CN101935486B - PVC (polyvinyl chloride) artificial leather pigment color paste - Google Patents
PVC (polyvinyl chloride) artificial leather pigment color paste Download PDFInfo
- Publication number
- CN101935486B CN101935486B CN200910032641A CN200910032641A CN101935486B CN 101935486 B CN101935486 B CN 101935486B CN 200910032641 A CN200910032641 A CN 200910032641A CN 200910032641 A CN200910032641 A CN 200910032641A CN 101935486 B CN101935486 B CN 101935486B
- Authority
- CN
- China
- Prior art keywords
- pigment
- resin
- resin liquid
- calcium carbonate
- liquid component
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000049 pigment Substances 0.000 title claims abstract description 38
- 229920000915 polyvinyl chloride Polymers 0.000 title claims description 23
- 239000004800 polyvinyl chloride Substances 0.000 title claims description 23
- 239000002649 leather substitute Substances 0.000 title abstract 2
- 229920005989 resin Polymers 0.000 claims abstract description 30
- 239000011347 resin Substances 0.000 claims abstract description 30
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 26
- 239000007788 liquid Substances 0.000 claims abstract description 18
- 239000000843 powder Substances 0.000 claims abstract description 14
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 13
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims abstract description 10
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 claims abstract description 8
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 claims abstract description 8
- 238000003756 stirring Methods 0.000 claims abstract description 4
- 239000002904 solvent Substances 0.000 claims abstract description 3
- 239000000080 wetting agent Substances 0.000 claims abstract description 3
- 229960004418 trolamine Drugs 0.000 claims description 9
- 239000006229 carbon black Substances 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 4
- 229920002803 thermoplastic polyurethane Polymers 0.000 claims description 4
- 239000001038 titanium pigment Substances 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 239000006185 dispersion Substances 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 239000012463 white pigment Substances 0.000 claims description 3
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 2
- 239000000975 dye Substances 0.000 claims description 2
- 238000010008 shearing Methods 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims description 2
- 239000001055 blue pigment Substances 0.000 claims 1
- 239000002270 dispersing agent Substances 0.000 abstract 2
- 229920005749 polyurethane resin Polymers 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 239000002994 raw material Substances 0.000 abstract 1
- 230000008676 import Effects 0.000 description 4
- 238000000034 method Methods 0.000 description 3
- 239000003086 colorant Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 210000002345 respiratory system Anatomy 0.000 description 1
- 235000013599 spices Nutrition 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
- Coloring (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
The invention relates to a PVC artificial leather pigment color paste. Cyclohexanone is adopted as a main solvent and PVC resin powder is adopted as structural resin, and polyurethane resin is utilized to improve a shear force to improve the grinding performance; dibutyl phthalate is used as a wetting agent to be prepared into the component of resin liquid in proportion; triethanolamine is used as a dispersing agent, light calcium carbonate is used as filling, and a red, yellow, blue, black and white organic raw material is used as developing pigment. When in preparation, one of the filling and the pigment is fused into the component of the resin liquid; the dispersing agent is added; grind is carried out by a three-roller grinder after sufficient stirring, and the fineness is between 3-5 microns.
Description
Technical field
The present invention relates to a kind of SE is the PVC dispersible pigment color paste, specifically refers to the painted mill base when being used for the PVC leatheroid makes.
Background technology
The PVC leatheroid is the every aspect that artificial polyvinyl chloride leather has been widely applied to people's life.Yet aspect painted, still continue to use the promptly direct pigment powder that adds of traditional method, its drawback has two: at first dry powder attitude pigment is prone to drift and is sucked contaminate environment and unhealthful by the human respiratory tract when spice; Secondly, common pigments is mostly at 400 orders, and promptly particle diameter is about 38 microns, and the pigment usage quantity of equal effect is 1000 ~ 1200 orders, 10 ~ 13 microns import pigment of particle diameter about 10 times, and the price of import pigment is again 20 ~ 25 times of common pigments.Because the generation visitor color matching service of import pigment has watered down expensive shade.
Summary of the invention
The present invention discloses a kind of sole pigment mill base of PVC leatheroid, the accurate nanometer fineness of semi liquid state paste, and the benchmark color base is independent separately, promptly possesses the advantage that the import amount of pigment is few, the generation visitor matches colors, and possesses the cost advantage of common pigments again.
It is main solvent that the present invention adopts pimelinketone, and the polyvinyl chloride resin powder is a structural resin, improves nonferromagnetic substance with the resin component raising shearing force of urethane, and Witcizer 300 is made wetting agent, is mixed with the resin liquid component in proportion; Trolamine is a dispersion agent, and light calcium carbonate is a stopping composition, and red, yellow, blue, black, white pigment dyestuff is colour developing pigment.With a kind of resin liquid component that is blended in of stopping composition and pigment, add dispersion agent during making, after fully stirring, grind with three-roll grinder, fineness should be between 3 ~ 5 microns.
The invention has the beneficial effects as follows: keep the cost advantage of common pigments, overcome that the common pigments consumption is big, powder pollutes, can't be for the drawback of visitor's color matching.
Embodiment:
By weight percentage, pimelinketone 50%, polyvinyl chloride resin powder 5%; Urethane resin 30%, Witcizer 300 15%, water-bath is heated and earlier the polyvinyl chloride resin powder is dissolved in pimelinketone; The back urethane resin that dissolves adds Witcizer 300 at last and fully stirs afterwards subsequent use for the resin liquid component.
Get resin liquid component 54%, white titanium pigment 35%, light calcium carbonate 10%; Trolamine 1% under the situation of agitating resin component, adds light calcium carbonate behind the adding white titanium pigment again; Add trolamine Deng the whole moistening backs of solid powder, restir promptly is available on the machine approximately and grinds to form white colorant half a hour;
Get resin liquid component 59%, carbon black 20%, light calcium carbonate 20%, trolamine 1% are processed into black color paste with method;
Get resin liquid component 54%, Pigment blue 25%, light calcium carbonate 20%, trolamine 1% is processed into blue mill base with method;
The adding Pigment red is red mill base, and adding Pigment Yellow 73 is yellow mill base, and prescription is with together blue.
When last three-roll grinder ground, roll spacing needed descending by all over tightening, and carbon black especially is difficult for moisteningly, grinds with 1 millimeter roll spacing first pass and to make it fully moistening, and second time slightly tightly roll spacing is promptly normal basically.All over after grinding, scrape to such an extent that get final product between 3 ~ 5 microns of the fineness values through some with the fineness plate.
Claims (2)
1. PVC leatheroid dispersible pigment color paste; It is characterized in that: the employing pimelinketone is a main solvent, and the polyvinyl chloride resin powder is a structural resin, improves nonferromagnetic substance with the resin component raising shearing force of urethane; Witcizer 300 is made wetting agent, is mixed with the resin liquid component in proportion; Trolamine is a dispersion agent, and light calcium carbonate is a stopping composition, and red, yellow, blue, black, white pigment dyestuff is colour developing pigment.
2. resin liquid is characterized in that: by weight percentage, and pimelinketone 50%; Polyvinyl chloride resin powder 5%; Urethane resin 30%, Witcizer 300 15%, water-bath is heated and earlier the polyvinyl chloride resin powder is dissolved in pimelinketone; Urethane resin is dissolved in the back, adds at last to be the resin liquid component after Witcizer 300 fully stirs.
3, a kind of PVC leatheroid dispersible pigment color paste is characterized in that: resin liquid component 54% as claimed in claim 2, white titanium pigment 35%; Light calcium carbonate 10%; Trolamine 1% under the situation of agitating resin liquid component, adds light calcium carbonate behind the adding white titanium pigment again; Add trolamines Deng the whole moistening backs of solid powder, restir promptly is available on the machine and is ground to become between 3 ~ 5 microns PVC leatheroid white pigment mill base half a hour.
4, a kind of PVC leatheroid dispersible pigment color paste is characterized in that: resin liquid component 59% as claimed in claim 2, carbon black 20%; Light calcium carbonate 20%; Trolamine 1% under the situation of agitating resin liquid component, adds light calcium carbonate behind the adding carbon black again; Add trolamines Deng the whole moistening backs of solid powder, restir promptly is available on the machine and is ground to become between 3 ~ 5 microns PVC leatheroid black pigment mill base half a hour.
5, a kind of PVC leatheroid dispersible pigment color paste is characterized in that: resin liquid component 54% as claimed in claim 2, Pigment blue 25%; Light calcium carbonate 20%; Trolamine 1% under the situation of agitating resin liquid component, adds light calcium carbonate behind the adding Pigment blue again; Add trolamines Deng the whole moistening backs of solid powder, restir promptly is available on the machine and is ground to become between 3 ~ 5 microns PVC leatheroid blue pigments mill base half a hour.
6, PVC leatheroid dispersible pigment color paste according to claim 5 is characterized in that: replace Pigment blue with Pigment red.
7, PVC leatheroid dispersible pigment color paste according to claim 5 is characterized in that: replace Pigment blue with Pigment Yellow 73.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910032641A CN101935486B (en) | 2009-06-30 | 2009-06-30 | PVC (polyvinyl chloride) artificial leather pigment color paste |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910032641A CN101935486B (en) | 2009-06-30 | 2009-06-30 | PVC (polyvinyl chloride) artificial leather pigment color paste |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101935486A CN101935486A (en) | 2011-01-05 |
| CN101935486B true CN101935486B (en) | 2012-10-03 |
Family
ID=43389065
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200910032641A Expired - Fee Related CN101935486B (en) | 2009-06-30 | 2009-06-30 | PVC (polyvinyl chloride) artificial leather pigment color paste |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101935486B (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102146220B (en) * | 2011-05-04 | 2013-03-20 | 贝内克一长顺汽车内饰材料（张家港）有限公司 | Method for preparing titanium white pigment paste for automobile interior trim leather |
| CN103483924B (en) * | 2013-10-15 | 2014-11-05 | 福建宝利特新材料科技有限公司 | Environment-friendly polyvinyl chloride (PVC) anti-flooding color paste for artificial leather and preparation method thereof |
| CN104356766B (en) * | 2014-12-01 | 2016-05-04 | 苏州冰心文化用品有限公司 | A kind of mill base material for polyvinyl chloride and preparation method thereof |
| CN107400415A (en) * | 2016-05-18 | 2017-11-28 | 东莞市集丰塑化材料有限公司 | Lucite pigment preparations cream |
| EP3910106A4 (en) * | 2020-03-30 | 2022-02-09 | Canadian General-Tower (Changshu) Co., Ltd | Light-transmitting artificial leather, preparation method therefor, and automobile interior |
| CN111455683A (en) * | 2020-04-08 | 2020-07-28 | 桐乡市迪诺纺织股份有限公司 | Coating manufacturing method |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1229819A (en) * | 1999-01-27 | 1999-09-29 | 吴厚钰 | Method of using wasted plastic for preparing leather colorant |
| CN1878835A (en) * | 2005-02-11 | 2006-12-13 | 德古萨公司 | Aqueous compositions |
-
2009
- 2009-06-30 CN CN200910032641A patent/CN101935486B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1229819A (en) * | 1999-01-27 | 1999-09-29 | 吴厚钰 | Method of using wasted plastic for preparing leather colorant |
| CN1878835A (en) * | 2005-02-11 | 2006-12-13 | 德古萨公司 | Aqueous compositions |
Non-Patent Citations (2)
| Title |
|---|
| 张云云.用于PU合成革的碱性碳黑分散剂的合成与分析.《杭州师范学院学报(自然科学版)》.2007,第6卷(第5期), * |
| 许大生等.合成革用黑色浆制备工艺改进探讨.《聚氨酯工业》.1998,第13卷(第4期), * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101935486A (en) | 2011-01-05 |
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| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C53 | Correction of patent for invention or patent application | ||
| CB02 | Change of applicant information |
Address after: 362216, Fujian, Quanzhou, Jinjiang province Xintang Street apricot community sun District No. 79 Applicant after: Wang Wenting Address before: Jianye District of Nanjing City, Jiangsu province 210029 4 Building No. 12 Nanyuan Qu Yuan Village Applicant before: Wang Wenting |
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| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| ASS | Succession or assignment of patent right |
Owner name: NANTONG ZHONG'AO VEHICLES NEW MATERIALS CO., LTD. Free format text: FORMER OWNER: WANG WENTING Effective date: 20141030 |
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| C41 | Transfer of patent application or patent right or utility model | ||
| COR | Change of bibliographic data |
Free format text: CORRECT: ADDRESS; FROM: 362216 QUANZHOU, FUJIAN PROVINCE TO: 226352 NANTONG, JIANGSU PROVINCE |
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| TR01 | Transfer of patent right |
Effective date of registration: 20141030 Address after: Tongzhou District four stone river highway 226352 in Jiangsu city of Nantong province No. 168 Patentee after: Nantong Zhong'ao Vehicles New Materials Co., Ltd. Address before: 362216, Fujian, Quanzhou, Jinjiang province Xintang Street apricot community sun District No. 79 Patentee before: Wang Wenting |
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| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20121003 Termination date: 20180630 |
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| CF01 | Termination of patent right due to non-payment of annual fee |