CN101914216A - Method for efficiently decomposing macromolecular organic compound - Google Patents

Method for efficiently decomposing macromolecular organic compound Download PDF

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Publication number
CN101914216A
CN101914216A CN2010102435137A CN201010243513A CN101914216A CN 101914216 A CN101914216 A CN 101914216A CN 2010102435137 A CN2010102435137 A CN 2010102435137A CN 201010243513 A CN201010243513 A CN 201010243513A CN 101914216 A CN101914216 A CN 101914216A
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CN
China
Prior art keywords
organic compound
macromolecular organic
pressure
efficiently decomposing
temperature
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Pending
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CN2010102435137A
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Chinese (zh)
Inventor
陈东升
张申宝
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Individual
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Individual
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Priority to CN2010102435137A priority Critical patent/CN101914216A/en
Publication of CN101914216A publication Critical patent/CN101914216A/en
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/62Plastics recycling; Rubber recycling

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  • Processing Of Solid Wastes (AREA)

Abstract

The invention belongs to the technical field of organic matter decomposition, in particular to a method for efficiently decomposing a macromolecular organic compound. The macromolecular organic compound can be decomposed through treatment under a closed environment at a saturated humidity, a temperature of not lower than 180 DEG C and the pressure of not lower than 18MPa. The method can realize efficient decomposition of the macromolecular organic compound; and materials obtained from the decomposition can be used as nutrients of animals and plants without causing further pollution, and can be recycled.

Description

A kind of method of efficiently decomposing macromolecular organic compound
(1) technical field
The invention belongs to organism decomposition technique field, particularly a kind of method of efficiently decomposing macromolecular organic compound.
(2) background technology
In the modern life, macromolecular organic compound is extensive use of.The rubbish that these materials use the back to form is very difficult to dispose, and at present, generally the method for Shi Yonging mainly is to burn, bury etc., but these methods of disposal have formed secondary pollution to atmosphere, soil and water.From the angle of environmental protection and Sustainable development, study a kind of simple and macromolecular organic compound decomposition method environmental protection and be necessary very much.
(3) summary of the invention
The object of the present invention is to provide a kind of method of efficiently decomposing macromolecular organic compound, can overcome the defective that existing treatment process is easy to generate secondary pollution.
The technical solution used in the present invention is as follows:
A kind of method of efficiently decomposing macromolecular organic compound is under closed environment, in saturated humidity, be not less than 180 ℃ temperature and be not less than under the pressure of 18MPa macromolecular organic compound is handled.
Treatment time generally is controlled to be 60-75min.
Described temperature generally is controlled to be 180-240 ℃, and pressure is 18-24MPa.
Further, described macromolecular organic compound is protein, fat or polysaccharide, and Controllable Temperature is made as 180-200 ℃, and pressure is 18-20MPa.
Described macromolecular organic compound is the high molecular polymer except protein or polysaccharide, and described temperature is 200-230 ℃, and pressure is 20-23MPa.
Present method adopts High Temperature High Pressure to decompose under the condition of saturated humidity to macromolecular organic compound, provide sufficient energy to break the intermolecular chemical bond of macromolecular organic compound, can be decomposed to form the small molecules polymkeric substance after the processing, as the nutrient of animal and plant, for garbage as resource provides an effective way.For example become glucose behind the amylolysis, the protein decomposition obtains amino acid, and the grease decomposition obtains higher fatty acid and glycerine or higher alcohols, and superpolymer decomposes acquisition gac and water.
The present invention has following advantage with respect to prior art:
The inventive method can realize the efficient decomposition of macromolecular organic compound, and the material that decompose to obtain can be used as vegeto-animal nutrient, not only can not cause further pollution, can also resource reutilization.
(4) embodiment:
Below with specific embodiment technical scheme of the present invention is described, but protection scope of the present invention is not limited thereto:
Embodiment 1
Albumin is carried out disaggregating treatment, carry out under closed environment, humidity is 100%, and temperature is controlled to be 200 ℃, and pressure is 20MPa.Handle and detect after 60 minutes, no protein detects, and proteinic rate of decomposition is 100%, and total amino acid content is 31.86%, and all the other mainly are moisture.
Embodiment 2
The beef protein powder is carried out disaggregating treatment, carry out under closed environment, humidity is 100%, and temperature is controlled to be 200 ℃, and pressure is 18MPa.Handle and detect after 60 minutes, no protein detects, and proteinic rate of decomposition is 100%, and aminoacids content is 32.86%.
Embodiment 3
Soybean protein is carried out disaggregating treatment, carry out under closed environment, humidity is 100%, and temperature is controlled to be 200 ℃, and pressure is 20MPa.Handle and detect after 60 minutes, proteinic rate of decomposition is 100%, and aminoacids content is 31.76%.
Embodiment 4
Pork fat is carried out disaggregating treatment, carry out under closed environment, humidity is 100%, and temperature is controlled to be 200 ℃, and pressure is 18MPa.Handle and detect after 60 minutes, fat-free detecting, fatty acid content wherein is 21.24%, and glycerol content is 18.72%, and the rate of decomposition of fat is 100%.
Embodiment 5
Sesame oil is carried out disaggregating treatment, carry out under closed environment, humidity is 100%, and temperature is controlled to be 200 ℃, and pressure is 20MPa.Handle and detect after 60 minutes, fat-free detecting, fatty acid content wherein is 23.18%, and glycerol content is 16.73%, and the rate of decomposition of fat is 100%.
Embodiment 6
W-Gum is carried out disaggregating treatment, carry out under closed environment, humidity is 100%, and temperature is controlled to be 180 ℃, and pressure is 18MPa.Handle and detect after 60 minutes, no macromole sugar detects, and glucose content wherein is 57.56%, fructose 7.42%, and the rate of decomposition of polysaccharide is 100%.
Embodiment 7
The pine Mierocrystalline cellulose is carried out disaggregating treatment, carry out under closed environment, humidity is 100%, and temperature is controlled to be 180 ℃, and pressure is 18MPa.Handle and detect after 60 minutes, no macromole sugar detects, and glucose content wherein is 57.56%, fructose 7.42%, and the rate of decomposition of polysaccharide is 100%.
Embodiment 8-11
Be that raw material carries out disaggregating treatment with polyethylene (PE), polyvinyl chloride (PVC), polystyrene (PS), phenolic aldehyde (PF), carry out under closed environment that humidity is 100% respectively, temperature is controlled to be 220 ℃, and pressure is 20MPa.Handle and detect after 60 minutes, the rate of decomposition of superpolymer is respectively 99.6%, 99.03%, 98.82%, 98.77%, to decompose what obtain be gac and moisture to each raw material.

Claims (5)

1. the method for an efficiently decomposing macromolecular organic compound is characterized in that, under closed environment, in saturated humidity, be not less than 180 ℃ temperature and be not less than under the pressure of 18MPa macromolecular organic compound is handled.
2. the method for efficiently decomposing macromolecular organic compound as claimed in claim 1 is characterized in that, the treatment time is 60-75min.
3. the method for efficiently decomposing macromolecular organic compound as claimed in claim 1 or 2 is characterized in that, described temperature is 180-240 ℃, and pressure is 18-24MPa.
4. the method for efficiently decomposing macromolecular organic compound as claimed in claim 3 is characterized in that, described macromolecular organic compound is protein, fat or polysaccharide, and temperature is 180-200 ℃, and pressure is 18-20MPa.
5. the method for efficiently decomposing macromolecular organic compound as claimed in claim 3 is characterized in that, described macromolecular organic compound is the high molecular polymer except protein or polysaccharide, and described temperature is 200-230 ℃, and pressure is 20-23MPa.
CN2010102435137A 2010-08-03 2010-08-03 Method for efficiently decomposing macromolecular organic compound Pending CN101914216A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2010102435137A CN101914216A (en) 2010-08-03 2010-08-03 Method for efficiently decomposing macromolecular organic compound

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2010102435137A CN101914216A (en) 2010-08-03 2010-08-03 Method for efficiently decomposing macromolecular organic compound

Publications (1)

Publication Number Publication Date
CN101914216A true CN101914216A (en) 2010-12-15

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105061805A (en) * 2015-07-22 2015-11-18 浙江大学 Recovery process for crosslinked polyethylene wastes

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1188776A (en) * 1997-01-20 1998-07-29 株式会社神户制钢所 Decomposition method and device for discarded material
CN101448581A (en) * 2006-09-28 2009-06-03 Eco原料株式会社 Processing system for organic waste
CN101456809A (en) * 2009-01-08 2009-06-17 中国科学院嘉兴材料与化工技术工程中心 Method for disaggregation of waste and old PET

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1188776A (en) * 1997-01-20 1998-07-29 株式会社神户制钢所 Decomposition method and device for discarded material
CN101448581A (en) * 2006-09-28 2009-06-03 Eco原料株式会社 Processing system for organic waste
CN101456809A (en) * 2009-01-08 2009-06-17 中国科学院嘉兴材料与化工技术工程中心 Method for disaggregation of waste and old PET

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
《化工进展》 19980531 黄发荣 废旧聚合物材料的化学循环利用 44-49 1-5 , 第5期 2 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105061805A (en) * 2015-07-22 2015-11-18 浙江大学 Recovery process for crosslinked polyethylene wastes
CN105061805B (en) * 2015-07-22 2018-06-29 浙江大学 A kind of recovery process of crosslinked polyethylene waste

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Open date: 20101215