Sewage is recycled high-performance polyethersulfone separating membrane and device
Technical field
The present invention relates to separation technology field, is that a kind of industries such as medicine, chemical industry, weaving that are widely used in are used for high-performance polyethersulfone separating membrane and the device that sewage is recycled.
Background technology
Because membrane technology is the new technology that is developing, that existing membrane material still exists is single, the anti-strong acid of film, highly basic, anti-biological corrosion, grease resistance, resistance to elevated temperatures are relatively poor, deficiencies such as service life is short, the penetrating amount of water is little, anti-pressure ability difference.
Summary of the invention
Technical problem to be solved by this invention is: provide a kind of anti-strong acid, highly basic, anti-biological corrosion, grease resistance, high temperature resistant, high-voltage performance good, the pollution analytic ability is strong, the sewage of high water flux is recycled high-performance polyethersulfone separating membrane, and provide rational in infrastructure, widely used device with polyethersulfone separating membrane.
Solving the technical scheme that its technical problem takes is: a kind of sewage is recycled high-performance polyethersulfone separating membrane, it is characterized in that: polyethersulfone separating membrane is vertical and put the hollow fiber bundle that is pencil and form by some.
A kind of device with polyethersulfone separating membrane, it is characterized in that: it comprises housing, housing is connected in proper order by upper shell, middle shell and lower house, in housing, be provided with polyethersulfone separating membrane, the two ends of polyethersulfone separating membrane are connected with the upper shell oral area and the lower house oral area of housing respectively, and the upper shell of housing is connected by first clamp nut and upper cover; The lower house of housing is connected by second clamp nut and low head, be provided with dense drain outlet at the top of upper cover, on the upper shell sidewall of housing, be provided with the recycle-water outlet, be provided with the sewage import, on the lower house sidewall of housing, be provided with the backwash water import in the bottom of low head.
Sewage of the present invention is recycled high-performance polyethersulfone separating membrane, have characteristics such as strong alkali-acid resistance, high temperature high voltage resistant, anti-biological corrosion, oleophobic be hydrophilic, can be widely used in water reuse in the processing, enterprise of the various sewage in city, oil field wastewater re-injection, pure water and separate low molecular organic matter in the field such as produce, be specially adapted to oil field and extraordinary chemical industry use; Because polyethersulfone separating membrane is vertical and put the hollow fiber bundle that is pencil and form by some, doughnut is followed successively by hollow wall layer, compacted zone and outer wall layer from the inside to the outside, sewage realizes that through the hollow compacted zone cross-flow separates, promptly separate and concentrate simultaneously and finish, has high water flux, water flux is than the high twice of normal film, and sewage is realized zero-emission; Have biological features and automatic washing capacity of carrying cross-flow to separate, have, solved the technical barrier of film pollution and concentration polarization from the parsing ability.Device with polyethersulfone separating membrane also has rational in infrastructurely except that all advantages with polyethersulfone separating membrane, advantage such as is widely used.
Description of drawings
Fig. 1 is the single doughnut structure section schematic diagram that sewage of the present invention is recycled high-performance polyethersulfone separating membrane.
Fig. 2 is the apparatus structure schematic diagram with polyethersulfone separating membrane of the present invention.
The sewage piece-rate system schematic diagram that Fig. 3 constitutes for the device with polyethersulfone separating membrane of the present invention.
Among the figure: 1 dense drain outlet, 2 upper covers, 3 second clamp nuts, 4 avirulent adhesion agents, 5 sewage imports, 6 housings, the 6-1 upper shell, 6-2 middle shell, 6-3 lower house, 7 polyethersulfone separating membranes, the outlet of 11 recycle-waters, 12 first clamp nuts, 13 backwash water imports, 16 low heads, the device of 20 polyethersulfone separating membranes.
The specific embodiment
The invention will be further described to utilize drawings and Examples below.
With reference to Fig. 1, it is vertical and put the hollow fiber bundle that is pencil and form by some that sewage of the present invention is recycled high-performance polyethersulfone separating membrane.In a doughnut, A3 is that doughnut inner wall layer, A2 are that doughnut compacted zone, A1 are the doughnut outer wall layer.
With reference to Fig. 2, the device with polyethersulfone separating membrane of the present invention comprises housing 6, and housing 6 is connected in proper order by upper shell 6-1, middle shell 6-2 and lower house 6-3, and its connection is bonding with avirulent adhesion agent.In housing 6, be provided with polyethersulfone separating membrane 7, the two ends of polyethersulfone separating membrane 7 are connected with the upper shell 6-1 oral area and the lower house 6-3 oral area of housing respectively, its technology that is connected is, avirulent adhesion agent 4 is pressed into from recycle-water outlet 11, backwash water import 13, under action of centrifugal force, the upper shell 6-1 oral area and the lower house 6-3 oral area that reach housing between the doughnut of avirulent adhesion agent 4 with one section hollow fiber bundle of the two ends setting of polyethersulfone separating membrane 7 are bonding firmly.The upper shell 6-1 of housing and upper cover 2 are by the built-in O type silicone rubber O-ring sealing of upper cover 2 grooves, and the upper shell 6-1 of housing is connected with upper cover 2 by first clamp nut 12.Equally, the lower house 6-3 of housing and low head 16 are by the built-in O type silicone rubber O-ring sealing of low head 16 grooves, and the lower house 6-3 of housing is connected with low head 16 by second clamp nut 6.Be provided with dense drain outlet 1 at the top of upper cover 2, on the upper shell 6-1 of housing sidewall, be provided with recycle-water outlet 11, be provided with sewage import 5, on the lower house 6-3 of housing sidewall, be provided with backwash water import 13 in the bottom of low head 16.
With reference to Fig. 3, wherein: 1D1-backwash water import magnetic valve, 1D3-backwashing pump pressure-regulating valve, 1D2-backwashing pump blowoff valve, the device sewage import magnetic valve of 1D4-backwashing pump import magnetic valve 1D5-polyethersulfone separating membrane, the device recycle-water outlet magnetic valve of 1D6-polyethersulfone separating membrane, the dense discharge outlet valve of the device of 1D7-polyethersulfone separating membrane, 1D8-sewage pump pressure-regulating valve, 1D9-sewage pump import magnetic valve, 1D10-sewage pump blowoff valve, the P-1-backwashing pump, P-2-sewage pump, V-1-accurate filter.
The control mode of the sewage piece-rate system that the device with polyethersulfone separating membrane of the present invention constitutes: by programmable controller PLC control output.Loop start, running.
Before the startup: 1D1-1D10 valve group Close All.PLC time-delay 10 seconds, 1D10 and 1D1,1D2 valve group is closed, and all the other valve groups are all opened.
In service: programmable controller PLC time-delay started P-2 in 10 seconds and closes 1D8 and 1D7 valve group simultaneously.Effluent stream to: by 1D9, P-2, V-1,1D5 enter the device 20 of several polyethersulfone separating membranes to the sewage that need to separate through the sewage import.The recycle-water that separates is through removing water from the recycle-water outlet by 1D6.Dense draining enters sewer line through dense drain outlet by 1D7.Control cycle: the working time is 18000 seconds.Stop P-2 in 18000 seconds when finishing and close 1D5 unlatching 1D7,1D8 valve group simultaneously.
During backwash: programmable controller PLC time-delay started P-1 in 10 seconds and closes 1D3 and 1D6 valve group simultaneously.Backwash water flows to; Backwash water is through backwash water import 1D4, and P-1,1D1 enter the device 20 of several polyethersulfone separating membranes.The dense water of backwash enters sewer line through dense drain outlet by 1D7.Control cycle: the backwash time is 300 seconds.Stop P-1 when finishing in 300 seconds and close 1D1 unlatching 1D3 and 1D6,1D7,1D8 valve group simultaneously.
Use the device of polyethersulfone separating membrane of the present invention the separation that sewage carried out 10 months to be tried out, produce effects fruit significantly, realized the object of the invention and effect in certain oil field.