
(6) in proportion oyster shell whiting is mixed with various raw materials of soap powder, nipagin esters, essence after the pulverization process, after 10～20 minutes, step (5) gained emulsified microcrystalline wax is carried out thermospray 30～60 ℃ of heated and stirred, then under heating condition not, stirring is cooled to normal temperature, gets product.
The present invention utilizes oyster shell whiting to be main raw material, and it is not only friction agent, sorbent material, antiseptic-germicide and stain remover among the present invention, and has softening of water, fractionation by adsorption and ion exchange.Contain mass crystallization inorganics and natural polymer in the shell, inorganics such as lime carbonate and calcium phosphate, natural polymer such as protein and polysaccharide organically couple together big right inorganics by natural polymer.Since the inorganic phase in the shell and the characteristic dimension of organic phase in submicron to nano level, be a kind of natural organic---inorganic hybrid material, guaranteed that shell has very high hardness, has simultaneously good toughness again, it is to being had stronger mechanical friction effect and don't can causing cut by the article of wiping, simultaneously natural organism is to cleaning the effect that thing has increases luminance brightness; Shellfish material has inside and has formed uniform duct, many apertures and the very big advantage of internal surface area, cause oyster shell whiting to have very strong adsorptive power, can adsorb various dusts and dirt expeditiously and have softening of water, fractionation by adsorption and ion exchange; Simultaneously, oyster shell whiting fine size, quality are light, the whiteness sense organ is good, and high stability is convenient to storing; Shell contains abundant natural chitin class binding agent and active substance, totally nontoxic not only, and have good adhesive property and anti-water etch resistant properties; Oyster shell whiting contains chitin itself and possesses anticorrosionly and prevent the microbial attack function, is natural antibacterial bacteriostatic material, can reduce the usage quantity of poisonous antisepsis and sterilization component, does not even use; The advantage of these natural structures just is the natural materials that serves as scrubbing powder or scrubbing powder base-material, can protect vessel to preserve from and strong soil removability.Shell is a kind of natural resource of cheapness, and is inexhaustible.At present, Comprehensive Utilization of Shells is limited in one's ability, and pile up like a mountain by the sea often can to see shell, rots, and when environment is caused very big pollution, also wastes valuable resource.
Shell has adsorbed a certain amount of sodium hydroxide or potassium hydroxide through after the alkali cleaning, and sodium hydroxide or potassium hydroxide are white crystalline powder, the complete and greasy dirt react with of energy, thus having stronger scrubbing effect, it is the stain remover among the present invention.The adding of auxiliary material essence can make product distribute strong aromatic odour stably and lastingly, and it is the perfume agent among the present invention.Major ingredient nipagin esters, toxicity are extremely low, and be non-stimulated to human body, anticorrosion mechanism: para hydroxybenzene acid esters class sanitas is typical growth inhibitor.It suppresses nutritive substance and shifts to bacterial cell.By one of following several means, as permease is quit work, destroy how empty passage, change the pH value gradient of film or the charge voltage of film both sides etc., para hydroxybenzene acid esters class has obviously suppressed the absorption of bacterial cell to nutritive substance.The change of membrane potential can prevent the transfer of enzyme substrate and the generation of ATP.The antibacterial mechanism of nipagin esters: the cytolemma of destroy microorganisms makes intracellular protein denaturation, and can suppress the activity of respiratory enzyme system with the electron transport enzyme system of microorganism cells.The bacteriostatic activity of nipagin esters mainly is that molecular state works, and its intramolecular hydroxyl esterification, and no longer ionization is so it all has good fungistatic effect in the scope of pH 3～8.Nipagin esters is mould inhibitor and the sterilant among the present invention.
Major ingredient soap powder (consisting of fat acid sodium-salt and bubble flower alkali) is the alkalify chemical product with sodium alkyl benzene sulfonate entirely, its pH value is between 9～11, these anion surfactants are the dispersed encapsulated oil droplet in decontamination process, thereby can make grease emulsifying, form emulsion, greasy dirt just is eliminated easily.Sodium soap and sodium alkyl benzene sulfonate in the special soap powder can produce " collaborative decontamination effect ", soap powder can suppress the foaming power of sodium alkyl benzene sulfonate, it is clear excessively to make article-cleaning be easy to rinsing, because the two has used many benefits with, mixes the soil removability that has improved the two mutually.Sodium dodecylbenzene sulfonate and soap powder are stain remover and the lubricants among the present invention.
Oxidized microcrystalline wax be paraffin by oxidation, introduce the product of oxy radical because paraffin mainly is made up of alkane, be the inactive organic compound of a class, do not react at normal temperatures with strong acid, highly basic and strong oxidizer.Many new characteristics have been given to paraffin after the oxidation, widened the paraffin Application Areas, especially but the emulsifying property of paraffin is greatly improved, when making paraffin wax emulsions, can reduce the emulsifying agent consumption greatly, thereby reduce the cost of emulsified olefin, and the emulsion-stabilizing performance has also obtained large increase, oxidized petroleum wax can partly or entirely substitute the field that some expensive carnauba waxs, montanin wax, river wax, beeswax could be used, as leather glazing, automobile glazing, leather shoes glazing, furniture glossing etc.Oxidized microcrystalline wax is emulsifying agent and the lustering agent among the present invention.
Embodiment
Leather type shell scrubbing powder of the present invention is made up of oyster shell whiting, oxidized microcrystalline wax, Sodium dodecylbenzene sulfonate, soap powder, nipagin esters, dimethyl silicone oil, essence and deionized water.Shell is cleaned with clear water earlier, washs with the NaOH or the KOH aqueous solution soaking of 0.1% concentration then, with dirt and the residual slough of removing shell surface; Shell after washing and the alkali cleaning is ground into 80～150 orders and two kinds of other oyster shell whitings of level of 200～300 purposes with pulverizer; Oyster shell whiting after pulverizing is dry under 40～100 ℃ of temperature, to remove the entrained crystal water of oyster shell whiting; Be not less than 100 purpose meals with what soap powder, nipagin esters and essence obtained after the pulverization process separately; In proportion with oxidized microcrystalline wax, the Sodium dodecylbenzene sulfonate composition mixture 60～90 ℃ of following heated and stirred 20～30 minutes, adds dimethyl silicone oil and deionized water then, 60～90 ℃ of following heated and stirred 20～40 minutes, makes emulsified microcrystalline wax; Oyster shell whiting is mixed with various raw materials of soap powder, nipagin esters, essence after the pulverization process, after 10～20 minutes, carries out thermospray, under heating condition not, stir and be cooled to normal temperature then with emulsified microcrystalline wax 30～60 ℃ of heated and stirred, product.
Embodiment 1
1. in proportion with 10g oxidized microcrystalline wax, 2g Sodium dodecylbenzene sulfonate composition mixture 90 ℃ of following heated and stirred 25 minutes, adds 1g dimethyl silicone oil and 11g deionized water then, 70 ℃ of following heated and stirred 20 minutes, makes emulsified microcrystalline wax; 2. take by weighing the low order oyster shell whiting 45g of 85 purposes, the high order oyster shell whiting of 200 purposes 34g, soap powder 4g, Tegosept M 0.2g, essence 3g, Hybrid Heating stirred 15 minutes under 40 ℃ of conditions, step emulsified microcrystalline wax is 1. carried out thermospray, under heating condition not, stir and be cooled to normal temperature then, product.
Embodiment 2
1. in proportion with 25g oxidized microcrystalline wax, 5g Sodium dodecylbenzene sulfonate composition mixture 80 ℃ of following heated and stirred 20 minutes, adds 1.5g dimethyl silicone oil and 30g deionized water then, 80 ℃ of following heated and stirred 30 minutes, makes emulsified microcrystalline wax; 2. take by weighing the low order oyster shell whiting 95g of 90 purposes, the high order oyster shell whiting of 200 purposes 80g, soap powder 13g, ethyl p-hydroxybenzoate 0.8g, essence 7g, Hybrid Heating stirred 30 minutes under 60 ℃ of conditions, step emulsified microcrystalline wax is 1. carried out thermospray, under heating condition not, stir and be cooled to normal temperature then, product.
Embodiment 3
1. in proportion with 42g oxidized microcrystalline wax, 8g Sodium dodecylbenzene sulfonate composition mixture 75 ℃ of following heated and stirred 24 minutes, adds 2g dimethyl silicone oil and 40g deionized water then, 80 ℃ of following heated and stirred 20 minutes, makes emulsified microcrystalline wax; 2. take by weighing the low order oyster shell whiting 140g of 100 purposes, the high order oyster shell whiting of 200 purposes 120g, soap powder 25g, propylben 1.2g, essence 15g, Hybrid Heating stirred 10 minutes under 50 ℃ of conditions, step emulsified microcrystalline wax is 1. carried out thermospray, under heating condition not, stir and be cooled to normal temperature then, product.
Embodiment 4
1. in proportion with 60g oxidized microcrystalline wax, 12g Sodium dodecylbenzene sulfonate composition mixture 65 ℃ of following heated and stirred 30 minutes, adds 4g dimethyl silicone oil and 70g deionized water then, 90 ℃ of following heated and stirred 30 minutes, makes emulsified microcrystalline wax; 2. take by weighing the low order oyster shell whiting 260g of 100 purposes, the high order oyster shell whiting of 210 purposes 220g, soap powder 40g, Tegosept B 2g, essence 20g, Hybrid Heating stirred 15 minutes under 60 ℃ of conditions, step emulsified microcrystalline wax is 1. carried out thermospray, under heating condition not, stir and be cooled to normal temperature then, product.
Embodiment 5
1. in proportion with 10g oxidized microcrystalline wax, 3g Sodium dodecylbenzene sulfonate composition mixture 60 ℃ of following heated and stirred 20 minutes, adds 0.7g dimethyl silicone oil and 10g deionized water then, 80 ℃ of following heated and stirred 20 minutes, makes emulsified microcrystalline wax; 2. take by weighing the low order oyster shell whiting 50g of 110 purposes, the high order oyster shell whiting of 220 purposes 40g, soap powder 5g, Tegosept E monooctyl ester 0.2g, essence 4g, Hybrid Heating stirred 16 minutes under 50 ℃ of conditions, step emulsified microcrystalline wax is 1. carried out thermospray, under heating condition not, stir and be cooled to normal temperature then, product.
Embodiment 6
1. in proportion with 70g oxidized microcrystalline wax, 14g Sodium dodecylbenzene sulfonate composition mixture 85 ℃ of following heated and stirred 25 minutes, adds 4.5g dimethyl silicone oil and 80g deionized water then, 85 ℃ of following heated and stirred 40 minutes, makes emulsified microcrystalline wax; 2. take by weighing the low order oyster shell whiting 210g of 150 purposes, the high order oyster shell whiting of 280 purposes 200g, soap powder 45g, soluble metyl hydroxybenzoate 2.3g, essence 25g, Hybrid Heating stirred 12 minutes under 30 ℃ of conditions, step emulsified microcrystalline wax is 1. carried out thermospray, under heating condition not, stir and be cooled to normal temperature then, product.
Embodiment 7
1. in proportion with 30g oxidized microcrystalline wax, 5g Sodium dodecylbenzene sulfonate composition mixture 81 ℃ of following heated and stirred 27 minutes, adds 1.5g dimethyl silicone oil and 30g deionized water then, 85 ℃ of following heated and stirred 30 minutes, makes emulsified microcrystalline wax; 2. take by weighing the low order oyster shell whiting 130g of 130 purposes, the high order oyster shell whiting of 300 purposes 120g, soap powder 15g, nipagin A sodium 0.5g, essence 8g, Hybrid Heating stirred 40 minutes under 40 ℃ of conditions, step emulsified microcrystalline wax is 1. carried out thermospray, under heating condition not, stir and be cooled to normal temperature then, product.
Embodiment 8
1. in proportion with 140g oxidized microcrystalline wax, 30g Sodium dodecylbenzene sulfonate composition mixture 78 ℃ of following heated and stirred 30 minutes, adds 9g dimethyl silicone oil and 150g deionized water then, 80 ℃ of following heated and stirred 40 minutes, makes emulsified microcrystalline wax; 2. take by weighing the low order oyster shell whiting 450g of 120 purposes, the high order oyster shell whiting of 210 purposes 420g, soap powder 90g, soluble propylhydroxybenzoate 4.5g, essence 48g, Hybrid Heating stirred 30 minutes under 50 ℃ of conditions, step emulsified microcrystalline wax is 1. carried out thermospray, under heating condition not, stir and be cooled to normal temperature then, product.
Embodiment 9
1. in proportion with 75g oxidized microcrystalline wax, 15g Sodium dodecylbenzene sulfonate composition mixture 88 ℃ of following heated and stirred 27 minutes, adds 5g dimethyl silicone oil and 80g deionized water then, 85 ℃ of following heated and stirred 34 minutes, makes emulsified microcrystalline wax; 2. take by weighing the low order oyster shell whiting 220g of 140 purposes, the high order oyster shell whiting of 260 purposes 200g, soap powder 50g, nipabutyl sodium 0.5g, essence 25g, Hybrid Heating stirred 20 minutes under 45 ℃ of conditions, step emulsified microcrystalline wax is 1. carried out thermospray, under heating condition not, stir and be cooled to normal temperature then, product.
Embodiment 10
1. in proportion with 110g oxidized microcrystalline wax, 25g Sodium dodecylbenzene sulfonate composition mixture 77 ℃ of following heated and stirred 28 minutes, adds 5.5g dimethyl silicone oil and 120g deionized water then, 87 ℃ of following heated and stirred 36 minutes, makes emulsified microcrystalline wax; 2. take by weighing the low order oyster shell whiting 250g of 100 purposes, the high order oyster shell whiting of 250 purposes 220g, soap powder 60g, compound sodium nipagin esters 2.5g, essence 30g, Hybrid Heating stirred 22 minutes under 40 ℃ of conditions, step emulsified microcrystalline wax is 1. carried out thermospray, under heating condition not, stir and be cooled to normal temperature then, product.
Claims (4)
1. leather type shell scrubbing powder is characterized in that: be to be made by the raw material of following weight part:
35～45 parts of the low order oyster shell whitings of 80～150 purposes
30～40 parts of the high order oyster shell whitings of 200～300 purposes
1～3 part of 8～15 parts of Sodium dodecylbenzene sulfonate of oxidized microcrystalline wax
0.1～0.5 part of 2～10 parts of nipagin esters of soap powder
10～20 parts of 1～5 part of deionized waters of 0.5～1 part of essence of dimethyl silicone oil;
It is standby that pretreated shell is ground into two kinds of other oyster shell whitings of level of high and low order on request; Oxidized microcrystalline wax and Sodium dodecylbenzene sulfonate composition mixture 60～90 ℃ of following heated and stirred 20～30 minutes, add dimethyl silicone oil and deionized water then, 60～90 ℃ of following heated and stirred 20～40 minutes, make emulsified microcrystalline wax; In proportion oyster shell whiting is mixed with various raw materials of soap powder, nipagin esters, essence after the pulverization process, after 10～20 minutes, emulsified microcrystalline wax is carried out thermospray, under heating condition not, stir and be cooled to normal temperature then 30～60 ℃ of heated and stirred, product.
2. according to the described leather type of claim 1 shell scrubbing powder, it is characterized in that: described nipagin esters comprises one or more in Tegosept M, ethyl p-hydroxybenzoate, propylben, Tegosept B, Tegosept E monooctyl ester and soluble metyl hydroxybenzoate, nipagin A sodium, soluble propylhydroxybenzoate, nipabutyl sodium and the compound sodium nipagin esters.
3. according to the described leather type of claim 1 shell scrubbing powder, it is characterized in that: described soap powder, nipagin esters and essence are to be not less than 100 purpose meals.
4. the preparation method of a leather type shell scrubbing powder, it is characterized in that: this leather type shell scrubbing powder is made up of the raw material of following weight part: 35～45 parts of the low order oyster shell whitings of 80～150 purposes, 30～40 parts of the high order oyster shell whitings of 200～300 purposes, 8～15 parts of oxidized microcrystalline waxs, 1～3 part of Sodium dodecylbenzene sulfonate, 2～10 parts of soap powder, 0.1～0.5 part of nipagin esters, dimethyl silicone oil 0.5～1,1～5 part in essence, 10～20 parts of deionized waters;
The preparation method:
(1) shell is cleaned with clear water earlier, washs with the NaOH or the KOH aqueous solution soaking of 0.1% concentration then, with dirt and the residual slough of removing shell surface;
(2) will wash with alkali cleaning after shell be ground into 80～150 orders and two kinds of other oyster shell whitings of level of 200～300 purposes with pulverizer;
(3) oyster shell whiting that step (2) is made is dry under 40～100 ℃ of temperature, to remove the entrained crystal water of oyster shell whiting;
What (4) soap powder, nipagin esters and essence are obtained after the pulverization process separately is not less than 100 purpose meals;
(5) in proportion with oxidized microcrystalline wax, the Sodium dodecylbenzene sulfonate composition mixture 60～90 ℃ of following heated and stirred 20～30 minutes, adds dimethyl silicone oil and deionized water then, 60～90 ℃ of following heated and stirred 20～40 minutes, makes emulsified microcrystalline wax;
(6) in proportion oyster shell whiting is mixed with various raw materials of soap powder, nipagin esters, essence after the pulverization process, after 10～20 minutes, step (5) gained emulsified microcrystalline wax is carried out thermospray 30～60 ℃ of heated and stirred, then under heating condition not, stirring is cooled to normal temperature, gets product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010295198 CN101955865B (en) | 2010-09-28 | 2010-09-28 | Shell cleanser for leather and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010295198 CN101955865B (en) | 2010-09-28 | 2010-09-28 | Shell cleanser for leather and preparation method thereof |
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| Publication Number | Publication Date |
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| CN101955865A true CN101955865A (en) | 2011-01-26 |
| CN101955865B CN101955865B (en) | 2013-03-27 |
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| CN 201010295198 Expired - Fee Related CN101955865B (en) | 2010-09-28 | 2010-09-28 | Shell cleanser for leather and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107828341A (en) * | 2017-11-17 | 2018-03-23 | 枣庄市博源人造石有限公司 | A kind of antimicrobial form artificial stone polishing fluid and preparation method thereof |
| CN108587822A (en) * | 2018-04-18 | 2018-09-28 | 佛山慧创正元新材料科技有限公司 | A kind of aerial fog type leather and fur products decontamination brightener |
| CN111849360A (en) * | 2020-05-25 | 2020-10-30 | 中山市西美高汽车护理用品有限公司 | Cleaning vehicle wax spray and preparation method thereof |
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| CN1475520A (en) * | 2002-08-15 | 2004-02-18 | 孙建宁 | Shell micro powder filler and its use |
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| KR100572559B1 (en) * | 2003-04-01 | 2006-04-24 | 박남종 | soap production for oyster shells and aluminum oxide |
| KR100889390B1 (en) * | 2008-03-10 | 2009-03-19 | 우희경 | A process for preparing black soap containing black soybean powder |
| CN101831364A (en) * | 2010-05-07 | 2010-09-15 | 广东工业大学 | Sterilized mildew-proof cleaning powder of natural shell powder and preparation method thereof |
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2010
- 2010-09-28 CN CN 201010295198 patent/CN101955865B/en not_active Expired - Fee Related
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1475520A (en) * | 2002-08-15 | 2004-02-18 | 孙建宁 | Shell micro powder filler and its use |
| KR100572559B1 (en) * | 2003-04-01 | 2006-04-24 | 박남종 | soap production for oyster shells and aluminum oxide |
| CN1613990A (en) * | 2003-11-03 | 2005-05-11 | 张国强 | Process and formula of soap cream for removing oily dirt |
| KR20050110733A (en) * | 2004-05-19 | 2005-11-23 | 김연이 | Removing material for bond- traces of advertising matter |
| KR100889390B1 (en) * | 2008-03-10 | 2009-03-19 | 우희경 | A process for preparing black soap containing black soybean powder |
| CN101831364A (en) * | 2010-05-07 | 2010-09-15 | 广东工业大学 | Sterilized mildew-proof cleaning powder of natural shell powder and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107828341A (en) * | 2017-11-17 | 2018-03-23 | 枣庄市博源人造石有限公司 | A kind of antimicrobial form artificial stone polishing fluid and preparation method thereof |
| CN108587822A (en) * | 2018-04-18 | 2018-09-28 | 佛山慧创正元新材料科技有限公司 | A kind of aerial fog type leather and fur products decontamination brightener |
| CN111849360A (en) * | 2020-05-25 | 2020-10-30 | 中山市西美高汽车护理用品有限公司 | Cleaning vehicle wax spray and preparation method thereof |
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| Publication number | Publication date |
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| CN101955865B (en) | 2013-03-27 |
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