CN101919450A - Corn oil containing medium chain fatty acid ester and preparation method thereof - Google Patents
Corn oil containing medium chain fatty acid ester and preparation method thereof Download PDFInfo
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Abstract
The invention belongs to the technical field of the preparation of corn oil, in particular to the corn oil containing a medium chain fatty acid ester and a preparation method thereof. The weight percentage of the medium chain fatty acid ester in the corn oil containing the medium chain fatty acid ester is between 25 and 40 percent. In the corn oil containing the medium chain fatty acid ester obtained by ester exchange technology, medium chain fatty acid is successfully combined with long-chain fatty acid, so that a product has a health-care function of reducing the accumulation of fat and has the characteristic of usability for cooking delicious food like ordinary edible oil.
Description
Technical field
The invention belongs to the technical field of corn oil preparation, be specially a kind of corn oil that contains medium chain fatty acid ester and preparation method thereof.
Background technology
Vegetable oil and animal oil all are the triglyceride fatty compounds.So-called triglycerides is made up of the aliphatic acid of the glycerine of a molecule and three molecules.According to the quantity of carbon atom in the fatty acid molecule, triglycerides can be divided into three types of LCT, medium chain triglyceride and SCTs.
LCT is to be combined with glycerine by the aliphatic acid that contains 12 above carbon atoms to generate.In edible oil, the composition more than 95% is made up of LCT, and the fat that stores in the human body mainly is LCT.
Medium chain triglyceride is that the aliphatic acid that contains 6～12 carbon atoms combines generation with glycerine.Medium chain triglyceride has following three big characteristics:
1. digestion rate (also being hydrolysis rate) is fast.
Triglycerides mainly is in small intestine, through the bile acid effect, is emulsified into tiny colloid droplet; Under the effect of pancreatic lipase, be hydrolyzed into the aliphatic acid of two molecules and the monoglyceride of a molecule again, absorbed by intestinal epithelial cell afterwards.
Because the hydrophily of medium chain triglyceride is more intense, the emulsifying colloid droplet of formation is littler, needed emulsifying agent (being bile acid) still less, therefore easier generation hydrolysis.In other words, the digestion rate of medium chain triglyceride is faster than LCT.
2. infiltration rate is fast.
Medium chain fatty acid only needs a few minutes just can directly absorb from intestinal epithelial cell, enters blood circulation by vena portae hepatica again.And LCFA will be combined into triglycerides with glycerine again in intestinal epithelial cell, forms chylomicron with apolipoprotein, phosphatide and cholesterol again, then could enter blood circulation through lymphatic system, needs just can finish in 3～4 hours.Therefore medium chain triglyceride is faster than the LCT absorption, is a kind of nutrient that energy can be provided fast.
3. easier to be oxidized in catabolism.
In liver and musculature, the decomposition of fatty acids metabolism is to carry out in the mitochondria of cell.Different with LCFA, medium chain fatty acid does not rely on the delivery of L-meat alkali shuttle system just can enter mitochondria, in other words, their catabolism is not subjected to the restriction of L-meat alkali shuttle system, consequently medium chain fatty acid is than the easier generation oxidation of LCFA, can provide heat energy at any time and is difficult for being stored.In addition, because the chain of medium chain fatty acid is shorter, before not taking place to prolong the metabolic response of carbochain, they can not be used as the structural material of adipocyte.
The effect of MCT Oil:
1, eats the favourable fat-reducing of medium chain triglyceride
Japan a comparative study show, every day heat be in 2200 kilocalories the food, be respectively two groups of experimenters add 10 the gram medium chain triglycerides and 10 the gram LCTs.After 8 weeks, edible medium chain triglyceride group people's body fat and subcutaneous fat begin obvious minimizing; After 12 weeks, with the physiognomy ratio of edible LCT group, preceding group of people's body weight, waistline and waistline hip circumference are than all obviously reducing; But less than 23 people, significant difference does not appear in most measurement results of two groups of people for body-mass index.
Another research approach of Japan is the fat ratio that increases in experimenter's food, takes in the food of 2500 kilocalories of heats in every day, about 1000 kilocalories of heats is arranged from fat.
Comparative study shows, physiognomy ratio with edible LCT group, the amount of oxidation of edible medium chain triglyceride group people's energy consumption and fat increases, and does not find medium chain fatty acid in their red blood cell, and this shows that medium chain fatty acid does not have summation in human body.
In addition, contain the high food of medium chain triglyceride and all highlight calorigenic action.Calendar year 2001, there is the researcher to carry out the research in 4 weeks by a definite date.In a fortnight, the Ms's of edible medium chain triglyceride group hunger is weak, and satiety is strong.Because compare with having the food that same heat contains LCT, the food that contains medium chain triglyceride has increased the speed of heating after digestion.Adhere to using the edible oil cooking that contains medium chain fatty acid ester, and cooperate rational meals and an amount of motion, overweight, obese people's group energy have been played the health care of fat-reducing, to people with hyperlipidemia, can play the control body weight, reduce triglycerides and improve the effect of apolipoprotein metabolism.Therefore, the edible oil that contains medium chain fatty acid ester is a prevention and effective healthy food of controlling fat chronic diseases.
2, eat medium chain triglyceride and can improve endurance
Medium chain triglyceride to the influence of exercise performance also clearly.Fat and carbohydrate are two main energy sources that energy is provided for motion.Glycogen in blood sugar and the muscle comes self-carbon water compound.When the glycogen in the muscle was low, it is tired that the people will feel.For avoiding consuming the glycogen in the muscle, ediblely contain the food that medium chain triglyceride combines with carbohydrate and can improve the endurance of moving.For example, allowing the sportsman eat at training period contains the food that a large amount of medium chain triglycerides combine with carbohydrate their endurance is increased.
General edible oil is mostly based on LCFA, if too much will becoming body fat, picked-up piles up, and employed medium chain fatty acid on the clinical nutrition, its metabolic pathway is to send to liver fast via vena portae hepatica to resolve into heat, can not pile up in vivo, but the medium chain fatty acid smoke point is low, is unsuitable for culinary art, only is suitable for modulating dish.
At present, in oil with common edible, the content of medium chain fatty acid ester is very low, mostly be long-chain fatty acid ester, and the medium chain fatty acid ester in the corn oil only accounts for about 0.3% of TFA ester content, and this also is limited by the aliphatic acid composition of grease contained in the raw materials for production maize germ of corn oil own.
Summary of the invention
The objective of the invention is to, provide a kind of corn oil that contains medium chain fatty acid ester and preparation method thereof at the problems referred to above.The present invention adopts ester-exchange technology, the corn oil that contains medium chain fatty acid ester that obtains, successfully medium chain fatty acid and LCFA are combined, make the healthy functions of the existing minimizing fat of product accumulation, have the same characteristics of cooking out delicious food again with oil with common edible.
The corn oil that contains medium chain fatty acid ester of the present invention is characterized in that, the weight percentage of medium chain fatty acid ester is 25-40% in this corn oil.
The preparation method who contains the corn oil of medium chain fatty acid ester of the present invention, at first refined maize oil is carried out enzymatic hydrolysis, hydrolysate adopts molecular clock that LCFA is separated, add medium chain fatty acid again in the mixture after separation and carry out esterification, esterification finishes to obtain thick medium chain fatty acid ester corn oil, carry out molecular clock at last again, obtain the corn oil that contains medium chain fatty acid ester of the present invention.
Its detailed process step is:
A, corn oil enzymatic hydrolysis step:
Refined maize oil is sent in the reactor I, the water that adds 10%-15% corn oil weight then, add 20 U/g-50 U/g fat hydrolases (is benchmark with corn oil) again, in temperature is under 40 ℃ of-60 ℃ of conditions, reaction 6-10h, hydrolysate is LCFA, long-chain fat acid glyceride and glycerine;
B, molecular clock step:
Hydrolysate in the reactor I is carried out molecular clock by molecular still, degassing still pressure is 0.1-0.5kPa, and distillation pressure is 6.0-7.5Pa, and the distillation inlet amount is 1000-1200g/h, isolate LCFA, obtain the mixture of long-chain fat acid glyceride and glycerine;
C, esterif iotacation step:
The mixture that above-mentioned steps obtains is sent in the reactor II, added medium chain fatty acid then and carry out esterification, get thick medium chain fatty acid ester corn oil after esterification finishes;
D, molecular clock step:
The above-mentioned thick medium chain fatty acid ester corn oil that obtains is carried out molecular clock, degassing still pressure 0.05-0.45kPa, molecular clock pressure 5.5-7.0Pa, distillation inlet amount 1000-1200g/h, remove wherein nonesterified medium chain fatty acid, obtain the medium chain fatty acid ester corn oil that contains of the present invention.
Wherein, adopt phosphotungstic acid as catalyst in the described c step, catalyst consumption is the 1-5% of mixture quality; The temperature of reaction system is initial temperature 130-140 ℃, warm 160-180 ℃ eventually, and residual voltage 5-10kPa, the reaction time is 1-2.5h; The mol ratio of medium chain fatty acid and glycerine is (2.8-3.5): 1.
Medium chain fatty acid among the present invention is sad or/and capric acid, is preferably sad and mixture capric acid, and both can adjust as required usage ratio relation, is preferably sad and mol ratio capric acid is 1:1.
Beneficial effect of the present invention is: the present invention adopts new preparation technology, by hydrolysis, molecular clock, concrete operations such as esterification, and employing rational catalyst, a whole set of technologies such as equipment and technological parameter and material consumption, successfully medium chain fatty acid and LCFA are combined, obtain a kind of corn oil new product, the medium chain fatty acid ester that wherein contains high level, make the healthy functions of the existing minimizing fat of product accumulation, have the same characteristics that modulate delicious food again with oil with common edible, to promoting the human body tachymetabolism, quickly supplementing energy has positive meaning.
In addition, medium chain fatty acid ester has the character that can dissolve in a large number high-melting-point compounds such as cholesterine, and distinctive antibiotic property and facilitation that rectum is absorbed, therefore in the application aspect hospital's product broad application prospect is arranged.
The specific embodiment
Below in conjunction with specific embodiment technical scheme of the present invention is described in detail.
Embodiment 1
A, corn oil enzymatic hydrolysis step:
Refined maize oil is sent in the reactor I, the water that adds 10% corn oil weight then adds 20 U/g fat hydrolases (is benchmark with corn oil) again, is under 40 ℃ of conditions in temperature, reaction 10h, hydrolysate is LCFA, long-chain fat acid glyceride and glycerine;
B, molecular clock step:
Hydrolysate in the reactor I is carried out molecular clock by molecular still, and degassing still pressure is 0.1kPa, and distillation pressure is 6.0Pa, and the distillation inlet amount is 1000g/h, isolates LCFA, obtains the mixture of long-chain fat acid glyceride and glycerine;
C, esterif iotacation step:
The mixture that above-mentioned steps obtains is sent in the reactor II, adopted phosphotungstic acid as catalyst, catalyst consumption is 1% of a mixture quality; Add the sad esterification of carrying out then, sad and mol ratio glycerine is 2.8:1; The temperature of reaction system is 130 ℃ of initial temperature, and temperature is 160 ℃ eventually, residual voltage 5kPa, and the reaction time is 1h, gets thick medium chain fatty acid ester corn oil after esterification finishes;
D, molecular clock step:
The above-mentioned thick medium chain fatty acid ester corn oil that obtains is carried out molecular clock, degassing still pressure 0.05kPa, molecular clock pressure 5.5Pa, distillation inlet amount 1000g/h, remove wherein nonesterified medium chain fatty acid, obtain the medium chain fatty acid ester corn oil that contains of the present invention.
This technology obtains contains medium chain fatty acid ester corn oil, and the weight percentage of its medium chain fatty acid ester is 26%.
Embodiment 2
A, corn oil enzymatic hydrolysis step:
Refined maize oil is sent in the reactor I, the water that adds 15% corn oil weight then adds 50 U/g fat hydrolases (is benchmark with corn oil) again, is under 60 ℃ of conditions in temperature, reaction 6h, hydrolysate is LCFA, long-chain fat acid glyceride and glycerine;
B, molecular clock step:
Hydrolysate in the reactor I is carried out molecular clock by molecular still, and degassing still pressure is 0.5kPa, and distillation pressure is 7.5Pa, and the distillation inlet amount is 1200g/h, isolates LCFA, obtains the mixture of long-chain fat acid glyceride and glycerine;
C, esterif iotacation step:
The mixture that above-mentioned steps obtains is sent in the reactor II, adopted phosphotungstic acid as catalyst, catalyst consumption is 5% of a mixture quality; Add capric acid then and carry out esterification, the mol ratio of capric acid and glycerine is 3.5:1; The temperature of reaction system is 140 ℃ of initial temperature, and temperature is 180 ℃ eventually, residual voltage 10kPa, and the reaction time is 2.5h, gets thick medium chain fatty acid ester corn oil after esterification finishes;
D, molecular clock step:
The above-mentioned thick medium chain fatty acid ester corn oil that obtains is carried out molecular clock, degassing still pressure 0.45kPa, molecular clock pressure 7.0Pa, distillation inlet amount 1200g/h, remove wherein nonesterified medium chain fatty acid, obtain the medium chain fatty acid ester corn oil that contains of the present invention.
This technology obtains contains medium chain fatty acid ester corn oil, and the weight percentage of its medium chain fatty acid ester is 37%.
Embodiment 3
A, corn oil enzymatic hydrolysis step:
Refined maize oil is sent in the reactor I, the water that adds 13% corn oil weight then adds 30 U/g fat hydrolases (is benchmark with corn oil) again, is under 50 ℃ of conditions in temperature, reaction 8h, hydrolysate is LCFA, long-chain fat acid glyceride and glycerine;
B, molecular clock step:
Hydrolysate in the reactor I is carried out molecular clock by molecular still, and degassing still pressure is 0.4kPa, and distillation pressure is 7.07Pa, and the distillation inlet amount is 1100g/h, isolates LCFA, obtains the mixture of long-chain fat acid glyceride and glycerine;
C, esterif iotacation step:
The mixture that above-mentioned steps obtains is sent in the reactor II, adopted phosphotungstic acid as catalyst, catalyst consumption is 3% of a mixture quality; Add sad and capric acid then and carry out esterification, this mol ratio sad and capric acid and glycerine is 3.0:1; The temperature of reaction system is 135 ℃ of initial temperature, and temperature is 170 ℃ eventually, residual voltage 8kPa, and the reaction time is 2.0h, gets thick medium chain fatty acid ester corn oil after esterification finishes;
D, molecular clock step:
The above-mentioned thick medium chain fatty acid ester corn oil that obtains is carried out molecular clock, degassing still pressure 0.40kPa, molecular clock pressure 6.0Pa, distillation inlet amount 1100g/h, remove wherein nonesterified medium chain fatty acid, obtain the medium chain fatty acid ester corn oil that contains of the present invention.
This technology obtains contains medium chain fatty acid ester corn oil, and the weight percentage of its medium chain fatty acid ester is 31%.
Claims (8)
1. a corn oil that contains medium chain fatty acid ester is characterized in that, the weight percentage of medium chain fatty acid ester is 25-40% in this corn oil.
2. the preparation method who contains the corn oil of medium chain fatty acid ester as claimed in claim 1, at first refined maize oil is carried out enzymatic hydrolysis, hydrolysate adopts molecular clock that LCFA is separated, add medium chain fatty acid again in the mixture after separation and carry out esterification, esterification finishes to obtain thick medium chain fatty acid ester corn oil, carry out molecular clock at last again, obtain the corn oil that contains medium chain fatty acid ester of the present invention.
3. the preparation method who contains the corn oil of medium chain fatty acid ester as claimed in claim 2, its detailed process step is:
A, corn oil enzymatic hydrolysis step:
Refined maize oil is sent in the reactor I, the water that adds 10%-15% corn oil weight then, add 20 U/g-50 U/g fat hydrolases (is benchmark with corn oil) again, in temperature is under 40 ℃ of-60 ℃ of conditions, reaction 6-10h, hydrolysate is LCFA, long-chain fat acid glyceride and glycerine;
B, molecular clock step:
Hydrolysate in the reactor I is carried out molecular clock by molecular still, degassing still pressure is 0.1-0.5kPa, and distillation pressure is 6.0-7.5Pa, and the distillation inlet amount is 1000-1200g/h, isolate LCFA, obtain the mixture of long-chain fat acid glyceride and glycerine;
C, esterif iotacation step:
The mixture that above-mentioned steps obtains is sent in the reactor II, added medium chain fatty acid then and carry out esterification, get thick medium chain fatty acid ester corn oil after esterification finishes;
D, molecular clock step:
The above-mentioned thick medium chain fatty acid ester corn oil that obtains is carried out molecular clock, degassing still pressure 0.05-0.45kPa, molecular clock pressure 5.5-7.0Pa, distillation inlet amount 1000-1200g/h, remove wherein nonesterified medium chain fatty acid, obtain the medium chain fatty acid ester corn oil that contains of the present invention.
4. preparation method as claimed in claim 3 is characterized in that, adopts phosphotungstic acid as catalyst in the described c step, and catalyst consumption is the 1-5% of mixture quality.
5. preparation method as claimed in claim 3 is characterized in that, the temperature of reaction system is initial temperature 130-140 ℃ in the described c step, warm 160-180 ℃ eventually, and residual voltage 5-10kPa, the reaction time is 1-2.5h.
6. preparation method as claimed in claim 3 is characterized in that, the mol ratio of medium chain fatty acid and glycerine is (2.8-3.5) in the described c step: 1.
7. as claim 2 or 3 or 6 described preparation methods, it is characterized in that described medium chain fatty acid is sad or/and capric acid.
8. preparation method as claimed in claim 7 is characterized in that, when described medium chain fatty acid was sad and capric acid mixture, its sad and mol ratio capric acid was 1:1.
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103891920A (en) * | 2012-12-25 | 2014-07-02 | 中粮营养健康研究院有限公司 | Grease composition containing medium and long carbon chain triglycerides, and preparation method thereof |
| CN104522188A (en) * | 2015-01-07 | 2015-04-22 | 广州倚德生物科技有限公司 | Powdered oil rich in medium and low carbonic acid and preparation method thereof |
| CN104642570A (en) * | 2015-03-11 | 2015-05-27 | 重庆第二师范学院 | Modification preparation method of maize germ oil |
| CN105104583A (en) * | 2015-09-22 | 2015-12-02 | 河南工业大学 | Preparation method of medium-long-chain fatty acid grease |
| CN107205419A (en) * | 2015-01-26 | 2017-09-26 | 日清奥利友集团株式会社 | grease |
| CN109645424A (en) * | 2019-01-04 | 2019-04-19 | 颐海（上海）食品有限公司 | A kind of chafing dish bottom flavorings and preparation method thereof containing medium chain triglyceride |
| CN111423935A (en) * | 2020-04-22 | 2020-07-17 | 郑州市美宴食品有限公司 | Preparation method of sesame oil rich in medium-chain fatty acids, tocopherols and phytosterol |
| CN115151628A (en) * | 2020-02-28 | 2022-10-04 | 株式会社钟化 | Process for producing long-chain fatty acid and use thereof |
| CN115226780A (en) * | 2022-07-22 | 2022-10-25 | 广州福汇食品科技有限公司 | Light edible oil for losing weight and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1454251A (en) * | 2000-08-22 | 2003-11-05 | 日清奥利友株式会社 | Fat compositions |
-
2010
- 2010-06-04 CN CN 201010191714 patent/CN101919450B/en active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1454251A (en) * | 2000-08-22 | 2003-11-05 | 日清奥利友株式会社 | Fat compositions |
Non-Patent Citations (3)
| Title |
|---|
| 《中国优秀博硕士学位论文全文数据库（硕士）工程科技I辑》 20050315 余春涛 中碳链甘三酯合成与纯化的研究 第B018-40页 2-8 , 第1期 2 * |
| 《现代商贸工业》 20031231 吴道银等 结构脂质及其制备方法 44-46 1-8 , 第9期 2 * |
| 《生物技术》 19921231 陈清馥等 酶法水解油脂生产脂肪酸的研究 42-44 1-8 第2卷, 第1期 2 * |
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| CN103891920B (en) * | 2012-12-25 | 2015-09-30 | 中粮营养健康研究院有限公司 | A kind of fat or oil composition containing middle Long carbon chain triglycerides and preparation method thereof |
| CN103891920A (en) * | 2012-12-25 | 2014-07-02 | 中粮营养健康研究院有限公司 | Grease composition containing medium and long carbon chain triglycerides, and preparation method thereof |
| CN104522188A (en) * | 2015-01-07 | 2015-04-22 | 广州倚德生物科技有限公司 | Powdered oil rich in medium and low carbonic acid and preparation method thereof |
| CN107205419B (en) * | 2015-01-26 | 2021-12-07 | 日清奥利友集团株式会社 | Oil and fat |
| CN107205419A (en) * | 2015-01-26 | 2017-09-26 | 日清奥利友集团株式会社 | grease |
| CN104642570A (en) * | 2015-03-11 | 2015-05-27 | 重庆第二师范学院 | Modification preparation method of maize germ oil |
| CN105104583A (en) * | 2015-09-22 | 2015-12-02 | 河南工业大学 | Preparation method of medium-long-chain fatty acid grease |
| CN105104583B (en) * | 2015-09-22 | 2018-08-28 | 河南工业大学 | The preparation method of middle long-chain fat acid lipid |
| CN109645424A (en) * | 2019-01-04 | 2019-04-19 | 颐海（上海）食品有限公司 | A kind of chafing dish bottom flavorings and preparation method thereof containing medium chain triglyceride |
| CN115151628A (en) * | 2020-02-28 | 2022-10-04 | 株式会社钟化 | Process for producing long-chain fatty acid and use thereof |
| CN111423935A (en) * | 2020-04-22 | 2020-07-17 | 郑州市美宴食品有限公司 | Preparation method of sesame oil rich in medium-chain fatty acids, tocopherols and phytosterol |
| CN111423935B (en) * | 2020-04-22 | 2024-02-20 | 郑州市美宴食品有限公司 | Preparation method of sesame oil rich in medium-chain fatty acid, tocopherol and phytosterol |
| CN115226780A (en) * | 2022-07-22 | 2022-10-25 | 广州福汇食品科技有限公司 | Light edible oil for losing weight and preparation method thereof |
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Address after: Shandong Samsung Corn Industry Technology Co., Ltd., Handian Town, Zouping County, Binzhou City, Shandong Province, 256209 Patentee after: longevity flower food co., ltd. Address before: Shandong Samsung Corn Industry Technology Co., Ltd., Handian Town, Zouping County, Binzhou City, Shandong Province, 256209 Patentee before: SHANDONG SANXING CORN INDUSTRY TECHNOLOGY Co.,Ltd. |