CN101844909B - Autoclaved fly ash brick for construction and manufacturing method thereof - Google Patents

Autoclaved fly ash brick for construction and manufacturing method thereof Download PDF

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Publication number
CN101844909B
CN101844909B CN2010101800788A CN201010180078A CN101844909B CN 101844909 B CN101844909 B CN 101844909B CN 2010101800788 A CN2010101800788 A CN 2010101800788A CN 201010180078 A CN201010180078 A CN 201010180078A CN 101844909 B CN101844909 B CN 101844909B
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CN
China
Prior art keywords
fly ash
construction
flyash
compound
slag
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
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CN2010101800788A
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Chinese (zh)
Other versions
CN101844909A (en
Inventor
徐义德
宋立梅
刘大伟
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GAOMI FURI BUILDING MATERIALS CO Ltd
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GAOMI FURI BUILDING MATERIALS CO Ltd
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Priority to CN2010101800788A priority Critical patent/CN101844909B/en
Publication of CN101844909A publication Critical patent/CN101844909A/en
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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/08Slag cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00017Aspects relating to the protection of the environment
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00034Physico-chemical characteristics of the mixtures
    • C04B2111/00068Mortar or concrete mixtures with an unusual water/cement ratio
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

The invention discloses an autoclaved fly ash brick for construction, which is prepared from the following raw materials by weight in mixture ratio: 13 to 17 of boiler slag, 13 to 17 of fly ash, 8 to 12 of granolithic, 18 to 22 of carbide slag and 38 to 42 of mountain flour. When the fly ash brick is prepared, the boiler slag, the fly ash, the granolithic, the carbide slag and the mountain flour which are ground into a powder shape are mixed evenly according to the mixture ratio by weight of 13 to 17:13 to 17:8 to 12:18 to 22:38 to 42, water is added, and a mixed material with the water content of 10 to 15wt% is prepared and is autoclaved and cured to prepare a finished product after the mixed material is pressed and molded. The invention has simple technological formula, easy control of the technological operation and stable product quality and is a novel energy-saving environment-friendly process.

Description

A kind of autoclaved fly ash brick for construction and method of manufacture thereof
Technical field
The present invention relates to building material technical field, relate in particular to a kind of autoclaved fly ash brick for construction and preparation method thereof.
Background technology
At present, building wall material mainly contains clay solid brick and hollow brick, and is the concrete segment of main raw material with flyash, wherein takes product as the leading factor with clay brick especially.But the clay consumption is big when making owing to clay brick; Bigger to farmland and environmental destruction, therefore to the restriction of country to clay brick, and to the incentives of environment-friendly type standard square; And with the load-bearing main phenomenon to present residential housing; It is domestic that to have occurred many be the lightweight standard brick producer of main raw material with flyash and unslaked lime, but the drawback of this method be unslaked lime add water after character can change, not only be not easy to operation; And the bad control of technology, cause unstable product quality.Therefore, study and a kind ofly can substitute the main raw material clay, and simple, the stay-in-grade environment-friendly type building wall body brick of technology controlling and process technology, be to practice thrift the farmland resource, satisfy the key point of current load bearing construction materials demand.
Summary of the invention
First technical problem to be solved by this invention is: to the deficiency that the existing building standard brick exists aspect quality, environmental protection and energy saving, providing a kind of is main raw material with the trade waste, the autoclaved fly ash brick for construction of constant product quality.
Second technical problem to be solved by this invention is: providing a kind of is main raw material with the trade waste, and production operation is easy to control and the preparation method of the autoclaved fly ash brick for construction of constant product quality.
For solving above-mentioned first technical problem, technical scheme of the present invention is:
A kind of autoclaved fly ash brick for construction, process by following materials of weight proportions:
Boiler slag: flyash: Mi Shi: carbide slag: stone flour=13~17: 13~17: 8~12: 18~22: 38~42.
Preferably, said flyash brick is processed by the raw material of following weight ratio: boiler slag: flyash: Mi Shi: carbide slag: stone flour=15: 15: 10: 20: 40.
For solving above-mentioned second technical problem, technical scheme of the present invention is:
A kind of preparation method of autoclaved fly ash brick for construction; With powdered boiler slag, flyash, Mi Shi, carbide slag and stone flour by 13~17: 13~17: 8~12: 18~22: 38~42 weight proportion mixes; Add entry and process the mixture of water ratio at 10~15wt%, with said mixture compression moulding after steam press maintenance is processed finished product.
As a kind of improvement; Earlier with rice material stone, carbide slag and stone flour by 8~12: 18~22: 38~42 weight proportion mixes; Make compound; Said compound was placed 36~72 hours, and then said compound and powdered boiler slag and flyash by 64~76: 13~17: 13~17 weight proportion mixes, and adds entry and processes the mixture of water ratio at 10~15wt%.
Preferably; Earlier rice material stone, carbide slag and the stone flour weight proportion by 10: 20: 40 is mixed; Make compound; Said compound was placed 36~72 hours, and then mixed said compound and powdered boiler slag and flyash weight proportion, add entry and process the mixture that water ratio is 12wt% by 70: 15: 15.
Wherein, said steam press maintenance comprises and vacuumizes, intensification, constant temperature, leads vapour and steps of exhausting; Vacuum tightness during said vacuumizing is-0.05MPa; Feed saturation steam during said intensification, 2~3 hours TRTs, pressure is 0.95MPa; Said constant temperature time 3~5 hours, pressure 0.95MPa.
Owing to adopted technique scheme, the invention has the beneficial effects as follows:
1, the inventor is through testing and verification in many ways; Worked out and used the unslaked lime that uses in the existing fine coal brickwork skill of the replacing carbide slag prescription, and added the production technique prescription of Mi Shi, stone flour, adopted steaming pressuring curing process; Not only prescription is simple; Technological operation is more prone to control with respect to the prior art of using unslaked lime, and the flyash brick steady quality produced of the present invention, on each item index all apparently higher than the like product level of national regulation.
2, the present invention uses trade waste flyash and boiler slag to be main raw material, has not only handled the part industrial solid castoff, turns waste into wealth, but also has practiced thrift the farmland resource, has protected ecotope, is a kind of novel process of energy-conserving and environment-protective.
Embodiment
Further set forth the present invention below in conjunction with concrete embodiment.Present embodiment only be used to the present invention is described and be not used in the restriction scope of the present invention.After this external content of reading the present invention's instruction, those skilled in the art can do various changes or modification to the present invention, and these equivalent form of values fall within the application's appended claims institute restricted portion equally.
Embodiment 1
Earlier rice material stone, carbide slag and the stone flour weight proportion by 12: 21: 39 is mixed; And constantly make raw materials mix even with shoveling the mode of mixing, and make compound, said compound was placed 64 hours; Make the abundant homogenizing of compound, make the good compound of abundant homogenizing again through high fine crushing crusher machine.
Boiler slag through the levigate powder of processing of ball mill; Mix the compound after the said fragmentation and powdered boiler slag and flyash weight proportion then by 70: 17: 13; In forced stirrer, adding entry mixes; Add entry and process the mixture of water ratio 10wt%, then with mixture through the compression moulding of Full Automatic Liquid brick pressing machine, obtain the work in-process adobe.
The work in-process adobe sent into carry out steam press maintenance in the autoclave, at first the open vacuum pump vacuumizes, when the still internal pressure is closed vacuum pump during for-0.05MPa; In still, evenly feed saturation steam through the steam guiding tube road, make the still internal pressure in 2 hours, reach 0.95MPa; Keep autoclave internal pressure 0.95MPa;, the still internal pressure replenishes saturation steam when descending; Behind the constant temperature 4 hours; Import to the steam in the autoclave in other autoclave through the steam guiding tube road, discharge remaining steam in the still through gas exhaust duct then, when the autoclave internal pressure reaches 0.1MPa, open wash water valve and discharge the water of condensation in the still.
Product coal-dust brick behind the steam press maintenance is stacked maintenance 28 days.
Embodiment 2
Earlier rice material stone, carbide slag and the stone flour weight proportion by 9: 20: 41 is mixed; And constantly make raw materials mix even with shoveling the mode of mixing, and make compound, said compound was placed 64 hours; Make the abundant homogenizing of compound, make the good compound of abundant homogenizing again through high fine crushing crusher machine.
Boiler slag through the levigate powder of processing of ball mill; Mix the compound after the said fragmentation and powdered boiler slag and flyash weight proportion then by 70: 15: 15; In forced stirrer, add entry and mix, add the mixture that water ratio 15wt% is processed in entry; Then with mixture through the compression moulding of Full Automatic Liquid brick pressing machine, obtain the work in-process adobe.
The work in-process adobe sent into carry out steam press maintenance in the autoclave, at first the open vacuum pump vacuumizes, when the still internal pressure is closed vacuum pump during for-0.05MPaa; In still, evenly feed saturation steam through the steam guiding tube road, make the still internal pressure in 3 hours, reach 0.95MPa; Keep autoclave internal pressure 0.95MPa;, the still internal pressure replenishes saturation steam when descending; Behind the constant temperature 3 hours; Import to the steam in the autoclave in other autoclave through the steam guiding tube road, discharge remaining steam in the still through gas exhaust duct then, when the autoclave internal pressure reaches 0.1MPa, open wash water valve and discharge the water of condensation in the still.
Product coal-dust brick behind the steam press maintenance is stacked maintenance 28 days.
Embodiment 3
Earlier rice material stone, carbide slag and the stone flour weight proportion by 10: 20: 40 is mixed; And constantly make raw materials mix even with shoveling the mode of mixing, and make compound, said compound was placed 64 hours; Make the abundant homogenizing of compound, make the good compound of abundant homogenizing again through high fine crushing crusher machine.
Boiler slag through the levigate powder of processing of ball mill; Mix the compound after the said fragmentation and powdered boiler slag and flyash weight proportion then by 72: 16: 12; In forced stirrer, add entry and mix, add the mixture that water ratio 13wt% is processed in entry; Then with mixture through the compression moulding of Full Automatic Liquid brick pressing machine, obtain the work in-process adobe.
The work in-process adobe sent into carry out steam press maintenance in the autoclave, at first the open vacuum pump vacuumizes, when the still internal pressure is closed vacuum pump during for-0.05MPaa; In still, evenly feed saturation steam through the steam guiding tube road, make the still internal pressure in 2.5 hours, reach 0.95MPa; Keep autoclave internal pressure 0.95MPa;, the still internal pressure replenishes saturation steam when descending; Behind the constant temperature 3.5 hours; Import to the steam in the autoclave in other autoclave through the steam guiding tube road, discharge remaining steam in the still through gas exhaust duct then, when the autoclave internal pressure reaches 0.1MPa, open wash water valve and discharge the water of condensation in the still.
Product coal-dust brick behind the steam press maintenance is stacked maintenance 28 days.

Claims (6)

1. autoclaved fly ash brick for construction is characterized in that being processed by following materials of weight proportions:
Boiler slag: flyash: Mi Shi: carbide slag: stone flour=13~17: 13~17: 8~12: 18~22: 38~42.
2. autoclaved fly ash brick for construction as claimed in claim 1 is characterized in that: said flyash brick is processed by the raw material of following weight ratio: boiler slag: flyash: Mi Shi: carbide slag: stone flour=15: 15: 10: 20: 40.
3. the preparation method of an autoclaved fly ash brick for construction; It is characterized in that: with powdered boiler slag, flyash, Mi Shi, carbide slag and stone flour by 13~17: 13~17: 8~12: 18~22: 38~42 weight proportion mixes; Add entry and process the mixture that water ratio is 10~15wt%, with said mixture compression moulding after steam press maintenance is processed finished product.
4. the preparation method of autoclaved fly ash brick for construction as claimed in claim 3; It is characterized in that: earlier with rice material stone, carbide slag and stone flour by 8~12: 18~22: 38~42 weight proportion mixes; Make compound; Said compound was placed 36~72 hours, and then said compound and powdered boiler slag and flyash by 64~76: 13~17: 13~17 weight proportion mixes, and adds entry and processes the mixture of water ratio at 10~15wt%.
5. the preparation method of autoclaved fly ash brick for construction as claimed in claim 4; It is characterized in that: earlier rice material stone, carbide slag and the stone flour weight proportion by 10: 20: 40 is mixed; Make compound; Said compound was placed 36~72 hours, and then mixed said compound and powdered boiler slag and flyash weight proportion, add entry and process the mixture that water ratio is 12wt% by 70: 15: 15.
6. the preparation method of autoclaved fly ash brick for construction as claimed in claim 4 is characterized in that: said steam press maintenance comprises and vacuumizes, intensification, constant temperature, leads vapour and steps of exhausting; Vacuum tightness during said vacuumizing is-0.05MPa; Feed saturation steam during said intensification, 2~3 hours TRTs, pressure is 0.95MPa; Said constant temperature time 3~5 hours, pressure 0.95MPa.
CN2010101800788A 2010-05-15 2010-05-15 Autoclaved fly ash brick for construction and manufacturing method thereof Expired - Fee Related CN101844909B (en)

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Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
CN2010101800788A CN101844909B (en) 2010-05-15 2010-05-15 Autoclaved fly ash brick for construction and manufacturing method thereof

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CN101844909B true CN101844909B (en) 2012-07-04

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Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103496942B (en) * 2013-08-09 2016-01-06 舟山弘业环保材料有限公司 The preparation method of autoclaved fly ash brick
CN104211369A (en) * 2014-08-15 2014-12-17 五河鼎顺新型建材有限公司 Environmentally-friendly hollow brick and preparation method thereof
CN105036672A (en) * 2015-06-26 2015-11-11 安徽恒创环保建材有限公司 Autoclaved fly-ash brick and manufacturing method thereof
CN105272142A (en) * 2015-10-17 2016-01-27 无为县华标新型墙体材料有限公司 Fly ash sintered brick and production process thereof
CN106082940B (en) * 2016-06-17 2018-09-25 舞钢市科建建材有限公司 A kind of fly ash autoclaved brick and preparation method thereof
CN106426512A (en) * 2016-08-26 2017-02-22 舟山市荣科建材有限公司 Hollow fly ash brick and manufacturing method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
李庆繁等.高性能蒸压粉煤灰砖生产工艺综述.《砖瓦世界》.2010,(第2期),全文. *

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