CN101906722A - Method for manufacturing polyurethane leather for high-durability, high-wear-resistance and flame-retardant sofa furniture - Google Patents

Method for manufacturing polyurethane leather for high-durability, high-wear-resistance and flame-retardant sofa furniture Download PDF

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Publication number
CN101906722A
CN101906722A CN 201010214327 CN201010214327A CN101906722A CN 101906722 A CN101906722 A CN 101906722A CN 201010214327 CN201010214327 CN 201010214327 CN 201010214327 A CN201010214327 A CN 201010214327A CN 101906722 A CN101906722 A CN 101906722A
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China
Prior art keywords
parts
synthetic leather
flame
durability
wear
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CN 201010214327
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CN101906722B (en
Inventor
黄万里
王燕武
姚和平
李道鹏
笪丽红
武春余
陈茂祥
唐涛
吴建民
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Anhui Anli Material Technology Co Ltd
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ANHUI ANLI ARTIFICIAL LEATHER Co Ltd
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  • Treatment And Processing Of Natural Fur Or Leather (AREA)

Abstract

The invention relates to a method for manufacturing polyurethane leather for high-durability, high-wear-resistance and flame-retardant sofa furniture. The polyurethane leather for the high-durability, high-wear-resistance and flame-retardant sofa furniture is particularly manufactured by the following steps of: processing synthetic leather on raising base cloth; and performing a synthetic leather process on a polycarbonate type polyurethane paste material according to a specific formula ratio. The product of the invention has the performance such as high durability, high wear resistance, flame retardancy and the like, improves the durability and the service performance and has broad market prospect.

Description

A kind of high-durability, high-wear-resistance and flame-retardant sofa furniture manufacture method of Synthetic Leather
Technical field
The present invention relates to the manufacture method of a kind of high-durability, high-wear-resistance and flame-retardant sofa furniture with Synthetic Leather.
Background technology
Artificial leather in recent years, the synthetic leather industry development is rapid, the synthetic leather product is widely used in people's various fields in life, but being almost external producer as the high-durability, high-wear-resistance and flame-retardant sofa furniture of its high-end product with the Synthetic Leather series products monopolizes, and developing rapidly along with the domestic market, increasing to the high-end synthetic leather market demand, our company is according to the market demand, through continually developing research, be chosen in and apply special kinds polyurethane resin and functional material blend above the raising base cloth, and it is high durable by technological innovation product to be had, high abrasion, performance such as fire-retardant, improve the durability and the serviceability of product, had extensive market prospects.
Summary of the invention
The invention discloses a kind of manufacture method with high durable, high abrasion, flame-retardant sofa furniture with leather.
For the present invention that achieves the above object has adopted following technical scheme:
The present invention passes through: the polyurethane coating resin of selecting for use in the step (a) and (b) is a polycarbonate type resin, in the polyurethane slurry, add various functional materials such as fire-retardant, wear-resisting and be used the synthetic leather processing technology, make the synthetic leather of manufacturing have functions such as permanent fire retardant, high durable, high abrasion, the synthetic leather in the step (b) is placed on kneading can obtain a kind of high-durability, high-wear-resistance and flame-retardant sofa furniture Synthetic Leather finished product in the rub barrel again.
Description of drawings
Below in conjunction with accompanying drawing the present invention is described in further details.
Accompanying drawing 1 is a wet coating technology Synthetic Leather process chart;
Accompanying drawing 2 is a dry coating Synthetic Leather process chart;
Accompanying drawing 3 is rubbed the leather process chart for post processing.
The specific embodiment
Shown in figure (1), this high-durability, high-wear-resistance sofa furniture with the wet-method synthetic leather technological process of leather is: raising base cloth → soak contains the 0-50%DMF aqueous solution → base cloth moisture percentage adjustment → wet coating → solidify → wash → drying and shaping, can obtain high-durability, high-wear-resistance and flame-retardant sofa furniture Synthetic Leather wet half-finished product.
Shown in figure (2), this high-durability, high-wear-resistance and flame-retardant polyurethane sofa furniture is (two skill in using a kitchen knife in cookery) with the dry process flow process of leather: the surface layer slurry that is coated with one deck suitable thickness on release liners, advancing baking oven suitably dries, be coated with one deck adhesive linkage again and stick as figure (1) flow process manufacturing wet method base material, enter peel off after the oven for drying get final product a kind of high-durability, high-wear-resistance and flame-retardant sofa furniture Synthetic Leather semifinished or finished goods.
Shown in figure (3), the semi-finished product that will shown in figure (2), make after special process is handled, put in the rub barrel kneading get final product manufactured goods.
Case study on implementation 1
The high-durability, high-wear-resistance and flame-retardant sofa furniture manufacture method of Synthetic Leather may further comprise the steps:
(a) on any one side of raising base cloth, apply polyurethane slurry and form coating, make semi-finished product.
(b) on the semi-finished product that step (a) makes, apply polyurethane slurry adhesive linkage and surface layer, make Synthetic Leather or again the Synthetic Leather kneading in rub barrel that makes is got the Synthetic Leather finished product.
(c) batching.
The formulation by weight of step (a) wet polyurethane coating paste is:
100 parts of polycarbonate polyurethane resins
85 parts of dimethyl formamides (DMF)
2 parts in colorant
5 parts of wood powders
0.6 part in surfactant (BYK-L-9520)
5 parts of antiwear assistants (Silok 6500)
Flame retardant (Al (OH) 3) 5 parts
The formulation by weight of step (b) dry method polyurethane slurry is:
Surface layer
100 parts of polycarbonate polyurethane resins
65 parts of dimethyl formamides (DMF)
5 parts in colorant
Help 0.2 part of remover (BYK-325)
Flame retardant (Al (OH) 3) 1 part
0.5 part of antiwear assistant (Silok 6500)
Adhesive linkage
100 parts of polycarbonate polyurethane resins
50 parts of dimethyl formamides (DMF)
12 parts of mill bases
Help 0.2 part of remover (BYK-325)
Flame retardant (Al (OH) 3) 1 part
(d) select release paper flower to spin size as required, dry method surface layer wet pulp consumes 80~100g/m 2, 100~120 ℃ of oven temperatures; The adhesive linkage wet pulp consumes 100~120g/m 2, 100~130 ℃ of oven temperatures, 130 ℃ of heat-seal temperatures, laminate pressure 5.5kg.
(e) in rub barrel, get final product after the kneading required finished product.The wear-resisting detection of common synthetic leather: taber H-18/1kg can only do 300 to be changeed, and uses the prepared synthetic leather of the present invention to accomplish more than 2000 commentaries on classics.Common synthetic leather is durable to be 2 years, uses the prepared synthetic leather of the present invention durable 10 years; Common synthetic leather is not fire-retardant, uses the made synthetic leather of the present invention fire-retardant by CA 117E flame-retardant standard.
Case study on implementation 2
The high-durability, high-wear-resistance and flame-retardant sofa furniture manufacture method of Synthetic Leather may further comprise the steps:
(a) on any one side of raising base cloth, apply polyurethane slurry and form coating, make semi-finished product.
(b) on the semi-finished product that step (a) makes, apply polyurethane slurry adhesive linkage and surface layer, make Synthetic Leather or again the Synthetic Leather kneading in rub barrel that makes is got the Synthetic Leather finished product.
(c) batching.
The formulation by weight of step (a) wet polyurethane coating paste is:
100 parts of poly-carbon type polyurethane resins
170 parts of dimethyl formamides (DMF)
0.2 part in surfactant (BYK-L-9520)
10 parts in colorant
Flame retardant (Al (OH) 3) 8 parts
The formulation by weight of step (b) dry method polyurethane coating slurry is:
Surface layer
100 parts of polycarbonate type polyurethanes
55 parts of dimethyl formamides (DMF)
18 parts in colorant
Help 0.2 part of remover (BYK-325)
Flame retardant (Al (OH) 3) 2 parts
Adhesive linkage
100 parts of polycarbonate type polyurethanes
40 parts of dimethyl formamides (DMF)
10 parts in colorant
Help 0.2 part of remover (BYK-325)
Flame retardant (Al (OH) 3) 1.5 parts
(d) select release paper flower to spin size as required, dry method surface layer wet pulp consumes 80~120g/m 2, 100~120 ℃ of oven temperatures.The adhesive linkage wet pulp consumes 100~160g/m 2, 120~140 ℃ of oven temperatures, 140 ℃ of heat-seal temperatures, laminate pressure 6.5kg.
(e) in rub barrel, get final product after the kneading required finished product.The wear-resisting detection of common synthetic leather: taber H-18/1kg can only do 300 to be changeed, and the synthetic leather that the present invention makes can reach more than 3000 commentaries on classics.Common synthetic leather is durable to be 2 years, and the synthetic leather that the present invention makes is durable more than 15 years; Common synthetic leather is not fire-retardant, and the synthetic leather that the present invention makes is fire-retardant by BS 5852 PART I, FMVSS-302, GB 8410-20006 flame-retardant standard.
Annotate: surfactant B YK-9520, to help remover BYK-325 be German Bi Ke chemical company product; Antiwear assistant Silok 6500 compositions: the active polyether modified polyorganosiloxane, Guangzhou Si Luoke chemistry Co., Ltd produces
The polyether-modified polymethyl siloxane of BYK-325
The polyether-modified polysiloxanes of BYK-L-9520
The public WWW.byk-chemi.com of Bi Ke chemistry.

Claims (2)

1. a high-durability, high-wear-resistance and flame-retardant sofa furniture is characterized in that may further comprise the steps with the manufacture method of Synthetic Leather:
(a) on any one side of raising base cloth, apply polyurethane slurry and form coating, make semi-finished product;
(b) on the semi-finished product that step (a) makes, apply polyurethane slurry adhesive linkage and surface layer, make Synthetic Leather or again the Synthetic Leather kneading in rub barrel that makes is got the Synthetic Leather finished product.
2. high-durability, high-wear-resistance and flame-retardant sofa furniture Synthetic Leather manufacture method according to claim 1 is characterized in that: the coating described in the step (a) is meant adopts the synthetic processing technology of wet method; Described semi-finished product are wet half-finished product; Dry method release liners decorative pattern shifting process is adopted in coating described in the step (b).
The formulation by weight of the wet polyurethane coating paste described in the step (a) is:
100 parts of polycarbonate polyurethane resins
60~150 parts of dimethyl formamides (DMF)
0~10 part in colorant
0~10 part of wood powder
0.4~4 part in surfactant (BYK-L-9520)
1~10 part of antiwear assistant (Silok 6500)
Flame retardant (Al (OH) 3) 1~10 part
The formulation by weight of dry method polyurethane slurry adhesive linkage described in the step (b) and surface layer is:
Surface layer:
100 parts of polycarbonate polyurethane resins
50~70 parts of dimethyl formamides (DMF)
2~20 parts in colorant
Help 0.2~1 part of remover (BYK-325)
0.5~1.5 part of antiwear assistant (Silok 6500)
Flame retardant (Al (OH) 3) 0.5~3 part
Adhesive linkage:
100 parts of poly-carbon ester type polyurethane resins
30~50 parts of dimethyl formamides (DMF)
0.5~15 part in colorant
Help 0.2~1 part of remover (BYK-325)
0.5~1.5 part of antiwear assistant (Silok 6500)
Flame retardant (Al (OH) 3) 0.5~3 part
CN2010102143270A 2010-06-30 2010-06-30 Method for manufacturing polyurethane leather for high-durability, high-wear-resistance and flame-retardant sofa furniture Active CN101906722B (en)

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Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102191693A (en) * 2011-05-16 2011-09-21 福州福营塑胶制品有限公司 Method for producing high-visibility polyurethane artificial leather
CN102965965A (en) * 2012-11-27 2013-03-13 安徽安利合成革股份有限公司 Preparation method of abrasion-resistant hydrolyzation-resistant polyurethane synthetic leather
CN103031746A (en) * 2011-10-10 2013-04-10 昆山协兴合成革有限公司 Manufacturing method of sofa leather
CN103255640A (en) * 2013-04-19 2013-08-21 晋江市闽高纺织科技有限公司 Environmentally-friendly flame retardant polyurethane synthetic leather, preparation method and product thereof
CN104404778A (en) * 2014-11-26 2015-03-11 安徽宝博合成革有限公司 Automobile decoration sofa leather
CN104480735A (en) * 2014-10-23 2015-04-01 合肥金伶俐服饰有限公司 Flame-retardant polyurethane synthetic leather and producing method thereof
CN104480737A (en) * 2014-10-23 2015-04-01 合肥金伶俐服饰有限公司 Wear-resistant polyurethane synthetic leather and producing method thereof
CN106087448A (en) * 2016-08-19 2016-11-09 安徽安利材料科技股份有限公司 A kind of preparation method of soft matte high resiliency artificial leather polyurethane synthetic leather for sofa furniture
CN107447538A (en) * 2017-08-18 2017-12-08 天守(福建)超纤科技股份有限公司 A kind of preparation method of only water dry method Trademark leather
CN108951193A (en) * 2018-09-26 2018-12-07 安徽安利材料科技股份有限公司 A kind of preparation method of B1 grades of fire-retardant engineering Synthetic Leather
CN109252384A (en) * 2018-10-18 2019-01-22 清远市齐力合成革有限公司 A kind of two-sided leather of Environment-friendlywear-resistant wear-resistant scratch resistance
CN109706751A (en) * 2018-12-29 2019-05-03 扬州市德运塑业科技股份有限公司 A kind of manufacturing method of abrasion resistant fire blocking automobile synthetic leather
CN110951030A (en) * 2019-12-11 2020-04-03 上海华峰超纤科技股份有限公司 Low-temperature-resistant and wear-resistant non-yellowing polyurethane resin and superfine fiber synthetic leather prepared from same

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CN101021045A (en) * 2007-03-09 2007-08-22 浙江禾欣实业集团股份有限公司 Process of producing fireproof sofa artificial leather
CN101440578A (en) * 2008-12-19 2009-05-27 安徽安利合成革股份有限公司 Novel waterproof air previous polyurethane artificial leather and preparation thereof
CN101503861A (en) * 2008-12-19 2009-08-12 安徽安利合成革股份有限公司 Two-liquid type rapid stripping synthetic leather composite overlay

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CN101021045A (en) * 2007-03-09 2007-08-22 浙江禾欣实业集团股份有限公司 Process of producing fireproof sofa artificial leather
CN101440578A (en) * 2008-12-19 2009-05-27 安徽安利合成革股份有限公司 Novel waterproof air previous polyurethane artificial leather and preparation thereof
CN101503861A (en) * 2008-12-19 2009-08-12 安徽安利合成革股份有限公司 Two-liquid type rapid stripping synthetic leather composite overlay

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Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102191693B (en) * 2011-05-16 2012-10-03 福州福营塑胶制品有限公司 Method for producing high-visibility polyurethane artificial leather
CN102191693A (en) * 2011-05-16 2011-09-21 福州福营塑胶制品有限公司 Method for producing high-visibility polyurethane artificial leather
CN103031746A (en) * 2011-10-10 2013-04-10 昆山协兴合成革有限公司 Manufacturing method of sofa leather
CN102965965A (en) * 2012-11-27 2013-03-13 安徽安利合成革股份有限公司 Preparation method of abrasion-resistant hydrolyzation-resistant polyurethane synthetic leather
CN102965965B (en) * 2012-11-27 2014-09-10 安徽安利合成革股份有限公司 Preparation method of abrasion-resistant hydrolyzation-resistant polyurethane synthetic leather
CN103255640B (en) * 2013-04-19 2015-03-25 晋江市闽高纺织科技有限公司 Environmentally-friendly flame retardant polyurethane synthetic leather, preparation method and product thereof
CN103255640A (en) * 2013-04-19 2013-08-21 晋江市闽高纺织科技有限公司 Environmentally-friendly flame retardant polyurethane synthetic leather, preparation method and product thereof
CN104480735A (en) * 2014-10-23 2015-04-01 合肥金伶俐服饰有限公司 Flame-retardant polyurethane synthetic leather and producing method thereof
CN104480737A (en) * 2014-10-23 2015-04-01 合肥金伶俐服饰有限公司 Wear-resistant polyurethane synthetic leather and producing method thereof
CN104404778A (en) * 2014-11-26 2015-03-11 安徽宝博合成革有限公司 Automobile decoration sofa leather
CN106087448A (en) * 2016-08-19 2016-11-09 安徽安利材料科技股份有限公司 A kind of preparation method of soft matte high resiliency artificial leather polyurethane synthetic leather for sofa furniture
CN107447538A (en) * 2017-08-18 2017-12-08 天守(福建)超纤科技股份有限公司 A kind of preparation method of only water dry method Trademark leather
CN108951193A (en) * 2018-09-26 2018-12-07 安徽安利材料科技股份有限公司 A kind of preparation method of B1 grades of fire-retardant engineering Synthetic Leather
CN109252384A (en) * 2018-10-18 2019-01-22 清远市齐力合成革有限公司 A kind of two-sided leather of Environment-friendlywear-resistant wear-resistant scratch resistance
CN109706751A (en) * 2018-12-29 2019-05-03 扬州市德运塑业科技股份有限公司 A kind of manufacturing method of abrasion resistant fire blocking automobile synthetic leather
CN110951030A (en) * 2019-12-11 2020-04-03 上海华峰超纤科技股份有限公司 Low-temperature-resistant and wear-resistant non-yellowing polyurethane resin and superfine fiber synthetic leather prepared from same
CN110951030B (en) * 2019-12-11 2021-11-05 上海华峰超纤科技股份有限公司 Low-temperature-resistant and wear-resistant non-yellowing polyurethane resin and superfine fiber synthetic leather prepared from same

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Owner name: ANHUI ANLI MATERIAL TECHNOLOGY CO., LTD.

Free format text: FORMER NAME: ANHUI ANLI ARTIFICIAL LEATHER CO., LTD.

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Address after: 230601 peach blossom Industrial Park, Hefei economic and Technological Development Zone, Anhui

Patentee after: Anhui Amway material Science and Technology Co., Ltd.

Address before: 230601 peach blossom Industrial Park, Hefei economic and Technological Development Zone, Anhui

Patentee before: Anhui Anli Artificial Leather Co., Ltd.