CN101834034A - Production method of niobium-titanium-nickel alloy modified acetal resin superconductor enameled sheet wire - Google Patents

Production method of niobium-titanium-nickel alloy modified acetal resin superconductor enameled sheet wire Download PDF

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Publication number
CN101834034A
CN101834034A CN201010160875A CN201010160875A CN101834034A CN 101834034 A CN101834034 A CN 101834034A CN 201010160875 A CN201010160875 A CN 201010160875A CN 201010160875 A CN201010160875 A CN 201010160875A CN 101834034 A CN101834034 A CN 101834034A
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CN
China
Prior art keywords
acetal resin
superconductor
titanium
production method
niobium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201010160875A
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Chinese (zh)
Inventor
卢廷杰
刘万明
于逸翔
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JIANGSU BAOJIELONG MAGNET WIRES CO Ltd
Original Assignee
JIANGSU BAOJIELONG MAGNET WIRES CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by JIANGSU BAOJIELONG MAGNET WIRES CO Ltd filed Critical JIANGSU BAOJIELONG MAGNET WIRES CO Ltd
Priority to CN201010160875A priority Critical patent/CN101834034A/en
Publication of CN101834034A publication Critical patent/CN101834034A/en
Pending legal-status Critical Current

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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E40/00Technologies for an efficient electrical power generation, transmission or distribution
    • Y02E40/60Superconducting electric elements or equipment; Power systems integrating superconducting elements or equipment

Abstract

The invention discloses a production method of a niobium-titanium-nickel alloy modified acetal resin superconductor enameled sheet wire, which relates to the technical field of a production process of enameled wires. The production method comprises the following steps of: coating a copper layer outside a Ni-Ti alloy to form a composite conductor; coating modified acetal resin outside the composite conductor; and lacquering and baking the composite conductor for multiple times to continuously produce the enameled sheet wires on a lacquering machine, wherein the lacquering speed is 40 m/min, and the furnace temperature of the lacquering machine is between 370 and 390 DEG C. By adopting the process of the invention, the production without a resistance superconducting function can be realized, each property of an insulating layer cannot be influenced, and the niobium-titanium-nickel alloy modified acetal resin superconductor enameled sheet wire can be widely applied in the fields of superconductor motors of nuclear magnetic resonance spectrometers and the like, superconducting cable cores and the like.

Description

The production method of niobium-titanium-nickel alloy modified acetal resin superconductor enameled sheet wire
Technical field
The present invention relates to the technical field of producing of enamelled wire.
Background technology
Common enamelled wire generally adopts common process, promptly coats common paint film as required at the skin of conductor (copper or aluminium), produces insulation effect, is mainly used in the winding wire of general motor, transformer etc.
All insulating varnish all are not suitable for temperature for the use of the environment below-269 ℃ both at home and abroad at present, therefore can't produce low temperature resistant enamelled wire.Simultaneously, common enamelled wire paint is poor with the tack of conductor, comes off easily, has influenced insulation effect.In addition, common enamelled wire manufacturing cost is than higher, and vibration and noise when the motor of producing moves are bigger, and volume and weight is bigger, and stability is relatively poor relatively.
Summary of the invention
The object of the invention be to invent a kind of can bear-269 ℃ of environment, with the production method of the strong niobium-titanium-nickel alloy modified acetal resin superconductor enameled sheet wire of conductor adhesion.
Technical solution of the present invention is: coat the copper layer outside the Ni-Ti alloy, form composite conductor, be coated in outside the described composite conductor with modified acetal resin, on the coating machine of repeatedly japanning, repeatedly baking, produce enameled sheet wire continuously, described japanning speed is 40m/min, and the furnace temperature of coating machine is 370 ℃~390 ℃.
Each thickness that applies modified acetal resin is the 1-1.2 silk, and the total insulation thickness after the baking is not more than 11.
The inlet temperature of coating machine is that 150 ℃ ± 2 ℃, lower floor's temperature are that 250 ℃ ± 2 ℃, middle level temperature are that 340 ℃ ± 2 ℃, upper strata temperature are 390 ℃ ± 2 ℃.
Adopt technology of the present invention can realize the production of non-resistance superconduction function, do not influence every performance of insulating barrier, this product can be widely used in fields such as superconductor motor, hyperconductive cable core such as NMR.Compare with the motor that conventional enamelled wire is made, the present invention can be carried bigger electric current, produces stronger magnetic field, and under the identical situation of power output, the advantage of the superconducting motor of being produced by the present invention is more outstanding:
1, reduced manufacturing cost;
2, reduce operating cost, increase operational efficiency;
Vibration and noise when 3, reducing the motor operation;
4, volume and weight reduces 4/5;
5, single-machine capacity increases;
6, stability improves;
7, its resistance value is≤160 Ω/km when normality, is 0 Ω/km when-269 ℃ (4K);
8, the every index of product can require below also satisfying under subzero 269 ℃ of states:
(1) puncture voltage 1000V;
After (2) 10 times the mechanical bend insulating barrier wrinkle resistant, do not ftracture;
(3) cold-resistant enzyme.
The mass ratio of Ni and Ti is 1: 8~15 in the described Ni-Ti alloy.
Embodiment
One, production craft step is as follows:
1) Ni and Ti are made into the Ni-Ti alloy according to 1: 8~15 mass ratio.
2) utilize metallurgical equipment outside the Ni-Ti alloy conductor, to coat the layer of copper layer, form composite conductor.
3) with the modified acetal resin be insulating paint, the employing linear velocity is that 40m/min, furnace temperature are 370 ℃~390 ℃ coating machine, the continuous producing method that the enamel-cover process adopts repeatedly japanning, repeatedly toasts, wherein each film thickness should be controlled at the 1-1.2 silk, and total insulation is not more than 11.The inlet temperature of control coating machine is 150 ℃ ± 2 ℃, 250 ℃ ± 2 ℃ of lower floor's temperature, 340 ℃ ± 2 ℃ of middle level temperature, 390 ℃ ± 2 ℃ of upper strata temperature.
4) be the product rolling at last, product inspection
Two, check:
1, the ultralow temperature stability of paint film:
Cryogenic superconductor generally cools off with gas helium, liquid helium or superfluid helium, and cold excessively (pressurization) superfluid helium then is optimum selection.As the enamelled wire that the superconducting motor stator winding is used, requiring heart yearn is superconductor.
2, the tack between paint film and the composite conductor:
Because the general Ni-Ti alloys of using of the superconductor of the superconduction enamelled wire of motor windings more, and the Ni-Ti alloy is poor with the adhesive force of paint resin, coat layer of copper in order just to address this problem outside the Ni-Ti alloy superconductor, the adhesive force of metallic copper and macromolecular material is fine.

Claims (4)

1. the production method of niobium-titanium-nickel alloy modified acetal resin superconductor enameled sheet wire, it is characterized in that outside the Ni-Ti alloy, coating the copper layer, form composite conductor, be coated in outside the described composite conductor with modified acetal resin, on the coating machine of repeatedly japanning, repeatedly baking, produce enameled sheet wire continuously, described japanning speed is 40m/min, and the furnace temperature of coating machine is 370 ℃~390 ℃.
2. according to the production method of the described niobium-titanium-nickel alloy modified acetal resin superconductor enameled sheet wire of claim 1, the thickness that it is characterized in that at every turn applying modified acetal resin is the 1-1.2 silk, and the total insulation thickness after the baking is not more than 11.
3. according to the production method of the described niobium-titanium-nickel alloy modified acetal resin superconductor enameled sheet wire of claim 1, the inlet temperature that it is characterized in that coating machine is that 150 ℃ ± 2 ℃, lower floor's temperature are that 250 ℃ ± 2 ℃, middle level temperature are that 340 ℃ ± 2 ℃, upper strata temperature are 390 ℃ ± 2 ℃.
4. according to the production method of the described niobium-titanium-nickel alloy modified acetal resin superconductor enameled sheet wire of claim 1, it is characterized in that the mass ratio of Ni and Ti is 1: 8~15 in the described Ni-Ti alloy.
CN201010160875A 2010-04-21 2010-04-21 Production method of niobium-titanium-nickel alloy modified acetal resin superconductor enameled sheet wire Pending CN101834034A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201010160875A CN101834034A (en) 2010-04-21 2010-04-21 Production method of niobium-titanium-nickel alloy modified acetal resin superconductor enameled sheet wire

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201010160875A CN101834034A (en) 2010-04-21 2010-04-21 Production method of niobium-titanium-nickel alloy modified acetal resin superconductor enameled sheet wire

Publications (1)

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CN101834034A true CN101834034A (en) 2010-09-15

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116313282A (en) * 2023-05-15 2023-06-23 西安聚能超导线材科技有限公司 Paint film defect repairing method for surface of enamelled superconducting wire

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1588565A (en) * 2004-10-10 2005-03-02 西北有色金属研究院 High temperature super conductive material with insulation layer and its preparing method
US20060165983A1 (en) * 2002-04-12 2006-07-27 Jongo Yoon Enameled wire having magnetic reluctance properties and preparation method thereof, and coil using the same and preparation method thereof
CN101650985A (en) * 2009-06-09 2010-02-17 无锡锡洲电磁线有限公司 Class-155 acetal flat enamelled copper wire and method of producing same

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060165983A1 (en) * 2002-04-12 2006-07-27 Jongo Yoon Enameled wire having magnetic reluctance properties and preparation method thereof, and coil using the same and preparation method thereof
CN1588565A (en) * 2004-10-10 2005-03-02 西北有色金属研究院 High temperature super conductive material with insulation layer and its preparing method
CN101650985A (en) * 2009-06-09 2010-02-17 无锡锡洲电磁线有限公司 Class-155 acetal flat enamelled copper wire and method of producing same

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
《光纤与电缆及其应用技术》 19921231 顾新吾 国内外电子线材发展动态综述 29-34 1-4 第1992年卷, 第5期 2 *
《绝缘材料》 19801231 马宏达等 超导线绝缘的选择和试用经验 75-79 1-4 第1980年卷, 第Z1期 2 *
《绝缘材料通讯》 19921231 Haruyki Fujino 日本超导装置电绝缘技术 40-43 1-4 第1992年卷, 第3期 2 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116313282A (en) * 2023-05-15 2023-06-23 西安聚能超导线材科技有限公司 Paint film defect repairing method for surface of enamelled superconducting wire
CN116313282B (en) * 2023-05-15 2023-08-25 西安聚能超导线材科技有限公司 Paint film defect repairing method for surface of enamelled superconducting wire

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Open date: 20100915