CN101892117B - Water-based lubricant for drawing processing of brass-plated steel wire and preparation method thereof - Google Patents
Water-based lubricant for drawing processing of brass-plated steel wire and preparation method thereof Download PDFInfo
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Abstract
The invention relates to a water-based lubricant for metal pressure processing. The water-based lubricant for drawing processing of a brass-plated steel wire comprises the following components by weight percent: 10-25% of oiliness agent, 3-10% of phosphorus-containing extreme pressure agent, 3-8% of mineral oil, 3-6% of assistant emulsifier, 1-5% of rust inhibitor, 1-3% of mildew inhibitor, 0.1-0.3% of defoamer and the balance of water, wherein the oiliness agent is polyamide-epoxyethane-epoxypropane copolymer with the following general formula, wherein R and R' are straight chain alkyl with 11-21 carbon atoms or straight chain alkenyl containing one double-bond, m1 and m2 are integers from 1 to 8, n1 and n2 are integers from 0 to 8, m1 plus m2 plus n1 plus n2 is not more than 16; and the molecular weight of the water-based lubricant is 800-1500, and the melting point is 100-150 DEG C. The water-based lubricant has excellent lubrication performance, good corrosion resistance and good rust resistance; furthermore, the water-based lubricant can realize fast drawing speed and less surface residue by being used for drawing processing of the brass-plated steel wire.
Description
Technical field
The present invention relates to water-based lubricant for metal pressure processing, be specifically related to a kind of water base lubricant of processing usefulness for the brass-plated steel wire drawing and preparation method thereof.
Background technology
Brass-plated steel wire generally is used for doughnut and the framework material of high-pressure rubber pipe and the cutting of silicon chip, and its coating is thin, and wire diameter is thin
Intensity is high.Its production technique is that galvanizing first and drawing afterwards pulls out, and drawing is finished in water tank drawbench.For normal drawing, must add water base lubricant in the water tank.Water base lubricant has the effects such as good lubricated, cooling, cleaning.It mainly is comprised of oiliness improver, extreme pressure agent, emulsifying agent, sanitas, rust-preventive agent etc.Oiliness improver has wettability, can be adsorbed on Steel Wire Surface and play lubrication, reduces drawing force, reduces the loss of mould.Extreme pressure agent is the additive that prevents steel wire and mould adhesion in the steel wire drawing process, and extreme pressure agent is generally the compound that contains S, P, Cl isoreactivity element.But the lubricant drawing residue that uses on the existing market is more, can affect the quality of Steel Wire Surface, makes steel wire and rubber adhesion bad, is difficult to reach the production requirement of qualified steel wire.
Ro92148 has introduced a kind of water-base metal lubricant, and filling a prescription is:
Stearylamide oxirane compound 17%
Polyoxyethylene nonylphenol ether phosphoric acid ester ethanolamine salt 20.5%
Clorafin 7.5%
Mineral oil 6%
Silicon defoaming agent 2.5%
Trolamine 6%
Water surplus
This water-base metal lubricant adopts the stearylamide oxirane compound to make oiliness improver, and its molecular weight is little, and oilness is inadequate, and this lubricant is chloride, is corrosive, and is not suitable for the high speed drawing of brass-plated steel wire.
Summary of the invention
Technical problem to be solved by this invention provides water base lubricant of a kind of brass-plated steel wire drawing processing usefulness and preparation method thereof.This preparation method is easy, and the Lubricity of Water-Based Lubricants that obtains is good, and antiseptic and rustproof property is good, and is residual few, can satisfy the high speed drawing of brass-plated steel wire.
The technical problem that proposes in order to solve the present invention, the technical solution adopted in the present invention is:
A kind of water base lubricant of brass-plated steel wire drawing processing usefulness, it is characterized in that: it consists of by weight percentage:
Oiliness improver 10～25%
Phosphorous extreme pressure agent 3～10%
Mineral oil 3～8%
Assistant for emulsifying agent 3～6%
Rust-preventive agent 1～5%
Mould inhibitor 1～3%
Defoamer 0.1～0.3%
Water surplus;
Described oiliness improver is polymeric amide-PEP-101, and its general formula is
Wherein, R, R ' are that carbonatoms is the straight chained alkyl of 11-21 or the straight-chain alkenyl that contains two keys, m
1, m
2Be the integer between the 1-8, n
1, n
2Be the integer between the 0-8, and m
1+ m
2+ n
1+ n
2≤ 16;
Its molecular weight is 800-1500, and fusing point is 100-150 ℃.
Press such scheme, described oiliness improver is the two erucicamide-PEP-101 of ethylene or ethylene bis stearamide-PEP-101.
Press such scheme, the content of described oiliness improver is preferably 12.5～22.5% (weight percentage).
Press such scheme, described phosphorous extreme pressure agent is a kind of in emulsible phosphorous acid diester amine salt, the Tritolyl Phosphate, and its content is preferably 5.0～8.0% (weight percentage).
Press such scheme, described mineral oil is a kind of in 7# white oil, 10# white oil, the 20# white oil, and its content is preferably 3.0～5.0% (weight percentage).
Press such scheme, described assistant for emulsifying agent is diethanolamine, trolamine, C
12The mixture of one or both in aliphatic amine polyoxyethylene (10) ether, polyoxyethylene glycol (400) monoleate, glycol ether, the ethanol, its content is preferably 3.5～5.5% (weight percentage).
Press such scheme, described rust-preventive agent is the 5-methyl benzotriazazole, benzotriazole, the mixture of one or more in phosphorylethanolamine salt, nitranol salt, boric acid ethanolamine salt, Sodium orthomolybdate or the potassium molybdate, its content are preferably 3.0～5.0% (weight percentage).
Press such scheme, described mould inhibitor is hexahydro--1,3,5 three (hydroxyethyl)-s-triazine, 1, the mixture of one or both in 2-benzisothiazole-3-ketone, Kathon, (2-pyridine mercapto alcohol-1-oxide compound) sodium, its content is preferably 1.0～2.0% (weight percentage).
Press such scheme, described defoamer is silicone antifoam agent, and its content is preferably 0.1～0.2% (weight percentage).
Press such scheme, the preparation method of the water base lubricant of described brass-plated steel wire drawing processing usefulness is: oiliness improver and phosphorous extreme pressure agent, mineral oil, assistant for emulsifying agent are warming up to 90～120 ℃, the water that under constantly stirring, adds 90～100 ℃, then be cooled to below 40 ℃, add mould inhibitor, rust-preventive agent, defoamer, stirring namely gets product again.
Polymeric amide is a kind of preferably solid lubricant, and lubricity is good, and it is residual few to rub, but because of its poorly water-soluble, directly makes the water base lubricant poor stability with polyamide ligand, and work-ing life is short.By polymeric amide and oxyethane and propylene oxide are carried out polyreaction, generate the strong multipolymer of wetting ability, be re-dubbed again water base lubricant, its stability can improve greatly, and oilness is good, be used for the drawing of brass-plated steel wire, the remained on surface amount is few, thereby is applicable to the high speed drawing of brass-plated steel wire fully.
Beneficial effect of the present invention:
(1) Lubricity of Water-Based Lubricants provided by the invention is good, is used for the drawing processing of brass-plated steel wire, and drawing speed is fast, and the remained on surface amount is few.
(2) preparation method's simple process of this water base lubricant.
Embodiment:
At first the common oiliness improver that adopts of various embodiments of the present invention being done some specifies: described oiliness improver polymeric amide-PEP-101 adopts following preparation method to obtain: in withstand voltage reactor, add polymeric amide, add KOH or NaOH catalyzer, the usage quantity of catalyzer is 0.3～0.5% (weight percentage) of polymeric amide weight, at 150～180 ℃, under the pressure of 1～3atm, add oxyethane, the usage quantity of oxyethane is the 20%-120% (weight percentage) of polymeric amide weight, slaking reaction 0.5-1 hour, add again propylene oxide, the usage quantity of propylene oxide is the 0-155% (weight percentage) of polymeric amide weight, slaking reaction 0.5-1 hour, namely get polymeric amide-PEP-101.The below provides the concrete preparation method of the two erucicamide-PEP-101 of ethylene and ethylene bis stearamide-PEP-101.
The preparation of the two erucicamide-PEP-101 of ethylene: in withstand voltage reactor, add the two erucicamides of ethylene, add KOH or NaOH catalyzer, the usage quantity of catalyzer is the 0.3-0.5% (weight percentage) of the two erucicamide weight of ethylene, at 150-180 ℃, 2.5-3atm under the pressure, add oxyethane, the usage quantity of oxyethane is 37.7% (weight percentage) of the two erucicamide weight of ethylene, slaking reaction half an hour, add again propylene oxide, the usage quantity of propylene oxide is 49.7% (weight percentage) of the two erucicamide weight of ethylene, slaking reaction half an hour, namely gets the two erucicamide-PEP-101 of ethylene, fusing point 100-120 ℃, molecular formula is as follows:
The preparation of ethylene bis stearamide-PEP-101:
In withstand voltage reactor, add ethylene bis stearamide, add KOH or NaOH catalyzer, the usage quantity of catalyzer is the 0.3-0.5% (weight percentage) of ethylene bis stearamide weight, at 150-180 ℃, 1.5-2.5atm under the pressure, add oxyethane, the usage quantity of oxyethane is 58.7% (weight percentage) of ethylene bis stearamide weight, slaking reaction half an hour, add again propylene oxide, the usage quantity of propylene oxide is 38.7% (weight percentage) of ethylene bis stearamide weight, slaking reaction half an hour, namely gets ethylene bis stearamide-PEP-101, fusing point 130-150 ℃, molecular formula is as follows:
Embodiment 1
Press respectively each component concentration in the table 1, two erucicamide-the PEP-101 of ethylene, di-n-butyl phosphite amine salt, 10# white oil, polyoxyethylene glycol (400) monoleate and diethanolamine are mixed, be warming up to 90～120 ℃, the water that under constantly stirring, adds 90～100 ℃, then be cooled to below 40 ℃, add again hexahydro--1,3,5 three (hydroxyethyl)-s-triazine, phosphorylethanolamine salt, 5-methyl benzotriazazole and silicon defoaming agent, stirring namely gets product.
Table 1
| Component | Content (weight percentage %) |
| Two erucicamide-the PEP-101 of ethylene | 17.5 |
| The di-n-butyl phosphite amine salt | 6.0 |
| The 10# white oil | 3.0 |
| Polyoxyethylene glycol (400) monoleate | 3.5 |
| Diethanolamine | 1.0 |
| Phosphorylethanolamine salt | 2.5 |
| The 5-methyl benzotriazazole | 0.20 |
| Silicon defoaming agent | 0.10 |
| Hexahydro--1,3,5 three (hydroxyethyl)-s-triazine | 1.5 |
| Water | Surplus |
The brass-plated steel wire drawing processing water base lubricant of present embodiment, for the high speed drawing of high-pressure rubber pipe weaving wire, its application result is as follows:
Drawing wires: 72A brass plating steel wire
Wire drawing type: TB4 water tank
Inlet wire diameter: 1.35mm
Finished silk diameter: 0.3 ± 0.01mm
Core rod material: carbon tungsten alloy
The working concentration of water base lubricant (wt%): 8.0-12.0
Drawing speed (m/s): 10-18
Embodiment 2
Each component of pressing respectively in the table 2 is mixed ethylene bis stearamide-PEP-101, Tritolyl Phosphate, 20# white oil, polyoxyethylene glycol (400) monoleate and diethanolamine, be warming up to 90～120 ℃, the water that under constantly stirring, adds 90～100 ℃, then be cooled to below 40 ℃, add again hexahydro--1,3,5 three (hydroxyethyl)-s-triazine, phosphorylethanolamine salt, 5-methyl benzotriazazole and silicon defoaming agent stir and get final product.
Table 2
| Component | Content (weight percentage %) |
| Ethylene bis stearamide-PEP-101 | 10.0 |
| Tritolyl Phosphate | 8.5 |
| The 20# white oil | 8.0 |
| Polyoxyethylene glycol (400) monoleate | 4.5 |
| Diethanolamine | 1.5 |
| Phosphorylethanolamine salt | 2.5 |
| The 5-methyl benzotriazazole | 0.30 |
| Silicon defoaming agent | 0.10 |
| Hexahydro--1,3,5 three (hydroxyethyl)-s-triazine | 1.5 |
| Water | Surplus |
The brass-plated steel wire drawing processing water base lubricant of present embodiment, for the high speed drawing of high-pressure rubber pipe weaving wire, its application result is as follows:
Drawing wires: 72A brass plating steel wire
Wire drawing type: TB4 water tank
Inlet wire diameter: 1.35mm
Finished silk diameter: 0.3 ± 0.01mm
Core rod material: carbon tungsten alloy
The working concentration of water base lubricant (wt%): 8.0-12.0
Drawing speed (m/s): 10-18
Embodiment 3
Each component of pressing respectively in the table 3 is mixed the two erucicamide-PEP-101 of ethylene, di-n-butyl phosphite amine salt, 7# white oil, polyoxyethylene glycol (400) monoleate and diethanolamine, be warming up to 90～120 ℃, the water that under constantly stirring, adds 90～100 ℃, then be cooled to below 40 ℃, add again hexahydro--1,3,5 three (hydroxyethyl)-s-triazine, (2-pyridine mercapto alcohol-1-oxide compound) sodium, phosphorylethanolamine salt, benzotriazole and silicon defoaming agent stir and get final product.
Table 3
| Component | Content (weight percentage %) |
| Two erucicamide-the PEP-101 of ethylene | 25 |
| The di-n-butyl phosphite amine salt | 3.5 |
| The 7# white oil | 3.0 |
| Polyoxyethylene glycol (400) monoleate | 3.0 |
| Diethanolamine | 1.0 |
| Phosphorylethanolamine salt | 3.5 |
| Benzotriazole | 0.20 |
| Silicon defoaming agent | 0.15 |
| Hexahydro--1,3,5 three (hydroxyethyl)-s-triazine | 1.0 |
| (2-pyridine mercapto alcohol-1-oxide compound) sodium | 0.2 |
| Water | Surplus |
The brass-plated steel wire drawing processing water base lubricant of present embodiment, for the high speed drawing of high-pressure rubber pipe weaving wire, its application result is as follows:
Drawing wires: 72A brass plating steel wire
Wire drawing type: TB4 water tank
Inlet wire diameter: 1.35mm
Finished silk diameter: 0.3 ± 0.01mm
Core rod material: carbon tungsten alloy
The working concentration of water base lubricant (wt%): 8.0-12.0
Drawing speed (m/s): 10-18
Embodiment 4
Press respectively each component in the table 4 with ethylene bis stearamide-PEP-101, di-n-butyl phosphite amine salt, 10# white oil, C
12Aliphatic amine polyoxyethylene (10) ether and trolamine mix, be warming up to 90～120 ℃, the water that under constantly stirring, adds 90～100 ℃, then be cooled to below 40 ℃, add again hexahydro--1,3,5 three (hydroxyethyl)-s-triazine, 1,2-benzisothiazole-3-ketone, phosphorylethanolamine salt, boric acid ethanolamine salt, 5-methyl benzotriazazole and silicon defoaming agent stir and get final product.
Table 4
| Component | Content (weight percentage %) |
| Two erucicamide-the PEP-101 of ethylene | 17.5 |
| The di-n-butyl phosphite amine salt | 5.5 |
| The 10# white oil | 4.0 |
| C 12Aliphatic amine polyoxyethylene (10) ether | 1.5 |
| Trolamine | 2.5 |
| Phosphorylethanolamine salt | 2.0 |
| The boric acid ethanolamine salt | 2.5 |
| The 5-methyl benzotriazazole | 0.30 |
| Silicon defoaming agent | 0.20 |
| Hexahydro--1,3,5 three (hydroxyethyl)-s-triazine | 1.0 |
| BIT | 0.25 |
| Water | Surplus |
The brass-plated steel wire drawing processing water base lubricant of present embodiment, for the high speed drawing of steel steel for tyre cord silk, its application result is as follows:
Drawing wires: 82A brass plating steel wire
Wire drawing type: TB4 water tank
Inlet wire diameter: 0.98mm
Finished silk diameter: 0.22 ± 0.01mm
Core rod material: carbon tungsten alloy
The working concentration of water base lubricant (wt%): 8.0-12.0
Drawing speed (m/s): 8-12
Steel wire is twisted the steel cord of 2+7 * 0.22, and the extraction power of rubber: the 608N/ root, and apparently higher than standard value (〉=500N/ root)
Embodiment 5
Press respectively each component in the table 5 with ethylene bis stearamide-PEP-101, di-n-butyl phosphite amine salt, 10# white oil, C
12Aliphatic amine polyoxyethylene (10) ether and trolamine mix, be warming up to 90～120 ℃, the water that under constantly stirring, adds 90～100 ℃, then be cooled to below 40 ℃, add again hexahydro--1,3,5 three (hydroxyethyl)-s-triazine, Kathon, phosphorylethanolamine salt, boric acid ethanolamine salt, 5-methyl benzotriazazole and silicon defoaming agent stir and get final product.
Table 5
| Component | Content (weight percentage %) |
| Two erucicamide-the PEP-101 of ethylene | 17.5 |
| The di-n-butyl phosphite amine salt | 5.5 |
| The 10# white oil | 3.0 |
| C 12Aliphatic amine polyoxyethylene (10) ether | 2.5 |
| Trolamine | 2.0 |
| Phosphorylethanolamine salt | 1.5 |
| The boric acid ethanolamine salt | 2.0 |
| The 5-methyl benzotriazazole | 0.15 |
| Silicon defoaming agent | 0.10 |
| Hexahydro--1,3,5 three (hydroxyethyl)-s-triazine | 1.0 |
| Kathon | 0.25 |
| Water | Surplus |
The brass-plated steel wire drawing processing water base lubricant of present embodiment, for the high speed drawing of steel steel for tyre cord silk, its application result is as follows:
Drawing wires: 82A brass plating steel wire
Wire drawing type: TB4 water tank
Inlet wire diameter: 1.25mm
Finished silk diameter: 0.25 ± 0.01mm
Core rod material: carbon tungsten alloy
The working concentration of water base lubricant (wt%): 8.0-12.0
Drawing speed (m/s): 8-12
Steel wire is twisted the steel cord of 2+2 * 0.25, and the extraction power of rubber: the 428N/ root, and apparently higher than standard value (〉=380N/ root)
Embodiment 6
Press respectively each component in the table 6 with ethylene bis stearamide-PEP-101, di-n-butyl phosphite amine salt, 10# white oil, C
12Aliphatic amine polyoxyethylene (10) ether and diethanolamine mix, be warming up to 90～120 ℃, the water that under constantly stirring, adds 90～100 ℃, then be cooled to below 40 ℃, add again hexahydro--1,3,5 three (hydroxyethyl)-s-triazine, Sodium orthomolybdate, 5-methyl benzotriazazole and silicon defoaming agent stir and get final product.
Table 6
| Component | Content (weight percentage %) |
| Ethylene bis stearamide-PEP-101 | 17.5 |
| The di-n-butyl phosphite amine salt | 5.5 |
| The 10# white oil | 4.0 |
| C 12Aliphatic amine polyoxyethylene (10) ether | 1.5 |
| Diethanolamine | 2.0 |
| Sodium orthomolybdate | 1.0 |
| The 5-methyl benzotriazazole | 0.30 |
| Silicon defoaming agent | 0.20 |
| Hexahydro--1,3,5 three (hydroxyethyl)-s-triazine | 2.0 |
| Water | Surplus |
The brass-plated steel wire drawing processing water base lubricant of present embodiment, for the high speed drawing of cutting steel wire, its application result is as follows:
Drawing wires: 82A brass plating steel wire
Wire drawing type: TB4 water tank
Inlet wire diameter: 0.90mm
Finished silk diameter: 0.09mm
Core rod material: carbon tungsten alloy
The working concentration of water base lubricant (wt%): 5.0-10.0
Drawing speed (m/s): 6-10
Claims (10)
1. the water base lubricant of usefulness is processed in a brass-plated steel wire drawing, and it is characterized in that: it consists of by weight percentage:
Oiliness improver 10～25%
Phosphorous extreme pressure agent 3～10%
Mineral oil 3～8%
Assistant for emulsifying agent 3～6%
Rust-preventive agent 1～5%
Mould inhibitor 1～3%
Defoamer 0.1～0.3%
Water surplus;
Described oiliness improver is polymeric amide-PEP-101, and its general formula is
Wherein, R, R ' are that carbonatoms is the straight chained alkyl of 11-21 or the straight-chain alkenyl that contains two keys, m
1, m
2Be the integer between the 1-8, n
1, n
2Be the integer between the 0-8.And m
1+ m
2+ n
1+ n
2≤ 16;
Its molecular weight is 800-1500, and fusing point is 100-150 ℃.
2. the water base lubricant of usefulness is processed in brass-plated steel wire drawing according to claim 1, it is characterized in that: described oiliness improver is the two erucicamide-PEP-101 of ethylene or ethylene bis stearamide-PEP-101.
3. the water base lubricant of usefulness is processed in brass-plated steel wire drawing according to claim 1, and it is characterized in that: the content of described oiliness improver is 12.5～22.5% (weight percentage).
4. the water base lubricant of usefulness is processed in brass-plated steel wire drawing according to claim 1, it is characterized in that: described phosphorous extreme pressure agent is a kind of in emulsible phosphorous acid diester amine salt, the Tritolyl Phosphate, and its content is 5.0～8.0% (weight percentage).
5. the water base lubricant of brass-plated steel wire drawing according to claim 1 processing usefulness is characterized in that: described mineral oil is a kind of in 7# white oil, 10# white oil, the 20# white oil, and its content is 3.0～5.0% (weight percentage).
6. the water base lubricant of usefulness is processed in brass-plated steel wire drawing according to claim 1, and it is characterized in that: described assistant for emulsifying agent is diethanolamine, trolamine, C
12The mixture of one or both in aliphatic amine polyoxyethylene (10) ether, polyoxyethylene glycol (400) monoleate, glycol ether, the ethanol, its content is 3.5～5.5% (weight percentage).
7. the water base lubricant of usefulness is processed in brass-plated steel wire drawing according to claim 1, it is characterized in that: described rust-preventive agent is the 5-methyl benzotriazazole, benzotriazole, the mixture of one or more in phosphorylethanolamine salt, nitranol salt, boric acid ethanolamine salt, Sodium orthomolybdate or the potassium molybdate, its content are 3.0～5.0% (weight percentage).
8. the water base lubricant of usefulness is processed in brass-plated steel wire drawing according to claim 1, it is characterized in that: described mould inhibitor is hexahydro--1,3,5 three (hydroxyethyl)-s-triazine, 1, the mixture of one or both in 2-benzisothiazole-3-ketone, Kathon, (2-pyridine mercapto alcohol-1-oxide compound) sodium, its content is 1.0～2.0% (weight percentage).
9. the water base lubricant of usefulness is processed in brass-plated steel wire drawing according to claim 1, and it is characterized in that: described defoamer is silicone antifoam agent, and its content is 0.1～0.2% (weight percentage).
10. the preparation method of the water base lubricant of usefulness is processed in brass-plated steel wire drawing according to claim 1, it is characterized in that: oiliness improver and phosphorous extreme pressure agent, mineral oil, assistant for emulsifying agent are warming up to 90～120 ℃, the water that under constantly stirring, adds 90～100 ℃, then be cooled to below 40 ℃, add mould inhibitor, rust-preventive agent, defoamer, stirring namely gets product again.
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