CN101805149A - Polyurethane ceramic tile imitation product - Google Patents
Polyurethane ceramic tile imitation product Download PDFInfo
- Publication number
- CN101805149A CN101805149A CN 201010125901 CN201010125901A CN101805149A CN 101805149 A CN101805149 A CN 101805149A CN 201010125901 CN201010125901 CN 201010125901 CN 201010125901 A CN201010125901 A CN 201010125901A CN 101805149 A CN101805149 A CN 101805149A
- Authority
- CN
- China
- Prior art keywords
- ceramic tile
- product
- imitation product
- mdi
- ethylene glycol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Polyurethanes Or Polyureas (AREA)
Abstract
The invention discloses a polyurethane ceramic tile imitation product. The product is prepared by stirring and mixing a polyalcohol compound with the molecular weight of between 250 and 2,000, MDI and an inorganic material through a cement mixer, pouring the mixture in a mold, degassing, solidifying, demolding and trimming, wherein ratio of the polyalcohol compound to the MDI to the inorganic is 100:(40-100):(200-2,000). The product has the advantages that the ceramic tile imitation manufacture is performed at a temperature close to normal temperature, and saves mass energy consumption compared with ceramic tile high-temperature sintering. The product has simple manufacture process, low cost, light mass, good toughness, hard destruction, abrasion resistance and no maintenance, can be manufactured into different shapes, such as wide width products, tongue-and-groove products and the like, and is more convenient for installation, use and the like.
Description
Technical field
The present invention relates to a kind of polyurethane ceramic tile imitation product, belong to technical field of construction and decoration materials.
Background technology
Along with the progress of society, building and ornament materials more and more are much accounted of.At present, the material that exterior wall is used mainly contains ceramic tile, grouan, coating etc., because grouan cost height, and coating is thinner, can not stand the Nature rainwater, dust storm, ultraviolet erosion, has therefore limited their application greatly.In fact since the eighties in last century most of skin all be to use ceramic tile.Ceramic tile, it is with fireproof metal oxide and half-metal oxide, the building of the porcelain of a kind of acid and alkali-resistance that forms via the process of grinding, mixing, compacting, glazing, sintering or Shi Zhi etc. or the material of decoration, always be referred to as ceramic tile, its starting material are many to be mixed by clay, quartz sand or the like.There is following shortcoming in it: need high temperature sintering, consume lot of energy; Complex manufacturing technology, the cost height; Quality is heavy, easily breaks into pieces.Though also there are some ceramic tile imitation products to come out now, or manufacturing process complexity, cost height, or appearance is coarse, does not have the effect of decoration, has limited its application.For this reason, how to prepare with existing ceramic tile and compare favourably, but than ceramic tile light weight, good toughness, and the ceramic tile imitation product that preparation technology is simple, cost is low is people's urgent problems.
Summary of the invention
In order to overcome the shortcoming of above-mentioned existing ceramic tile and ceramic tile imitation product, the invention provides a kind of light weight, good toughness, and a kind of polyurethane ceramic tile imitation product that manufacturing process is simple, cost is low.
Technical scheme of the present invention is: a kind of polyurethane ceramic tile imitation product, it is characterized in that, it is to be that 250～2000 polyol compound, diphenylmethanediisocyanate (MDI) and inorganic materials are after cement mixer mixes with molecular weight, be poured in the mould, form through the degassing, curing, the demoulding, trimming again.The ratio of described polyol compound, MDI and inorganic materials is polyol compound: MDI: inorganic materials=100: (40-100): (200-2000); Described inorganic materials can be red mud, lime carbonate or silicon-dioxide etc.
Described molecular weight is that 250～2000 polyol compound is (as Oleum Gossypii semen by vegetables oil, Viscotrol C, soybean oil, the palm wet goods) with ethylene glycol or glycerol, with titanate ester (as: tetra isopropyl titanate) or organic tin compound (as: dibutyl tin dilaurate etc.) is catalyzer, get down at 200-240 ℃ through alcoholysis and transesterification reaction 5-10 hour, wherein the add-on of vegetables oil is the 92-65% (wt/wt) of vegetables oil and ethylene glycol or glycerol total amount, ethylene glycol or glycerol are the 8-35% (wt/wt) of vegetables oil and ethylene glycol or glycerol total amount, the add-on of catalyzer be vegetables oil and ethylene glycol or glycerol total amount 1-5/ 1,000,000.
The invention has the beneficial effects as follows: it is near carrying out under the normal temperature that (1) imitative ceramic tile of the present invention is made, and compares with the high temperature sintering of ceramic tile and has saved a large amount of energy consumptions; (2) manufacture craft is simple, cost is low (cost of the present invention is every square metre of 20-50 unit, and the cost of general ceramic tile is a 40-80 unit); (3) light weight (the present invention is every square metre of 2-6 kilogram, and ceramic tile is the 4-8 kilogram), good toughness are not easy breakage; (4) wear-resistant (being caused by its molecular structure) do not need maintenance; (5) can be made into different shapes, for example, wide cut, the band tongue and groove etc., be more convenient for installing and using.The main performance index contrast of the imitative ceramic tile of common ceramic tile and the present invention sees Table 1.
The main performance index contrast table of common ceramic tile of table 1 and imitative ceramic tile
| Common ceramic tile | The present invention imitates ceramic tile | |
| Water-intake rate (wt/wt) | ??≤0.5％ | ??≤0.3％ |
| Thickness＜7.5mm, strength at break mean value | Be not less than 700N | Be not less than 1000N |
| Wear resistance: the wear volume of anti-the degree of depth | Be not more than 175mm 3 | Be not more than 150mm 3 |
Embodiment
Embodiment 1:
92 gram Oleum Gossypii semens and 8 gram ethylene glycol are joined in the reaction vessel, and then add 10
-6The gram tetra isopropyl titanate under 200-240 ℃, reacted 8 hours, obtained molecular weight and be 250～2000 polyol compound.
With 100 gram molecular weights is 250～2000 polyol compounds, 50 gram diphenylmethanediisocyanates (MDI) and 500 gram dehydration red muds are after cement mixer mixes, be poured in the mould, obtain polyurethane ceramic tile imitation through the degassing, curing, the demoulding, trimming again, every index of the imitative ceramic tile of gained is: water-intake rate≤0.3%; Thickness＜7.5mm, strength at break mean value is not less than 1000N; Wear resistance: the wear volume of anti-the degree of depth is not more than 175mm
3
Embodiment 2:
90 gram soybean oil and 10 gram ethylene glycol are joined in the reaction vessel, and then add 2 * 10
-6The gram tetra isopropyl titanate under 200-240 ℃, reacted 10 hours, obtained molecular weight and be 250～2000 polyol compound.
With 100 gram molecular weights is 250～2000 polyol compounds, 60 gram diphenylmethanediisocyanates (MDI) and 800 gram dehydration red muds are after cement mixer mixes, be poured in the mould, obtain polyurethane ceramic tile imitation through the degassing, curing, the demoulding, trimming again, every index of the imitative ceramic tile of gained is: water-intake rate≤0.3%; Thickness＜7.5mm, strength at break mean value is not less than 1000N; Wear resistance: the wear volume of anti-the degree of depth is not more than 175mm
3
Embodiment 3:
80 gram plam oils and 20 gram ethylene glycol are joined in the reaction vessel, and then add 3 * 10
-6The gram dibutyl tin dilaurate under 200-240 ℃, was reacted 6 hours, obtained molecular weight and be 250～2000 polyol compound.
With 100 gram molecular weights is 250～2000 polyol compounds, 40 gram diphenylmethanediisocyanates (MDI) and 200 gram lime carbonate are after cement mixer mixes, be poured in the mould, obtain polyurethane ceramic tile imitation through the degassing, curing, the demoulding, trimming again, every index of the imitative ceramic tile of gained is: water-intake rate≤0.3%; Thickness＜7.5mm, strength at break mean value is not less than 1000N; Wear resistance: the wear volume of anti-the degree of depth is not more than 175mm
3
Embodiment 4
65 gram soybean oil and 35 gram glycerol are joined in the reaction vessel, and then add 5 * 10
-6The gram tetra isopropyl titanate under 200-240 ℃, reacted 8 hours, obtained molecular weight and be 250～2000 polyol compound.
With 100 gram molecular weights is 250～2000 polyol compounds, 100 gram diphenylmethanediisocyanates (MDI) and 1000 gram silicon-dioxide are after cement mixer mixes, be poured in the mould, obtain polyurethane ceramic tile imitation through the degassing, curing, the demoulding, trimming again, every index of the imitative ceramic tile of gained is: water-intake rate≤0.3%; Thickness＜7.5mm, strength at break mean value is not less than 1000N; Wear resistance: the wear volume of anti-the degree of depth is not more than 175mm
3
Claims (6)
1. polyurethane ceramic tile imitation product, it is characterized in that, it is to be that 250～2000 polyol compound, MDI and inorganic materials are after cement mixer mixes with molecular weight, be poured in the mould, form through the degassing, curing, the demoulding, trimming, the ratio of described polyol compound, MDI and inorganic materials is polyol compound: MDI: inorganic materials=100: (40-100): (200-2000) again.
2. a kind of polyurethane ceramic tile imitation product as claimed in claim 1 is characterized in that, described inorganic materials is red mud, lime carbonate or silicon-dioxide.
3. a kind of polyurethane ceramic tile imitation product as claimed in claim 1 or 2, it is characterized in that, described molecular weight is that 250～2000 polyol compound is by vegetables oil and ethylene glycol or glycerol, with titanate ester or organic tin compound is catalyzer, get down at 200-240 ℃ through alcoholysis and transesterification reaction 5-10 hour, wherein the add-on of vegetables oil is the 92-65% of vegetables oil and ethylene glycol or glycerol gross weight, ethylene glycol or glycerol add-on are the 8-35% of vegetables oil and ethylene glycol or glycerol gross weight, the add-on of catalyzer be vegetables oil and ethylene glycol or glycerol gross weight 1-5/ 1,000,000.
4. a kind of polyurethane ceramic tile imitation product as claimed in claim 3 is characterized in that, described vegetables oil is Oleum Gossypii semen, Viscotrol C, soybean oil or plam oil.
5. a kind of polyurethane ceramic tile imitation product as claimed in claim 4 is characterized in that, described titanate ester compound is a tetra isopropyl titanate.
6. a kind of polyurethane ceramic tile imitation product as claimed in claim 4 is characterized in that, described organic tin compound is a dibutyl tin dilaurate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010101259015A CN101805149B (en) | 2010-03-17 | 2010-03-17 | Polyurethane ceramic tile imitation product |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010101259015A CN101805149B (en) | 2010-03-17 | 2010-03-17 | Polyurethane ceramic tile imitation product |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101805149A true CN101805149A (en) | 2010-08-18 |
| CN101805149B CN101805149B (en) | 2012-04-18 |
Family
ID=42607124
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2010101259015A Expired - Fee Related CN101805149B (en) | 2010-03-17 | 2010-03-17 | Polyurethane ceramic tile imitation product |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101805149B (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103232703A (en) * | 2013-04-27 | 2013-08-07 | 苏州市德莱尔建材科技有限公司 | Polyester floor board and preparation method thereof |
| CN104261790A (en) * | 2014-09-23 | 2015-01-07 | 北京艾施姆科技有限公司 | Polyurethane/silicate composite material for rapidly repairing concrete pavement pit and preparation method thereof |
| CN107322945A (en) * | 2017-08-18 | 2017-11-07 | 漳平市美利达装饰材料有限公司 | A kind of imitative ceramic tile building materials preparation method |
| CN111454567A (en) * | 2020-04-16 | 2020-07-28 | 航锦科技股份有限公司 | Preparation method for producing polyurethane imitation marble decorative material by using industrial saponified waste residue |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1087371A (en) * | 1992-11-27 | 1994-06-01 | 周庆云 | Multifunctional light board |
-
2010
- 2010-03-17 CN CN2010101259015A patent/CN101805149B/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1087371A (en) * | 1992-11-27 | 1994-06-01 | 周庆云 | Multifunctional light board |
Non-Patent Citations (1)
| Title |
|---|
| 《聚氨酯原料及助剂手册》 20050430 刘益军 编著 聚氨酯原料及助剂手册 3-6 , 1 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103232703A (en) * | 2013-04-27 | 2013-08-07 | 苏州市德莱尔建材科技有限公司 | Polyester floor board and preparation method thereof |
| CN104261790A (en) * | 2014-09-23 | 2015-01-07 | 北京艾施姆科技有限公司 | Polyurethane/silicate composite material for rapidly repairing concrete pavement pit and preparation method thereof |
| CN107322945A (en) * | 2017-08-18 | 2017-11-07 | 漳平市美利达装饰材料有限公司 | A kind of imitative ceramic tile building materials preparation method |
| CN111454567A (en) * | 2020-04-16 | 2020-07-28 | 航锦科技股份有限公司 | Preparation method for producing polyurethane imitation marble decorative material by using industrial saponified waste residue |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101805149B (en) | 2012-04-18 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104163017B (en) | A kind of composite artificial stone sheet material and preparation method thereof | |
| CN102070343B (en) | Permeable brick and production method thereof | |
| CN101423368B (en) | Light wall board and manufacturing technology thereof | |
| CN102875065A (en) | Preparation process for fluorite slag-containing aerated brick | |
| CN102875067A (en) | Modified nano mineral powder-containing aerated brick | |
| CN103848641A (en) | Artificial stone with irregular pore and preparation method thereof | |
| CN103541288A (en) | High-performance environment-friendly permeable brick and production method thereof | |
| CN111003989B (en) | Preparation method for preparing granite decorative plate by utilizing granite saw mud | |
| CN107640943B (en) | Self-decoration recycled aggregate pervious concrete product and preparation method thereof | |
| CN101805149B (en) | Polyurethane ceramic tile imitation product | |
| CN102875069B (en) | Preparation process for aerated concrete block with raw materials containing modified nano mineral powder | |
| KR101471399B1 (en) | Fence manufactured from artificial stone using paste composition for manufacturing artificial stone of corrosion-resistance | |
| CN102850006A (en) | Flyash brick | |
| CN104311105A (en) | Green and environment-friendly foam ceramic product and manufacturing process thereof | |
| CN103924763A (en) | Manufacturing process for external wall decoration hanging plate | |
| CN101549982A (en) | Calcination-free desulfurized gypsum brick | |
| CN105569305A (en) | Handmade sandstone plate and preparation method therefor | |
| CN101734905B (en) | Coal gangue ceramic wall and ground brick and preparation method thereof | |
| CN102431080B (en) | Method for preparing colored autoclaved brick from lake sludge | |
| CN102875191A (en) | Preparation process for aerated concrete block | |
| CN102372468A (en) | Novel environmentally-friendly ceramic permeable brick and preparation method thereof | |
| CN102199027B (en) | Rostone and preparation method thereof | |
| CN101774799B (en) | Ceramic scrap product and preparation method thereof | |
| CN101948332A (en) | Steam-curing-free foam concrete building block and preparation method thereof | |
| CN107573003A (en) | A kind of mine tailing synthesis wood grain wall decorative material and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20120418 Termination date: 20160317 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |