CN101869536B - Gallic acid hair dyes and preparation method and application thereof - Google Patents
Gallic acid hair dyes and preparation method and application thereof Download PDFInfo
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- CN101869536B CN101869536B CN201010207891XA CN201010207891A CN101869536B CN 101869536 B CN101869536 B CN 101869536B CN 201010207891X A CN201010207891X A CN 201010207891XA CN 201010207891 A CN201010207891 A CN 201010207891A CN 101869536 B CN101869536 B CN 101869536B
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Abstract
The invention provides gallic acid hair dyes and a preparation method and an application thereof. The hair dyes comprises the following components according to mass percent: 2.0-12.0% of gallic acid, 11.0-13.3% of auxiliary agent, 16.0-20.0% of cosolvent, 2.0-13.0% of metal ferrite and 43-66.8% of distilled water. The preparation method comprises the following steps: a. completing dissolving each component in the auxiliary agent except alkali neutralizer and cosolvent and distilled water according to the content and dividing into two equal parts, adding gallic acid to one part to form dye, and adding metal ferrite to form metal ionic agent; and b. regulating pH value to 7-9 with the alkali neutralizer after two parts of mixture are completely dissolved, and respectively packaging the obtained dye and metal ionic agent. The gallic acid hair dye is used for black-dyeing of human hair. The invention is characterized by easily obtained raw materials, simple extraction process, non-toxity and harmlessness, and safe and reliable use, and is beneficial for environmental protection.
Description
[technical field]
The present invention relates to the Crinis Carbonisatus hair dye, particularly relate to a kind of gallic acid hair dyes by the preparation of plant extract gallic acid.
[background technology]
At present, increasing people uses commercially available hair dye that hair is dyed black, brown, multiple color such as brown.Wherein, use that maximum hair color hair dyes is dark with color and luster, strong coloring force, dye black fast characteristics and adopted by people for a long time.Yet; Know as people; Existing hair dye is a feedstock production with the chemical synthetic dye pigment all; Along with people's is to the attention of health, uses the chemical synthetic dye pigment to contain carcinogenic chemical analysis (aniline dyes) as the hair dye of feedstock production because of it and the composition that is harmful to health (powerful oxidation agent hydrogen peroxide, benzoyl peroxide etc.) has caused the concern of people to its safety in utilization.For this reason, people attempt to seek to use natural plants, extract pigment as Crinis Carbonisatus hair color hair dye like Chinese crude drugs such as branch and leaf, flower, grass and Radix Polygoni Multiflori, have obtained certain progress.But in existing Crinis Carbonisatus black hair dye, do not find black hair dye as yet, and gallic acid has application widely as by plant extract and purified product in the food and medicine industry with the gallic acid preparation.Therefore, its natural botanical hair dye that is developed as safety, environmental protection is just become a kind of objective demand.
[summary of the invention]
The present invention is intended to overcome the insecurity that chemical synthetic dye pigment hair dye uses, and provides a kind of raw material to be easy to get, and extraction process is simple, and is nontoxic, safe and reliable, helps the gallic acid hair dyes of environmental conservation.
The present invention also aims to provide the method for preparing of this gallic acid hair dyes.
Further purpose of the present invention is to provide the purposes of this gallic acid hair dyes.
For realizing that above-mentioned order holds, the present invention provides a kind of gallic acid hair dyes, and this hair dye comprises following component by percentage to the quality:
Gallic acid 2.0～12.0
Auxiliary agent 11.0～13.3
Cosolvent 16.0～20.0
Metal ferrous salt 2.0～13.0
Distilled water 43～66.8%.
Preferably, this hair dye comprises following component by percentage to the quality:
Gallic acid 7.0
Auxiliary agent 12.0
Cosolvent 18.0
Metal ferrous salt 8.0
Distilled water 55.
Said auxiliary agent comprises wetting agent, thickening agent, penetrating agent, alkali nertralizer, antiseptic, chelating agent.
Said wetting agent is one or more the combination among Arlacel-20, tween 80, the NPE 10EO; Thickening agent is a kind of or its combination in hydroxyethyl-cellulose, the soluble starch; Penetrating agent is the aqueous azone; The alkali nertralizer is one or more the combination in ethanolamine, ammonia, the sodium hydroxide; Antiseptic is a sodium benzoate; Chelating agent is a kind of or its combination in disodiumedetate, the ascorbic acid.
The mass percentage content of each component in hair dye of said auxiliary agent is:
Wetting agent 0.8～1.0
Thickening agent 1.2～1.5
Penetrating agent 0.8～1.0
Alkali nertralizer 8.0～9.2
Antiseptic 0.1～0.3
Chelating agent 0.1～0.3
Said cosolvent is one or more the combination in ethylene glycol, ethanol, the isopropyl alcohol.
Said metal ferrous salt is a kind of or its combination in ferrous sulfate, the ferrous chloride.
The present invention also provides the method for preparing of gallic acid hair dyes, and this method comprises the steps:
A, each combination except that the alkali nertralizer and cosolvent and distilled water in the auxiliary agent are divided into two equal portions after by the dissolving fully of its content, a copy of it adds gallic acid, forms dyestuff; Another part adds the metal ferrous salt, forms the metal ion agent;
After b, two parts of mixture dissolve fully, pH value is transferred to 7～9, then gained dyestuff and metal ion agent are packed respectively with the alkali nertralizer.
The present invention further provides the purposes of gallic acid hair dyes, and it is black that gallic acid hair dyes of the present invention is used for dying of Crinis Carbonisatus.
Contribution of the present invention is that it provides a kind of human hair dying agent of using the effective active thing gallic acid of plant extract as the dyestuff preparation.The chemical constituent of the main component gallic acid of this hair dye is a polyhydroxy benzenes formic acid, and it can generate black plant metal complex with metallic iron and ferrous ion in air.The present invention utilizes it in air, can generate the black complex with metallic iron and ferrous ion to be illuminating colour, and preparation gallic acid hair black hair dye is used for human hair dying.Gallic acid in this hair dye is little because of molecule, and part can get into through the horny layer of hair in the hair and generate the ferrous metal complex with ferrum and ferrous ion at hair, makes hair-dyeing.Its hair dyeing color and luster nature has certain durability.This hair dye does not contain aniline dyes and the strong oxidizer hydrogen peroxide and the benzoyl peroxide that help the aniline dyes color development because of dyestuff; Therefore employed component and prepared hair dye meet the security clearance of country and industry, can be the hair dyeing industry a kind of nontoxic safe plants dyestuff hair dye product is provided.
[specific embodiment]
The following example is to further explanation of the present invention and explanation, and the present invention is not constituted any limitation.
Embodiment 1
Getting distilled water 66.8 gram, ethanol 10.0 grams, ethylene glycol 7.5 grams, Arlacel-20 0.3 gram, NPE 10EO 0.6 gram, sodium benzoate 0.3 gram, disodiumedetate 0.2 gram puts into glass beaker and dissolves; Add successively again after hydroxyethyl-cellulose 0.5 gram, soluble starch 1.0 grams, aqueous azone 0.8 gram stir dissolving; Equivalent is divided into two parts; A add gallic acid 2.0 grams, another part adds ferrous chloride 2.0 grams, dissolving and transfers pH value 7.0-9.0 with ammonia 8 grams in the back fully, pack as dyestuff and metal ion agent respectively to get final product.
Embodiment 2
Get distilled water 30.0 gram, that hydroxyethyl-cellulose 1.5 grams are put into glass beaker 1 dissolving is subsequent use.Get distilled water 31.70 grams, isopropyl alcohol 8.0 grams, ethylene glycol 8.8 grams, tween 80 0.2 gram, NPE 10EO 0.3 gram, disodiumedetate 0.2 gram, sodium benzoate 0.3 gram, put into glass beaker 2 dissolvings; Again 31.5 grams of the hydroxy ethyl fiber cellulose solution in the glass beaker 1, water solublity azone 0.8 gram are added in the beaker 2; After stirring dissolving; Equivalent is divided into two parts; A add Galla Turcica (Galla Helepensis) 4.0 grams, another part adds ferrous sulfate 5.0 grams, dissolving and transfers pH value 7.0-9.0 with ammonia 5.0 grams, ethanolamine 4.2 grams in the back fully, pack as dyestuff and metal ion agent respectively to get final product.
Embodiment 3
After getting distilled water 52.3 gram, ethanol 12.0 grams, ethylene glycol 7.0 grams, tween 80 0.5 gram, NPE 10EO 0.5 gram, sodium benzoate 0.3 gram, disodiumedetate 0.2 gram and putting into glass beaker and stir; After adding hydroxy ethyl fiber 1.2 grams, aqueous azone 1.0 grams stir dissolving; Equivalent is divided into two parts; A add gallic acid 7.0 grams, another part adds ferrous sulfate 10.0 grams, dissolving and transfers pH value 7.0-9.0 with ammonia 5.0 grams, ethanolamine 3.0 grams in the back fully, pack as dyestuff and metal ion agent respectively to get final product.
Embodiment 4
After getting distilled water 43.0 gram, ethanol 10.0 grams, ethylene glycol 10.0 grams, tween 80 1.0 grams, sodium benzoate 0.3 gram, ascorbic acid 0.3 gram, disodiumedetate 0.2 gram and putting into glass beaker and stir; Add successively again after hydroxy ethyl fiber 1.2 gram, aqueous azone 1.0 grams stir dissolving; Equivalent is divided into two parts; A adding gallic acid 12.0 restrains, another part adds ferrous chloride 13.0 grams, dissolve complete back restrains accent pH value 7.0-9.0 with sodium hydroxide 0.5 gram, ammonia 5.0 grams, ethanolamine 2.5, gets final product as dyestuff and metal ion agent packing respectively.
Different with existing chemical hair dye method for using is; Gallic acid hair dyes of the present invention in use; Dyestuff with gallic acid hair dyes is coated on the hair earlier; Again the metal ion agent is coated on the hair after 20 minutes (but temperature low time proper extension time), keeps 20 minutes when temperature is hanged down (but proper extension time), clean up the hair loose colour with shampoo then and get final product.
Claims (6)
1. a gallic acid hair dyes is characterized in that, this hair dye is made up of following component by percentage to the quality:
Said metal ferrous salt is a kind of or its combination in ferrous sulfate, the ferrous chloride, and said auxiliary agent is selected from wetting agent, thickening agent, penetrating agent, alkali nertralizer, antiseptic, chelating agent;
The method for preparing of this gallic acid hair dyes is following:
A, each combination except that the alkali nertralizer and cosolvent and distilled water in the auxiliary agent are divided into two equal portions after by the dissolving fully of its content, a copy of it adds gallic acid, forms dyestuff; Another part adds the metal ferrous salt, forms the metal ion agent;
After b, two parts of mixture dissolve fully, pH value is transferred to 7～9, then gained dyestuff and metal ion agent are packed respectively with the alkali nertralizer.
2. gallic acid hair dyes as claimed in claim 1 is characterized in that, this hair dye is made up of following component by percentage to the quality:
3. gallic acid hair dyes as claimed in claim 1 is characterized in that, said wetting agent is one or more the combination among Arlacel-20, tween 80, the NPE 10EO; Thickening agent is a kind of or its combination in hydroxyethyl-cellulose, the soluble starch; Penetrating agent is the aqueous azone; The alkali nertralizer is one or more the combination in ethanolamine, ammonia, the sodium hydroxide; Antiseptic is a sodium benzoate; Chelating agent is a kind of or its combination in disodiumedetate, the ascorbic acid.
4. gallic acid hair dyes as claimed in claim 1 is characterized in that, the mass percentage content of each component in hair dye of said auxiliary agent is:
5. according to claim 1 or claim 2 gallic acid hair dyes is characterized in that, said cosolvent is one or more the combination in ethylene glycol, ethanol, the isopropyl alcohol.
6. it is black that gallic acid hair dyes as claimed in claim 1 is used for dying of Crinis Carbonisatus.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201010207891XA CN101869536B (en) | 2010-06-23 | 2010-06-23 | Gallic acid hair dyes and preparation method and application thereof |
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| CN201010207891XA CN101869536B (en) | 2010-06-23 | 2010-06-23 | Gallic acid hair dyes and preparation method and application thereof |
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| CN101869536B true CN101869536B (en) | 2012-08-29 |
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Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102154854A (en) * | 2011-03-08 | 2011-08-17 | 贵州阿斯科科技开发有限公司 | Wool ecological dye paste, preparation method thereof and dyeing method |
| CN103622844B (en) | 2012-08-24 | 2016-04-20 | 浙江养生堂天然药物研究所有限公司 | hair dyeing product |
| CN103911891A (en) * | 2013-12-27 | 2014-07-09 | 苏州华策纺织科技有限公司 | Sheep leather coloring agent |
| CN105748325A (en) * | 2016-03-10 | 2016-07-13 | 蚌埠团结日用化学有限公司 | Auxiliaries for hair perming and hair dyeing and preparation method thereof |
| CN108042379A (en) * | 2017-12-21 | 2018-05-18 | 南通强生石墨烯科技有限公司 | Graphene is modified hair dye |
| CN112957269A (en) * | 2021-02-09 | 2021-06-15 | 常州大学 | Plant hair dye and dyeing method thereof |
| CN113230149B (en) * | 2021-05-25 | 2022-04-22 | 台州学院 | Gallic acid hair dye and using method thereof |
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| CN1164255C (en) * | 2001-08-15 | 2004-09-01 | 王明彰 | Use of DL-cystine, DL-cysteine and their salt in dyeing and perming hair |
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Effective date of registration: 20151209 Address after: 550001 No. 388 Baisha Road, Guizhou, Guiyang Patentee after: Guizhou Prov. Engineering Composite Material Center Address before: 528300 Guangdong province Shunde Daliang Xianghe road Schwab City Garden 1 9 5A Patentee before: Liu Yuqin |
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Effective date of registration: 20211116 Address after: 550000 plant building 13, high tech industrial innovation base, Guizhou Academy of Sciences, shawen Industrial Park, Guiyang National High tech Industrial Development Zone, Guiyang City, Guizhou Province Patentee after: Guizhou engineering composite material Center Co., Ltd Address before: 550001 No. 388 Baisha Road, Guiyang, Guizhou Patentee before: Guizhou engineering composite material center |
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