CN101872147A - Reinforced thin-wall metal base pipe and manufacturing method thereof - Google Patents
Reinforced thin-wall metal base pipe and manufacturing method thereof Download PDFInfo
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- CN101872147A CN101872147A CN200910068578A CN200910068578A CN101872147A CN 101872147 A CN101872147 A CN 101872147A CN 200910068578 A CN200910068578 A CN 200910068578A CN 200910068578 A CN200910068578 A CN 200910068578A CN 101872147 A CN101872147 A CN 101872147A
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Abstract
The invention discloses a reinforced thin-wall metal base pipe and a manufacturing method thereof. Matrix metal and second-phase insoluble nano solid particles are manufactured into the metal-based composite base pipe by a composite electroforming method. The thin-wall metal base pipe has the advantages of good comprehensive performance, particularly better mechanical property and high-temperature oxidation resistance in a high-temperature use state, and long service life. The manufacturing method has the advantages of low equipment investment, low production expense, low energy consumption and higher utilization rate of raw materials, and is easy to meet multi-species mass production.
Description
Technical field:
The present invention relates to a kind of heat fixing device that is applied in printer in the modern office equipment field, digital duplicating machine, the facsimile recorder etc.Be particularly related to a kind of thin-wall metal base pipe and manufacture method thereof of enhanced type.
Background technology:
Since the greatly universal and application of computer nowadays technical products, the output peripheral equipment that it is associated.As: also corresponding having obtained such as duplicating machine, printer, facsimile recorder greatly popularized and used.From save the energy, aspect such as operation is considered fast, the hot photographic fixing technology that current printer, digital duplicating machine, facsimile recorder etc. are interior, than early stage product technology bigger improvement has been arranged.Apparent in view performance is and realizes photographic fixing function critical piece fixing roller now, has all selected relatively thin wall type wall thickness composite bushing.For the development and the production of this specific (special) requirements product, the existing research of part producer and producing in the world in recent years, but major part all is dropped in and uses on the heat resistant type resin material aspect product, and manufacturer relates to less for metal thin-wall type parent tube.Produce in the thin wall type metal parent tube producer existing, some producer has adopted the drawing process of knowing such as everybody, spinning process or cut grinding process.For adopting these explained hereafter, often production efficiency is not high, cost big, its product also is difficult to guarantee to use chronicity.Though also some producer has adopted electrochemical deposition method, they also often electroforming go out single metal or its alloy product.Because single metal and alloy have various reasons can cause the metallic crystal defective in crystallization, and these defectives can greatly influence the various performances of metal material.Present office equipment all towards work high speed and photographic fixing low temperatureization trend under, this explained hereafter thin wall type metal parent tube also will be subjected to certain limitation its serviceable life.
Summary of the invention:
The object of the present invention is to provide a kind of thin-wall metal base pipe and manufacture method thereof of enhanced type, this metal parent tube is when high temperature uses, have preferable mechanical property and high temperature oxidation resistance, thereby guarantee to have than the long life when using at high speed, high temperature.While is easily manufactured, cost is controlled.
Technical scheme of the present invention is: a kind of thin-wall metal base pipe of enhanced type is characterized in that: be the metal parent tube of being made by the metal-base composites that the matrix metal and second mutually the insoluble nano-solid particulate are made.
The manufacture method of the thin-wall metal base pipe of above-mentioned enhanced type is characterized in that: the metal parent tube that the metal-base composites that the insoluble nano-solid particulate of the matrix metal and second phase is made by composite electroformed method is made.
Above-mentioned matrix metal can be: nickel (Ni) base, copper (Cu) base, cobalt (Co) base, ferronickel (Ni-Fe) base, nickel cobalt (Ni-Co) base, nickel manganese (Ni-Mn) base, nickel phosphorus (Ni-P) base or their alloy substrate metal.
The insoluble nano-solid diameter of particle of above-mentioned second phase is the 1-100 nanometer.
The insoluble nano-solid particulate of above-mentioned second phase is present in amount in the compound substance parent tube and accounts for percent by volume and be: 1-50%.
The garden diameter is in the above-mentioned metal parent tube: the 1-250 millimeter.
Above-mentioned Metal Substrate thickness of pipe is: the 1-200 micron.
Above-mentioned Metal Substrate length of tube is: the 10-2000 millimeter.
The insoluble nano-solid particulate of above-mentioned second phase can be for the nanoparticle of inanimate matter, can be the nanoparticle of organic matter, can also be metallic nanoparticle.
Advantage of the present invention is:
Since nano particle with the codeposition process of matrix metal in, the crystal grain that makes matrix metal greatly refinement and the second phase nano particle even dispersion in matrix metal.So the mechanical property of metal-base composites, Wear-resistant performance, decay resistance, high temperature oxidation resistance etc. have all had bigger lifting than composite metal host material not.Especially the composite metal parent tube is under higher temperature, still maintains its invigoration effect and begin to produce the stress value of high-temerature creep high greatly.Thereby fully guaranteed to improve requirement serviceable life with the metal thin-wall parent tube for fixing members such as modern office equipment field duplicating machine, printer, facsimile recorders.Thin-wall metal base pipe good combination property of the present invention, especially during the high temperature user mode, mechanical property, high temperature oxidation resistance are excellent.Long product lifecycle; In the manufacture method, the equipment less investment, producing cost is low, energy resource consumption is few, utilization rate of raw materials is than higher, and many kinds that are content with very little, and produces in enormous quantities.
Embodiment:
Embodiment 1:
By 350 (g/l) nickel sulfamic acid, 7.5 (g/l) nickel chloride, 30 (g/l) boric acid and an amount of various additives proportioning are made the electroforming base fluid, with 100 (g/l) nanometer Al
2O
3After dispersion liquid is deployed.Pour in the electrotyping bath, adopt ultrasonic method to disperse plating bath.With with the thin-wall metal base pipe uniform internal diameter and be that the stainless-steel tube of minute surface is a negative electrode through surface treatment.Setting current density is 3 (A/dm
2); The groove temperature is 50 ℃, and it is Ni-based and contain nanometer Al to make 40 microns of wall thickness
2O
3The compound substance parent tube of particulate.
Embodiment 2:
By 250 (g/l) nickelous sulfate, 4.5 (g/l) nickel chloride, 40 (g/l) boric acid and an amount of various additives proportioning are made the electroforming base fluid, with 30 (g/l) nanometer BN dispersion liquid deployed after.Pour in the electrotyping bath, adopt ultrasonic method to disperse plating bath.With with the thin-wall metal base pipe uniform internal diameter and be that the stainless-steel tube of minute surface is a negative electrode through surface treatment.Setting current density is 10 (A/dm
2); The groove temperature is 50 ℃, and it is Ni-based and contain the compound substance parent tube of nanometer BN particulate to make 50 microns of wall thickness.
Embodiment 3:
By 450 (g/l) nickel sulfamic acid, 10 (g/l) nickel chloride, 40 (g/l) boric acid, 1 (ml/l) cobalt chloride solution (50wet%) and an amount of various additives proportioning are made the electroforming base fluid, with 25 (g/l) nanometer Zro
2After dispersion liquid is deployed.Pour in the electrotyping bath, adopt ultrasonic method to disperse plating bath.With with the thin-wall metal base pipe uniform internal diameter and be that the stainless-steel tube of minute surface is a negative electrode through surface treatment.Setting current density is 2.5 (A/dm
2); The groove temperature is 53 ℃, makes 45 microns nickel cobalt-baseds of wall thickness and contains nanometer Zro
2The compound substance parent tube of particulate.
Embodiment 4:
By 200 (g/l) nickelous sulfate, 20 (g/l) ferrous sulphate, 40 (g/l) boric acid and an amount of various additives proportioning are made the electroforming base fluid, with 80 (g/l) nanometer sic dispersion liquid deployed after.Pour in the electrotyping bath, adopt ultrasonic method to disperse plating bath.With with the thin-wall metal base pipe uniform internal diameter and be that the stainless-steel tube of minute surface is a negative electrode through surface treatment.Setting current density is 3 (A/dm
2); The groove temperature is 60 ℃, makes 35 microns ferronickel bases of wall thickness and contains the compound substance parent tube of nanometer sic particulate.
Embodiment 5:
By 260 (g/l) nickelous sulfate, 4 (g/l) ferrous sulphate, 50 (g/l) boric acid and an amount of various additives proportioning are made the electroforming base fluid, with 15 (g/l) nanometer Cr dispersion liquid deployed after.Pour in the electrotyping bath, adopt ultrasonic method to disperse plating bath.With with the thin-wall metal base pipe uniform internal diameter and be that the stainless-steel tube of minute surface is a negative electrode through surface treatment.Setting current density is 4 (A/dm
2); The groove temperature is 40 ℃, makes the compound substance parent tube of 30 microns ferronickel chromium of wall thickness base.
Claims (9)
1. the thin-wall metal base pipe of an enhanced type is characterized in that: be the metal parent tube of being made by the metal-base composites that the matrix metal and second mutually the insoluble nano-solid particulate are made.
2. the manufacture method of the thin-wall metal base pipe of an enhanced type according to claim 1 is characterized in that: the metal parent tube that the metal-base composites that the insoluble nano-solid particulate of the matrix metal and second phase is made by composite electroformed method is made.
3. the thin-wall metal base pipe of enhanced type according to claim 1 is characterized in that: matrix metal can be nickel (Ni) base, copper (Cu) base, cobalt (Co) base, ferronickel (Ni-Fe) base, nickel cobalt (Ni-Co) base, nickel manganese (Ni-Mn) base, nickel phosphorus (Ni-P) base or their alloy substrate metal.
4. the thin-wall metal base pipe of enhanced type according to claim 1, it is characterized in that: the insoluble nano-solid diameter of particle of above-mentioned second phase is the 1-100 nanometer.
5. the thin-wall metal base pipe of enhanced type according to claim 1 is characterized in that: the insoluble nano-solid particulate of above-mentioned second phase is present in that amount according to percent by volume is in the compound substance parent tube: 1-50%.
6. the thin-wall metal base pipe of enhanced type according to claim 1 is characterized in that: the garden diameter is in the above-mentioned metal parent tube: the 1-250 millimeter.
7. the thin-wall metal base pipe of enhanced type according to claim 1, it is characterized in that: above-mentioned thin wall type Metal Substrate thickness of pipe is: the 1-200 micron.
8. the thin-wall metal base pipe of enhanced type according to claim 1 and manufacture method thereof, above-mentioned thin wall type Metal Substrate length of tube is: the 10-2000 millimeter.
9. the manufacture method of the thin-wall metal of enhanced type according to claim 2 is characterized in that: the insoluble nano-solid particulate of second phase can also be metallic nanoparticle for the nanoparticle of inanimate matter, organic nanoparticle.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910068578A CN101872147A (en) | 2009-04-22 | 2009-04-22 | Reinforced thin-wall metal base pipe and manufacturing method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910068578A CN101872147A (en) | 2009-04-22 | 2009-04-22 | Reinforced thin-wall metal base pipe and manufacturing method thereof |
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| CN101872147A true CN101872147A (en) | 2010-10-27 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN200910068578A Pending CN101872147A (en) | 2009-04-22 | 2009-04-22 | Reinforced thin-wall metal base pipe and manufacturing method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103205792A (en) * | 2013-04-15 | 2013-07-17 | 河南科技大学 | Plating solution for nickel-cubic boron nitride film through electroplating method and preparation method thereof |
| CN104534184A (en) * | 2014-12-01 | 2015-04-22 | 常熟市东涛金属复合材料有限公司 | Metal composite tube with low thermal expansion rate |
| CN114775003A (en) * | 2022-06-17 | 2022-07-22 | 浮山县广和精密制造有限公司 | Electroforming liquid, electroforming method and application of electroforming liquid in laser printer fixing film |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6077815A (en) * | 1996-06-01 | 2000-06-20 | Glyco-Metall-Werke Glyco B.V. & Co. Kg | Laminated material for sliding members, and process for the production thereof |
| JP2001125413A (en) * | 1999-10-27 | 2001-05-11 | Shinwa Denki Kk | Fixing roller for electrophotograph and its manufacturing method |
| CN1332272A (en) * | 2001-07-09 | 2002-01-23 | 杭州五源材料发展有限公司 | Manufacture of nanometer material reinforced electroformed crystalline metal product |
| JP2007169771A (en) * | 2005-12-19 | 2007-07-05 | Tadamasa Fujimura | Method of plating inside wall of narrow tube and narrow tube manufactured by the same plating method |
-
2009
- 2009-04-22 CN CN200910068578A patent/CN101872147A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6077815A (en) * | 1996-06-01 | 2000-06-20 | Glyco-Metall-Werke Glyco B.V. & Co. Kg | Laminated material for sliding members, and process for the production thereof |
| JP2001125413A (en) * | 1999-10-27 | 2001-05-11 | Shinwa Denki Kk | Fixing roller for electrophotograph and its manufacturing method |
| CN1332272A (en) * | 2001-07-09 | 2002-01-23 | 杭州五源材料发展有限公司 | Manufacture of nanometer material reinforced electroformed crystalline metal product |
| JP2007169771A (en) * | 2005-12-19 | 2007-07-05 | Tadamasa Fujimura | Method of plating inside wall of narrow tube and narrow tube manufactured by the same plating method |
Non-Patent Citations (2)
| Title |
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| 杨杰辉，程立新: "在复合镀层表面上实现滴状冷凝传热的研究", 《化学工程》 * |
| 程立新等: "复合电镀Ni-PTFE工艺和应用", 《电镀与环保》 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103205792A (en) * | 2013-04-15 | 2013-07-17 | 河南科技大学 | Plating solution for nickel-cubic boron nitride film through electroplating method and preparation method thereof |
| CN103205792B (en) * | 2013-04-15 | 2015-12-02 | 河南科技大学 | Electrochemical plating prepare plating solution of nickel-cubic boron nitride film and preparation method thereof |
| CN104534184A (en) * | 2014-12-01 | 2015-04-22 | 常熟市东涛金属复合材料有限公司 | Metal composite tube with low thermal expansion rate |
| CN114775003A (en) * | 2022-06-17 | 2022-07-22 | 浮山县广和精密制造有限公司 | Electroforming liquid, electroforming method and application of electroforming liquid in laser printer fixing film |
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Application publication date: 20101027 |