CN101870532A - Electrolytic water purifier capable of automatically controlling applied voltage based on water inflow change - Google Patents
Electrolytic water purifier capable of automatically controlling applied voltage based on water inflow change Download PDFInfo
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- CN101870532A CN101870532A CN200910164502A CN200910164502A CN101870532A CN 101870532 A CN101870532 A CN 101870532A CN 200910164502 A CN200910164502 A CN 200910164502A CN 200910164502 A CN200910164502 A CN 200910164502A CN 101870532 A CN101870532 A CN 101870532A
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/46104—Devices therefor; Their operating or servicing
- C02F1/4618—Devices therefor; Their operating or servicing for producing "ionised" acidic or basic water
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/46104—Devices therefor; Their operating or servicing
- C02F1/4618—Devices therefor; Their operating or servicing for producing "ionised" acidic or basic water
- C02F2001/4619—Devices therefor; Their operating or servicing for producing "ionised" acidic or basic water only cathodic or alkaline water, e.g. for reducing
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2201/00—Apparatus for treatment of water, waste water or sewage
- C02F2201/46—Apparatus for electrochemical processes
- C02F2201/461—Electrolysis apparatus
- C02F2201/46105—Details relating to the electrolytic devices
- C02F2201/4612—Controlling or monitoring
- C02F2201/46125—Electrical variables
- C02F2201/46135—Voltage
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2201/00—Apparatus for treatment of water, waste water or sewage
- C02F2201/46—Apparatus for electrochemical processes
- C02F2201/461—Electrolysis apparatus
- C02F2201/46105—Details relating to the electrolytic devices
- C02F2201/4612—Controlling or monitoring
- C02F2201/46145—Fluid flow
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2307/00—Location of water treatment or water treatment device
- C02F2307/10—Location of water treatment or water treatment device as part of a potable water dispenser, e.g. for use in homes or offices
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- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
Abstract
The present invention is about an electrolytic water purifier capable of automatically controlling applied voltage based on water inflow change, comprising an electrolytic part through a primary electrolytic tank divided into a primary acid water production electrode chamber and an alkaline water production electrode chamber and a secondary electrolytic tank divided into a secondary acid water electrode chamber, a strong alkaline water production electrode chamber and a weak alkaline water production motor chamber for twice electrolysis so as to respectively obtain three electrolytic ion water of strong alkaline water, acid water and weak alkaline water, wherein the electrolytic water purifier further comprises a flow sensor installed at the water inlet pipeline of the electrolytic part for detecting the water inflow flowing through a water valve, and a control part inputting the water inflow value detected by the flow sensor so as to automatically control the applied voltage of the electrolytic part based on the flow change. Therefore, the invention provides an electrolytic water purifier automatically controlling the applied voltage to maintain electrolysis stably all the time based on the water inflow change flowing into the electrolytic tank.
Description
Technical field
The present invention relates to by water is carried out the electrolysis water purifier that twice electrolysis obtains drinkable alkalescent water, relate in particular to based on the automatic control of the variation of flooding velocity and apply voltage, and carry out stable electrolysis thus, thereby can stablize and less expensive ground generates the electrolysis water purifier of three kinds of ion brine electrolysis of fine.
Background technology
For existing water is carried out electrolysis and is 7.4～8.5 the alkalescent water electrolysis water purifier as tap water with drinkable PH, the applicant is open No. the 651654th, Korean Patent grant number.The structure of this water purifier is by carrying out electrolytic electrolysis portion, the alkalescent water that generates by the electrolysis of described electrolysis portion being purified its water purification portion that can drink is constituted.
At this moment, described electrolysis portion is made of three electrode vessels that a positive plate and two negative plates are arranged between two barrier films that the ion that only makes in the water to be contained moves.Two cathode electrode chambers generate strong alkaline water and alkalescent water, and the anode electrode chamber generates the electrolytic ionic water of sour water.Wherein, drinkable alkalescent water is as tap water.
But, this water purifier is when generating three kinds of electrolytic ionic waters, because water is only carried out once electrolytic, thereby according to the difference of the character that flows into water, near the negative electrode hydrogen ion concentration is non-constant, and can not remove positively charged ion fully, thereby be difficult to reduce redox potential, therefore can not stably obtain alkalescent water.
And then in order to address the above problem, twice electrolysis brought out in No. the 419536th, the Korean Patent mandate that the applicant applied for, obtained stable alkalescent water thus.But the shortcoming of this structure is: bring out the competent electrolytic time of discharge owing to grasping in electrolytic process, thereby can not obtain containing the high-quality alkalescent water of a large amount of active hydrogens and active mineral.
And, though formerly the Korean Patent mandate of Shou Quaning has been guaranteed to bring out the electrolytic time for No. 651654, but because the voltage that is applied to electrolyzer keeps constant always, thereby along with being provided with that place and changes of seasons change and the difference in flow that causes causes the electrolysis characteristic irregular.
Therefore, not only can not stably obtain containing the high-quality alkalescent water of abundant active hydrogen and active mineral, and, because variable electrolysis state causes consumed power to increase, therefore also need to come maintenance management to be used to obtain the water purifier of alkalescent drinking water with high ground expense.
Summary of the invention
Invention proposes in order to address the above problem, its purpose is to provide the flooding quantity that no matter flows into electrolysis portion also can carry out stable electrolysis, thus also can be always under low consumpting power stably and less expensive obtain comprising the electrolysis water purifier of the electrolytic ionic water of drinkable alkalescent water.
The object of the invention to solve the technical problems realizes by the following technical solutions.Can control the electrolysis water purifier that applies voltage automatically according to a kind of variation that the present invention proposes based on flooding quantity, this electrolysis water purifier has: generate the once electrolytic groove of electrode vessel and alkaline water generation electrode vessel and be divided into the acid water electrode of secondary chamber by being divided into a sour water, strong alkaline water generates electrode vessel, the re-electrolysis groove that alkalescent water generates the motor room carries out twice electrolysis and obtains strong alkaline water respectively water, sour water, the electrolysis portion of these three kinds of electrolytic ionic waters of alkalescent water, wherein, described electrolysis water purifier also comprises: be located at the flow sensor of the entry pipeline of electrolysis portion, to be used to detect the influx by the inflow water of going into the water valve inflow; Input is according to the flux values of the inflow water of described flow sensor mensuration, to control the control part that applies voltage of electrolysis portion automatically based on fluctuations in discharge.
The object of the invention to solve the technical problems also can be applied to the following technical measures to achieve further.
Aforesaid electrolysis water purifier, wherein, the entry pipeline of described electrolysis portion also is provided with the ionogen detecting sensor that is used to detect the electrolytical amount that flows into water, and the electrolytical detected value of the inflow water of measuring by described ionogen detecting sensor is input to described control part, automatically regulates the voltage that applies of self-acting control portion based on the variation of the electrolytical amount that flows into water thus.
Aforesaid electrolysis water purifier, wherein, described control part operates to and makes based on the scope that applies voltage of the electrolyzer of the inflow water yield that flow into described electrolysis portion to as following table four～table seven.
It is that the electrolysis portion of 1.2L when following applies the voltage-regulation scope that table four flows into the water yield
| Sequence number | Conduction impedance (K) | Electrolyzer applies voltage (V) |
| ??1 | More than 42 | ??20.4 |
| ??2 | Below 42～more than 38 | ??18.0 |
| ??3 | Below 38～more than 32 | ??15.6 |
| ??4 | Below 32～more than 26 | ??13.2 |
| ??5 | Below 26～more than 21 | ??10.8 |
| ??6 | Below 21～more than 16 | ??8.4 |
| ??7 | Below 16 | ??6 |
Table five flows into the water yield and is more than 1.2～and electrolysis portion when 1.4L is following applies the voltage-regulation scope
| Sequence number | Conduction impedance (K) | Electrolyzer applies voltage (V) |
| ??1 | More than 42 | ??21.6 |
| ??2 | Below 42～more than 38 | ??19.2 |
| ??3 | Below 38～more than 32 | ??16.8 |
| ??4 | Below 32～more than 26 | ??14.4 |
| ??5 | Below 26～more than 21 | ??12 |
| ??6 | Below 21～more than 16 | ??9.6 |
| Sequence number | Conduction impedance (K) | Electrolyzer applies voltage (V) |
| ??7 | Below 16 | ??7.2 |
Table six flows into the water yield and is more than 1.4～and electrolysis portion when 1.6L is following applies the voltage-regulation scope
| Sequence number | Conduction impedance (K) | Electrolyzer applies voltage (V) |
| ??1 | More than 42 | ??22.8 |
| ??2 | Below 42～more than 38 | ??20.4 |
| ??3 | Below 38～more than 32 | ??18.0 |
| ??4 | Below 32～more than 26 | ??15.6 |
| ??5 | Below 26～more than 21 | ??13.2 |
| ??6 | Below 21～more than 16 | ??10.8 |
| ??7 | Below 16 | ??8.4 |
It is that the electrolysis portion of 1.6L when above applies the voltage-regulation scope that table 7 flows into the water yield
| ??NO | Conduction impedance (K) | Electrolyzer applies voltage (V) |
| ??1 | More than 42 | ??24 |
| ??2 | Below 42～more than 38 | ??21.6 |
| ??3 | Below 38～more than 32 | ??19.2 |
| ??4 | Below 32～more than 26 | ??16.8 |
| ??5 | Below 26～more than 21 | ??14.4 |
| ??6 | Below 21～more than 16 | ??12 |
| ??7 | Below 16 | ??9.6 |
Aforesaid electrolysis water purifier wherein comprises: a sour water relief outlet that is formed on described sour water generation electrode vessel is formed with the sour water regulation cock, to be used to regulate the aquifer yield of a sour water; Be formed on the secondary sour water relief outlet that the acid water of described secondary generates electrode vessel and be formed with sour water water outlet bolt, to be used to regulate the aquifer yield with the secondary sour water that is discharged from after a sour water by described sour water regulation cock discharge mixes; The strong alkaline water relief outlet is formed with strong alkaline water water outlet bolt, to be used to regulate the aquifer yield of strong alkaline water; The weakly alkaline relief outlet is formed with the alkalescent water outlet valve, to be used to regulate the aquifer yield of alkalescent water; Posttreatment filter being used for when described alkalescent water passes through this posttreatment filter by described alkalescent water outlet valve, determines the water yield according to the pressure drop of its inside.
Aforesaid electrolysis water purifier wherein, is adjusted to 1 with the water outlet proportion of described sour water and described alkaline water: (12～15); The water outlet proportion of described strong alkaline water, described alkalescent water and described sour water is adjusted to 1: (1.5～2): (1～1.1).
Aforesaid electrolysis water purifier, wherein, the described alkalescent water of described alkalescent water outlet valve with the discharge of making flow into the function of changing between the cleaning model that described posttreatment filter discharges by the surplus water outlet pipeline with the water purification pattern that purifies and the alkalescent water that cuts off the passage that flows into posttreatment filter and make described discharge.
Aforesaid electrolysis water purifier, wherein, the lower end inflow portion that is formed with the influx of described once electrolytic groove is equipped with an entry and regulates film, to be used to regulate the ratio that a described sour water generates the water yield of electrode vessel and described alkaline water generation electrode vessel that flow into; The lower end inflow portion of described re-electrolysis groove is equipped with the secondary entry and regulates film, to be used to regulate the ratio that the acid water of described secondary generates the water yield of electrode vessel, described strong alkaline water generation electrode vessel and described alkalescent water generation electrode vessel that flow into.
Aforesaid electrolysis water purifier, wherein, described entry is regulated to be formed with on the film to make and is flow into a described sour water to generate ratio that electrode vessel and described alkaline water generate the water yield of electrode vessel be 1: 4 water inlet.
Aforesaid electrolysis water purifier, wherein, described secondary entry is regulated to be formed with on the film to make and is flow into the acid water of described secondary and generate electrode vessel, described strong alkaline water to generate ratio that electrode vessel and described alkalescent water generate the water yield of electrode vessel be 1: 1: 10 water inlet.
Aforesaid electrolysis water purifier, wherein, described electrolysis portion upper inside face assembling silicon liner mixes with the water between each electrode vessel that is used for preventing described once electrolytic groove and re-electrolysis groove.
Aforesaid electrolysis water purifier, wherein, the inside lower end of described electrolysis portion forms battery lead plate fitting recess and barrier film fitting recess, to be used to keep the determining deviation between battery lead plate and the barrier film.
The present invention compared with prior art has tangible advantage and beneficial effect.As known from the above, for achieving the above object, the invention provides a kind of electrolysis water purifier and comprise: the flow sensor that is located at the entry pipeline of electrolysis portion; Input has the control part of the flux values of the inflow water of measuring by described flow sensor, to be used for regulating the voltage that applies of electrolysis portion automatically based on the fluctuations in discharge that flows into water.And the entry pipeline has the ionogen detecting sensor that is used to detect electrolytical amount, thus according to the variation based on the electrolytical amount that flows into discharge, applies voltage by automatic adjusting of control part.
By technique scheme, the variation that the present invention is based on flooding quantity can be controlled the electrolysis water purifier that applies voltage automatically and have following advantage and beneficial effect at least:
Water purifier of the present invention, apply voltage and form stable always electrolysis by regulating automatically based on the fluctuations in discharge that flows into water, thus by stably carrying out electrolysis, not only consume lower power compared to existing technology, but also can access three kinds of electrolytic ionic waters of pH value almost stable, thereby not only can stably obtain can be used as the high-quality alkalescent water of tap water, but also the sour water that can stably obtain can be used as the strong alkaline water of washing water and can be used as washing water, thereby can separately use by purposes.
And, according to variation, regulate and apply voltage, thereby can access more stable electrolytic ionic water based on the electrolytical amount of the flow that flows into water, therefore can access the fine alkalescent water that contains abundant active hydrogen and as tap water.
In sum, the present invention relates to by water is carried out the electrolysis water purifier that twice electrolysis obtains drinkable alkalescent water, relate in particular to based on the automatic control of the variation of flooding quantity and apply voltage, and carry out stable electrolysis thus, thereby can stablize and less expensive ground generates high-quality ion brine electrolysis and the electrolysis water purifier supplied with.Existingly water is carried out twice electrolysis and obtain the electrolysis water purifier of alkalescent water, keep constant owing to be applied to the voltage of electrolyzer always, thereby along with place and changes of seasons are set, when the flow that flow into the inflow water of electrolyzer changed, the electrolysis of carrying out was irregular.Therefore, because variable electrolysis, it is big that consumed power becomes, the pH value instability of three kinds of electrolytic ionic waters of discharge, thus can not stably obtain the fine alkalescent water.Therefore, the invention provides by based on the fluctuations in discharge of the inflow water that flow into electrolyzer automatically control apply voltage and come stably to keep electrolytic electrolysis water purifier always.The present invention has obvious improvement technically, and has tangible positively effect, really is a new and innovative, progressive, practical new design.
Above-mentioned explanation only is the general introduction of technical solution of the present invention, for can clearer understanding technique means of the present invention, and can be implemented according to the content of specification sheets, and for above-mentioned and other purposes, feature and advantage of the present invention can be become apparent, below especially exemplified by preferred embodiment, and conjunction with figs., be described in detail as follows.
Description of drawings
Fig. 1 is the system diagram that the brief configuration of the embodiment of water purifier according to the present invention is shown.
Fig. 2 is the structure iron of the electrolysis portion of water purifier of the present invention.
Fig. 3 is the side-view of the electrolysis portion of water purifier of the present invention.
Fig. 3 a is the vertical view of the electrolysis portion of water purifier of the present invention.
Fig. 4 is the brief configuration figure of the ionogen detecting sensor of water purifier of the present invention.
Fig. 5 is the longitudinal section of water purifier of the present invention.
Fig. 6 illustrates the longitudinal section that the flow passage of film is regulated in once water inlet.
Fig. 6 a illustrates the sectional elevation that the flow passage of film is regulated in once water inlet.
Fig. 7 illustrates the longitudinal section that the flow passage of film is regulated in the secondary water inlet.
Fig. 7 a illustrates the sectional elevation that the flow passage of film is regulated in the secondary water inlet.
1: 2: partition walls of electrolysis portion
3: secondary partition wall 4: flow passage
5: 6: sour water relief outlets of influx
7: secondary sour water relief outlet 8: strong alkaline water relief outlet
9: alkalescent water relief outlet 10: the once electrolytic groove
12: sour waters of 11: barrier films generate electrode vessel
13: alkaline water generates electrode vessel 14: positive plate
15: negative plate 16: once film is regulated in water inlet
17: film 18 is regulated in the secondary water inlet: silicagel pad
19: water intaking valve 20: the re-electrolysis groove
21,22: secondary barrier film 23: the acid water of secondary generates electrode vessel
24: strong alkaline water generates electrode vessel 25: alkalescent water generates electrode vessel
26: positive plate 27,28: negative plate
29: ionogen detecting sensor 31: the alkalescent water outlet valve
32: test pin 33: flow sensor
34: sour water regulation cock 35: sour water water outlet bolt
36: strong alkaline water water outlet bolt 39: control part
40: power supply unit 41: posttreatment filter
42: pre-treatment strainer 43: water lines
44: outlet pipeline 45: the rinse water outlet pipeline.
Embodiment
Reach technique means and the effect that predetermined goal of the invention is taked for further setting forth the present invention, below in conjunction with accompanying drawing and preferred embodiment, can control its embodiment of electrolysis water purifier, structure, feature and the effect thereof that apply voltage automatically to the variation based on flooding quantity of foundation the present invention proposition and be elaborated.
Below, with reference to description of drawings the preferred embodiments of the present invention.
As shown in Figure 1, electrolysis water purifier of the present invention has and can carry out twice electrolysis by once electrolytic groove 10 and 20 pairs of water of re-electrolysis groove and obtain the electrolysis portion 1 of three kinds of electrolytic ionic waters such as strong alkaline water, sour water, alkalescent water respectively.Described electrolysis water purifier also comprises: be located at the flow sensor 33 of the entry pipeline 43 of electrolysis portion 1, to be used to detect the influx by the inflow water of going into water valve 33 inflows; Input has the control part 39 of the flux values of the inflow water that utilizes described flow sensor 33 mensuration, to be used for controlling automatically based on the fluctuations in discharge that flows into water the voltage that applies of electrolysis portion 1.
At this moment, the front end of described electrolysis portion 1 has and is used for flowing into the pre-treatment strainer 42 that carries out clean water treatment before the electrolysis portion 1 flowing into water, and the rear end has posttreatment filter, to be used for the drinking alkalescent water that is applied as tap water of discharging by electrolysis portion 1 more safely.
At this moment, described pre-treatment strainer 42 is owing to make with the material that can remove the foreign matter that flows into water or organism, rust, chlorine, peculiar smell, thereby has a water purification function, and owing to be located at the front end of described electrolysis portion 1, water was cleaned before electrolysis in advance, thereby not only can prevent that electrolysis portion 1 from breaking down, but also have excellent purifying water effect.
Below, further describe the structure of described electrolysis portion 1.
As depicted in figs. 1 and 2, being included in electrolysis of the present invention portion 1 is formed with partition wall 2 of peristome 2a and bottom according to top and is formed with the flow passage 4 that forms between the secondary partition wall 3 of peristome 3a and is divided into once electrolytic groove 10 and re-electrolysis groove 20.
At this moment, described once electrolytic groove 10 is in lower openings and under the state of top sealing, and a barrier film 11 that is closed according to top is divided into two electrode vessels and forms that sour water generates electrode vessel 12 and alkaline water generates electrode vessel 13.And,, in a sour water generation electrode vessel 12, generate sour water for the first time, and in alkaline water generation electrode vessel 13, generate alkaline water according to positive plate 14 that is installed in each electrode vessel and negative plate 15.
And, described re-electrolysis groove 20 is in lower openings and under the state of top sealing, and two the secondary barrier films 21,22 that are closed according to top are divided into three electrode vessels and form that the acid water of secondary generates electrode vessel 23 and alkalescent water generates electrode vessel 24 and strong alkaline water generates electrode vessel 25.According to a positive plate 26 and two negative plates 27,28 of being installed in each electrode vessel, generate secondary time generation sour water in the electrode vessel 23 at the acid water of secondary, and in alkalescent water generation electrode vessel 24, generate alkalescent water, generate in the electrode vessel 25 at strong alkaline water and generate strong alkaline water.
And, be formed on the sour water regulation cock 34 that a sour water relief outlet 6 that described sour water generates electrode vessel 12 is formed with the aquifer yield that is used for regulating a sour water, be formed with the sour water water outlet bolt 35 that is used for regulating with the aquifer yield of the secondary sour water that is discharged from after a sour water by described sour water regulation cock 34 discharges mixes and be formed on secondary sour water relief outlet 7 that the acid water of described secondary generates electrode vessel 23, and strong alkaline water relief outlet 8 is formed with the strong alkaline water water outlet bolt 36 of the aquifer yield that is used for regulating strong alkaline water, and weakly alkaline relief outlet 9 is formed with the alkalescent water outlet valve 31 of the aquifer yield that is used for regulating alkalescent water, can regulate the water outlet proportion of three kinds of electrolytic ionic waters in view of the above.
Promptly, the ratio of the sour water that generates in once electrolytic groove 10 and the aquifer yield of alkaline water is determined according to the sour water regulation cock 34 that is formed on the sour water relief outlet 6 of once electrolytic groove 10, be discharged to an outside sour water with determined water outlet proportion and mix, and alkaline water is discharged with three kinds of electrolytic ionic waters (alkalescent water, strong alkaline water, sour water) respectively through electrolysis after flowing into re-electrolysis groove 20 with the secondary sour water of discharging from re-electrolysis groove 20.At this moment, the secondary sour water of discharging from re-electrolysis groove 20 mixes with a sour water of sour water regulation cock 34 by once electrolytic groove 10, and when passing through sour water regulation cock 35, its aquifer yield is determined according to this sour water regulation cock 35; And the strong alkaline water of discharging from re-electrolysis groove 20 is determined its aquifer yields according to this strong alkaline water water outlet bolt 36 during through strong alkaline water water outlet bolt 36; During alkalescent water process posttreatment filter 41, its aquifer yield is determined according to the pressure drop of posttreatment filter 41 inside.
At this moment, described alkalescent water outlet valve 31 makes the alkalescent water of discharge flow into described posttreatment filter 41 and discharges through after the purifying treatment, operates to the water purification pattern in view of the above; Perhaps, alkalescent water outlet valve 31 cuts off to the flow channel of posttreatment filter 41 and will make alkaline water be discharged to surplus water outlet pipeline 45, and converting the surplus water that makes discharge in view of the above to can be as the cleaning model of multi-purpose rinse water.Thereby alkalescent water outlet valve 31 can be changed between water purification pattern and cleaning model.
And, the sour water of discharging by described sour water regulation cock 34 and the water outlet proportion of alkaline water are controlled at 1: (12～15), and the water outlet proportion of strong alkaline water of discharging by strong alkaline water water outlet bolt 36 and the alkalescent water of discharging by alkalescent water relief outlet 9 and the sour water of discharging by sour water water outlet bolt 35 is controlled at 1: and (1.5～2): (1～1.1).
At this moment, if the water outlet proportion of described sour water and alkaline water and the water outlet proportion of strong alkaline water and alkalescent water and sour water exceed described scope, then bigger variation can take place in the pH value of the electrolytic ionic water of Pai Chuing, thereby can not stably obtain three kinds of electrolytic ionic waters.
And the lower end inflow portion that is formed with the influx 5 of described once electrolytic groove 10 is equipped with an entry and regulates film 16, regulates flowing into sour water and generate the ratio that electrode vessel 12 and alkaline water generate the water yield of electrode vessel 13 with this.And the lower end inflow portion of described re-electrolysis groove 20 is equipped with secondary entry adjusting film 17, regulates the ratio that the acid water of secondary generates the water yield of electrode vessel 23 and strong alkaline water generation electrode vessel 24 and alkalescent water generation electrode vessel 25 that flow into this.
At this moment, shown in Fig. 6,6a and Fig. 7,7a, film 16 is regulated in a described entry and film 17 comes regulating pondage respectively by the quantity of water inlet 16a, 17a ratio is regulated in the secondary entry, and this water inlet 16a, 17a form with identical size and be used to move the water to flow into to each electrode vessel 12,13,23,24,25.
At this moment, described entry quantity of regulating the water inlet 16a that forms on the film 16 can make and flow into sour water to generate the ratio that electrode vessel 12 and alkaline water generate the water yield of electrode vessel 13 be 1: 4.And described secondary entry is regulated the quantity of the water inlet 17a that forms on the film 17 and can be made and flow into the acid water of secondary and generate electrode vessel 23 and strong alkaline water to generate the ratio that electrode vessel 24 and alkalescent water generate the water yield of electrode vessel 25 be 1: 1: 10.
Therefore, under this water yield ratio, the PH of the electrolytic ionic water of discharge changes little, thereby can access stable electrolytic ionic water.
In view of the above, the inflow water that influx 5 by described once electrolytic groove 10 flows into, regulating film 16 according to an entry determines to flow into sour water and generates the water yield that electrode vessel 12 and alkaline water generate electrode vessel 13, thereby there is grace time to carry out electrolysis filling the time gradually, generates the sour water that generates in the electrode vessel 12 at sour water in view of the above and be discharged to the outside by a sour water relief outlet 6 that is formed at sour water and generates electrode vessel 12 tops; Flow into flow passage 4 by top by the peristome 2a of a partition wall 2 of opening and generate the alkaline water that generates in the electrode vessel 13, and move to the bottom of second electrode groove 20 by flow passage 4 at alkaline water.
After this, the alkaline water that in one-time electrode groove 10, generates, regulate film 17 according to the secondary entry and determine to flow into the water yield that the acid water of secondary generates electrode vessel 23, strong alkaline water generation electrode vessel 24 and alkalescent water generation electrode vessel 25, thereby the filling water level has grace time to carry out electrolysis when rising gradually, the secondary sour water relief outlet 7 of the sour water, strong alkaline water, alkalescent water that is created on each electrode vessel 23,24,25 in view of the above by electrolysis by being formed on each electrode vessel 23,24,25 top, strong alkaline water relief outlet 8, alkalescent water relief outlet 9 and be discharged from respectively.
And, electrolysis portion 1 upper inside face is equipped with the upper side of being close to described negative plate 15,27,28 and positive plate 14,26 and first and second barrier film 11,21,22 and first and second partition wall 2,3, prevents the water blended silicagel pad 18 between each electrode vessel 23,24,25 of each electrode vessel 12,13 of once electrolytic groove 10 and re-electrolysis groove 20 in view of the above.
And the inside lower end of described electrolysis portion 1 forms battery lead plate fitting recess 14a, 15a, 26a, 27a, 28a and barrier film fitting recess 11a, 21a, 22a, being used to keep the determining deviation between battery lead plate and the barrier film, thereby reduces the assembling deviation between product.
And 11,21,22 in first and second barrier film that is formed in described first and second electrolyzer 10,20 allows the ion in the water to pass through.
And, the alkalescent water of discharging from the alkalescent water relief outlet 9 of electrolyzer is during through alkalescent water outlet valve 31 and by posttreatment filter 41, can adsorb the chlorine that remains in the alkalescent water and small organism and remove peculiar smell, thereby the raising mouthfeel, and utilize active carbon loading silver can suppress the breeding of bacterium.
Therefore, the generative process of the electrolytic ionic water that can obtain by the water purifier of the present invention that constitutes as above-mentioned structure is as follows.
At first, the water that is cleaned in water purification portion flow into the bottom of once electrolytic groove 10 by the influx 5 of electrolysis portion 1, and the water level of the water that flows into is when rising gradually, according to be provided to the positive plate 14 of power supply and the power supply of negative plate 15 by power supply unit 40, a sour water between positive plate 14 and barrier film 11 generates in the electrode vessel 12 and generates sour water, this sour water will be discharged by a sour water relief outlet 6, and the alkaline water between barrier film 11 and the positive plate 15 generates and generates alkaline water in the electrode vessel 13, this alkaline water will flow into flow passage 4 by the peristome 2a of a partition wall 2, and flow into the below of re-electrolysis groove 20 by flow passage 4.
After this, the alkaline water that the peristome 3a of the secondary partition wall 3 by re-electrolysis groove 20 flows into from the below is according to being provided to positive plate 26 and negative plate 27 by power supply unit 40,28 power supply, the acid water of secondary between positive plate 26 and secondary barrier film 21 generates in the electrode vessel 23 and generates sour water, this sour water will converge the back with the sour water that generates and discharge and use as washing water by secondary sour water relief outlet 7 in once electrolytic groove 10, and generate strong alkaline water between secondary barrier film 21 and negative plate 27 and in the generation of the strong alkaline water between negative plate 27 and the secondary barrier film 22 electrode vessel 24, this strong alkaline water will be discharged from and use as washing water by strong alkaline water relief outlet 8, and, alkalescent water between secondary barrier film 22 and negative plate 28 generates in the electrode vessel 25 and generates alkalescent water, and this alkalescent water will be discharged from and use as tap water by alkalescent water relief outlet 9.
Therefore, in re-electrolysis groove 20, electrolysis occurs in from the bottom gradually equally to the alkaline water that fill on top, can stably carry out electrolysis in view of the above, and because adequate time is arranged, thereby can ion fully be exchanged by barrier film.
And the water purifier of the present invention that is made of said structure is measured the flow that flows into water by flow sensor 33, and regulates based on the fluctuations in discharge of inflow water by control part 39 and to apply voltage, thereby keeps the electrolysis of the appropriateness in the electrolysis portion all the time.
Promptly, if it is less to be delivered to the flux values of described control part 9, then explanation is slower by the flow velocity of the water of electrolysis portion 1, therefore reduce and apply voltage and reduce the electrolysis amount, and if flux values is more, then raising applies voltage increases the electrolysis amount, in view of the above, do not flow into electrolysis portion 1 flow influence and can access alkalescent water, strong alkaline water and sour water with stable pH value.
Below, can confirm that by the table one that from embodiment 1, obtains and the value of table two water purifier of the present invention can be regulated automatically based on the flow that flows into water and apply voltage and stably discharge fine alkalescent water, strong alkaline water, sour water.
＜embodiment one 〉
Test conditions:
-enter total inflow water yield of electrolyzer: 0.8L/min～1.5L/min
Table one is less than the electrolysis characteristic of the existing electrolysis water purifier of controlling based on flow
The electrolysis characteristic of the electrolysis water purifier of the present invention that table two is controlled based on flow
The measured value of the situation that table of measuring by the foregoing description one one and table two are controlled for situation about not controlling based on flow with based on flow.With reference to table one, for existing water purifier,, change even therefore flow into the flow of water owing to do not control based on flow, still apply constant voltage to electrolyzer, thus when flow hour, electrolysis is stronger,, and work as flow more for a long time, the electrolysis amount is less.Therefore, the electrolysis characteristic changes according to the flow that flows into water, thereby can confirm the alkalescent water, the strong alkaline water that generate according to electrolysis, and the pH value of sour water changes greatly.
Otherwise, with reference to table two, for water purifier of the present invention, change the voltage that is applied to electrolyzer by detecting the inflow water yield based on flow, therefore work as flow more for a long time, the voltage that is applied to electrolyzer uprises, when flow hour, the voltage that is applied to electrolyzer is step-down then, thereby can confirm the alkalescent water, the strong alkaline water that generate according to electrolysis, the pH value of sour water changes less, can access the electrolysis characteristic of all-the-time stable thus.
In addition, water purifier of the present invention also is provided with the ionogen detecting sensor 29 that is used to detect the electrolytical amount that flows into water in the entry pipeline 43 of electrolysis portion 1, thereby the electrolytical detected value of the inflow water that will measure by described ionogen detecting sensor 29 is input to described control part 39, and regulate at control part 39 based on the variation of the electrolytical amount that flows into water and to apply voltage, make electrolysis portion stably carry out appropriate electrolysis thus always.
At this moment, described ionogen detecting sensor 29 is guaranteed to store the space that flows into water in the central authorities of the main body 29a of up/down perforation, and is inserted test pin 29b herein as shown in Figure 4.
At this moment, electrolytical detection is to be undertaken by sampling when out of service when moving applying power supply to water purifier and after using.
At this moment, if will carry out the water purifier sampling, then need water at ionogen detecting sensor 29 internal flow certain hours, close then into water valve 19, through certain hour, when the water that accumulates in ionogen detecting sensor 29 inside does not tremble and when stablizing, apply power supply to test pin 29b and measure the electric current at the test pin 29b two ends of flowing through, utilize the conduction resistance value of the water of ionogen detecting sensor 29 inside to measure electrolytical amount thus, at this moment, the low more then ionogen of conduction resistance value is many more.
At this moment, keep constant electrolysis amount, then need to keep stable electric current in order to make described electrolysis portion 1.Therefore, when the electrolytical amount by described ionogen detecting sensor 29 detected inflow water more for a long time, reduce the magnitude of voltage that is applied to electrolysis portion 1, otherwise electrolytical amount improves the magnitude of voltage that is applied to electrolysis portion 1 more after a little while, to keep the constant electrolysis.
And then the following examples two can confirm that by table three water purifier of the present invention stably obtains the fine alkalescent water by the variation regulating voltage based on the electrolytical amount that flows into water.
＜embodiment two 〉
Test conditions:
-flow into total inflow water yield of electrolyzer: 1.4L/min, flow into the PH:7.6 of water
Table three is based on the electrolysis characteristic of the variation of electrolytical amount
Above-mentioned table three shows electrolysis characteristic based on the variation of electrolytical amount by measuring based on the voltage that is applied to electrolysis portion and the electrical current of the electrolytical variation that flow into electrolysis portion (variation of conduction impedance) and the PH characteristic of measuring each drainage water.This can be seen that, when the less and conduction resistance value of electrolytical amount is big, increase the voltage that is applied to electrolysis portion, otherwise, when the more and conduction resistance value of electrolytical amount hour, reduce the voltage that is applied to electrolysis portion.
And, it can also be seen that, less based on the deviation of the PH characteristic of the electrolyzer electrical current value of the variation of electrolytical amount and each drainage water.
Therefore, according to described embodiment two susceptible of proofs, if regulate the voltage of electrolysis portion by detecting the inflow electrolytical amount that water contained, even then flowing into the electrolytical amount of water changes, also can carry out the constant electrolysis all the time, thereby can access fine electrolysis drainage water, i.e. fine alkalescent water, strong alkaline water, sour water.
At this moment, electrolysis water purifier of the present invention, the voltage that is applied to electrolyzer based on electrolytical variation is to regulate its regulation range such as following table four～table seven according to the flow that flow into water purifier.
It is that the electrolysis portion of 1.2L when following applies the voltage-regulation scope that table four flows into the water yield
| Sequence number | Conduction impedance (K) | Electrolysis portion applies voltage (V) |
| ??1 | More than 42 | ??20.4 |
| ??2 | Below 42～more than 38 | ??18.0 |
| Sequence number | Conduction impedance (K) | Electrolysis portion applies voltage (V) |
| ??3 | Below 38～more than 32 | ??15.6 |
| ??4 | Below 32～more than 26 | ??13.2 |
| ??5 | Below 26～more than 21 | ??10.8 |
| ??6 | Below 21～more than 16 | ??8.4 |
| ??7 | Below 16 | ??6 |
Table five flows into the water yield and is more than 1.2～and electrolysis portion when 1.4L is following applies the voltage-regulation scope
Table six flows into the water yield and is more than 1.4～and electrolysis portion when 1.6L is following applies the voltage-regulation scope
It is that the electrolysis portion of 1.6L when above applies the voltage-regulation scope that table 7 flows into the water yield
And, water purifier of the present invention, certain water outlet proportion of the strong alkaline water that generates according to electrolysis by control, sour water, alkalescent water can obtain containing the alkalescent water of a large amount of active hydrogens and active mineral.
Promptly, the ratio of the sour water that produces in once electrolytic groove 10 and the aquifer yield of alkaline water is determined according to the sour water regulation cock 34 that is formed at the sour water relief outlet 6 of once electrolytic groove 10, be discharged to an outside sour water with determined water outlet proportion thus and mix, and alkaline water is discharged with three kinds of electrolytic ionic waters (alkalescent water, strong alkaline water, sour water) respectively through electrolysis after flowing into re-electrolysis groove 20 with the secondary sour water of discharging from re-electrolysis groove 20.At this moment, the secondary sour water of discharging from re-electrolysis groove 20 mixes with a sour water of sour water regulation cock 34 by once electrolytic groove 10, and when passing through sour water regulation cock 35, its aquifer yield is determined according to this sour water regulation cock 35; And the strong alkaline water of discharging from re-electrolysis groove 20 is determined its aquifer yields according to this strong alkaline water regulation cock 36 through strong alkaline water regulation cock 36 time; During alkalescent water process posttreatment filter 41, its aquifer yield is determined according to the pressure drop of posttreatment filter 41 inside.
At this moment, the water outlet proportion of strong alkaline water and alkalescent water and sour water is controlled at 1: (1.5～2): (1～1.1).
At this moment, if the water outlet proportion of described strong alkaline water and alkalescent water and sour water exceeds described scope, then bigger variation can take place in the pH value of the electrolytic ionic water of Pai Chuing, thereby can not stably obtain three kinds of electrolytic ionic waters.
Therefore, the determined aquifer yield of water outlet proportion is determined the aquifer yield of strong alkaline water, alkalescent water, sour water according to the total flux that flow into water purifier as mentioned above, and is as shown in the table.
Table eight is according to the total inflow water yield that flow into water purifier and the aquifer yield of definite electrolytic ionic water
The strong alkaline water of discharging from electrolysis water purifier of the present invention by the water outlet proportion shown in the described table eight stably maintains more than the PH9.0, and alkalescent water stably maintains PH7.4～8.5, and sour water stably maintains below the PH6.9.
Therefore therefore, this water outlet proportion makes as the aquifer yield of the alkalescent water of tap water more with respect to other ionized waters, for the user of functions of use water not, the water waste is minimized.
And water purifier of the present invention can prevent electrolysis portion 1 fouling (schelling) by multiple cleaning way.
That is, can prevent 1 fouling of electrolysis portion by multiple cleaning way.Prevent that by multiple cleaning way 1 fouling of electrolysis portion is meant, the calcium ion that produces when preventing electrolysis portion 1 and the fouling that causes by electrolysis.To this, to prevent that calcium is in the electrolyzer inside deposition by periodically working repeatedly and connect contrary power supply to electrolysis portion when the cleaning model between water purification pattern and cleaning model with vain hope.But, if be that 5～20L calculates, also can not carry out cleaning model in 3～5 days, so calcium can be deposited on electrolyzer inside even then use by the usage quantity of every day in the average family, in view of the above, the electrolysis performance reduces, and water outlet is blocked.In order to address the above problem, the present invention uses by periodically carrying out water purification pattern and cleaning model repeatedly and finishes the cleaning way of cleaning and move the multiple cleaning way that carries out the cleaning model of certain hour when stopping afterwards.So, by using this multiple cleaning way, cause fouling at the inner calcium ion that produces of electrolyzer when preventing owing to electrolysis.
The above, it only is preferred embodiment of the present invention, be not that the present invention is done any pro forma restriction, though the present invention discloses as above with preferred embodiment, yet be not in order to limit the present invention, any those skilled in the art, in not breaking away from the technical solution of the present invention scope, when the technology contents that can utilize above-mentioned announcement is made a little change or is modified to the equivalent embodiment of equivalent variations, in every case be the content that does not break away from technical solution of the present invention, according to technical spirit of the present invention to any simple modification that above embodiment did, equivalent variations and modification all still belong in the scope of technical solution of the present invention.
Claims (11)
1. the variation based on flooding quantity can be controlled the electrolysis water purifier that applies voltage automatically, this electrolysis water purifier has: generate electrode vessel and alkaline water and generate the once electrolytic groove of electrode vessel and be divided into that the acid water electrode of secondary chamber, strong alkaline water generate that re-electrolysis groove that electrode vessel, alkalescent water generate the motor room carries out twice electrolysis to water and the electrolysis portion that obtains strong alkaline water, sour water, these three kinds of electrolytic ionic waters of alkalescent water respectively by being divided into sour water, it is characterized in that
Described electrolysis water purifier also comprises: be located at the flow sensor of the entry pipeline of electrolysis portion, to be used to detect the influx by the inflow water of going into the water valve inflow; Input is according to the flux values of the inflow water of described flow sensor mensuration, to control the control part that applies voltage of electrolysis portion automatically based on fluctuations in discharge.
2. the variation based on flooding quantity according to claim 1 can be controlled the electrolysis water purifier that applies voltage automatically, it is characterized in that,
The entry pipeline of described electrolysis portion also is provided with the ionogen detecting sensor that is used to detect the electrolytical amount that flows into water, and the electrolytical detected value of the inflow water of measuring by described ionogen detecting sensor is input to described control part, automatically regulates the voltage that applies of self-acting control portion based on the variation of the electrolytical amount that flows into water thus.
3. the variation based on flooding quantity according to claim 2 can be controlled the electrolysis water purifier that applies voltage automatically, it is characterized in that,
Described control part operates to and makes based on the scope that applies voltage of the electrolyzer of the inflow water yield that flow into described electrolysis portion to as following table four～table seven,
It is that the electrolysis portion of 1.2L when following applies the voltage-regulation scope that table four flows into the water yield
Table five flows into the water yield and is more than 1.2～and electrolysis portion when 1.4L is following applies the voltage-regulation scope
Table six flows into the water yield and is more than 1.4～and electrolysis portion when 1.6L is following applies the voltage-regulation scope
It is that the electrolysis portion of 1.6L when above applies the voltage-regulation scope that table seven flows into the water yield
4. the variation based on flooding quantity according to claim 1 can be controlled the electrolysis water purifier that applies voltage automatically, it is characterized in that comprising:
A sour water relief outlet that is formed on described sour water generation electrode vessel is formed with the sour water regulation cock, to be used to regulate the aquifer yield of a sour water;
Be formed on the secondary sour water relief outlet that the acid water of described secondary generates electrode vessel and be formed with sour water water outlet bolt, to be used to regulate the aquifer yield with the secondary sour water that is discharged from after a sour water by described sour water regulation cock discharge mixes;
The strong alkaline water relief outlet is formed with strong alkaline water water outlet bolt, to be used to regulate the aquifer yield of strong alkaline water;
The weakly alkaline relief outlet is formed with the alkalescent water outlet valve, to be used to regulate the aquifer yield of alkalescent water;
Posttreatment filter being used for when described alkalescent water passes through this posttreatment filter by described alkalescent water outlet valve, determines the water yield according to the pressure drop of its inside.
5. the variation based on flooding quantity according to claim 4 can be controlled the electrolysis water purifier that applies voltage automatically, it is characterized in that,
The water outlet proportion of described sour water and described alkaline water is adjusted to 1: (12～15);
The water outlet proportion of described strong alkaline water, described alkalescent water and described sour water is adjusted to 1: (1.5～2): (1～1.1).
6. the variation based on flooding quantity according to claim 4 can be controlled the electrolysis water purifier that applies voltage automatically, it is characterized in that,
The described alkalescent water that described alkalescent water outlet valve has the discharge of making flow into the function of changing between the cleaning model that described posttreatment filter discharges by the surplus water outlet pipeline with the water purification pattern that purifies and the alkalescent water that cuts off the passage that flows into posttreatment filter and make described discharge.
7. can control the electrolysis water purifier that applies voltage automatically according to each described variation in the claim 1 to 3, it is characterized in that based on flooding quantity,
The lower end inflow portion that is formed with the influx of described once electrolytic groove is equipped with an entry and regulates film, to be used to regulate the ratio that a described sour water generates the water yield of electrode vessel and described alkaline water generation electrode vessel that flow into;
The lower end inflow portion of described re-electrolysis groove is equipped with the secondary entry and regulates film, to be used to regulate the ratio that the acid water of described secondary generates the water yield of electrode vessel, described strong alkaline water generation electrode vessel and described alkalescent water generation electrode vessel that flow into.
8. the variation based on flooding quantity according to claim 7 can be controlled the electrolysis water purifier that applies voltage automatically, it is characterized in that,
Described entry is regulated to be formed with on the film to make and is flow into a described sour water to generate ratio that electrode vessel and described alkaline water generate the water yield of electrode vessel be 1: 4 water inlet.
9. the variation based on flooding quantity according to claim 7 can be controlled the electrolysis water purifier that applies voltage automatically, it is characterized in that,
Described secondary entry is regulated to be formed with on the film to make and is flow into the acid water of described secondary and generate electrode vessel, described strong alkaline water to generate ratio that electrode vessel and described alkalescent water generate the water yield of electrode vessel be 1: 1: 10 water inlet.
10. can control the electrolysis water purifier that applies voltage automatically according to any described variation in the claim 1 to 3, it is characterized in that based on flooding quantity,
Described electrolysis portion upper inside face assembling silicon liner mixes with the water between each electrode vessel that is used for preventing described once electrolytic groove and re-electrolysis groove.
11. can control the electrolysis water purifier that applies voltage automatically according to any described variation in the claim 1 to 3 based on flooding quantity, it is characterized in that,
The inside lower end of described electrolysis portion forms battery lead plate fitting recess and barrier film fitting recess, to be used to keep the determining deviation between battery lead plate and the barrier film.
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