CN101898059B - Corrosion-resisting and heat-resisting compound filter material and preparation method thereof - Google Patents

Corrosion-resisting and heat-resisting compound filter material and preparation method thereof Download PDF

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Publication number
CN101898059B
CN101898059B CN 201010238714 CN201010238714A CN101898059B CN 101898059 B CN101898059 B CN 101898059B CN 201010238714 CN201010238714 CN 201010238714 CN 201010238714 A CN201010238714 A CN 201010238714A CN 101898059 B CN101898059 B CN 101898059B
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filter
fibre
base cloth
felt
filter felt
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CN101898059A (en
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王爱民
杨福良
孙月芹
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JIANGSU FITTOW FILTER MEDIA CO Ltd
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JIANGSU FITTOW FILTER MEDIA CO Ltd
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Abstract

The invention relates to a corrosion-resisting and heat-resisting compound filter material and a preparation method thereof. The compound filter material comprises a base fabric and filter felts, wherein the upper surface and the lower surface of the base fabric are both coated with the filter felts, and the surface of an upper filter layer of the upper surface is coated with a polytetrafluoroethylene membrane; the base fabric is impregnated with an impregnating liquid; the filter felts on the upper surface are all prepared by mixing chemical polyester fiber, glass fiber, polyphenylene sulfide fiber, polyarmide fiber and polytetrafluoroethylene fiber; the filter felt on the lower surface is prepared by mixing chemical polyester fiber, glass fiber, polyphenylene sulfide fiber and polyarmide fiber; and the lengths of all the fiber materials ranges from 60 to 70 mm. The preparation method comprises the following steps of: weaving the glass fiber into a woven base fabric; impregnating the woven base fabric, drying for use; making the filter felts on the upper surface and the lower surface, and coating the filter felts on the upper surface and the lower surface to form a compound filter felt; impregnating once again, and drying; and finally, coating the polytetrafluoroethylene membrane on the surface of the upper filter layer.

Description

Corrosion-resisting and heat-resisting compound filter material and preparation method thereof
Technical field
The present invention relates to a kind of filtering material and preparation method thereof, especially a kind of corrosion-resisting and heat-resisting compound filter material that purifies for coal-burning boiler and flue gas of garbage furnace and preparation method thereof.
Background technology
The present filtering material that uses at the flue gas purification system of coal-burning boiler and incinerator mainly is polyphenylene sulfide (PPS) Nomex, or polytetrafluoroethylene (PTFE) (PTFE) fiber needled felt, or adopt glass fibre to cover the filtrate of poly tetrafluoroethylene, wherein, the oxidation resistent susceptibility of PPS Nomex is bad, can't adapt to the filtration environment under the high oxygen condition, and do not have water repellency, under low temperature or the condition of high temperature, move, very easily cause sticking with paste bag, affect the effect of gas cleaning.Be generally 1~2 year the normal service life of PPS Nomex.Although the PTFE Nomex has water repellency, oxidation resistent susceptibility, its price is higher, and is also very high to the requirement of equipment for after-treatment, increased the operating cost of enterprise, affected its promoting the use of in the general enterprise of profitability.Be generally 3 years the normal service life of PTFE Nomex.The base material that glass fibre covers the polytetrafluoroethylene (PTFE) film filtering material is glass fibre, and its folding resistance is relatively poor, should not use under the high wind speed state, especially in running, after being adhered to by oil droplet etc., also causes easily filter bag to lose efficacy.
The raw material that How to choose is suitable is made Nomex, and they are combined into the filtering material of new corrosion-resistant and high-temperature resistant, to adapt to the specific environment for use of coal-burning boiler and flue gas of garbage furnace cleaning system, is the long-term major subjects of paying close attention in this area always.
Summary of the invention
The object of the invention is to: for the problem that the main filtering material that generally uses in present coal-burning boiler and the flue gas of garbage furnace gas cleaning exists, proposes filtering material of a kind of corrosion-resistant and high-temperature resistant by multiple fiber composite making and preparation method thereof.
The object of the present invention is achieved like this: a kind of corrosion-resisting and heat-resisting compound filter material, comprise base cloth and filter felt, it is characterized in that: the upper and lower surface of base cloth all is covered with filter felt, wherein: the filter felt that is overlying on upper surface is the upper filter course of dust-collecting face, and the filter felt that is overlying on lower surface is lower filter course; Surface at upper filter course is covered with poly tetrafluoroethylene; Described base cloth is through the maceration extract impregnation process; The filter felt of described upper filter course is to make after evenly being mixed by every square metre of 55-65g, 45-55g, 40-50g, 35-45g and 30-40g respectively by terylene chemical fibre, glass fibre, polyphenylene sulfide fibre, Fypro and polytetrafluoroethylene fibre; The filter felt of described lower filter course is to make after evenly being mixed by every square metre of 55-65g, 45-55g, 40-50g and 35-45g respectively by terylene chemical fibre, glass fibre, polyphenylene sulfide fibre and Fypro; The length of the various fibrous materials in upper filter course and the lower filter course is 60-70mm.
In the present invention: described base cloth is glass fiber weaving cloth, and the weight per unit area of base cloth is 300g/m 2
In the present invention: described maceration extract is comprised of ptfe emulsion, 285-1 polymethylphenyl siloxane fluid emulsion and water, and their weight ratio is 12: 4: 59.
In the present invention: the specification of described terylene chemical fibre is 2.5d-2.8d, the specification of glass fibre is 5d-7d, the specification of polyphenylene sulfide fibre is 2d-2.5d, the specification of Fypro is 5d-7d, the specification of polytetrafluoroethylene fibre is 5d-7d, the length of described fibrous material is 60mm-70mm, is overlying on base cloth upper surface and lower surface and is respectively 220-230g/m as the weight per unit area of the filter felt of filter course 2And 190-200g/m 2
A kind of preparation method of above-mentioned composite filtering material is characterized in that: the maceration extract of base cloth is comprised of ptfe emulsion, 285-1 polymethylphenyl siloxane fluid emulsion and water, and their weight ratio is 12: 4: 59, and the preparation process of composite filtering material is:
A) fiberglass weaving is become woven fabric, as the base cloth of composite filtering material, the weight per unit area of base cloth is 300g/m 2
B) base cloth is immersed in carries out impregnation process in the maceration extract, drain maceration extract again, drying is for subsequent use after processing;
C) terylene chemical fibre, glass fibre, polyphenylene sulfide fibre, Fypro and polytetrafluoroethylene fibre are evenly made filter felt after the mixing by every square metre of 55-65g, 45-55g, 40-50g, 35-45g and 30-40g respectively, as upper filter course, the weight per unit area of upper filter felt is 220-230g/m 2Terylene chemical fibre, glass fibre, polyphenylene sulfide fibre and Fypro are evenly made filter felt after the mixing by every square metre of 55-65g, 45-55g, 40-50g and 35g-45g respectively, as lower filter course, the weight per unit area of lower filter felt is 190-200g/m 2
D) filter felt as upper and lower filter course that the c step is obtained is overlying on respectively the upper and lower surface of the base cloth for subsequent use of b step acquisition, forms composite filter felt;
E) composite filter felt that the d step is obtained drains ptfe emulsion again through behind the dipping of ptfe emulsion, and drying is processed;
F) adopt conventional method filter course surface on the composite filter felt after the end of process e step to carry out overlay film with polytetrafluoroethylene (PTFE) and process, finally form corrosion-resisting and heat-resisting compound filter material, the weight per unit area of composite filtering material is 760-800g/m 2
In the preparation method of filtering material: in the c step, the specification of described terylene chemical fibre is 2.5d-2.8d, the specification of glass fibre is 5d-7d, the specification of polyphenylene sulfide fibre is 2d-2.5d, the specification of Fypro is 5d-7d, the specification of polytetrafluoroethylene fibre is 5d-7d, and the length of described fibrous material is 60mm-70mm.
In the preparation method of filtering material: drying described in b step and the e step is processed and is referred to: air-dry or naturally dry or dry through baking device; The method of making upper and lower filter felt in the c step is needle point method; The d step is needle point method with the method that the filter felt of upper and lower filter course is overlying on respectively the upper and lower surface of base cloth for subsequent use.
The invention has the advantages that: because the terylene chemical fibre has very strong coherent, glass fibre has resistant to elevated temperatures characteristics, polyphenylene sulfide fibre has stronger corrosion-resistant, resistant to elevated temperatures performance, in as filter course, use simultaneously four kinds or five kinds of fibers in terylene chemical fibre, glass fibre, polyphenylene sulfide fibre, Fypro and the polytetrafluoroethylene fibre, both can remedy the deficiency in the use of PPS Nomex, can avoid again the PTFE Nomex to the exigent drawback of equipment for after-treatment, reduce the enterprise operation cost; Estimate service life of the present invention can reach more than 3 years.
Description of drawings:
Fig. 1 is the section structure schematic diagram of the embodiment of the invention
Among the figure: 1, base cloth, 2, upper filter course, 3, lower filter course, 4, poly tetrafluoroethylene.
The specific embodiment
As seen from Figure 1, section structure of the present invention is all to cover filter felt on the upper and lower surface of base cloth 1, and wherein: the filter felt that is overlying on upper surface is the upper filter course 2 of dust-collecting face, and the filter felt that is overlying on lower surface is lower filter course 3; Be covered with poly tetrafluoroethylene 4 on the surface of upper filter course.
The filter felt of upper filter course 2 is to make after evenly being mixed by every square metre of 55-65g, 45-55g, 40-50g, 35-45g and 30-40g respectively by terylene chemical fibre, glass fibre, polyphenylene sulfide fibre, Fypro and polytetrafluoroethylene fibre.The filter felt of lower filter course 3 is to make after evenly being mixed by every square metre of 55-65g, 45-55g, 40-50g and 35-45g respectively by terylene chemical fibre, glass fibre, polyphenylene sulfide fibre and Fypro; The length of the various fibrous materials in upper filter course 2 and the lower filter course 3 is 60mm-70mm.
Embodiment 1
The preparation of maceration extract
Ptfe emulsion (Guangzhou pine and cypress chemical industry Co., Ltd provides), 285-1 polymethylphenyl siloxane fluid emulsion (Jiangyin double heroes new material Co., Ltd provides) and water are mixed according to 12: 4: 59 weight ratio, and it is rear for subsequent use to stir.
Embodiment 2
The preparation of corrosion-resisting and heat-resisting compound filter material
1) processing of base cloth:
Base cloth is by glass fiber weaving cloth (cooperation processing), and the weight per unit area of base cloth is 300g/m 2
Place the maceration extract of embodiment 1 to flood base cloth, after base cloth soaks into fully, drain again maceration extract, through air-dry or for subsequent use after the baking device oven dry.
2) making of upper and lower filter course:
The polytetrafluoroethylene fibre of selecting specification is the terylene chemical fibre of 2.5d-2.8d, glass fibre that specification is 5d-7d, specification is 2d-2.5d polyphenylene sulfide fibre, Fypro that specification is 5d-7d and specification to be 5d-7d is got the raw materials ready by every square metre of 55-65g, 45-55g, 40-50g, 35-45g and 30-40g respectively, they are evenly made filter felt with needle point method or other method after the mixing, as upper filter course, the weight per unit area of filter felt is 220-230g/m 2The Fypro of selecting specification is the terylene chemical fibre of 2.5d-2.8d, glass fibre that specification is 5d-7d, specification is 2d-2.5d polyphenylene sulfide fibre and specification to be 5d-7d is got the raw materials ready by every square metre of 55-65g, 45-55g, 40-50g and 35-45g respectively, they are evenly made filter felt with needle point method or other method after the mixing, as lower filter course, the weight per unit area of filter felt is 190-200g/m 2The length of selected fibrous material is 60mm-70mm.
3, the preparation of composite filtering material
The filter felt as upper and lower filter course of having made is overlying on respectively through the upper and lower surface of base cloth air-dry or after the baking device oven dry, by needle point method or other method they is integrated, form composite filter felt.
With composite filter felt through maceration extract (embodiment 1 provides) dipping after (dipping method is with the processing of 1 base cloth of embodiment 2), drain again maceration extract, through air-dry or naturally dry or dry through baking device.
Utilizing traditional technique is dust-collecting face carries out the overlay film processing with polytetrafluoroethylene (PTFE) (Guangzhou pine and cypress chemical industry Co., Ltd provides) after, finally to form corrosion-resisting and heat-resisting compound filter material on the filter felt surface of upper filter course.The weight per unit area of corrosion-resisting and heat-resisting compound filter material is 760g/m 2-800g/m 2
Embodiment 3
The present invention's (embodiment 2 provides) contrasts with the result of use of PPS Nomex and PTFE Nomex filtering material:
Filtering material Specification Service time Filter efficiency Continue heatproof Moment heatproof Unit cost
The present invention ¢130×2450 36 months 99.8% 270℃ 280℃ 98 yuan
The PPS filtrate ¢130×2450 18 months 99.8% 190℃ 220℃ 140 yuan
The PTFE filtrate ¢130×2450 36 months 99.8% 200℃ 230℃ 327 yuan

Claims (5)

1. corrosion-resisting and heat-resisting compound filter material, comprise base cloth and filter felt, it is characterized in that: the upper and lower surface of base cloth all is covered with filter felt, and wherein: the filter felt that is overlying on upper surface is the upper filter course of dust-collecting face, and the filter felt that is overlying on lower surface is lower filter course; Surface at upper filter course is covered with poly tetrafluoroethylene; Described base cloth is through the maceration extract impregnation process; The filter felt of described upper filter course is to make after evenly being mixed by every square metre of 55-65g, 45-55g, 40-50g, 35-45g and 30-40g respectively by terylene chemical fibre, glass fibre, polyphenylene sulfide fibre, Fypro and polytetrafluoroethylene fibre; The filter felt of described lower filter course is to make after evenly being mixed by every square metre of 55-65g, 45-55g, 40-50g and 35-45g respectively by terylene chemical fibre, glass fibre, polyphenylene sulfide fibre and Fypro; The length of the various fibrous materials in upper filter course and the lower filter course is 60-70mm;
Described base cloth is glass fiber weaving cloth, and the weight per unit area of base cloth is 300g/m 2
Described maceration extract is comprised of ptfe emulsion, 285-1 polymethylphenyl siloxane fluid emulsion and water, and their weight ratio is 12: 4: 59.
2. corrosion-resisting and heat-resisting compound filter material according to claim 1, it is characterized in that: the specification of described terylene chemical fibre is 2.5d-2.8d, the specification of glass fibre is 5d-7d, the specification of polyphenylene sulfide fibre is 2d-2.5d, the specification of Fypro is 5d-7d, the specification of polytetrafluoroethylene fibre is 5d-7d, and the length of described fibrous material is 60-70mm, is overlying on base cloth upper surface and lower surface and is respectively 220-230g/m as the weight per unit area of the filter felt of filter course 2And 190-200g/m 2
3. preparation method of composite filtering material as claimed in claim 1, it is characterized in that: the maceration extract of base cloth is comprised of ptfe emulsion, 285-1 polymethylphenyl siloxane fluid emulsion and water, and their weight ratio is 12: 4: 59, and the preparation process of composite filtering material is:
A) fiberglass weaving is become woven fabric, as the base cloth of composite filtering material, the weight per unit area of base cloth is 300g/m 2
B) base cloth is immersed in carries out impregnation process in the maceration extract, drain maceration extract again, drying is for subsequent use after processing;
C) terylene chemical fibre, glass fibre, polyphenylene sulfide fibre, Fypro and polytetrafluoroethylene fibre are evenly made filter felt after the mixing by every square metre of 55-65g, 45-55g, 40-50g, 35-45g and 30-40g respectively, as upper filter course, the weight per unit area of upper filter felt is 220-230g/m 2Terylene chemical fibre, glass fibre, polyphenylene sulfide fibre and Fypro are evenly made filter felt after the mixing by every square metre of 55-65g, 45-55g, 40-50g and 35g-45g respectively, as lower filter course, the weight per unit area of lower filter felt is 190-200g/m 2
D) filter felt as upper and lower filter course that the c step is obtained is overlying on respectively the upper and lower surface of the base cloth for subsequent use of b step acquisition, forms composite filter felt;
E) composite filter felt that the d step is obtained drains ptfe emulsion again through behind the dipping of ptfe emulsion, and drying is processed;
F) adopt conventional method filter course surface on the composite filter felt after the end of process e step to carry out overlay film with polytetrafluoroethylene (PTFE) and process, finally form corrosion-resisting and heat-resisting compound filter material, the weight per unit area of composite filtering material is 760-800g/m 2
4. the preparation method of composite filtering material according to claim 3, it is characterized in that: in the c step, the specification of described terylene chemical fibre is 2.5d-2.8d, the specification of glass fibre is 5d-7d, the specification of polyphenylene sulfide fibre is 2d-2.5d, the specification of Fypro is 5d-7d, and the specification of polytetrafluoroethylene fibre is 5d-7d, and the length of described fibrous material is 60-70mm.
5. the preparation method of composite filtering material according to claim 3 is characterized in that: the drying described in b step and the e step is processed and is referred to: air-dry or naturally dry or dry through baking device; The method of making upper and lower filter felt in the c step is needle point method; The d step is needle point method with the method that the filter felt of upper and lower filter course is overlying on respectively the upper and lower surface of base cloth for subsequent use.
CN 201010238714 2010-07-28 2010-07-28 Corrosion-resisting and heat-resisting compound filter material and preparation method thereof Expired - Fee Related CN101898059B (en)

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CN102995498B (en) * 2012-10-31 2015-10-07 蚌埠首创滤清器有限公司 A kind of corrosion-and high-temp-resistant filter paper of filter and preparation method thereof
CN103691201B (en) * 2013-11-25 2015-08-12 盐城工学院 The manufacture method of chimney exhaust gas dust removal and filtration cloth
CN105365305A (en) * 2014-08-27 2016-03-02 徐珂 Glass fiber and polyester composite needle-punched felt and manufacturing method thereof
CN105625042A (en) * 2014-11-04 2016-06-01 厦门三维丝环保股份有限公司 High temperature resistant filter cartridge substrate filter material stiffening finishing method
CN105709503A (en) * 2014-12-05 2016-06-29 东丽纤维研究所(中国)有限公司 Base cloth with high gram weight and filter felt made of same
CN104674452B (en) * 2015-01-14 2017-09-26 上海特安纶纤维有限公司 The filtering material and its manufacture method of a kind of blending fiber type containing polyimide fiber and containing sulfuryl
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CN106215526A (en) * 2016-08-31 2016-12-14 何县香 A kind of composite filter felt
CN107627699A (en) * 2017-09-30 2018-01-26 张延青 The explosion-proof composite filtering material of coal industry anti-corrosion and its production technology
CN108261838B (en) * 2018-02-05 2020-08-14 安徽元琛环保科技股份有限公司 Special filter material for waste incineration and preparation method and application thereof

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