CN101898867A - Pyroceram-ceramic composite plate and preparation method thereof - Google Patents
Pyroceram-ceramic composite plate and preparation method thereof Download PDFInfo
- Publication number
- CN101898867A CN101898867A CN 201010230281 CN201010230281A CN101898867A CN 101898867 A CN101898867 A CN 101898867A CN 201010230281 CN201010230281 CN 201010230281 CN 201010230281 A CN201010230281 A CN 201010230281A CN 101898867 A CN101898867 A CN 101898867A
- Authority
- CN
- China
- Prior art keywords
- glass
- ceramic
- percent
- microcrystal
- pyroceram
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000919 ceramic Substances 0.000 title claims abstract description 15
- 238000002360 preparation method Methods 0.000 title claims description 20
- 239000002131 composite material Substances 0.000 title abstract 5
- 239000011521 glass Substances 0.000 claims abstract description 114
- 239000002245 particle Substances 0.000 claims abstract description 34
- 239000000843 powder Substances 0.000 claims abstract description 22
- 238000000137 annealing Methods 0.000 claims abstract description 8
- 238000002156 mixing Methods 0.000 claims abstract description 8
- 239000000203 mixture Substances 0.000 claims abstract description 6
- 239000002241 glass-ceramic Substances 0.000 claims description 33
- 239000013081 microcrystal Substances 0.000 claims description 28
- 239000004615 ingredient Substances 0.000 claims description 18
- 238000007669 thermal treatment Methods 0.000 claims description 15
- 239000002184 metal Substances 0.000 claims description 14
- 229910052751 metal Inorganic materials 0.000 claims description 14
- 238000000465 moulding Methods 0.000 claims description 7
- 238000003892 spreading Methods 0.000 claims description 7
- 239000000463 material Substances 0.000 abstract description 6
- 238000000034 method Methods 0.000 abstract description 5
- 238000010438 heat treatment Methods 0.000 abstract description 3
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 abstract 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 4
- YEAUATLBSVJFOY-UHFFFAOYSA-N tetraantimony hexaoxide Chemical compound O1[Sb](O2)O[Sb]3O[Sb]1O[Sb]2O3 YEAUATLBSVJFOY-UHFFFAOYSA-N 0.000 abstract 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 2
- 239000000395 magnesium oxide Substances 0.000 abstract 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 abstract 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 abstract 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 abstract 2
- 239000000377 silicon dioxide Substances 0.000 abstract 2
- 235000012239 silicon dioxide Nutrition 0.000 abstract 2
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 abstract 1
- 239000002196 Pyroceram Substances 0.000 abstract 1
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 abstract 1
- FZFYOUJTOSBFPQ-UHFFFAOYSA-M dipotassium;hydroxide Chemical compound [OH-].[K+].[K+] FZFYOUJTOSBFPQ-UHFFFAOYSA-M 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 abstract 1
- 239000002994 raw material Substances 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 6
- 229910004298 SiO 2 Inorganic materials 0.000 description 3
- 239000011362 coarse particle Substances 0.000 description 3
- 238000005034 decoration Methods 0.000 description 3
- 238000000280 densification Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000005245 sintering Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000013021 overheating Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
Landscapes
- Glass Compositions (AREA)
Abstract
The invention discloses a pyroceram-ceramic composite plate. The pyroceram in the composite plate consists of main materials and antimony trioxide (Sb2O3), wherein the Sb2O3 accounts for 0.8 to 1.2 percent of the total weight of the main materials; and the main materials consist of the following components in percentage by weight: 45 to 55 percent of silicon dioxide (SiO2), 4 to 10 percent of magnesium oxide (MgO), 15 to 20 percent of calcium oxide (CaO), 10 to 14 percent of aluminum oxide (Al2O3), 3 to 6 percent of sodium oxide (Na2O) or potassium oxide (K2O) and 6 to 10 percent of calcium fluoride (CaF2). The invention also discloses a method for preparing the pyroceram-ceramic composite plate. The method comprises the following steps of: 1) mixing the main materials and the Sb2O3 uniformly and heating the mixture; 2) pouring the obtained glass liquid into an iron mould to form and cool, then annealing, and preparing the obtained mother glass into glass powder and glass particles respectively; and 3) paving and scattering the glass powder and the glass particles on the conventional ceramic plate sequentially and then performing heat treatment. The pyroceram-ceramic composite plate has the characteristics of lower cost and high glossiness.
Description
Technical field
The present invention relates to a kind of microcrystal glass-ceramic compounded plate and preparation method thereof.
Background technology
Than traditional decorative ceramic board, advantage such as that microcrystalline glass decorative plate has is corrosion-resistant, wear-resistant, water-intake rate is low, but there are problems such as production cost height, complicated process of preparation, kind are single in present crystallizing glass decoration board, is difficult to promote on a large scale.
Crystallizing glass decoration board commonly used is generally selected CaO-Al for use
2O
3-SiO
2System, CaO-MgO-SiO
2System or CaO-MgO-Al
2O
3-SiO
2The devitrified glass of system, and, usually need in glass, add valuable ZnO, BaO and and Na in order to reach good sintering character and flowing property
2O (or K
2O) be mixed into ZnO+Na
2O, BaO+Na
2O or ZnO+BaO+Na
2Mixtures such as O are as fusing assistant.As being among CN00136831.1, CN1974455A, the CN1433985A at publication number, the add-on of its ZnO, BaO even reach about 10wt% makes that the production cost of devitrified glass is higher.At publication number is among CN101186129A and the CN101186443A, and the artificial devitrified glass production cost that reduces of invention adopts Li
2O replaces fusing assistant ZnO and BaO, but still needs to use the higher Li of price
2O, and its usage quantity is also bigger.Valuable raw material ZnO, BaO, Li
2The effect of fusing assistant has not only been played in the adding of O, thereby and the flowability that can improve glass reduce the thermal treatment temp of glass.
In addition, sintering process at present commonly used prepare devitrified glass generally be the direct lay of coarse particles frit that will obtain after the shrend on ceramic bases, thermal treatment then.It utilize the coarse particles frit to be because still can maintain gloss after Overheating Treatment; But because particle size is bigger, occur the space each other easily, in order to make final devitrified glass densification, thermal treatment temp generally reaches 1100～1200 ℃.As publication number is that treatment temp all reaches 1200 ℃ among CN101186129A and the CN101186443A.This certainly will improve the production cost of devitrified glass again, and is totally unfavorable for producing in enormous quantities, promoting on a large scale.
Summary of the invention
The technical problem to be solved in the present invention provides microcrystal glass-ceramic compounded plate that a kind of cost is lower, glossiness is good and preparation method thereof.
In order to solve the problems of the technologies described above, the invention provides a kind of microcrystal glass-ceramic compounded plate, the devitrified glass in this composition board is by major ingredient with as the Sb of finings
2O
3Form Sb
2O
3Account for 0.8～1.2% of major ingredient gross weight; Described major ingredient is grouped into by the one-tenth of following percentage composition: the SiO of 45～55wt%
2, 4～10wt% CaO, the Al of 10～14wt% of MgO, 15～20wt%
2O
3, 3～6wt% Na
2O or K
2The CaF of O and 6～10wt%
2
The present invention also provides the preparation method of above-mentioned microcrystal glass-ceramic compounded plate simultaneously, may further comprise the steps:
1), with major ingredient and Sb
2O
3Thorough mixing is even, places stove to be heated to 1450～1500 ℃ and be incubated 3.5～4.5h then, obtains clarifying uniform glass metal;
2), glass metal is poured in the swage into moulding and cooled off 1～2min, in 480～520 ℃ of annealing 0.5～1h down, obtain blocky mother glass afterwards; After half of mother glass pulverized glass powder, second half of mother glass is broken into the glass particle that particle diameter is 0.1～0.3mm;
3), get glass powder and evenly be laid on the conventional ceramic plate, becoming thickness is the glass frit layer of 1～2mm; And then with the glass particle of individual layer (being that glass particle does not produce superposition phenomenon up and down each other) evenly spreading on glass frit layer,, obtain microcrystal glass-ceramic compounded plate through 950～1000 ℃ of thermal treatment 2～3h.
Improvement as the preparation method of microcrystal glass-ceramic compounded plate of the present invention: the glass powder step 2) needed 200 mesh sieves.
The present invention be the contriver on the basis of devitrified glass that studies for a long period of time, obtain through exploring technological process repeatedly.The present invention only adopts Na
2O and K
2O utilizes glass powder to replace coarse particles as fusing assistant, has not only removed valuable oxide compound ZnO, BaO, Li from
2The adding of O, and remedied because of lacking ZnO, BaO, Li
2O and the glass flow variation that causes have also reduced the thermal treatment temp of glass simultaneously.In addition, the present invention lays glass particle on glass powder, relies on glass particle to handle the glossiness characteristics in back, has guaranteed the surface gloss after the devitrified glass thermal treatment.
In sum, the present invention has following advantage:
The first, preparation devitrified glass desired raw material is cheap raw material, does not contain Li
2The more expensive fusing assistants of price such as O, ZnO, BaO have effectively reduced the production cost of crystallizing glass sheet material, help it and produce and promote on a large scale.
The second, the present invention has glossiness two specific characters preferably after combining easy densification of glass powder low-temperature heat treatment and glass particle thermal treatment, the mother glass material is prepared into powder and particle respectively, and be layed in thermal treatment again on the ceramic plate successively, so both effectively reduce thermal treatment temp (minimum only need get final product for 950 ℃), guaranteed the glossiness on devitrified glass surface simultaneously again.
Therefore, the present invention overcome existing microcrystal glass-ceramic compounded plate production cost higher, need to use the heat treated shortcoming of comparatively high temps.
Adopt the microcrystal glass-ceramic plate that the present invention produced, can be widely used in the family decorations such as exterior wall finish and high-grade public place such as airport, hotel, office building.
Embodiment
The preparation method of embodiment 1, a kind of microcrystal glass-ceramic compounded plate, its processing step is as follows:
1), with the SiO of 45wt%
2, 10wt% CaO, the Al of 14wt% of MgO, 20wt%
2O
3, 5wt% Na
2The CaF of O, 6wt%
2Form major ingredient, adding accounts for major ingredient gross weight 1wt%Sb
2O
3As finings, thorough mixing is even; Place stove to be heated to 1450 ℃ and be incubated 4h then, obtain clarifying uniform glass metal;
2), glass metal is poured in the swage into moulding and cooled off 2min, in 480 ℃ of annealing 0.5h down, obtain blocky mother glass afterwards.Half was ground into the glass powder of 200 mesh sieves with mother glass, and second half then is broken into the glass particle that particle diameter is 0.1～0.15mm, as the raw material of preparation glass-ceramic layer;
3), get glass powder and evenly be laid on the conventional ceramic plate, forming thickness is the glass frit layer of 1.5mm; And then on glass frit layer, (be the thickness≤0.15mm),, obtain microcrystal glass-ceramic compounded plate of glass particle layer through 950 ℃ of thermal treatment 2h with the even spreading of the glass particle of individual layer.
Through range estimation, this microcrystal glass-ceramic compounded plate has surface gloss preferably.
The preparation method of embodiment 2, a kind of microcrystal glass-ceramic compounded plate, its processing step is as follows:
1), with the SiO of 47wt%
2, 10wt% CaO, the Al of 10wt% of MgO, 20wt%
2O
3, 3wt% K
2The CaF of O, 10wt%
2Form major ingredient, adding accounts for major ingredient gross weight 1wt%Sb
2O
3As finings, thorough mixing is even; Place stove to be heated to 1470 ℃ and be incubated 4h then, obtain clarifying uniform glass metal;
2), glass metal is poured in the swage into moulding and cooled off 1min, in 500 ℃ of annealing 0.5h down, obtain blocky mother glass afterwards.Half was ground into the glass powder of 200 mesh sieves with mother glass, and second half then is broken into the glass particle that particle diameter is 0.15～0.2mm, as the raw material of preparation glass-ceramic layer;
3), get glass powder and evenly be laid on the conventional ceramic plate, forming thickness is the glass frit layer of 2mm; And then on glass frit layer, (be the thickness≤0.2mm),, obtain microcrystal glass-ceramic compounded plate of glass particle layer through 980 ℃ of thermal treatment 3h with the even spreading of the glass particle of individual layer.
Through range estimation, this microcrystal glass-ceramic compounded plate has surface gloss preferably.
The preparation method of embodiment 3, a kind of microcrystal glass-ceramic compounded plate, its processing step is as follows:
1), with the SiO of 50wt%
2, 9wt% CaO, the Al of 11wt% of MgO, 15wt%
2O
3, 6wt% Na
2The CaF of O, 9wt%
2Form major ingredient, adding accounts for major ingredient gross weight 1wt%Sb
2O
3As finings, thorough mixing is even; Place stove to be heated to 1480 ℃ and be incubated 4h then, obtain clarifying uniform glass metal;
2), glass metal is poured in the swage into moulding and cooled off 2min, in 510 ℃ of annealing 1h down, obtain blocky mother glass afterwards.Half was ground into the glass powder of 200 mesh sieves with mother glass, and second half then is broken into the glass particle that particle diameter is 0.2～0.3mm, as the raw material of preparation glass-ceramic layer;
3), get glass powder and evenly be laid on the conventional ceramic plate, forming thickness is the glass frit layer of 1mm; And then on glass frit layer, (be the thickness≤0.3mm),, obtain microcrystal glass-ceramic compounded plate of glass particle layer through 1000 ℃ of thermal treatment 2h with the even spreading of the glass particle of individual layer.
Through range estimation, this microcrystal glass-ceramic compounded plate has surface gloss preferably.
The preparation method of embodiment 4, a kind of microcrystal glass-ceramic compounded plate, its processing step is as follows:
1), with the SiO of 52wt%
2, 4wt% CaO, the Al of 13wt% of MgO, 17wt%
2O
3, 4wt% Na
2The CaF of O, 10wt%
2Form major ingredient, adding accounts for major ingredient gross weight 1wt%Sb
2O
3As finings, thorough mixing is even; Place stove to be heated to 1490 ℃ and be incubated 4h then, obtain clarifying uniform glass metal;
2), glass metal is poured in the swage into moulding and cooled off 1min, in 520 ℃ of annealing 0.5h down, obtain blocky mother glass afterwards.Half was ground into the glass powder of 200 mesh sieves with mother glass, and second half then is broken into the glass particle that particle diameter is 0.2～0.3mm, as the raw material of preparation glass-ceramic layer;
3), get glass powder and evenly be laid on the conventional ceramic plate, forming thickness is the glass frit layer of 1.5mm; And then on glass frit layer, (be the thickness≤0.3mm),, obtain microcrystal glass-ceramic compounded plate of glass particle layer through 980 ℃ of thermal treatment 2.5h with the even spreading of the glass particle of individual layer.
Through range estimation, this microcrystal glass-ceramic compounded plate has surface gloss preferably.
The preparation method of embodiment 5, a kind of microcrystal glass-ceramic compounded plate, its processing step is as follows:
1), with the SiO of 55wt%
2, 5wt% CaO, the Al of 14wt% of MgO, 16wt%
2O
3, 4wt% K
2The CaF of O, 6wt%
2Form major ingredient, adding accounts for major ingredient gross weight 1wt%Sb
2O
3As finings, thorough mixing is even; Place stove to be heated to 1500 ℃ and be incubated 4h then, obtain clarifying uniform glass metal;
2), glass metal is poured in the swage into moulding and cooled off 2min, in 520 ℃ of annealing 1h down, obtain blocky mother glass afterwards.Half was ground into the glass powder of 200 mesh sieves with mother glass, and second half then is broken into the glass particle that particle diameter is 0.2～0.3mm, as the raw material of preparation glass-ceramic layer;
3), get glass powder and evenly be laid on the conventional ceramic plate, forming thickness is the glass frit layer of 2mm; And then on glass frit layer, (be the thickness≤0.3mm),, obtain microcrystal glass-ceramic compounded plate of glass particle layer through 990 ℃ of thermal treatment 3h with the even spreading of the glass particle of individual layer.
Through range estimation, this microcrystal glass-ceramic compounded plate has surface gloss preferably.
At last, it is also to be noted that what more than enumerate only is several specific embodiments of the present invention.Obviously, the invention is not restricted to above embodiment, many distortion can also be arranged.All distortion that those of ordinary skill in the art can directly derive or associate from content disclosed by the invention all should be thought protection scope of the present invention.
Claims (3)
1. microcrystal glass-ceramic compounded plate is characterized in that: the devitrified glass in this composition board is by major ingredient with as the Sb of finings
2O
3Form Sb
2O
3Account for 0.8～1.2% of major ingredient gross weight; Described major ingredient is grouped into by the one-tenth of following percentage composition: the SiO of 45～55wt%
2, 4～10wt% CaO, the Al of 10～14wt% of MgO, 15～20wt%
2O
3, 3～6wt% Na
2O or K
2The CaF of O and 6～10wt%
2
2. the preparation method of microcrystal glass-ceramic compounded plate as claimed in claim 1 is characterized in that may further comprise the steps:
1), with major ingredient and Sb
2O
3Thorough mixing is even, places stove to be heated to 1450～1500 ℃ and be incubated 3.5～4.5h then, obtains clarifying uniform glass metal;
2), glass metal is poured in the swage into moulding and cooled off 1～2min, in 480～520 ℃ of annealing 0.5～1h down, obtain blocky mother glass afterwards; After half of mother glass pulverized glass powder, second half of mother glass is broken into the glass particle that particle diameter is 0.1～0.3mm;
3), get glass powder and evenly be laid on the conventional ceramic plate, becoming thickness is the glass frit layer of 1～2mm; And then with the even spreading of the glass particle of individual layer on glass frit layer, through 950～1000 ℃ of thermal treatment 2～3h, obtain microcrystal glass-ceramic compounded plate.
3. the preparation method of microcrystal glass-ceramic compounded plate as claimed in claim 2, it is characterized in that: the glass powder described step 2) needed 200 mesh sieves.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010102302811A CN101898867B (en) | 2010-07-19 | 2010-07-19 | Pyroceram-ceramic composite plate and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010102302811A CN101898867B (en) | 2010-07-19 | 2010-07-19 | Pyroceram-ceramic composite plate and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101898867A true CN101898867A (en) | 2010-12-01 |
| CN101898867B CN101898867B (en) | 2012-02-01 |
Family
ID=43224849
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2010102302811A Expired - Fee Related CN101898867B (en) | 2010-07-19 | 2010-07-19 | Pyroceram-ceramic composite plate and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101898867B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102643024A (en) * | 2012-04-10 | 2012-08-22 | 中原工学院 | Magnesium oxide (MgO)-silicon dioxide (SiO2)-aluminum oxide (Al2O3)-boron trioxide (B2O3)-potassium fluoride (KF) glass ceramic composite material adopting silicon carbide (SiC) as enhanced-phase and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1884206A (en) * | 2006-07-10 | 2006-12-27 | 中国地质大学（武汉） | Process for preparing microcrystal glass-ceramic compounded plate |
| CN1974456A (en) * | 2006-12-11 | 2007-06-06 | 巫汉生 | Etched microcrystalline glass plate and its production process |
| CN1974455A (en) * | 2006-12-11 | 2007-06-06 | 佛山欧神诺陶瓷有限公司 | Integrally crystallization process microcrystaline glass-ceramic composite brick and its production process |
-
2010
- 2010-07-19 CN CN2010102302811A patent/CN101898867B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1884206A (en) * | 2006-07-10 | 2006-12-27 | 中国地质大学（武汉） | Process for preparing microcrystal glass-ceramic compounded plate |
| CN1974456A (en) * | 2006-12-11 | 2007-06-06 | 巫汉生 | Etched microcrystalline glass plate and its production process |
| CN1974455A (en) * | 2006-12-11 | 2007-06-06 | 佛山欧神诺陶瓷有限公司 | Integrally crystallization process microcrystaline glass-ceramic composite brick and its production process |
Non-Patent Citations (1)
| Title |
|---|
| 《陶瓷学报》 20010930 李玉平等 微晶玻璃/陶瓷复合墙地砖的研制 全文 1-3 第22卷, 第3期 2 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102643024A (en) * | 2012-04-10 | 2012-08-22 | 中原工学院 | Magnesium oxide (MgO)-silicon dioxide (SiO2)-aluminum oxide (Al2O3)-boron trioxide (B2O3)-potassium fluoride (KF) glass ceramic composite material adopting silicon carbide (SiC) as enhanced-phase and preparation method thereof |
| CN102643024B (en) * | 2012-04-10 | 2014-04-02 | 中原工学院 | Magnesium oxide (MgO)-silicon dioxide (SiO2)-aluminum oxide (Al2O3)-boron trioxide (B2O3)-potassium fluoride (KF) glass ceramic composite material adopting silicon carbide (SiC) as enhanced-phase and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101898867B (en) | 2012-02-01 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101591144B (en) | Thin-type CaO-Al2O3-SiO2 system glass ceramics and preparation | |
| CN101066837B (en) | Environment friendly heat resistant opal crystalline glass and its preparation process | |
| CN105130196B (en) | Process for the preparation of a ceramic glass plate, plate obtained by this process and its use | |
| CN102531397B (en) | Milky white glass ceramic suitable for all electric melting and preparation process for milky white glass ceramic | |
| CN107032621B (en) | Green glass ceramics and preparation method and application thereof | |
| CN102050581A (en) | MgO-Al2O3-SiO2-based crystallizable glass and crystallized glass, and manufacturing method thereof | |
| CN106810079A (en) | The method that mica glass ceramic is prepared using granite waste residues | |
| CN102173592A (en) | CaO-MgO-Al2O3-SiO2 microcrystalline glass and preparation method thereof | |
| CN103755143B (en) | A kind of devitrified glass and preparation method thereof | |
| CN105236747A (en) | Mechanical force arm | |
| CN105060718A (en) | Glass door made of devitrified glass | |
| CN101898867B (en) | Pyroceram-ceramic composite plate and preparation method thereof | |
| CN103663967A (en) | Preparation method for jade-like microcrystalline glass | |
| CN103739202B (en) | A kind of devitrified glass and production method thereof | |
| CN102515868A (en) | Lead-free transparent bone china frit and preparation method thereof | |
| CN113354288B (en) | Microcrystalline glass plate and preparation method thereof | |
| CN101186444B (en) | Low-cost microcrystalline glass material and preparing technique thereof | |
| CN107698159A (en) | A kind of pottery hacking sky blue glaze and preparation method thereof | |
| CN110104948A (en) | It is the heat-resistant opal glass and preparation method thereof of raw material preparation using recessed soil | |
| CN104030567B (en) | Si-Al-Ca microcrystalline glass in series prepared by Low-silica iron ore tailings and method | |
| CN102617036A (en) | Production method of microcrystalline glass adhering material for indoor decoration | |
| CN108675642A (en) | A kind of polycrystalline phase devitrified glass | |
| CN103896487A (en) | Neodymium oxide-containing colored glass ceramics | |
| CN115259678B (en) | Semitransparent foam jade glass manufacturing process | |
| CN104556706A (en) | Novel glass ceramic |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20120201 |