CN101851482A - Jointing glue for stone - Google Patents
Jointing glue for stone Download PDFInfo
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- CN101851482A CN101851482A CN 201010147222 CN201010147222A CN101851482A CN 101851482 A CN101851482 A CN 101851482A CN 201010147222 CN201010147222 CN 201010147222 CN 201010147222 A CN201010147222 A CN 201010147222A CN 101851482 A CN101851482 A CN 101851482A
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- unsaturated polyester
- polyester resin
- glue
- stone
- jointing
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Abstract
The invention provides jointing glue for stone, which at least comprises the following components in parts by weight: 100 parts of an air-dried unsaturated polyester resin, 1-5 parts of hydrogenated castor oil, 0-60 parts of micron-sized silica and 1-15 parts of an antishrinking agent. The jointing glue overcomes the defects of taking the existing common marble glue as the jointing glue such as poor air-drying properties, poor antishrinking capability, poor permeability and the like. The jointing glue for stone has the advantages of good permeability, no tackiness after curing, strong antishrinking capability, glue brightness after polishing and the like. The jointing glue enriches varieties of the marble glue and solves the problem of jointing difficulty among the stone.
Description
Technical field
The present invention relates to a kind of jointing glue for stone, it is mainly used in filling up or filling of slit between the stone material.It also can be used for pottery and waits the filling up or filling of other material of construction slit (being commonly called as jointing).
Background technology
Cloud stone glue is a unsaturated polyester glue and since its main be to be used on the marble, the cloud stone glue that is referred to as sanctified by usage in the native land.
Stone material bonding comprises structural bonding and unstructuredness is bonding.It is bonding that cloud stone glue is mainly used in the stone material property filled up, and also claims unstructuredness bonding.It is to be to utilize the defective of organic chemistry sizing agent to stone material with respect to a kind of of structural bonding (carry load is bonding), and damaged as crack, crackle, hole, sand holes, product, the finishing location is waited and repaired, fills, enhancing, a kind of technology of fixed.
The property filled up is bonding and structural to be bonded in has tangible difference on stressed, i.e. the load of the bonding not holding capacity of the property filled up.The effect of filling up is to play the effect that beautifies stone material outward appearance visual sense of beauty and modular product size.
In recent years, continuous development along with adhesive for building, also promoted the further growth of whole architectural chemistry product industry, the application of cloud stone glue also more and more widely, as the decorations of family, the quick location of stone material, repairing, parquets, splice, fill up stone hole and slit etc. and use all very general.
Now there is not special-purpose jointing glue for stone on the market, the common cloud stone glue of general employing replaces, but common cloud stone glue is if being used for jointing exists unreasonable part because common cloud stone glue is mainly used in the bonding of stone material and ground, or more than the ground to below 9 meters with bonding (the state compulsion regulation) of metope.Common cloud stone glue need bear certain less load, therefore for bonding intensity certain requirement is arranged, but requires lower for air-drying property, brightness, contractility, perviousness.And jointing adhesive is mainly used in filling up between the stone material slit, need contact with atmosphere.Therefore low for the bonding strength cloud stone glue that requires to compare, but then higher for contractility, brightness, air-drying property, infiltrative requirement.
Can there be following shortcoming with existing common cloud stone glue as jointing adhesive: 1.. air-drying property is poor, and colloid solidifies the sticking hand in back.2.. polishing back colloid is inconsistent with the brightness of polishing stone material, and aberration is arranged.3.. anti-contractility is poor, and adhesive curing forms depression easily or separates with stone material.4.. poor permeability, joint filling is discontented or exist empty.
Summary of the invention
Jointing glue for stone is as the term suggests it mainly is applicable to the stone material seam.Therefore need satisfy following performance as jointing adhesive:
1. perviousness will be got well (generally representing with viscosity): it promptly is requirement colloid exquisiteness that perviousness will be got well, and easily is in harmonious proportion, and has certain fluidity after being blended into solidifying agent, can be penetrated in the tiny stone material slit; And because the colloid exquisiteness, cemented side seam can be very thin, increases aesthetic property.2. solidify back tack-free (air-drying property will be got well): after colloid solidifies, at once tack-free, air-drying property will be got well.As when being used for the renovation of hotel stone floor, require jointing to stick with glue after, can just polish at once.If colloid glues hand, will make mill material on the polishing machine directly in water throwing or when do throwing, on cemented side seam, form black seam, influence attractive in appearance.3. anti-contractility is strong, can not form depression after the adhesive curing or throws off with stone material.4. polishing back glue will have brightness (available hardness represents that hardness is good, then polishing back brightness height), can be with stone polishing brightness unanimity.
The objective of the invention is to overcome above-mentioned having now common cloud stone glue is used for the weak point of jointing glue for stone, and a kind of jointing glue for stone is provided.
The objective of the invention is to reach: jointing glue for stone by following measure, it is characterized in which comprises at least air-dried unsaturated polyester resin 100 weight parts, hydrogenated castor oil 1-5 weight part, micron silica 0-60 weight part, antishrinking agent 1-15 weight part.
In technique scheme, which comprises at least air-dried unsaturated polyester resin 100 weight parts, hydrogenated castor oil 1-5 weight part, micron silica 10-60 weight part, antishrinking agent 1-15 weight part.
In technique scheme, described air-dried unsaturated polyester resin is 100 weight parts, and hydrogenated castor oil is the 2-4 weight part, and micron silica is the 30-50 weight part, and antishrinking agent is the 5-10 weight part.
In technique scheme, described air-dried unsaturated polyester resin is 100 weight parts, and hydrogenated castor oil is 3 weight parts, and micron silica is 40 weight parts, and antishrinking agent is 8 weight parts.
In technique scheme, described air-dried unsaturated polyester resin is: the modified unsaturated polyester resin that utilizes the synthetic dicyclopentadiene of half esterification process, the glycidyl allyl ether modified unsaturated polyester resin, the air-dried unsaturated polyester resin of trimethylolpropane allyl ether modification adds thinner, promotor and stopper (being furnished with thinner, promotor and stopper in the commercial unsaturated polyester resin product) by constant in the above-mentioned air-dried unsaturated polyester resin.
In technique scheme, it also comprises reactive thinner 1-5 weight part.
In technique scheme, described micron silica average out to 300-1000 order.
In technique scheme, described reactive thinner is vinylbenzene, alpha-methyl styrene, glycerine diallyl ether adipic acid ester, Phthalic acid, diallyl ester, chloro styrene, in the t-butyl styrene one or more.
In technique scheme, antishrinking agent comprises one or more in poly-propyl acetate, poly-hexanodioic acid glycerine ester, polyvinyl acetate, polyacrylic ester, polystyrene, polyethylene, polyvinyl chloride, the polymethylmethacrylate.
In technique scheme, described air-dried unsaturated polyester resin adds one or more in naphthenic hydrocarbon dibasic alcohol, Hydrogenated Bisphenol A and the trans pair of dehydration N.F,USP MANNITOL or the m-phthalic acid in building-up process.
Jointing glue for stone of the present invention has following advantage: 1.. good penetrability; The colloid exquisiteness easily is in harmonious proportion, and has certain fluidity after being blended into solidifying agent, can be penetrated in the tiny stone material slit; And because the colloid exquisiteness, cemented side seam can be very thin, the increase aesthetic property (jointing adhesive adopts reactive thinner, therefore easily is in harmonious proportion, and good penetrability, and do not influence bonding strength).2.. solidify back tack-free (air-drying property will be got well); After colloid solidifies, at once tack-free.Because if when being used for the renovation of hotel stone floor, require jointing adhesive to use up after, just polishing at once.If colloid glues hand, will make mill material on the sander directly in water throwing or when do throwing, on cemented side seam, form black seam, influence (adopt the good unsaturated polyester resin of air-drying property, so air-drying property being good) attractive in appearance especially.3.. anti-contractility is strong, can not form depression after the adhesive curing or separate (adopt antishrinking agent, the shrinking percentage of jointing glue for stone can be controlled in 1%) with stone material.4.. polishing back glue has brightness, quite (find after deliberation: the brightness of jointing adhesive is relevant with the hardness of unsaturated polyester resin with stone polishing brightness, and the hardness of unsaturated polyester resin is relevant with the softening temperature of polyester, can improve hardness by the softening temperature that improves polyester in building-up process).5.. enrich a kind of cloud stone glue, solved the difficult problem of jointing between the stone material.
Jointing glue for stone of the present invention has following advantage: 1.. and the colloid exquisiteness easily is in harmonious proportion good penetrability; 2.. solidify back tack-free (air-drying property is good); 3.. anti-contractility is strong, can not form depression after the adhesive curing; 4.. polishing back glue has brightness, and is suitable with stone polishing brightness.
Embodiment
Describe performance of the present invention below in detail, but they do not constitute limitation of the invention, only do for example.Simultaneously by illustrating that advantage of the present invention will become clear more and understanding easily.
Air-dried unsaturated polyester resin can not be subjected to the interference of oxygen and drying and forming-film in air set, and the surface is non-blocking.This specific character is called dry air again, is called for short air-drying property or empty dryness.
The reaction principle of air-drying property: during unsaturated polyester resin (being called for short UPR) ambient cure, the product surface stickness is made troubles to application usually.Because the curing mechanism of unsaturated polyester resin is a free radicals copolymerization reaction, the size of the activity of free radical decision polymerization rate and then impact polymer molecular weight.
Surface tack was owing to oxygen participation polyreaction in the air causes when unsaturated polyester resin solidified.The free radical R that initial stage generates combines with molecular oxygen and generates polymkeric substance peroxy radical RO
2, the specific activity RO of R
2Active big, the transformation period of R is 10
-8S, RO
2Be 10
-2S rests on RO on the surface
2In this stage, just suppressed the growth of polymericular weight.But peroxy radical RO
2Easily with electropositivity carbon on the hydrogen atom that links to each other react, the hydroperoxide of generation polymkeric substance, that is:
ROO·+HR
1→ROOH+R
1·
The polymkeric substance hydroperoxide can produce active strong free radical, and reaction is proceeded, and generate the high-molecular weight compound.
Such as allyl ethers (CH
2=CH-CH
2-O-) and unconjugated double bond (CH=CH-CH
2-CH=CH-) in the system positivity carbon atom is arranged all, all have the ability of automatic oxygen uptake.
The anti-contractile mechanism of antishrinking agent is: during the stone jointing adhesive curing, and antishrinking agent expanded by heating, the volumetric shrinkage when curable polyester has all around been offset in its expansion.Two-phase is cooled off simultaneously subsequently, because antishrinking agent is more much bigger than the shrinking percentage of polyester, therefore forms a lot of little spaces on biphase has a common boundary, and internal stress has been eliminated in its formation, and polyester is no longer shunk.
Better through the following air-dried unsaturated polyester resin air-drying property of a large amount of experiment screenings, air-dried unsaturated polyester resin among the present invention includes but are not limited to following material: the modified unsaturated polyester resin that utilizes the synthetic dicyclopentadiene of half esterification process, the glycidyl allyl ether modified unsaturated polyester resin, the air-dried unsaturated polyester resin of trimethylolpropane allyl ether modification (above material is all commercially available), the shrinking percentage of air-dried unsaturated polyester resin is about 5%-8%.
Behind a large amount of experiment screenings, following reactive thinner also has anti-contraction: Phthalic acid, diallyl ester, chloro styrene, to t-butyl styrene.Reactive thinner glycerine diallyl ether adipic acid ester can also reach the purpose (above material is all commercially available) that gas is done simultaneously.Need to prove: other reactive thinner commonly used also can adopt.
Antishrinking agent comprises polyvinyl acetate, polystyrene, polyethylene, polyvinyl chloride, polyacrylic ester, poly-propyl acetate, poly-hexanodioic acid glycerine ester, polymethylmethacrylate etc.
The cloud stone glue technical requirements
(the building material industry standard JC/T989-2006 of the People's Republic of China (PRC))
Embodiment 1 (consumption is a weight part)
Jointing glue for stone is by 100 parts of air-dried unsaturated polyester resins, 5 parts of hydrogenated castor oils, and polyvinyl acetate 15 parts (antishrinking agents) is formed.Air-dried unsaturated polyester resin is the modified unsaturated polyester resin that utilizes the synthetic dicyclopentadiene of half esterification process.
After testing: its compression shear strength (MPa) is: 14.8, and draw and cut intensity (MPa): 16.3, curved bullet (MPa): 4435.0, impelling strength (KJ/m
2): 2.2, hardness (HSD): 73.4, shrinking percentage (%): 0.09.
During use: need jointing glue for stone of the present invention to be mixed with solidifying agent and stir, the blending ratio of jointing glue for stone and solidifying agent is 100: 3
Embodiment 2 (consumption is a weight part)
Jointing glue for stone is by 100 parts of air-dried unsaturated polyester resins, 5 parts of hydrogenated castor oils, and 0 part of average out to 1000 purpose silica 1, polyvinyl acetate 15 parts (antishrinking agents) is formed.Air-dried unsaturated polyester resin is the modified unsaturated polyester resin that utilizes the synthetic dicyclopentadiene of half esterification process.
After testing: its compression shear strength (MPa) is: 16.4, and draw and cut intensity (MPa): 17.1, curved bullet (MPa): 4085.6, impelling strength (KJ/m
2): 3.0, hardness (HSD): 71.0, shrinking percentage (%): 0.05.
During use: need jointing glue for stone of the present invention to be mixed with solidifying agent and stir, the blending ratio of jointing glue for stone and solidifying agent is 100: 3
Embodiment 3 (consumption is a weight part)
Jointing glue for stone is by 100 parts of air-dried unsaturated polyester resins, 1 part of hydrogenated castor oil, 60 parts of average out to 300 purpose silicon-dioxide, 1 part of polystyrene (antishrinking agent), 3 parts of Phthalic acid, diallyl esters, 1 part of vinylbenzene, alpha-methyl styrene 1 part (reactive thinner) are formed.Air-dried unsaturated polyester resin is the glycidyl allyl ether modified unsaturated polyester resin.
After testing: its compression shear strength (MPa) is: 14.7, and draw and cut intensity (MPa): 15.6, curved bullet (MPa): 4673.2, impelling strength (KJ/m
2): 2.61, hardness (HSD): 64.5, shrinking percentage (%): 2.63.
Using method is with embodiment 1
Embodiment 4 (consumption is a weight part)
Jointing glue for stone is by 100 parts of air-dried unsaturated polyester resins, 3 parts of hydrogenated castor oils, and 40 parts of average out to 900 purpose micron silicas, 8 parts of polyethylene (antishrinking agent), chloro styrene 3 parts (reactive thinners) is formed.Air-dried unsaturated polyester resin is the modified unsaturated polyester resin that utilizes the synthetic dicyclopentadiene of half esterification process.
After testing: its compression shear strength (MPa) is: 14.6, and draw and cut intensity (MPa): 15.8, curved bullet (MPa): 4490.5, impelling strength (KJ/m
2): 2.89, hardness (HSD): 66.8, shrinking percentage (%): 0.85.
Using method is with embodiment 1
Embodiment 5 (consumption is a weight part)
Jointing glue for stone is by 100 parts of air-dried unsaturated polyester resins, 3 parts of hydrogenated castor oils, and 50 parts of micron silicas, 8 parts of polyacrylic ester (antishrinking agent) are formed t-butyl styrene 4 parts (reactive thinners).Micron silica average out to 800 orders.Air-dried unsaturated polyester resin is the air-dried unsaturated polyester resin of trimethylolpropane allyl ether modification.
After testing: its compression shear strength (MPa) is: 15.4, and draw and cut intensity (MPa): 16.7, curved bullet (MPa): 4583.0, impelling strength (KJ/m
2): 2.73, hardness (HSD): 65.2, shrinking percentage (%): 0.56.
Using method is with embodiment 1
Embodiment 6 (consumption is a weight part)
Jointing glue for stone is by 100 parts of air-dried unsaturated polyester resins, 3 parts of hydrogenated castor oils, and 40 parts of micron silicas, poly-propyl acetate 10 parts (antishrinking agents) is formed.Micron silica average out to 700 orders.Air-dried unsaturated polyester resin is the glycidyl allyl ether modified unsaturated polyester resin.
After testing: its compression shear strength (MPa) is: 15.8, and draw and cut intensity (MPa): 17.0, curved bullet (MPa): 4364.7, impelling strength (KJ/m
2): 2.94, hardness (HSD): 67.0, shrinking percentage (%): 0.96.
Using method is with embodiment 1
Embodiment 7 (consumption is a weight part)
Jointing glue for stone is by 100 parts of air-dried unsaturated polyester resins, 2 parts of hydrogenated castor oils, 30 parts of micron silicas, 2 parts of polyvinyl chloride, 3 parts of polyacrylic ester, 1 part of composition of glycerine diallyl ether adipic acid ester.Micron silica average out to 600 orders.Air-dried unsaturated polyester resin is the air-dried unsaturated polyester resin of trimethylolpropane allyl ether modification.
After testing: its compression shear strength (MPa) is: 16.2, and draw and cut intensity (MPa): 17.8, curved bullet (MPa): 4170.3, impelling strength (KJ/m
2): 2.96, hardness (HSD): 70.3, shrinking percentage (%): 1.34.
Using method is with embodiment 1
Embodiment 8 (consumption is a weight part)
Jointing glue for stone is by 100 parts of air-dried unsaturated polyester resins, 4 parts of hydrogenated castor oils, 30 parts of micron silicas, 2 parts of polyvinyl acetates, 2 parts of polystyrene, 1 part of poly-hexanodioic acid glycerine ester, 2 parts of polymethylmethacrylates, 2 parts of Phthalic acid, diallyl esters, 1 part of composition of glycerine diallyl ether adipic acid ester.Micron silica average out to 500 orders.Air-dried unsaturated polyester resin is the air-dried unsaturated polyester resin of trimethylolpropane allyl ether modification.
After testing: its compression shear strength (MPa) is: 14.9, and draw and cut intensity (MPa): 16.3, curved bullet (MPa): 4250.6, impelling strength (KJ/m
2): 2.85, hardness (HSD): 69.7, shrinking percentage (%): 0.81.
Using method is with embodiment 1
Embodiment 9 (consumption is a weight part)
Jointing glue for stone is by 100 parts of air-dried unsaturated polyester resins, 2 parts of hydrogenated castor oils, and 30 parts of micron silicas, 3 parts of polystyrene, 1 part of polymethylmethacrylate, 2 parts of Phthalic acid, diallyl esters, chloro styrene 3 parts (reactive thinners) are formed.Micron silica average out to 400 orders.Air-dried unsaturated polyester resin is the air-dried unsaturated polyester resin of trimethylolpropane allyl ether modification.
After testing: its compression shear strength (MPa) is: 16.3, and draw and cut intensity (MPa): 17.6, curved bullet (MPa): 4213.5, impelling strength (KJ/m
2): 2.90, hardness (HSD): 70.0, shrinking percentage (%): 1.38.
Using method is with embodiment 1
Embodiment 10 (consumption is a weight part)
Jointing glue for stone is by 100 parts of air-dried unsaturated polyester resins, 4 parts of hydrogenated castor oils, 40 parts of micron silicas, 5 parts of polyacrylic ester, 2 parts of polymethylmethacrylates, to 1 part of t-butyl styrene, 1 part of glycerine diallyl ether adipic acid ester, 1 part of Phthalic acid, diallyl ester, 1 part of composition of chloro styrene.Micron silica average out to 300 orders.Air-dried unsaturated polyester resin is the air-dried unsaturated polyester resin of trimethylolpropane allyl ether modification.
After testing: its compression shear strength (MPa) is: 15.1, and draw and cut intensity (MPa): 15.9, curved bullet (MPa): 4293.8, impelling strength (KJ/m
2): 2.78, hardness (HSD): 68.9, shrinking percentage (%): 1.07.
Using method is with embodiment 1
Satisfy the requirement of jointing between the stone material fully through trial edition invention dedicated transparent jointing glue for stone.
Need to prove: to those of ordinary skill in the art, under the prerequisite that does not change the principle of the invention, can also make suitable improvement and distortion to the present invention, this belongs to protection scope of the present invention equally.As cited materials of the present invention such as antishrinking agent, reactive thinner, air-dried unsaturated polyester resins, comprise but be not limited to above-mentioned substance simultaneously.
Claims (10)
1. jointing glue for stone is characterized in which comprises at least air-dried unsaturated polyester resin 100 weight parts, hydrogenated castor oil 1-5 weight part, micron silica 0-60 weight part, antishrinking agent 1-15 weight part.
2. jointing glue for stone according to claim 1 is characterized in which comprises at least air-dried unsaturated polyester resin 100 weight parts, hydrogenated castor oil 1-5 weight part, micron silica 10-60 weight part, antishrinking agent 1-15 weight part.
3. jointing glue for stone according to claim 1 and 2 is characterized in that described air-dried unsaturated polyester resin is 100 weight parts, and hydrogenated castor oil is the 2-4 weight part, and micron silica is the 30-50 weight part, and antishrinking agent is the 5-10 weight part.
4. jointing glue for stone according to claim 1 and 2 is characterized in that described air-dried unsaturated polyester resin is 100 weight parts, and hydrogenated castor oil is 3 weight parts, and micron silica is 40 weight parts, and antishrinking agent is 8 weight parts.
5. jointing glue for stone according to claim 1 and 2, it is characterized in that described air-dried unsaturated polyester resin is: the modified unsaturated polyester resin that utilizes the synthetic dicyclopentadiene of half esterification process, the glycidyl allyl ether modified unsaturated polyester resin, the air-dried unsaturated polyester resin of trimethylolpropane allyl ether modification is pressed constant and is added thinner, promotor and stopper in the above-mentioned air-dried unsaturated polyester resin.
6. jointing glue for stone according to claim 1 and 2 is characterized in that it also comprises reactive thinner 1-5 weight part.
7. jointing glue for stone according to claim 1 and 2 is characterized in that described micron silica average out to 300-1000 order.
8. jointing glue for stone according to claim 6, it is characterized in that described reactive thinner be vinylbenzene, alpha-methyl styrene, glycerine diallyl ether adipic acid ester, Phthalic acid, diallyl ester, chloro styrene, in the t-butyl styrene one or more.
9. jointing glue for stone according to claim 1 and 2 is characterized in that antishrinking agent comprises one or more in poly-propyl acetate, poly-hexanodioic acid glycerine ester, polyvinyl acetate, polyacrylic ester, polystyrene, polyethylene, polyvinyl chloride, the polymethylmethacrylate.
10. jointing glue for stone according to claim 5 is characterized in that described air-dried unsaturated polyester resin adds one or more in naphthenic hydrocarbon dibasic alcohol, neopentyl glycol, Hydrogenated Bisphenol A and the trans pair of dehydration N.F,USP MANNITOL or the m-phthalic acid in building-up process.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010101472228A CN101851482B (en) | 2009-03-25 | 2010-03-22 | Jointing glue for stone |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910061335.3 | 2009-03-25 | ||
| CN 200910061335 CN101531875A (en) | 2009-03-25 | 2009-03-25 | Stone pointing adhesive |
| CN2010101472228A CN101851482B (en) | 2009-03-25 | 2010-03-22 | Jointing glue for stone |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101851482A true CN101851482A (en) | 2010-10-06 |
| CN101851482B CN101851482B (en) | 2012-09-26 |
Family
ID=42803167
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2010101472228A Active CN101851482B (en) | 2009-03-25 | 2010-03-22 | Jointing glue for stone |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101851482B (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106634765A (en) * | 2016-12-16 | 2017-05-10 | 深圳市华星光电技术有限公司 | Black sealing compound and LCD (liquid crystal display) special-shaped screen, and manufacturing method thereof |
| CN107603095A (en) * | 2017-09-18 | 2018-01-19 | 张家港九力新材料科技有限公司 | It is a kind of can the shrinking agent that uses of normal temperature and preparation method thereof |
| CN108329878A (en) * | 2018-01-24 | 2018-07-27 | 武汉市科达云石护理材料有限公司 | A kind of jade glue and its production method |
| CN113897164A (en) * | 2021-10-26 | 2022-01-07 | 江苏大力士投资有限公司 | Marble adhesive with high adhesion and high toughness and preparation method thereof |
| CN115180865A (en) * | 2022-06-16 | 2022-10-14 | 安徽铁创新材料科技有限公司 | Tackifier for sprayed concrete and preparation method and application thereof |
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| CN1587334A (en) * | 2004-08-05 | 2005-03-02 | 武汉市科达云石护理材料有限公司 | Reinforced silicon dioxide transparent marble glue |
| CN101012360A (en) * | 2007-02-01 | 2007-08-08 | 厦门大学 | Artwork with modified urea-formaldehyde resin as adhesive and preparing method thereof |
| CN101323768A (en) * | 2007-06-14 | 2008-12-17 | 姚志明 | Manufacturing method of artificial marble plate adhesive |
| CN101531875A (en) * | 2009-03-25 | 2009-09-16 | 武汉市科达云石护理材料有限公司 | Stone pointing adhesive |
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| CN1587334A (en) * | 2004-08-05 | 2005-03-02 | 武汉市科达云石护理材料有限公司 | Reinforced silicon dioxide transparent marble glue |
| CN101012360A (en) * | 2007-02-01 | 2007-08-08 | 厦门大学 | Artwork with modified urea-formaldehyde resin as adhesive and preparing method thereof |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106634765A (en) * | 2016-12-16 | 2017-05-10 | 深圳市华星光电技术有限公司 | Black sealing compound and LCD (liquid crystal display) special-shaped screen, and manufacturing method thereof |
| CN107603095A (en) * | 2017-09-18 | 2018-01-19 | 张家港九力新材料科技有限公司 | It is a kind of can the shrinking agent that uses of normal temperature and preparation method thereof |
| CN108329878A (en) * | 2018-01-24 | 2018-07-27 | 武汉市科达云石护理材料有限公司 | A kind of jade glue and its production method |
| CN113897164A (en) * | 2021-10-26 | 2022-01-07 | 江苏大力士投资有限公司 | Marble adhesive with high adhesion and high toughness and preparation method thereof |
| CN115180865A (en) * | 2022-06-16 | 2022-10-14 | 安徽铁创新材料科技有限公司 | Tackifier for sprayed concrete and preparation method and application thereof |
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| Publication number | Publication date |
|---|---|
| CN101851482B (en) | 2012-09-26 |
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