CN101862467B - Wide waveband photocatalyst air cleaner - Google Patents
Wide waveband photocatalyst air cleaner Download PDFInfo
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- CN101862467B CN101862467B CN 200910196322 CN200910196322A CN101862467B CN 101862467 B CN101862467 B CN 101862467B CN 200910196322 CN200910196322 CN 200910196322 CN 200910196322 A CN200910196322 A CN 200910196322A CN 101862467 B CN101862467 B CN 101862467B
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Abstract
The invention discloses a wide waveband photocatalyst air cleaner, which comprises a container, wherein compound photocatalyst particles are arranged in the container. The container is prepared by sintering anion power, dolomite and pore-forming agent. The compound photocatalyst particles are prepared by sintering the anion power, tourmaline, maifanitum, nanometer titanium dioxide, cerous oxide and viscous pottery clay. The invention has the following great advantages: 1, the production rate of anions is high; and 2, no additional power supply is needed, and natural light can penetrate through a container wall and an air hole on the container wall to exchange with the surfaces of the compound photocatalyst particles so as to realize the purpose of purifying air, thereby bringing greatly convenience for use. The air cleaner in the invention can be arranged on desks, bedside tables and windows as well as in automobile and the like. The container can be made into various ornaments, such as egg-shaped, vase-shaped, animal-shaped, cartoon-shaped ornaments and the like, and has beautiful appearance and practical use.
Description
Technical field
The invention belongs to the daily living article field, specifically be meant a kind of (ultraviolet-infrared band all responds) photo-catalytic air cleaner that is placed on the wide-band response of removing airborne toxic and harmful in indoor or the automobile and improving the internal medium air.
Background technology
Photocatalyst also is photocatalyst, be one type with titanium dioxide (TiO
2) for representative, under the irradiation of light, self do not change, but can promote chemical reaction, have the general name of the semi-conducting material of catalysis.TiO
2As a kind of photocatalyst; Behind the ultraviolet in absorbing sunlight or lighting source; Redox reaction takes place under the exciting of ultraviolet energy; The surface forms the hydroxyl free radical and the ultra-oxygen anion free radical of strong oxidizing property, becomes harmless carbon dioxide and water to harmful substances in air and microbial decomposition, thereby reaches purpose such as the deodorization and sterilization that purifies air.But photocatalysis technology remains two problems at present, the one, and quantum efficiency is low, and the 2nd, TiO
2Only absorb the ultraviolet in the sunlight and since indoor ultraviolet a little less than, can not effectively produce photocatalysis.Therefore the photo-catalytic air cleaner of present indoor use generally need add a high tension generator and produce ultraviolet, reaches the purpose that purifies the air of a room.So increased cost undoubtedly, consumes energy, and use and limited to, as just not using in the automobile or in the wardrobe.Therefore, how to improve the quantum efficiency of photocatalysis system, it is infrared that the absorption spectrum of photocatalyst is extended to from ultraviolet, improves the utilization rate of luminous energy, is the target that these those skilled in the art pursue always.In addition, present photo-catalytic air cleaner anion generation is lower.
Summary of the invention
For overcoming the problem that above-mentioned prior art exists, the objective of the invention is to propose a kind of dispense with outer connecting power, directly utilize the photo-catalytic air cleaner of the wide-band response of nature luminous energy.And this depurator can produce the anion of higher needed by human body.
A kind of wide waveband photocatalyst air cleaner of the present invention comprises: container, container are built-in with the composite photo catalyst granule.It is characterized in that: said container is burnt till by anion powder, dolomite, pore former; Pore former is carbon or carborundum, and wherein the anion powder percentage by weight reaches 25-35%, and the dolomite percentage by weight reaches 35-45%; Pore former is a carborundum, and its percentage by weight reaches 30% or 35%; Pore former is a carbon, and its percentage by weight reaches 30%, and the perforation porosity of chamber wall reaches 30-40%.
Said composite photo catalyst granule is burnt till by anion powder, tourmaline, Maifanitum, nano titanium oxide, cerium oxide and viscosity potter's clay.Wherein the weight percent content of various raw materials is:
Advantage of the present invention is:
1. owing to contain transition elements, rare earth element, photocatalyst (nano titanium oxide), tourmaline in the composite photo catalyst granule; Therefore its energy gap forms from ultraviolet to infrared distribution; Thereby under infrared, ultraviolet, visible light or micro-natural radiation condition, all has the photocatalyst effect; Photocatalysis efficiency is greatly enhanced, and makes harmful poisonous organic and inorganic pollution resolve into nontoxic water and carbon dioxide.
2. because the two ends of tourmaline polar axis C have positive and negative charge respectively, and there is electric field in the surface, be similar to extremely son of electric coupling; Exist between granule and repel and attraction, mechanical lapping is added in the adding of rare earth element and nano titanium oxide, has formed the form of rare earth element and nano titanium oxide parcel tourmaline; When air molecule and enwrapped granule collision; The effect of highfield makes hydrone ionization, has increased airborne negative ion concentration, is of value to health of people.
3. owing to contain Maifanitum in the composite photo catalyst granule, increased the particulate degree of porosity of composite photo catalyst, effective contact area of luminous energy is increased, photocatalysis efficiency increases.
4. owing to all contain anion powder in container of the present invention and the photocatalyst particle, the amount that this anion powder discharges anion can reach 1500/cm
3, be that other any material is unapproachable, and "dead".This anion powder contains Mn, Cr, Co, Ni, Zn etc.; Than adopting many that single transition metal effect will be good; These d district metallic elements have the rank property of change; Can form an electron reaction chain, and, discharge more anion by the synergism of photocatalyst, tourmaline and rare earth element.
5. owing to the present invention the composite photo catalyst granule is placed in the container that is burnt till by anion powder, dolomite and pore former; Nature luminous energy sees through chamber wall and contacts with the particulate surface of composite photo catalyst with pore on the chamber wall and reach the purpose that purifies air; Need not additional power source; Bring great convenience to use, can be placed on the desk, on the bedside cabinet, on the windowsill, in the automobile etc.Container can be processed into various ornaments, like egg type, vase shape, animals shaped, cartoon shape etc.Both beautiful and practical.
Description of drawings
Fig. 1 is the structural representation of present embodiment.
The specific embodiment
Do further to specify below in conjunction with the embodiment specific embodiments of the invention:
Container of the present invention according to following percentage by weight batching, mixes and pulverizes respectively, and 250 mesh screen residues are less than 0.5%; Then according to the required form molding; Present embodiment is shaped to goose egg type (seeing accompanying drawing 1), 1100 ℃ of firing temperatures, and the porosity of chamber wall reaches 30-40%.
Container stock anion powder dolomite silicon carbide carbon
Component 1 (wt%) 25 40 35-
Component 2 (wt%) 30 40-30
Component 3 (wt%) 35 35 30-
The composite photo catalyst granule according to the percentage by weight batching of following each component, fully mixes respectively, is placed on the mechanical grinder then and grinds, pelletize again, firing temperature 300-500 ℃.
Photocatalyst raw material anion powder tourmaline Maifanitum nano titanium oxide cerium oxide viscosity potter's clay
Component 1 (wt%) 20 25 30 10 2 13
Component 2 (wt%) 15 30 25 15 1 14
Component 3 (wt%) 25 20 25 15 3 12
Goose egg type container of the present invention 1 bottom has an openning that is used to put into composite photo catalyst granule 2, and the composite photo catalyst granule is put the back into a lid 3 sealings, forms a complete photo-catalytic air cleaner.
The container that any component container stock of the present invention is burnt till can make up with the granule that any component photocatalyst raw material burns till.
Above-described embodiment has been merely explanation technological thought of the present invention and characteristics, and the scope of this patent also not only is confined to above-mentioned specific embodiment, and promptly all equal variation or modifications of doing according to disclosed spirit still are encompassed in protection scope of the present invention.
Claims (2)
1. wide waveband photocatalyst air cleaner, comprising: container, container are built-in with the composite photo catalyst granule, it is characterized in that:
Said container is burnt till by anion powder, dolomite, pore former; Pore former is carbon or carborundum, and wherein the anion powder percentage by weight reaches 25-35%, and the dolomite percentage by weight reaches 35-45%; Pore former is a carborundum; Its percentage by weight reaches 30% or 35%, and pore former is a carbon, and its percentage by weight reaches 30%;
Said composite photo catalyst granule is burnt till by anion powder, tourmaline, Maifanitum, nano titanium oxide, cerium oxide and viscosity potter's clay; Wherein the weight percent content of various raw materials is:
2. according to a kind of wide waveband photocatalyst air cleaner of claim 1, it is characterized in that: said pore former is carbon or carborundum, and the perforation porosity of chamber wall is 30-40%.
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CN 200910196322 CN101862467B (en) | 2009-09-24 | 2009-09-24 | Wide waveband photocatalyst air cleaner |
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CN 200910196322 CN101862467B (en) | 2009-09-24 | 2009-09-24 | Wide waveband photocatalyst air cleaner |
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CN101862467A CN101862467A (en) | 2010-10-20 |
CN101862467B true CN101862467B (en) | 2012-12-26 |
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Families Citing this family (3)
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CN101983739B (en) * | 2010-12-09 | 2014-03-19 | 上海弘康科技发展有限公司 | Health-care urn and manufacturing method thereof |
CN107482481B (en) * | 2017-08-22 | 2022-12-20 | 南京绿新能源研究院有限公司 | Anion generator based on dual-mode excitation of solar energy |
CN107648655A (en) * | 2017-11-10 | 2018-02-02 | 伦慧东 | A kind of photocatalyst strengthens antibacterial odor removing filter |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1413737A (en) * | 2002-09-26 | 2003-04-30 | 北京雅润泽科技有限公司 | Passive (hydroxide) anion generation material for indoor air purifying and its application |
CN1895751A (en) * | 2006-06-22 | 2007-01-17 | 武汉理工大学 | Air light catalytic purifier of moderate chemical pollution |
CN101450220A (en) * | 2007-12-02 | 2009-06-10 | 马美琴 | Passive(hydroxyl group) anion generation material for indoor air purification and use thereof |
-
2009
- 2009-09-24 CN CN 200910196322 patent/CN101862467B/en active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1413737A (en) * | 2002-09-26 | 2003-04-30 | 北京雅润泽科技有限公司 | Passive (hydroxide) anion generation material for indoor air purifying and its application |
CN1895751A (en) * | 2006-06-22 | 2007-01-17 | 武汉理工大学 | Air light catalytic purifier of moderate chemical pollution |
CN101450220A (en) * | 2007-12-02 | 2009-06-10 | 马美琴 | Passive(hydroxyl group) anion generation material for indoor air purification and use thereof |
Non-Patent Citations (1)
Title |
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JP特开2002-233583A 2002.08.20 |
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