CN101858200A - Diamond composite sheet matrix with carbon potential gradient - Google Patents

Diamond composite sheet matrix with carbon potential gradient Download PDF

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Publication number
CN101858200A
CN101858200A CN201010173680A CN201010173680A CN101858200A CN 101858200 A CN101858200 A CN 101858200A CN 201010173680 A CN201010173680 A CN 201010173680A CN 201010173680 A CN201010173680 A CN 201010173680A CN 101858200 A CN101858200 A CN 101858200A
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China
Prior art keywords
matrix
diamond
carbon potential
potential gradient
tungsten carbide
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CN201010173680A
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Chinese (zh)
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CN101858200B (en
Inventor
廖江雄
余立新
陆庆忠
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Wuhan Rui Te diamond Co., Ltd
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SUZHOU KINGDREAM SHAREATE CEMENTED CARBIDE CO Ltd
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Priority to CN 201010173680 priority Critical patent/CN101858200B/en
Publication of CN101858200A publication Critical patent/CN101858200A/en
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Abstract

The invention relates to a diamond composite sheet matrix with carbon potential gradient, the matrix is a dual-layer structure and comprises an upper part and a lower part connected with the upper part, the thickness of the upper part is 1-4mm, the thickness of the lower part is 4-20mm, and the upper part and the lower part comprise the following components by weight percent: 10%-18% of cobalt, and 82%-90% of tungsten carbide, wherein the carbon balance of the tungsten carbide of the upper part is lower than the carbon balance of the tungsten carbide of the lower part by 0.02-0.10%, and the upper part and the lower part constitute the carbon potential gradient. As the upper part of the matrix which is combined with diamond has lower carbon potential, the diamond composite sheet matrix can reduce or eliminate the carburization of the matrix caused by partial graphitization of the diamond on a diamond and hard alloy matrix composite interface; and the lower part of the matrix which is far away from the diamond, the diamond composite sheet matrix can ensure the toughness and the service life of the matrix.

Description

Diamond compact substrate with carbon potential gradient
Technical field
The present invention relates to a kind of diamond compact substrate, be applied to the cutting tip of oil, natural gas, geology drill bit.
Background technology
Diamond compact is to be composited by the superhigh-temperature and-pressure technology by polycrystalline diamond and hard alloy substrate, have high rigidity and high-wearing feature, the drill bit that studs with diamond compact has been widely used in fields such as oil, natural gas, mining geology, and drilling efficiency exceeds than common drill bit and manys times.In the building-up process of composite sheet, tend to occur cause carburizing occurring near the carbide matrix body portion of diamond layer because of part diamond graphitization, the combination property that the hard alloy substrate of carburizing occurs will significantly reduce, and also can further have influence on the performance and the application life of diamond compact.
Summary of the invention
The objective of the invention is to overcome the deficiency that prior art exists, a kind of diamond compact substrate with carbon potential gradient is provided.
Purpose of the present invention is achieved through the following technical solutions:
Diamond compact substrate with carbon potential gradient, characteristics are: described matrix is a double-decker, comprise top and connected bottom, the composition of described upper and lower: cobalt accounts for percentage by weight 10%~18%, tungsten carbide accounts for percentage by weight 82%~90%, wherein, tungsten carbide carbon equilibrium ratio bottom, top tungsten carbide carbon balance is low by 0.02~0.10%, and top and bottom constitute carbon potential gradient.
Further, above-mentioned diamond compact substrate with carbon potential gradient, wherein, described top thickness is 1~4mm, bottom thickness is 4~20mm.
Substantive distinguishing features and obvious improvement that technical solution of the present invention is outstanding are mainly reflected in:
1. the upper strata matrix that combines with diamond has lower carbon potential, can reduce or eliminate the matrix carburizing that diamond and hard alloy substrate compound interface cause because of diamond part graphitization;
2. be normal structure away from adamantine lower floor matrix, can guarantee the toughness and the application life of matrix.
Description of drawings
Below in conjunction with accompanying drawing technical solution of the present invention is described further:
Fig. 1: master of the present invention cuts open schematic diagram.
The implication of each Reference numeral is among the figure:
1-top; The 2-bottom.
The specific embodiment
The present invention designs a kind of hard alloy substrate that has carbon potential gradient simultaneously, reducing or to eliminate the matrix carburizing that diamond and hard alloy substrate compound interface cause because of diamond part graphitization, thereby guarantees that diamond compact has higher combination property.
As shown in Figure 1, diamond compact substrate with carbon potential gradient, matrix is a double-decker, comprises top 1 and connected bottom 2, and the thickness on top 1 is 1~4mm, the thickness of bottom 2 is 4~20mm, the composition of top 1 and bottom 2: cobalt accounts for percentage by weight 10%~18%, and tungsten carbide accounts for percentage by weight 82%~90%, wherein, tungsten carbide carbon equilibrium ratio bottom, top tungsten carbide carbon balance is low by 0.02~0.10%, and top and bottom constitute carbon potential gradient; The matrix top that combines with diamond has lower carbon potential, is normal structure away from adamantine matrix underpart.
In diamond compact substrate, has carbon potential gradient.Show following characteristics especially: the matrix top that 1) combines with diamond can reduce or eliminate the matrix carburizing that diamond and hard alloy substrate compound interface cause because of diamond part graphitization because of having lower carbon potential; 2) be normal structure away from adamantine matrix underpart, can guarantee the toughness and the application life of matrix.
What need understand is: the above only is a preferred implementation of the present invention; for those skilled in the art; under the prerequisite that does not break away from the principle of the invention, can also make some improvements and modifications, these improvements and modifications also should be considered as protection scope of the present invention.

Claims (2)

1. the diamond compact substrate that has carbon potential gradient, it is characterized in that: described matrix is a double-decker, comprise top and connected bottom, the composition of described upper and lower: cobalt accounts for percentage by weight 10%~18%, tungsten carbide accounts for percentage by weight 82%~90%, wherein, tungsten carbide carbon equilibrium ratio bottom, top tungsten carbide carbon balance is low by 0.02~0.10%, and top and bottom constitute carbon potential gradient.
2. the diamond compact substrate with carbon potential gradient according to claim 1 is characterized in that: described top thickness is 1~4mm, and bottom thickness is 4~20mm.
CN 201010173680 2010-05-14 2010-05-14 Diamond composite sheet matrix with carbon potential gradient Active CN101858200B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 201010173680 CN101858200B (en) 2010-05-14 2010-05-14 Diamond composite sheet matrix with carbon potential gradient

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Application Number Priority Date Filing Date Title
CN 201010173680 CN101858200B (en) 2010-05-14 2010-05-14 Diamond composite sheet matrix with carbon potential gradient

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CN101858200A true CN101858200A (en) 2010-10-13
CN101858200B CN101858200B (en) 2013-05-08

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102678057A (en) * 2012-05-22 2012-09-19 株洲西迪硬质合金科技有限公司 Diamond composite sheet and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000129386A (en) * 1998-10-29 2000-05-09 Sumitomo Electric Ind Ltd Highly friction-resistant cemented carbide for brazing, and its manufacture
JP2000309841A (en) * 1999-04-21 2000-11-07 Nippon Steel Corp Composite roll for hot rolling
CN1480544A (en) * 2003-07-22 2004-03-10 株洲硬质合金集团有限公司 Method for preparing hard alloy
CN2906032Y (en) * 2005-11-24 2007-05-30 江汉石油钻头股份有限公司 Polycrystalline diamond composite sheet with granular gradient

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000129386A (en) * 1998-10-29 2000-05-09 Sumitomo Electric Ind Ltd Highly friction-resistant cemented carbide for brazing, and its manufacture
JP2000309841A (en) * 1999-04-21 2000-11-07 Nippon Steel Corp Composite roll for hot rolling
CN1480544A (en) * 2003-07-22 2004-03-10 株洲硬质合金集团有限公司 Method for preparing hard alloy
CN2906032Y (en) * 2005-11-24 2007-05-30 江汉石油钻头股份有限公司 Polycrystalline diamond composite sheet with granular gradient

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
肖仲文等: "硬质合金气氛烧结过程中碳含量调整", 《硬质合金》 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102678057A (en) * 2012-05-22 2012-09-19 株洲西迪硬质合金科技有限公司 Diamond composite sheet and preparation method thereof
CN102678057B (en) * 2012-05-22 2015-01-21 株洲西迪硬质合金科技有限公司 Diamond composite sheet and preparation method thereof

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Publication number Publication date
CN101858200B (en) 2013-05-08

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PB01 Publication
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ASS Succession or assignment of patent right

Owner name: SUZHOU SHAREATE ALLOY TOOL CO., LTD.

Free format text: FORMER OWNER: SUZHOU KINGDREAM SHAREATE CEMENTED CARBIDE CO., LTD.

Effective date: 20120816

C41 Transfer of patent application or patent right or utility model
TA01 Transfer of patent application right

Effective date of registration: 20120816

Address after: 215121, No. 6, West Road, Ting Technology Park, Suzhou Industrial Park, Jiangsu

Applicant after: Suzhou Xinrui Alloy Tool Co.,Ltd.

Address before: 215121, No. 6, West Road, Ting Technology Park, Suzhou Industrial Park, Jiangsu

Applicant before: Suzhou KINGDREAM SHAREATE Cemented Carbide Co., Ltd.

C14 Grant of patent or utility model
GR01 Patent grant
TR01 Transfer of patent right
TR01 Transfer of patent right

Effective date of registration: 20170714

Address after: 430000, No. 5, Chinese workers' garden, Temple Hill community, East Lake New Technology Development Zone, Wuhan, Hubei

Patentee after: Wuhan Rui Te diamond Co., Ltd

Address before: 215121, No. 6, West Road, Ting Technology Park, Suzhou Industrial Park, Jiangsu

Patentee before: Suzhou Xinrui Alloy Tool Co.,Ltd.