CN101874130B - Imitating natural plant fiber, preparation method thereof and fabric made of it - Google Patents
Imitating natural plant fiber, preparation method thereof and fabric made of it Download PDFInfo
- Publication number
- CN101874130B CN101874130B CN200780101707XA CN200780101707A CN101874130B CN 101874130 B CN101874130 B CN 101874130B CN 200780101707X A CN200780101707X A CN 200780101707XA CN 200780101707 A CN200780101707 A CN 200780101707A CN 101874130 B CN101874130 B CN 101874130B
- Authority
- CN
- China
- Prior art keywords
- fiber
- polyalkenes
- microcapsules
- weight
- heat
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000835 fiber Substances 0.000 title claims abstract description 53
- 239000004744 fabric Substances 0.000 title claims abstract description 25
- 238000002360 preparation method Methods 0.000 title abstract 3
- 239000003094 microcapsule Substances 0.000 claims abstract description 36
- 239000000341 volatile oil Substances 0.000 claims abstract description 36
- 229920000098 polyolefin Polymers 0.000 claims abstract description 28
- 238000002844 melting Methods 0.000 claims abstract description 6
- 230000008018 melting Effects 0.000 claims abstract description 6
- 238000001816 cooling Methods 0.000 claims abstract description 5
- 238000002156 mixing Methods 0.000 claims abstract description 4
- 241000196324 Embryophyta Species 0.000 claims description 48
- 238000000034 method Methods 0.000 claims description 24
- 239000004033 plastic Substances 0.000 claims description 22
- 229920003023 plastic Polymers 0.000 claims description 22
- 229920001971 elastomer Polymers 0.000 claims description 19
- 239000000806 elastomer Substances 0.000 claims description 19
- -1 polypropylene Polymers 0.000 claims description 17
- 229920002994 synthetic fiber Polymers 0.000 claims description 13
- 238000000605 extraction Methods 0.000 claims description 12
- 239000004594 Masterbatch (MB) Substances 0.000 claims description 11
- 239000000463 material Substances 0.000 claims description 11
- 239000012634 fragment Substances 0.000 claims description 8
- 239000004743 Polypropylene Substances 0.000 claims description 7
- 229920001155 polypropylene Polymers 0.000 claims description 7
- 238000007493 shaping process Methods 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 5
- OEYQBKYISMRWQB-UHFFFAOYSA-N Santal Chemical compound C=1C(OC)=CC(O)=C(C2=O)C=1OC=C2C1=CC=C(O)C(O)=C1 OEYQBKYISMRWQB-UHFFFAOYSA-N 0.000 claims description 4
- 235000003717 Boswellia sacra Nutrition 0.000 claims description 3
- 235000012035 Boswellia serrata Nutrition 0.000 claims description 3
- 240000007551 Boswellia serrata Species 0.000 claims description 3
- 239000004863 Frankincense Substances 0.000 claims description 3
- 239000004698 Polyethylene Substances 0.000 claims description 3
- 229920000573 polyethylene Polymers 0.000 claims description 3
- 241000522254 Cassia Species 0.000 claims description 2
- 235000009024 Ceanothus sanguineus Nutrition 0.000 claims description 2
- 240000003538 Chamaemelum nobile Species 0.000 claims description 2
- 235000007866 Chamaemelum nobile Nutrition 0.000 claims description 2
- 229920002101 Chitin Polymers 0.000 claims description 2
- 235000005979 Citrus limon Nutrition 0.000 claims description 2
- 244000131522 Citrus pyriformis Species 0.000 claims description 2
- 241000675108 Citrus tangerina Species 0.000 claims description 2
- 240000000560 Citrus x paradisi Species 0.000 claims description 2
- 240000007311 Commiphora myrrha Species 0.000 claims description 2
- 235000006965 Commiphora myrrha Nutrition 0.000 claims description 2
- 240000004784 Cymbopogon citratus Species 0.000 claims description 2
- 235000017897 Cymbopogon citratus Nutrition 0.000 claims description 2
- 244000166652 Cymbopogon martinii Species 0.000 claims description 2
- 240000006927 Foeniculum vulgare Species 0.000 claims description 2
- 235000004204 Foeniculum vulgare Nutrition 0.000 claims description 2
- 244000153234 Hibiscus abelmoschus Species 0.000 claims description 2
- 235000010254 Jasminum officinale Nutrition 0.000 claims description 2
- 240000005385 Jasminum sambac Species 0.000 claims description 2
- 240000005308 Juniperus chinensis Species 0.000 claims description 2
- 244000165082 Lavanda vera Species 0.000 claims description 2
- 235000010663 Lavandula angustifolia Nutrition 0.000 claims description 2
- 240000003553 Leptospermum scoparium Species 0.000 claims description 2
- 235000015511 Liquidambar orientalis Nutrition 0.000 claims description 2
- 235000015459 Lycium barbarum Nutrition 0.000 claims description 2
- 235000007232 Matricaria chamomilla Nutrition 0.000 claims description 2
- 241000378544 Melaleuca quinquenervia Species 0.000 claims description 2
- 244000246386 Mentha pulegium Species 0.000 claims description 2
- 235000016257 Mentha pulegium Nutrition 0.000 claims description 2
- 235000004357 Mentha x piperita Nutrition 0.000 claims description 2
- 244000179970 Monarda didyma Species 0.000 claims description 2
- 235000010672 Monarda didyma Nutrition 0.000 claims description 2
- 235000007265 Myrrhis odorata Nutrition 0.000 claims description 2
- 235000010676 Ocimum basilicum Nutrition 0.000 claims description 2
- 240000007926 Ocimum gratissimum Species 0.000 claims description 2
- 235000011203 Origanum Nutrition 0.000 claims description 2
- 240000000783 Origanum majorana Species 0.000 claims description 2
- 241000208181 Pelargonium Species 0.000 claims description 2
- 244000046052 Phaseolus vulgaris Species 0.000 claims description 2
- 235000010627 Phaseolus vulgaris Nutrition 0.000 claims description 2
- 235000008331 Pinus X rigitaeda Nutrition 0.000 claims description 2
- 241000018646 Pinus brutia Species 0.000 claims description 2
- 235000011613 Pinus brutia Nutrition 0.000 claims description 2
- 235000011751 Pogostemon cablin Nutrition 0.000 claims description 2
- 240000002505 Pogostemon cablin Species 0.000 claims description 2
- 241000220317 Rosa Species 0.000 claims description 2
- 244000178231 Rosmarinus officinalis Species 0.000 claims description 2
- 235000017304 Ruaghas Nutrition 0.000 claims description 2
- 239000004870 Styrax Substances 0.000 claims description 2
- 244000028419 Styrax benzoin Species 0.000 claims description 2
- 235000000126 Styrax benzoin Nutrition 0.000 claims description 2
- 235000016639 Syzygium aromaticum Nutrition 0.000 claims description 2
- 244000223014 Syzygium aromaticum Species 0.000 claims description 2
- 235000006886 Zingiber officinale Nutrition 0.000 claims description 2
- 244000273928 Zingiber officinale Species 0.000 claims description 2
- 235000008397 ginger Nutrition 0.000 claims description 2
- 235000001050 hortel pimenta Nutrition 0.000 claims description 2
- 239000001102 lavandula vera Substances 0.000 claims description 2
- 235000018219 lavender Nutrition 0.000 claims description 2
- 229920003225 polyurethane elastomer Polymers 0.000 claims description 2
- 239000002023 wood Substances 0.000 claims description 2
- 238000009954 braiding Methods 0.000 claims 1
- 239000000203 mixture Substances 0.000 abstract description 11
- 229920002725 thermoplastic elastomer Polymers 0.000 abstract description 5
- 239000002131 composite material Substances 0.000 abstract 1
- 238000009998 heat setting Methods 0.000 abstract 1
- 238000003801 milling Methods 0.000 abstract 1
- 238000005096 rolling process Methods 0.000 abstract 1
- 238000009987 spinning Methods 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 17
- 230000000694 effects Effects 0.000 description 14
- 239000003205 fragrance Substances 0.000 description 14
- 238000005516 engineering process Methods 0.000 description 12
- 230000001550 time effect Effects 0.000 description 11
- 230000002045 lasting effect Effects 0.000 description 6
- 238000012827 research and development Methods 0.000 description 6
- 238000002474 experimental method Methods 0.000 description 5
- 230000000844 anti-bacterial effect Effects 0.000 description 4
- 230000002688 persistence Effects 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 230000036541 health Effects 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 238000005469 granulation Methods 0.000 description 2
- 230000003179 granulation Effects 0.000 description 2
- 230000036651 mood Effects 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 238000009958 sewing Methods 0.000 description 2
- 229920002943 EPDM rubber Polymers 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000003260 anti-sepsis Effects 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 238000002290 gas chromatography-mass spectrometry Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000013101 initial test Methods 0.000 description 1
- 239000002674 ointment Substances 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 235000013599 spices Nutrition 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 229940070527 tourmaline Drugs 0.000 description 1
- 229910052613 tourmaline Inorganic materials 0.000 description 1
- 239000011032 tourmaline Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D10/00—Physical treatment of artificial filaments or the like during manufacture, i.e. during a continuous production process before the filaments have been collected
- D01D10/02—Heat treatment
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/02—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D01F6/04—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyolefins
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/02—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D01F6/04—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyolefins
- D01F6/06—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyolefins from polypropylene
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/44—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
- D01F6/46—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polyolefins
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D13/00—Woven fabrics characterised by the special disposition of the warp or weft threads, e.g. with curved weft threads, with discontinuous warp threads, with diagonal warp or weft
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/20—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
- D03D15/283—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads synthetic polymer-based, e.g. polyamide or polyester fibres
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/50—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
- D10B2201/01—Natural vegetable fibres
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2501/00—Wearing apparel
- D10B2501/04—Outerwear; Protective garments
- D10B2501/042—Headwear
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2501/00—Wearing apparel
- D10B2501/04—Outerwear; Protective garments
- D10B2501/043—Footwear
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2503/00—Domestic or personal
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2505/00—Industrial
- D10B2505/04—Filters
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/298—Physical dimension
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/30—Woven fabric [i.e., woven strand or strip material]
- Y10T442/3065—Including strand which is of specific structural definition
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Mechanical Engineering (AREA)
- Artificial Filaments (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Woven Fabrics (AREA)
Abstract
An imitating natural plant fiber, preparation method thereof and the fabric made of it are provided. The preparation method includes the following steps: rolling and milling the mixture of plural first polyolefine chips, constant thermoplastic elastomer (TPE) and plural microcapsules which encapsulate essential oil extracted from natural plant in the twin-screw extruder, thus plural masterbatches can be made; melting and mixing the above masterbatches and plural second polyolefine which is same as the first one, thus a composite can be made, wherein the final content of the microcapsules is 1-32% by weight; and producing fibers by spinning, cooling, heat drawing, and heat setting. The fiber and the fabric made of it have durable natural plant aroma.
Description
[technical field that the present invention belongs to] the present invention is that relevant a kind of natural-like plant fiber, its method for making reach the fabric made from this fiber, but espespecially a kind of microcapsules, heat plastics elastomer (TPE) and polyalkenes blend that adopts inside to be coated with the plant extraction essential oil, and reel off raw silk from cocoons and make fiber, and can this fiber knit and make fabric, and make fiber or its fabric have lasting natural plants aromatic function.
[prior art]
The Legion Gold of the divinity of scent before 5000 just occurred, with plants essential oil, pursues the calmness of soul and the health of body and mind, even cosmetology " four large ancient civilized countries " early on the books in history in ancient times.The extraction smelting method that ancients commonly use and the essence of plant are slightly different from the modern times.Ancient times, the very few form with essential oil of plants essential oil used occurred in aromatotherapy, and on the contrary, resin, essence, dope and ointment etc. all are widely used, and the purposes of plant is spices, perfume, medicine and religious rites etc.The ancient Egyptian also utilizes the resin of essential oil and frankincense to be coated on mummy with the performance antisepsis.
By the made how rice microcapsules fiber of natural plant essential oils, can make the product timeliness that is effectively controlled, and then supply the Nature element that is short of in air quality, can obtain the effect of auxiliary mood and mood in other application.
By known technology, often adopt the man-made additives such as stacte or interpolation isopropyl alcohol that essential oil can be volatilized in air about essential oil product, but the easy effect that produces danger and lose original essential oil.It is coated in microcapsules and can makes the essential oil release that is effectively controlled, not only have a high security, and can effectively control its timeliness.Fabric is that present human lives institute is indispensable, and often is visible, clothings such as airstrainer, screen window, cap, cushion, bed and shoes, and curtain etc., weaved and formed by fiber.Because extensively being subject to the mankind, uses by fabric, and long-drawn-out health of closing human body, thereby existing many dynamopathic fabrics are developed, for example some technology is to produce the fabric with antibacterial deodourizing, to safeguard health and comfortableness, some technology is to make the fabric of sening as an envoy to have the effect of plant fragrance, to promote the comfortableness of using.
Only, commonly used known at present and made fabric tool anti-bacterial anti-foul function, or made fabric have the plant fragrance effect, but major part is all directly at fabric coating one deck, to have Antibiotic-odor Resistant Agent or aromatic, because of its volatilization fast, just started effect good, but soon because volatilizing and lost efficacy fast.Moreover,, though the mixed technology that contains antiseptic in fiber is arranged at present, mostly because be comprised in fiber, can't effectively bring into play its effect.Especially at present there is no a kind of goodly and can be contained in fibrous inside with the plant extraction essential oil is mixed in known techniques, and can keep the fragrant technology of long-time release.Therefore, the inventor to be to research and develop for many years the experience of sewing work, has high economic benefit and can produce the functional fiber and fabric of anion and tool antibacterial deodourizing except developing, the inventor and actively drop into simultaneously the fiber of the lasting plant fragrance of research and development tool.After research and development are fruitful, just in 2004, start to propose patent application about the fiber that can produce anion and antibacterial deodourizing, its technology such as No. 93129156 Patent Case of Taiwan application, it is in sight that this case has been got permission patent at present, and this technology is after the test through repeatedly and improvement, be and apply for 11/416, No. 155 case of United States Patent (USP).About the technology of natural-like plant fragrant fiber, through continuous research and experiment, concrete achievement is arranged, be and propose the application of this case.
Commonly use at present the technology that thermoplastic elastomer (TPE) comprises plants essential oil, for example the U.S. the 6th, 673, No. 857 Patent Cases, and it is mainly to do research and development at the material composition of thermoplastic elastomer (TPE), this thermoplastic elastomer (TPE) is to be used to make the article such as toy.Yet these front case technology are all different from the technology of the present invention feature.The present invention is that the inventor studies and the research and development achievement of manufacturing experience for many years, and the experiment proved that true tool practical effect, has met patent requirement, and whence proposes patent application, to ensure the research and development painstaking effort.
[summary of the invention]
Purpose of the present invention, be to provide a kind of method that can be made into tool natural-like plant fiber.Its method characteristic, but be to adopt the inner microcapsules that are coated with the plant extraction essential oil, heat plastics elastomer (TPE) and polyalkenes (polyolefine) mixing and reel off raw silk from cocoons and make fiber with better ratio, use and make fiber can discharge plant fragrance.
The second purpose of the present invention, be to provide a kind of fiber that can produce lastingly plant fragrance.Its fiber characteristics, but be in fiber to be mixed with the heat plastics elastomer, and include a plurality of microcapsules, and be coated with the plant extraction essential oil in microcapsules, but, by the release of the suitable regulation and control essential oil of heat plastics elastomer, and can reach, make the lasting purpose of fiber fragrance.
[embodiment]
I. basic technical features of the present invention
The present invention does research and development and test for the fiber with natural-like plant fragrance.Its basic technical features, be that but fiber of the present invention is formed by the microcapsules, heat plastics elastomer and the blend manufacturing of polyalkenes institute that include inside and be coated with the natural plant extraction essential oil, and then make fiber have the function of lasting release plant fragrance, and can be for being woven into various fabrics, wherein, fabric can be airstrainer or shoe-pad or cap or screen window or mouth mask or bed or back cushion or cushion or curtain or TV eye guard.
II. about fiber of the present invention
Fiber of the present invention, but be mainly one and be coated with microcapsules, a certain amount of heat plastics elastomer (TPE) and a certain amount of polyalkenes (polyolefine) (for example polypropylene or the polyethylene) blend of natural plant extraction essential oil and the fiber of making via reeling off raw silk from cocoons by a plurality of inside.It is by the plastic elastomeric effect of heat, and makes fiber of the present invention have long-time Stable Release plant fragrance, and then allows this sewing work have practical effect.
The first specific embodiment of the present invention, made fiber wire diameter are that 0.005mm～5mm (best is 0.01mm～3mm).And its microcapsules that add account for 1～32% percentage by weight of whole fiber.
The present invention makes the method for natural-like plant artificial fibre, comprises the following steps:
(a) prepare to make the material of master batch, include:
(a1) a plurality of the first polyalkenes (Polyolefine) fragment of 10%～80% percentage by weight that accounts for whole master batch weight is as base material, and the first polyalkenes can be that molecular weight is 3.15 * 10
5The polypropylene of g/mole, or molecular weight is 1.5～2.5 * 10
5The polyethylene fragment of g/mole (wherein, the following test of the present invention is to explain take polypropylene as specific embodiment);
(a2) account for a plurality of microcapsules of 5%～50% percentage by weight of whole master batch weight, each microcapsules inside is coated with plants essential oil, its preferred embodiment, and plants essential oil extracts from natural plants;
(a3) but account for the heat plastics elastomer (TPE or EPDM) of 1%～80% percentage by weight of whole master batch weight;
(b) but should a plurality of the first polyalkenes fragments, these a plurality of microcapsules and a certain amount of should the heat plastics elastomer, mix granulation and make a plurality of master batches with twin-screw;
(c) get again these a plurality of master batches and a plurality of the second polyalkenes fragment, wherein, this second polyalkenes and this first polyalkenes are same material, and should mix into a synthetic material with these a plurality of second polyalkenes fragments by a plurality of master batches, make the final content of microcapsules account for 1～32% percentage by weight of this synthetic material; And
(d) again with this synthetic material through reeling off raw silk from cocoons, cooling, hot extension, heat-shaping and make fiber.
Wherein, the temperature of reeling off raw silk from cocoons is that (200 ℃～250 ℃ of the temperature of reeling off raw silk from cocoons in the embodiment of concrete operations of the present invention polypropylene heat in the scope of 200 ℃～300 ℃, 250 ℃～300 ℃ of polyethylene), 3～8 times of drawing-off multiplying powers (in the embodiment of concrete operations of the present invention, the drawing-off multiplying power is 6 times), 100～160 ℃ of hot elongating temperatures (being to extend with 100 ℃ of hot water in the embodiment of concrete operations of the present invention), the heat-shaping temperature is 70 ℃～100 ℃.
It is with the synthetic material heating and melting that above-mentioned melting is reeled off raw silk from cocoons, and melting is extruded and entered air from spinneret orifice, cooling in air in, curling with certain speed, solidify in this stage synthetic material melt refinement, namely form fiber, carry out again hot-stretch, to improve the performances such as mechanics of fiber.The melting engineering of reeling off raw silk from cocoons, be the polymer with spinnability that will make at polymerization process at it temperature more than fusing point extrude from spinneret orifice, coolingly be refined into thread solid, reel simultaneously.
III. the embodiment of microcapsules of the present invention and plant extraction essential oil
The present invention is in order to allow fiber produce lasting plant fragrance, and its microcapsules that adopt, be coated with the plant extraction essential oil in inside.Wherein, but the material of these microcapsules is selected from one or more among chitin, polyurethane elastomer, heat plastics elastomer and tourmaline., by the microcapsule coated plants essential oil and in conjunction with the plastic elastomeric technology of heat, make the present invention have the effect that produces permanent fragrance, and the result of the test as shown in rear show that the present invention has the effect that makes fragrance lasting really.Wherein, a kind of preferred embodiment, can coat the plants essential oil more than two kinds in each microcapsules,, by the reciprocation of two kinds of different plants essential oils, make its fragrant persistence better.
Wherein, the extraction of this plants essential oil is from natural plants, and natural plants can be selected from lavender, lemon, Chinese juniper wood, rosemary, Xue MingRosma rinus officinalis, You Jiali, tea tree, santal, bergamot, pine, jasmine, rose, chamomile, Yilan, sweet basil, pelargonium, cajeputtree, Beans are cool, one or more in the natural plants of Moschus, myrrh, Chinese cassia tree, fennel, frankincense, tangerine, peppermint, cdear, Pogostemon cablin, palmarosa, cloves, grape fruit, styrax, ginger, lemongrass and marjoram.
IV. experimental example of the present invention
Experimental example of the present invention is take molecular weight as 3.15 * 10
5A plurality of polypropylene fragments of g/mole are as base material, its a plurality of polypropylene fragments account for 20% percentage by weight of whole master batch weight, the microcapsules of preparing account for 50% percentage by weight of whole master batch weight, the inner plants essential oil extraction that coats of each microcapsules is from natural plants, but the heat plastics elastomer (TPE) of preparing accounts for 30% of whole master batch weight.In this experimental example, technical characterstic of the present invention, but the deal that is first heat-obtaining plastics elastomer (30%) greater than polypropylene (20%), but make microcapsules can be easily first with polypropylene and heat plastics elastomer, evenly mix.
During manufacturing, but, with the microcapsules of the polypropylene fragment of above-mentioned 20% percentage by weight, 50% percentage by weight and the heat plastics elastomer of 30% percentage by weight, with twin-screw, mix granulation and make a plurality of master batches.Get these a plurality of master batches and extra a plurality of polypropylene fragments again, and these a plurality of master batches are mixed into a synthetic material with these extra a plurality of polypropylene fragments, the final content that makes microcapsules is 20% percentage by weight that accounts for this synthetic material.Again with this synthetic material through reeling off raw silk from cocoons, cooling, heat is extended, heat-shaping is made fiber.Wherein, the temperature of reeling off raw silk from cocoons is in 240 ℃ of scopes, 6 times of drawing-off multiplying powers, 100 ℃ of hot elongating temperatures.
In order to do concrete experiment, the present invention gets above-mentioned fibrous woven again and becomes fabric, namely with a plurality of fiber and a plurality of fibrages that are the broadwise extension that are the warp-wise extension, becomes fabric.
The peace and quiet ability of the fabric of natural-like plant fiber of the present invention and fragrant duration running result are as follows.
(i) peace and quiet capability analysis
The sample-size of this experiment is that (4in * 8in), the unit length distributed quantity of warp fiber is 42 of every English inch to 101.6mm * 203.2mm, and the unit length distributed quantity of weft fiber is 34 of every English inch.Find that by table 1 dictyosome of the present invention can effectively contain the peace and quiet ability of natural essential oil composition.
Table 1
(ii) Time Effect
The present invention has done following eight dynamic Time Effects, and by experimental result, shows that it has long persistence.Its method of testing is that (size 23.5CM * 36.5CM) is placed in (wind flux 3.3m in air cleaner with testing sample
3/ min), and after opening when the pre-regularly number of experiment, after the dictyosome of the present invention of clip proper area is put into the gas production bag and stablized 6 hours, carry out air sampling, sample connects gas chromatography mass spectrograph (GC/MS) with the thermal desorption device and analyzes it.
The Time Effect of (1) 0 hour, result such as following table:
Test result:
The Time Effect of (2) 600 hours, result such as following table:
Test result:
The Time Effect of (3) 800 hours, result such as following table:
Test result
The Time Effect of (4) 1200 hours, result such as following table:
Test result
The Time Effect of (5) 2500 hours, result such as following table:
Test result:
The Time Effect of (6) 3000 hours, result such as following table:
Test result:
The Time Effect of (7) 3500 hours, result such as following table:
Test result:
The Time Effect of (8) 4500 hours, result such as following table:
Test result:
(iii) preserve Time Effect:
Shown by the result of table 2, the present invention places general environment and goes through under standing and still had effective fragrance effect in 2 years, and sequitur method for making of the present invention and made fiber can be guaranteed the persistence of the fragrance of essential oil in the interpolation microcapsules.
Table 2: the fragrant persistence testing that adds the microcapsules that contain essential oil
| Pilot project | Result of the test (initial testing) | Result of the test (testing again after 2 years) |
| The smell official can assess | 3.4 | 4.0 |
(iv) physical condition of the present invention is analyzed:
Analysis result such as following table.
V. conclusion
The present invention adds while including the microcapsules of essential oil, but, because being added with simultaneously the heat plastics elastomer, can avoiding essential oil to volatilize fast by elastomeric effect, and essential oil is disengaged in the mode near quantitative, avoids waste and promotes durability.And, by the cooperation of each composition ratio, and the processing procedure that mixes of secondary, make the present invention be able to concrete enforcement, and really can reach the effect of expection.
The above, it is only possible embodiments of the present invention, not in order to limit the scope of the claims of the present invention, such as according to the described content of claims, feature take and spirit and as the equivalence of other variation implement, all should be contained in the scope of the claims of the present invention.
Claims (17)
1. the manufacture method of a natural-like plant fiber comprises the following steps:
(a) prepare to make the material of master batch:
(a1) account for a plurality of first polyalkenes fragments of 10%～80% percentage by weight of whole master batch weight as base material;
(a2) account for a plurality of microcapsules of 5%～50% percentage by weight of whole master batch weight, each microcapsules inside is coated with at least a plants essential oil; And
(a3) but account for the heat plastics elastomer (TPE) of 1%～80% percentage by weight of whole master batch weight;
(b) but should a plurality of the first polyalkenes fragments, these a plurality of microcapsules and this heat plastics elastomer be made of mixing a plurality of master batches;
(c) get these a plurality of master batches and a plurality of the second polyalkenes fragment, this second polyalkenes and this first polyalkenes are same material, should become a synthetic material with these a plurality of second polyalkenes fragment melting mixing by a plurality of master batches, and make these a plurality of microcapsules account for 1～32% percentage by weight of this synthetic material; And
(d) make this synthetic material make fiber.
2. the method for claim 1, wherein this first polyalkenes and this second polyalkenes are polypropylene.
3. method as claimed in claim 2, wherein this polyacrylic molecular weight is 3.15 * 10
5G/mole.
4. the method for claim 1, wherein this first polyalkenes and this second polyalkenes are polyethylene.
5. method as claimed in claim 4, wherein this poly molecular weight is 1.5～2.5 * 10
5G/mole.
6. the method for claim 1, wherein the material of these microcapsules is selected from chitin and the Re Ke plastics elastomer is wherein at least a.
7. method as claimed in claim 6, wherein, but the heat plastics elastomer in microencapsulation material comprises polyurethane elastomer.
The method of claim 1, wherein step (d) be with this synthetic material through reeling off raw silk from cocoons, cooling, hot extension and heat-shaping and make fiber.
9. method as claimed in claim 8, the temperature of wherein reeling off raw silk from cocoons are in the scope of 200 ℃～300 ℃, 3～8 times of drawing-off multiplying powers, and 100 ℃～160 ℃ of hot elongating temperatures, the heat-shaping temperature is 70 ℃～100 ℃.
10. method as claimed in claim 8, the temperature of wherein reeling off raw silk from cocoons are in the scope of 200 ℃～300 ℃, 3～8 times of drawing-off multiplying powers, and 100 ℃ of hot elongating temperatures, the heat-shaping temperature is 70 ℃～100 ℃.
11. the method for claim 1, wherein this plants essential oil extraction is from natural plants.
12. method as claimed in claim 11, wherein, this natural plants be selected from lavender, lemon, Chinese juniper wood, rosemary, Xue MingRosma rinus officinalis, You Jiali, tea tree, santal, bergamot, pine, jasmine, rose, chamomile, Yilan, sweet basil, pelargonium, cajeputtree, Beans are cool, Moschus, myrrh, Chinese cassia tree, fennel, frankincense, tangerine, peppermint, cdear, Pogostemon cablin, palmarosa, cloves, grape fruit, styrax, ginger, lemongrass and marjoram wherein at least a.
13. the method for claim 1, wherein the plastic elastomeric deal of this heat in this step (a) is greater than the deal of these a plurality of the first polyalkenes.
14. the method for claim 1, wherein this step (a) but in this heat plastics elastomer be 30% percentage by weight, these a plurality of first polyalkenes are 20% percentage by weight, and these microcapsules are 50% percentage by weight.
15. the fiber as the described method of arbitrary claim in claim 1 to 14, to make, this fiber wire diameter is 0.005mm～5mm, and this fibrous inside includes this a plurality of microcapsules, and each this microcapsules inside is coated with this plants essential oil.
16. a fabric made from fiber as claimed in claim 15, this fabric include mutual braiding a plurality of be this fiber that warp-wise extends and a plurality of are this fiber that broadwise is extended.
17. it is wherein a kind of that fabric as claimed in claim 16, this fabric are selected from airstrainer, shoe-pad, cap, screen window, curtain, mouth mask, bed, back cushion, cushion and TV eye guard.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/CN2007/003339 WO2009067840A1 (en) | 2007-11-27 | 2007-11-27 | Imitating natural plant fiber, preparation method thereof and fabric made of it |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101874130A CN101874130A (en) | 2010-10-27 |
| CN101874130B true CN101874130B (en) | 2013-11-13 |
Family
ID=40677998
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200780101707XA Expired - Fee Related CN101874130B (en) | 2007-11-27 | 2007-11-27 | Imitating natural plant fiber, preparation method thereof and fabric made of it |
Country Status (17)
| Country | Link |
|---|---|
| US (1) | US20100227522A1 (en) |
| EP (1) | EP2216430B1 (en) |
| JP (1) | JP2011504209A (en) |
| KR (1) | KR20100112552A (en) |
| CN (1) | CN101874130B (en) |
| AU (1) | AU2007361791B2 (en) |
| BR (1) | BRPI0722224A2 (en) |
| CA (1) | CA2706980A1 (en) |
| EA (1) | EA017657B1 (en) |
| ES (1) | ES2401466T3 (en) |
| IL (1) | IL205888A (en) |
| MA (1) | MA31986B1 (en) |
| MX (1) | MX2010005634A (en) |
| NO (1) | NO20100725L (en) |
| NZ (1) | NZ585912A (en) |
| TN (1) | TN2010000224A1 (en) |
| WO (1) | WO2009067840A1 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102733514B (en) * | 2012-06-06 | 2015-09-09 | 苏州金螳螂幕墙有限公司 | A kind of cell curtain wall end opening switching crossbeam |
| CN107849744A (en) * | 2015-10-21 | 2018-03-27 | 东丽纤维研究所（中国）有限公司 | A kind of flexible fibre and its fabric |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8231968B2 (en) * | 2006-05-03 | 2012-07-31 | Noveko Trading 2008 Llc | Natural tourmaline anion fiber and filter and producing method |
| JP5520826B2 (en) * | 2007-11-07 | 2014-06-11 | ノベコ トレーディング ２００８ エルエルシー | Functional fiber, method for producing the same, and fabric made from the fiber |
| US20170303383A1 (en) * | 2010-08-23 | 2017-10-19 | Exogenesis Corporation | Method for neutral beam processing based on gas cluster ion beam technology and articles produced thereby |
| US9799488B2 (en) * | 2010-08-23 | 2017-10-24 | Exogenesis Corporation | Method and apparatus for neutral beam processing based on gas cluster ion beam technology |
| US10825685B2 (en) | 2010-08-23 | 2020-11-03 | Exogenesis Corporation | Method for neutral beam processing based on gas cluster ion beam technology and articles produced thereby |
| US10181402B2 (en) | 2010-08-23 | 2019-01-15 | Exogenesis Corporation | Method and apparatus for neutral beam processing based on gas cluster ion beam technology and articles produced thereby |
| US10202684B2 (en) | 2010-08-23 | 2019-02-12 | Exogenesis Corporation | Method for neutral beam processing based on gas cluster ion beam technology and articles produced thereby |
| CN103649390A (en) * | 2011-06-03 | 2014-03-19 | Vegro有限责任公司 | Insecticidal polyethylene fiber, yarn or textile products with improved migration profiles and washing resistance |
| CA2845762C (en) | 2011-08-22 | 2019-01-08 | Exogenesis Corporation | Drug delivery system and method of manufacturing thereof |
| CN103409938A (en) * | 2013-08-12 | 2013-11-27 | 江南大学 | Preparation method of shredded ginger fiber/ginger slag/polypropylene lightweight composite material |
| CN103741305B (en) * | 2014-01-14 | 2017-01-04 | 河北瑞春纺织科技有限公司 | Scribbled containing Herba Pileae Scriptae fiber and mint fibers and preparation method thereof |
| CN105696160A (en) * | 2016-03-14 | 2016-06-22 | 廖舟 | Method for preparing towel special for skin tinea patient |
| CN105708378A (en) * | 2016-03-14 | 2016-06-29 | 廖舟 | Towel special for patient suffering from skin tinea |
| CN105696161A (en) * | 2016-03-14 | 2016-06-22 | 廖舟 | Preparation method of mouldproof towel |
| CN105714446A (en) * | 2016-03-14 | 2016-06-29 | 廖舟 | Preparation method for antibacterial towel |
| IT201600093856A1 (en) * | 2016-09-19 | 2018-03-19 | Humanwellness Sa | COSMETIC FABRIC |
| CN107475882A (en) * | 2017-09-12 | 2017-12-15 | 江阴芗菲服饰有限公司 | A kind of peppermint cotton blended knitted fabric and preparation method thereof |
| CN108523081A (en) * | 2018-03-27 | 2018-09-14 | 广州城市职业学院 | A kind of natural lichee flavouring and preparation method thereof |
| CN110777540A (en) * | 2019-11-21 | 2020-02-11 | 广州市迅泰通信设备有限公司 | Chamomile sanitary surface layer |
| CN111636132A (en) * | 2020-06-04 | 2020-09-08 | 刘裕芬 | Mint fiber antibacterial fabric |
| CN112220961B (en) * | 2020-09-14 | 2022-11-04 | 株洲千金药业股份有限公司 | Mattress-proof deodorization chip, puerpera pad and preparation method of mattress-proof deodorization chip |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1067276A (en) * | 1992-04-29 | 1992-12-23 | 营口化学纤维厂 | Perfume synthetic fibre and manufacture method thereof |
| CN1244106A (en) * | 1996-08-15 | 2000-02-09 | 加拿大吉勒特公司 | Dental floss |
| EP1367152A1 (en) * | 2002-05-28 | 2003-12-03 | Atex S.r.l. | Method for producing a non-woven fabric made of synthetic fiber with fragrancing means |
| CN1641080A (en) * | 2003-03-06 | 2005-07-20 | 王开利 | Nano antibacterial composite-function aromatic fiber |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01282305A (en) * | 1988-05-09 | 1989-11-14 | Kuraray Co Ltd | Aromatic fiber and production thereof |
| JP2736433B2 (en) * | 1989-03-22 | 1998-04-02 | タキロン株式会社 | Sustained-release pest repellent |
| EP0367140B1 (en) * | 1988-10-31 | 1995-01-18 | Takiron Co. Ltd. | Controlled release insect pest repellent |
| JP2904944B2 (en) * | 1991-02-20 | 1999-06-14 | 帝人株式会社 | Sustained release aromatic cushioning material |
| DE19920257A1 (en) | 1999-05-03 | 2000-11-09 | Basf Ag | Thermoplastic elastomer composition |
| JP4172617B2 (en) * | 2001-02-08 | 2008-10-29 | 川崎 智子 | Repellent-active sustained-release porous microparticles and uses thereof |
| CN1776034A (en) * | 2005-12-06 | 2006-05-24 | 颜志勇 | Medical X-ray developing fiber and its preparing method |
| US8231968B2 (en) * | 2006-05-03 | 2012-07-31 | Noveko Trading 2008 Llc | Natural tourmaline anion fiber and filter and producing method |
| CN201039770Y (en) * | 2007-03-12 | 2008-03-26 | 陈宏任 | Multifunctional functional health preserving self-purification shoe material |
| JP5520826B2 (en) * | 2007-11-07 | 2014-06-11 | ノベコ トレーディング ２００８ エルエルシー | Functional fiber, method for producing the same, and fabric made from the fiber |
-
2007
- 2007-11-27 ES ES07845710T patent/ES2401466T3/en active Active
- 2007-11-27 NZ NZ585912A patent/NZ585912A/en not_active IP Right Cessation
- 2007-11-27 WO PCT/CN2007/003339 patent/WO2009067840A1/en active Application Filing
- 2007-11-27 CA CA 2706980 patent/CA2706980A1/en not_active Abandoned
- 2007-11-27 MX MX2010005634A patent/MX2010005634A/en active IP Right Grant
- 2007-11-27 KR KR1020107013350A patent/KR20100112552A/en not_active Application Discontinuation
- 2007-11-27 CN CN200780101707XA patent/CN101874130B/en not_active Expired - Fee Related
- 2007-11-27 AU AU2007361791A patent/AU2007361791B2/en not_active Ceased
- 2007-11-27 BR BRPI0722224-6A2A patent/BRPI0722224A2/en not_active IP Right Cessation
- 2007-11-27 EP EP20070845710 patent/EP2216430B1/en not_active Not-in-force
- 2007-11-27 JP JP2010533408A patent/JP2011504209A/en active Pending
- 2007-11-27 EA EA201000870A patent/EA017657B1/en not_active IP Right Cessation
-
2010
- 2010-05-19 NO NO20100725A patent/NO20100725L/en not_active Application Discontinuation
- 2010-05-20 TN TN2010000224A patent/TN2010000224A1/en unknown
- 2010-05-20 IL IL205888A patent/IL205888A/en not_active IP Right Cessation
- 2010-05-21 US US12/784,692 patent/US20100227522A1/en not_active Abandoned
- 2010-06-18 MA MA32935A patent/MA31986B1/en unknown
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1067276A (en) * | 1992-04-29 | 1992-12-23 | 营口化学纤维厂 | Perfume synthetic fibre and manufacture method thereof |
| CN1244106A (en) * | 1996-08-15 | 2000-02-09 | 加拿大吉勒特公司 | Dental floss |
| EP1367152A1 (en) * | 2002-05-28 | 2003-12-03 | Atex S.r.l. | Method for producing a non-woven fabric made of synthetic fiber with fragrancing means |
| CN1641080A (en) * | 2003-03-06 | 2005-07-20 | 王开利 | Nano antibacterial composite-function aromatic fiber |
Non-Patent Citations (1)
| Title |
|---|
| JP1－282305A 1989.11.14 |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102733514B (en) * | 2012-06-06 | 2015-09-09 | 苏州金螳螂幕墙有限公司 | A kind of cell curtain wall end opening switching crossbeam |
| CN107849744A (en) * | 2015-10-21 | 2018-03-27 | 东丽纤维研究所（中国）有限公司 | A kind of flexible fibre and its fabric |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2009067840A8 (en) | 2009-11-26 |
| ES2401466T3 (en) | 2013-04-19 |
| AU2007361791B2 (en) | 2013-03-21 |
| NO20100725L (en) | 2010-05-27 |
| WO2009067840A1 (en) | 2009-06-04 |
| KR20100112552A (en) | 2010-10-19 |
| EP2216430A1 (en) | 2010-08-11 |
| TN2010000224A1 (en) | 2011-11-11 |
| EA017657B1 (en) | 2013-02-28 |
| EP2216430B1 (en) | 2013-01-09 |
| BRPI0722224A2 (en) | 2014-06-03 |
| EP2216430A4 (en) | 2011-05-25 |
| MX2010005634A (en) | 2010-06-09 |
| AU2007361791A1 (en) | 2009-06-04 |
| JP2011504209A (en) | 2011-02-03 |
| IL205888A (en) | 2013-10-31 |
| AU2007361791A2 (en) | 2010-07-08 |
| EA201000870A1 (en) | 2011-04-29 |
| CN101874130A (en) | 2010-10-27 |
| US20100227522A1 (en) | 2010-09-09 |
| MA31986B1 (en) | 2011-01-03 |
| NZ585912A (en) | 2011-11-25 |
| CA2706980A1 (en) | 2009-06-04 |
| IL205888A0 (en) | 2010-11-30 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101874130B (en) | Imitating natural plant fiber, preparation method thereof and fabric made of it | |
| CN100402715C (en) | Functional fiber and its manufacturing method | |
| KR920005729B1 (en) | Fragrant fiber | |
| CN104294404B (en) | The manufacture method of three-dimensional crimp bi-component composite hollow aromatic polyester staple fibre | |
| CN103215751B (en) | Preparation method of long-acting insect prevention and mosquito repelling PP (Polypropylene) non-woven fabric | |
| CN106400308B (en) | A kind of fragrance natural antibacterial Odor-Removing Nonwoven Fabrics and its application certainly | |
| CN106637498A (en) | Preparation method of self-fragrance natural antibacterial and deodorizing fiber and application thereof | |
| CN106283406B (en) | Disposable sanitary articles equipped with ventilative hole are used from fragrant non-woven cloth | |
| CN1641080A (en) | Nano antibacterial composite-function aromatic fiber | |
| CN104250880A (en) | Production method for multifunctional polyester wadding sheet | |
| CN100398705C (en) | Production of health-care fibre and health-care fibre | |
| CN106149089A (en) | A kind of preparation method with antibacterial functions fragrant fiber | |
| JP3635581B2 (en) | Sustained release core-sheath composite short fiber | |
| CN109537101A (en) | A kind of antibacterial emulation wig silk and its manufacturing method | |
| CN101067222A (en) | Capsule-shaped permanent fragrant filament | |
| JP2006097222A (en) | Polyvinylidene chloride-based fiber having perfume and its product | |
| CN1007362B (en) | Fragrant fiber | |
| KR101073179B1 (en) | The manufacturing method of the composition added natural minenals and The manufacturing method of the funtionnal yarn used that | |
| CN1114724C (en) | Process for preparing sheath-core polypropylene fibres containing gingko leaf extract | |
| CN206143429U (en) | From fragrant non -weaving cloth | |
| TWI337631B (en) | ||
| AU2017316317B2 (en) | Sustained release fibers | |
| JPS6285010A (en) | Hollow multi-sheath-core type conjugate fiber | |
| CN102400237A (en) | Lavender fiber for releasing negative ions and manufacturing method for lavender fiber | |
| JPS61201012A (en) | Hollow core-sheath type yarn |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| REG | Reference to a national code |
Ref country code: HK Ref legal event code: DE Ref document number: 1145345 Country of ref document: HK |
|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| ASS | Succession or assignment of patent right |
Owner name: POLOTIRE -X TECHNOLOGY LTD. Free format text: FORMER OWNER: NOVEKO INTERNATIONAL INC. Effective date: 20150805 Owner name: NOVEKO INTERNATIONAL INC. Free format text: FORMER OWNER: NOVEKO TRADING 2008 LLC Effective date: 20150805 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20150805 Address after: Ontario Patentee after: -X, Polytron Technologies Inc. Address before: Quebec Patentee before: Novick international Limited by Share Ltd. Effective date of registration: 20150805 Address after: Quebec Patentee after: Novick international Limited by Share Ltd. Address before: Budapest Patentee before: Noveko Trading 2008 LLC |
|
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20131113 Termination date: 20151127 |
|
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| REG | Reference to a national code |
Ref country code: HK Ref legal event code: WD Ref document number: 1145345 Country of ref document: HK |