CN101811833A - Anti-slip glass, multifunctional anti-slip glass floor and preparation methods thereof - Google Patents
Anti-slip glass, multifunctional anti-slip glass floor and preparation methods thereof Download PDFInfo
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- CN101811833A CN101811833A CN 201010170167 CN201010170167A CN101811833A CN 101811833 A CN101811833 A CN 101811833A CN 201010170167 CN201010170167 CN 201010170167 CN 201010170167 A CN201010170167 A CN 201010170167A CN 101811833 A CN101811833 A CN 101811833A
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Abstract
The invention discloses anti-slip glass, a multifunctional anti-slip glass floor based on the anti-slip glass and preparation methods of the anti-slip glass and the multifunctional anti-slip glass floor. The anti-slip glass comprises a glass substrate and an anti-slip layer, and is characterized in that the anti-slip layer is a resin film obtained through screen painting and curing, and anti-slip grain materials formed by mixing organic grain materials and inorganic grain materials are uniformly covered in the resin film. The anti-slip glass floor comprises the anti-slip glass, a coloring layer is coated on the lower surface of the glass substrate of the anti-slip glass, a safe film layer is coated on the surface of the coloring layer, and an alkaline-resisting glass fiber screen layer is pasted on the surface of the safe film layer. The invention has the advantages that the anti-slip glass has long anti-slip time, good anti-slip effect and simple preparation method; and the multifunctional anti-slip glass floor has high practicability, high safety performance, good anti-slip effect, simple manufacture method and easy realized conditions.
Description
Technical field
The present invention relates to a kind of anti slip glass and preparation method thereof.
The invention still further relates to a kind of multifunctional anti skid glass floor based on anti slip glass and preparation method thereof.
Background technology
The anti slip glass goods are known, and can pass through prepared in various methods, known anti slip glass mainly is to adopt inorganic glaze as filmogen, add an amount of anti-skidding pellet on the surface of inorganic glaze on the other hand, directly with the surface of high temperature sintering at glass substrate, Chinese patent CN1332302, CN101289282 disclose and have used the outside surface printed glass glaze of the method for silk screen printing at glass baseplate, and add the non-skid finish of the anti-pellet formation of mineral-type such as an amount of river sand, powder emery, diamond spar sand or glass microballon.Yet anti-skidding pellet is very irregular geometrical configuration, after the anti-skidding pellet film forming of admixture, relative with the binding property of glass glaze and glass substrate relatively poor, easily come off, matter is hard and crisp, corner angle easily polish after the rubbing effect of process external force, thereby the ageing weak point of maintenance skidproof effect, and after adding certain thickness inorganic anti-skidding pellet, glass glaze surface forms coarse surface, accumulate the dust dirt easily, significantly reduce as ornamental effect, in addition, when construction and installation, the method that keel must be installed or support with the fixed point that frames up is anti slip glass fixedly, and the apprentice enriches worker's puzzlement and safety worries.
On the other hand, existing glass floor does not have the function that keeps fragment, in case abrasive floor breaks, fragment flashes, and personnel's personnel safety brings serious harm around giving.
Usually antiskid glass floor is when being used for construction operation as the ground surface glass, the cement that contacts with glass-board surface is in process of setting, inner free water corrodes from antiskid glass floor periphery slit with the mortar that has alkalescence, causes the be full of cracks of cement layer, reduces the bonding strength of the two.Therefore should provide new technical scheme to address the above problem.
Summary of the invention
An object of the present invention is to provide anti slip glass of a kind of anti-skidding time length, good antiskid effect and preparation method thereof.
Another object of the present invention provides a kind of multifunctional anti skid glass floor and preparation method thereof.
For achieving the above object, the technical solution used in the present invention is:
A kind of anti slip glass comprises glass substrate and the non-skid finish that is fixed on the glass substrate upper surface, and described non-skid finish is silk screen printing and solidifies the resin molding that forms, is uniformly coated with the anti-skidding pellet that is mixed by organic pellet and inorganic pellet in the described resin molding.
Resin molding weight percent in the described non-skid finish is 40-80%, and described organic pellet weight percent is 20-50%, and inorganic pellet weight percent is 20-50%, and organic pellet of the anti-skidding pellet of described formation and inorganic pellet particle diameter are the 40-150 order.
Described resin molding is a kind of in aminoresin film, epoxy resin film or the polyurethanes resin molding.
Described resin molding is the polyurethanes resin molding.
Described organic pellet is a kind of in acrylic resin particle or the urethane resin particle, and described inorganic pellet is a kind of in silicon carbide or the aluminum oxide.
A kind of preparation method of anti slip glass, anti-skidding pellet is wetting and mix with resin solution in advance, secondly silk screen printing becomes the thick resin film layer of 100um-1.2mm on glass substrate, send into the cryodrying stove again and after under the 90-150 ℃ of temperature dry heat 25-35 minute, take out, solidify dry anti slip glass with non-skid finish thereby be formed on the glass substrate upper surface.
A kind of multifunctional anti skid glass floor, comprise aforesaid anti slip glass, the glass substrate lower surface of described anti slip glass is coated with one deck pigmented layer, and the surface coated of described pigmented layer has one deck safety rete, is pasted with the alkali resistant glass fibre stratum reticulare on the surface of described safe rete.
Also be bonded with one deck conduction heating rete between described pigmented layer and the safe rete.
A kind of preparation method of multifunctional anti skid glass floor, the glass substrate lower surface of step 1: the preparation of pigmented layer---the anti slip glass that at first will be prepared from by claim 6 is by a kind of coating one deck color layers in the mechanical coating process of spraying, roller coat or woods curtain, send into drying oven then and be cured heating, Heating temperature is 90-150 ℃, and the dry heat time is the 30-60 branch; Step 2: the preparation of conduction heating rete---at the surface adhesion one layer printed circuit heating film layer of pigmented layer, thereby form the conduction heating rete; Step 3: the preparation of safe rete and alkali resistant glass fibre stratum reticulare---be coated with one deck elastic polyurethane coating at the conduction heating film surface in the mode of blade coating, after finishing, a blade coating directly the alkali resistant glass fibre net is pasted on still undried elastic polyurethane coating surface, around antiskid glass floor, form uniform sealing ply with the method for brushing simultaneously, send into afterwards and carry out heat treated in the drying oven three times, the temperature of each heating is 140-155 ℃, be 25-35 minute heat-up time, solidify after strain through heat drying and become the thick safe rete of 0.5-4mm, then paste on the surface of safe rete and fixed the alkali resistant glass fibre stratum reticulare, finally make the multifunctional anti skid glass floor.
Coating pigmented layer used coating is a kind of in urethane, polyacrylic ester, Resins, epoxy or the fluorocarbon resin in the above-mentioned steps one, and the used coating of coating sealing ply is polyacrylic ester or fluorocarbon resin coating in the above-mentioned steps three.
Advantage of the present invention is: long, good antiskid effect of anti-skidding time of anti slip glass, and the preparation method is simple; The multifunctional anti skid glass floor is practical, safety performance is high, good antiskid effect, and its manufacture method is simple, and condition is easy to realize.
Description of drawings
Below in conjunction with the drawings and specific embodiments the present invention is described in further detail:
Fig. 1 is an anti slip glass structural representation of the present invention.
Fig. 2 is a multifunctional anti skid glass floor structural representation of the present invention.
Fig. 3 is another example structure synoptic diagram of multifunctional anti skid glass floor of the present invention.
Wherein: 1, glass substrate, 2, resin molding, 3, anti-skidding pellet, 4, non-skid finish, 5, pigmented layer, 6, the conduction heating rete, 7, safe rete, 8, the alkali resistant glass fibre stratum reticulare.
Embodiment
Embodiment 1
As Fig. 1, anti slip glass of the present invention, comprise glass substrate 1 and the non-skid finish 4 that is fixed on glass substrate 1 upper surface, non-skid finish 4 is for silk screen printing and solidify the resin molding 2 that forms, in the non-skid finish 4, resin molding 2 is the polyurethanes resin molding, and its weight percent is 40%, being uniformly coated with in the resin molding 2 by weight percent is that 20% acrylic resin particle and weight percent are the anti-skidding pellet 3 that 20% silicon carbide mixes, and the particle diameter of anti-skidding pellet 3 is 40 orders.
The preparation method of above-mentioned anti slip glass, be that anti-skidding pellet 3 is wetting and mix with resin solution in advance, secondly silk screen printing becomes the thick resin film layer of 100um-1.2mm on glass substrate 1, send into cryodrying stove dry heat under 90 ℃ of temperature again and take out after 25 minutes, solidify dry anti slip glass with non-skid finish thereby be formed on the glass substrate upper surface.
As Fig. 1, anti slip glass of the present invention, comprise glass substrate 1 and the non-skid finish 4 that is fixed on glass substrate 1 upper surface, non-skid finish 4 is for silk screen printing and solidify the resin molding 2 that forms, in the non-skid finish 4, resin molding 2 is the polyurethanes resin molding, and its weight percent is 60%, being uniformly coated with in the resin molding 2 by weight percent is that 35% urethane resin particle and weight percent are the anti-skidding pellet 3 that 35% aluminum oxide mixes, and the particle diameter of anti-skidding pellet 3 is 100 orders.
The preparation method of above-mentioned anti slip glass, be that anti-skidding pellet 3 is wetting and mix with resin solution in advance, secondly silk screen printing becomes the thick resin film layer of 100um-1.2mm on glass substrate 1, send into cryodrying stove dry heat under 130 ℃ of temperature again and take out after 30 minutes, solidify dry anti slip glass with non-skid finish thereby be formed on the glass substrate upper surface.
As Fig. 1, anti slip glass of the present invention, comprise glass substrate 1 and the non-skid finish 4 that is fixed on glass substrate 1 upper surface, non-skid finish 4 is for silk screen printing and solidify the resin molding 2 that forms, in the non-skid finish 4, resin molding 2 is the polyurethanes resin molding, and its weight percent is 80%, being uniformly coated with in the resin molding 2 by weight percent is that 50% urethane resin particle and weight percent are the anti-skidding pellet 3 that 50% aluminum oxide mixes, and the particle diameter of anti-skidding pellet 3 is 150 orders.
The preparation method of above-mentioned anti slip glass, be that anti-skidding pellet 3 is wetting and mix with resin solution in advance, secondly silk screen printing becomes the thick resin film layer of 100um-1.2mm on glass substrate 1, send into cryodrying stove dry heat under 150 ℃ of temperature again and take out after 35 minutes, solidify dry anti slip glass with non-skid finish thereby be formed on the glass substrate upper surface.
As Fig. 2, multifunctional anti skid glass floor of the present invention, comprise the anti slip glass among above-mentioned arbitrary embodiment, glass substrate 1 lower surface of described anti slip glass is coated with one deck pigmented layer 5, the surface coated of described pigmented layer 5 has one deck safety rete 7, is pasted with alkali resistant glass fibre stratum reticulare 8 on the surface of described safe rete 7.
The preparation method of above-mentioned multifunctional anti skid glass floor:
Glass substrate 1 lower surface of step 1: the preparation of pigmented layer---the anti slip glass that at first will be prepared from by embodiment 1-3 is the color layers of base material with the polyacrylic ester by spraying, roller coat or a kind of one deck that is coated with of drenching in the mechanical coating process of curtain, send into drying oven then and be cured heating, Heating temperature is 90 ℃, and the dry heat time is 30 minutes;
Step 2: the preparation of safe rete and alkali resistant glass fibre stratum reticulare---the mode on the surface of pigmented layer 5 with blade coating is coated with one deck elastic polyurethane coating, after finishing, a blade coating directly the alkali resistant glass fibre net is pasted on still undried elastic polyurethane coating surface, use polyacrylic ester or fluorocarbon resin coating to carry out sealing all around with the method for brushing simultaneously, send into afterwards and carry out heat treated in the drying oven three times, the temperature of each heating is 140 ℃, be 25 minutes heat-up time, solidify after strain through heat drying and become the thick safe rete 7 of 0.5-4mm, then paste on the surface of safe rete 7 and fixed alkali resistant glass fibre stratum reticulare 8, finally make the multifunctional anti skid glass floor.
As Fig. 2, multifunctional anti skid glass floor of the present invention, comprise the anti slip glass among above-mentioned arbitrary embodiment, glass substrate 1 lower surface of described anti slip glass is coated with one deck pigmented layer 5, the surface coated of described pigmented layer 5 has one deck safety rete 7, is pasted with alkali resistant glass fibre stratum reticulare 8 on the surface of described safe rete 7.
The preparation method of above-mentioned multifunctional anti skid glass floor:
Glass substrate 1 lower surface of step 1: the preparation of pigmented layer---the anti slip glass that at first will be prepared from by embodiment 1-3 is the color layers of base material with urethane by spraying, roller coat or a kind of one deck that is coated with of drenching in the mechanical coating process of curtain, send into drying oven then and be cured heating, Heating temperature is 120 ℃, and the dry heat time is 45 minutes;
Step 2: the preparation of safe rete and alkali resistant glass fibre stratum reticulare---the mode on the surface of pigmented layer 5 with blade coating is coated with one deck elastic polyurethane coating, after finishing, a blade coating directly the alkali resistant glass fibre net is pasted on still undried elastic polyurethane coating surface, use polyacrylic ester or fluorocarbon resin coating to carry out sealing all around with the method for brushing simultaneously, send into afterwards and carry out heat treated in the drying oven three times, the temperature of each heating is 145 ℃, be 30 minutes heat-up time, solidify after strain through heat drying and become the thick safe rete 7 of 0.5-4mm, then paste on the surface of safe rete and fixed alkali resistant glass fibre stratum reticulare 8, finally make the multifunctional anti skid glass floor.
Embodiment 6
As Fig. 2, multifunctional anti skid glass floor of the present invention, comprise the anti slip glass among above-mentioned arbitrary embodiment, glass substrate 1 lower surface of described anti slip glass is coated with one deck pigmented layer 5, the surface coated of described pigmented layer 5 has one deck safety rete 7, is pasted with alkali resistant glass fibre stratum reticulare 8 on the surface of described safe rete 7.
The preparation method of above-mentioned multifunctional anti skid glass floor:
Glass substrate 1 lower surface of step 1: the preparation of pigmented layer---the anti slip glass that at first will be prepared from by embodiment 1-3 is the color layers of base material with Resins, epoxy by spraying, roller coat or a kind of one deck that is coated with of drenching in the mechanical coating process of curtain, send into drying oven then and be cured heating, Heating temperature is 150 ℃, and the dry heat time is 60 minutes;
Step 2: the preparation of safe rete and alkali resistant glass fibre stratum reticulare---the mode on the surface of pigmented layer 5 with blade coating is coated with one deck elastic polyurethane coating, after finishing, a blade coating directly the alkali resistant glass fibre net is pasted on still undried elastic polyurethane coating surface, use polyacrylic ester or fluorocarbon resin coating to carry out sealing all around with the method for brushing simultaneously, send into afterwards and carry out heat treated in the drying oven three times, the temperature of each heating is 150 ℃, be 35 minutes heat-up time, solidify after strain through heat drying and become the thick safe rete of 0.5-4mm, then paste on the surface of safe rete and fixed the alkali resistant glass fibre stratum reticulare, finally make the multifunctional anti skid glass floor.
Embodiment 7
As Fig. 3, multifunctional anti skid glass floor of the present invention also is bonded with one deck conduction heating rete 6 between pigmented layer 5 and the safe rete 7.Its manufacture method is: at the surface adhesion one layer printed circuit heating film layer of pigmented layer 5, thereby form conduction heating rete 6, other structures of present embodiment and manufacture method are with embodiment 6.
Safe rete 7 can be in elastomeric state when normal temperature, have good snappiness, shock-resistance and chemical proofing, also has excellent low temperature resistant and rub resistance.This safe rete also has two-way avidity, and pigmented layer and sand-cement slurry are all had splendid sticking power.
In order further to increase the sticking power between the present invention and the sand-cement slurry, on the surface of safety rete 7, paste and be fixed with alkali-resistant glass fiber stratum reticulare 8, this alkali-resistant glass fiber stratum reticulare has extremely strong alkali-resistivity and high breaking tenacity, can resist atomic thin crack in the mortar, prevent the be full of cracks of cement layer, guarantee combining closely between the present invention and cement.
Conduction heating rete 6 can be regulated the transmission of heat, improves the temperature of antiskid glass floor, and can prevent the dewfall of floor surface, thereby provides comparatively dry comfortable ground for the lower environment of temperature.
Claims (10)
1. anti slip glass, comprise glass substrate and the non-skid finish that is fixed on the glass substrate upper surface, it is characterized in that: described non-skid finish is silk screen printing and solidifies the resin molding that forms, is uniformly coated with the anti-skidding pellet that is mixed by organic pellet and inorganic pellet in the described resin molding.
2. a kind of anti slip glass according to claim 1, it is characterized in that the resin molding weight percent in the described non-skid finish is 40-80%, described organic pellet weight percent is 20-50%, inorganic pellet weight percent is 20-50%, and organic pellet of the anti-skidding pellet of described formation and inorganic pellet particle diameter are the 40-150 order.
3. a kind of anti slip glass according to claim 1 and 2 is characterized in that described resin molding is a kind of in aminoresin film, epoxy resin film or the polyurethanes resin molding.
4. a kind of anti slip glass according to claim 3 is characterized in that described resin molding is the polyurethanes resin molding.
5. a kind of anti slip glass according to claim 1 and 2 is characterized in that described organic pellet is a kind of in acrylic resin particle or the urethane resin particle, and described inorganic pellet is a kind of in silicon carbide or the aluminum oxide.
6. the preparation method of an anti slip glass, it is characterized in that anti-skidding pellet in advance wetting and mix with resin solution, secondly silk screen printing becomes the thick resin film layer of 100um-1.2mm on glass substrate, send into the cryodrying stove again and after under the 90-150 ℃ of temperature dry heat 25-35 minute, take out, solidify dry anti slip glass with non-skid finish thereby be formed on the glass substrate upper surface.
7. multifunctional anti skid glass floor, it is characterized in that comprising the described anti slip glass of above-mentioned arbitrary claim, the glass substrate lower surface of described anti slip glass is coated with one deck pigmented layer, the surface coated of described pigmented layer has one deck safety rete, is pasted with the alkali resistant glass fibre stratum reticulare on the surface of described safe rete.
8. a kind of multifunctional anti skid glass floor according to claim 7 is characterized in that also being bonded with between described pigmented layer and the safe rete one deck conduction heating rete.
9. the preparation method of a multifunctional anti skid glass floor is characterized in that
The glass substrate lower surface of step 1: the preparation of pigmented layer---the anti slip glass that at first will be prepared from by claim 6 is by spraying, roller coat or drench a kind of coating one deck color layers in the mechanical coating process of curtain, send into drying oven then and be cured heating, Heating temperature is 90-150 ℃, and the dry heat time is the 30-60 branch;
Step 2: the preparation of conduction heating rete---at the surface adhesion one layer printed circuit heating film layer of pigmented layer, thereby form the conduction heating rete;
Step 3: the preparation of safe rete and alkali resistant glass fibre stratum reticulare---be coated with one deck elastic polyurethane coating at the conduction heating film surface in the mode of blade coating, after finishing, a blade coating directly the alkali resistant glass fibre net is pasted on still undried elastic polyurethane coating surface, around antiskid glass floor, form uniform sealing ply with the method for brushing simultaneously, send into afterwards and carry out heat treated in the drying oven three times, the temperature of each heating is 140-155 ℃, be 25-35 minute heat-up time, solidify after strain through heat drying and become the thick safe rete of 0.5-4mm, then paste on the surface of safe rete and fixed the alkali resistant glass fibre stratum reticulare, finally make the multifunctional anti skid glass floor.
10. the preparation method of a kind of multifunctional anti skid glass floor according to claim 9, it is characterized in that in the described step 1 that the used coating of coating pigmented layer is a kind of in urethane, polyacrylic ester, Resins, epoxy or the fluorocarbon resin, the used coating of coating sealing ply is polyacrylic ester or fluorocarbon resin coating in the described step 3.
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| CN 201010170167 CN101811833A (en) | 2009-11-30 | 2010-04-23 | Anti-slip glass, multifunctional anti-slip glass floor and preparation methods thereof |
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| CN200910224014.0 | 2009-11-30 | ||
| CN 201010170167 CN101811833A (en) | 2009-11-30 | 2010-04-23 | Anti-slip glass, multifunctional anti-slip glass floor and preparation methods thereof |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105297583A (en) * | 2015-10-19 | 2016-02-03 | 苏州群力防滑材料有限公司 | Antiskid strip sprayed with antiskid material |
| CN107827370A (en) * | 2017-11-20 | 2018-03-23 | 重庆艺美玻璃有限公司 | A kind of slide-proof hollow glass |
| CN108250913A (en) * | 2018-02-07 | 2018-07-06 | 合肥华盖生物科技有限公司 | A kind of park health and fitness facilities surface anti-skidding coating agent and preparation method thereof |
| CN108758104A (en) * | 2018-06-14 | 2018-11-06 | 江苏环宇建设工程有限公司 | Concrete clad structure of natural gas line and preparation method thereof |
| WO2019218485A1 (en) * | 2018-05-14 | 2019-11-21 | 华为技术有限公司 | Anti-slip mat, terminal and method for fabricating anti-slip mat on terminal |
| WO2020057710A1 (en) * | 2018-09-19 | 2020-03-26 | Garcia Smester Juan Antonio | Method for producing a decorative aseptic floor made in an artisanal manner with epoxy resin and recycled glass |
| CN112189044A (en) * | 2018-06-29 | 2021-01-05 | 三菱化学株式会社 | Anti-slip agent, anti-slip fiber processed product, and method for producing anti-slip fiber processed product |
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| US20090022979A1 (en) * | 2007-07-18 | 2009-01-22 | Sube Tsai | Anti-slip floor coating composition and anti-slip floor material made therefrom |
| CN201342818Y (en) * | 2008-08-28 | 2009-11-11 | 上海商润实业有限公司 | Special anti-skidding coating |
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| US20010051230A1 (en) * | 2000-11-13 | 2001-12-13 | Martin Colton | Glass repair system utilizing a transparent UV curable coating |
| US20090022979A1 (en) * | 2007-07-18 | 2009-01-22 | Sube Tsai | Anti-slip floor coating composition and anti-slip floor material made therefrom |
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105297583A (en) * | 2015-10-19 | 2016-02-03 | 苏州群力防滑材料有限公司 | Antiskid strip sprayed with antiskid material |
| CN107827370A (en) * | 2017-11-20 | 2018-03-23 | 重庆艺美玻璃有限公司 | A kind of slide-proof hollow glass |
| CN108250913A (en) * | 2018-02-07 | 2018-07-06 | 合肥华盖生物科技有限公司 | A kind of park health and fitness facilities surface anti-skidding coating agent and preparation method thereof |
| WO2019218485A1 (en) * | 2018-05-14 | 2019-11-21 | 华为技术有限公司 | Anti-slip mat, terminal and method for fabricating anti-slip mat on terminal |
| CN110832595A (en) * | 2018-05-14 | 2020-02-21 | 华为技术有限公司 | Anti-skid foot pad, terminal and method for manufacturing anti-skid foot pad on terminal |
| CN110832595B (en) * | 2018-05-14 | 2022-03-11 | 华为技术有限公司 | Anti-skid foot pad, terminal and method for manufacturing anti-skid foot pad on terminal |
| CN108758104A (en) * | 2018-06-14 | 2018-11-06 | 江苏环宇建设工程有限公司 | Concrete clad structure of natural gas line and preparation method thereof |
| CN112189044A (en) * | 2018-06-29 | 2021-01-05 | 三菱化学株式会社 | Anti-slip agent, anti-slip fiber processed product, and method for producing anti-slip fiber processed product |
| CN112189044B (en) * | 2018-06-29 | 2022-07-29 | 三菱化学株式会社 | Anti-slip agent, anti-slip fiber processed product, and method for producing anti-slip fiber processed product |
| WO2020057710A1 (en) * | 2018-09-19 | 2020-03-26 | Garcia Smester Juan Antonio | Method for producing a decorative aseptic floor made in an artisanal manner with epoxy resin and recycled glass |
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Application publication date: 20100825 |