CN101798502A - Scale inhibitor for preventing deposition of barium and strontium scales - Google Patents
Scale inhibitor for preventing deposition of barium and strontium scales Download PDFInfo
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- CN101798502A CN101798502A CN 201010144967 CN201010144967A CN101798502A CN 101798502 A CN101798502 A CN 101798502A CN 201010144967 CN201010144967 CN 201010144967 CN 201010144967 A CN201010144967 A CN 201010144967A CN 101798502 A CN101798502 A CN 101798502A
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- Prior art keywords
- acid
- industrial goods
- phosphonic acid
- add
- barium strontium
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- 239000002455 scale inhibitor Substances 0.000 title claims abstract description 30
- 230000008021 deposition Effects 0.000 title claims abstract description 27
- 229910052788 barium Inorganic materials 0.000 title description 2
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical group [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 title description 2
- 229910052712 strontium Inorganic materials 0.000 title description 2
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 title description 2
- NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 claims abstract description 42
- WOIHABYNKOEWFG-UHFFFAOYSA-N [Sr].[Ba] Chemical compound [Sr].[Ba] WOIHABYNKOEWFG-UHFFFAOYSA-N 0.000 claims abstract description 28
- 229940120146 EDTMP Drugs 0.000 claims abstract description 14
- NFDRPXJGHKJRLJ-UHFFFAOYSA-N edtmp Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CCN(CP(O)(O)=O)CP(O)(O)=O NFDRPXJGHKJRLJ-UHFFFAOYSA-N 0.000 claims abstract description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 14
- FPIPGXGPPPQFEQ-UHFFFAOYSA-N 13-cis retinol Natural products OCC=C(C)C=CC=C(C)C=CC1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-UHFFFAOYSA-N 0.000 claims abstract description 12
- CKLJMWTZIZZHCS-REOHCLBHSA-N L-aspartic acid Chemical compound OC(=O)[C@@H](N)CC(O)=O CKLJMWTZIZZHCS-REOHCLBHSA-N 0.000 claims abstract description 12
- FPIPGXGPPPQFEQ-BOOMUCAASA-N Vitamin A Natural products OC/C=C(/C)\C=C\C=C(\C)/C=C/C1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-BOOMUCAASA-N 0.000 claims abstract description 12
- FPIPGXGPPPQFEQ-OVSJKPMPSA-N all-trans-retinol Chemical compound OC\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-OVSJKPMPSA-N 0.000 claims abstract description 12
- 235000003704 aspartic acid Nutrition 0.000 claims abstract description 12
- OQFSQFPPLPISGP-UHFFFAOYSA-N beta-carboxyaspartic acid Natural products OC(=O)C(N)C(C(O)=O)C(O)=O OQFSQFPPLPISGP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 235000019155 vitamin A Nutrition 0.000 claims abstract description 12
- 239000011719 vitamin A Substances 0.000 claims abstract description 12
- 235000019154 vitamin C Nutrition 0.000 claims abstract description 12
- 239000011718 vitamin C Substances 0.000 claims abstract description 12
- 229940045997 vitamin a Drugs 0.000 claims abstract description 12
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 claims abstract 3
- 125000003368 amide group Chemical group 0.000 claims description 22
- GATNOFPXSDHULC-UHFFFAOYSA-N ethylphosphonic acid Chemical compound CCP(O)(O)=O GATNOFPXSDHULC-UHFFFAOYSA-N 0.000 claims description 22
- 235000007715 potassium iodide Nutrition 0.000 claims description 13
- 229960004839 potassium iodide Drugs 0.000 claims description 13
- KWYJDIUEHHCHCZ-UHFFFAOYSA-N 3-[2-[bis(2-carboxyethyl)amino]ethyl-(2-carboxyethyl)amino]propanoic acid Chemical compound OC(=O)CCN(CCC(O)=O)CCN(CCC(O)=O)CCC(O)=O KWYJDIUEHHCHCZ-UHFFFAOYSA-N 0.000 claims description 12
- 239000003109 Disodium ethylene diamine tetraacetate Substances 0.000 claims description 12
- 235000019301 disodium ethylene diamine tetraacetate Nutrition 0.000 claims description 12
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 claims description 11
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 11
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 11
- 238000003756 stirring Methods 0.000 claims description 10
- 238000002360 preparation method Methods 0.000 claims description 8
- 238000010438 heat treatment Methods 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 4
- 210000003298 dental enamel Anatomy 0.000 claims description 4
- NSOXQYCFHDMMGV-UHFFFAOYSA-N Tetrakis(2-hydroxypropyl)ethylenediamine Chemical compound CC(O)CN(CC(C)O)CCN(CC(C)O)CC(C)O NSOXQYCFHDMMGV-UHFFFAOYSA-N 0.000 claims 2
- 239000003129 oil well Substances 0.000 abstract description 15
- 230000000694 effects Effects 0.000 abstract description 10
- 230000005764 inhibitory process Effects 0.000 abstract description 10
- -1 dodecyl aminoethyl phosphate ester Chemical class 0.000 abstract description 4
- 238000012423 maintenance Methods 0.000 abstract description 3
- 238000000605 extraction Methods 0.000 abstract description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 abstract 2
- WRDITBHRAHNRQQ-UHFFFAOYSA-N 2-(tetradecylamino)ethyl dihydrogen phosphate Chemical compound CCCCCCCCCCCCCCNCCOP(=O)(O)O WRDITBHRAHNRQQ-UHFFFAOYSA-N 0.000 abstract 1
- ZZZCUOFIHGPKAK-UHFFFAOYSA-N D-erythro-ascorbic acid Natural products OCC1OC(=O)C(O)=C1O ZZZCUOFIHGPKAK-UHFFFAOYSA-N 0.000 abstract 1
- KZSNJWFQEVHDMF-UHFFFAOYSA-N Valine Chemical compound CC(C)C(N)C(O)=O KZSNJWFQEVHDMF-UHFFFAOYSA-N 0.000 abstract 1
- 229930003268 Vitamin C Natural products 0.000 abstract 1
- 238000007689 inspection Methods 0.000 abstract 1
- 230000002035 prolonged effect Effects 0.000 abstract 1
- CJVPOGPEEJPBFT-UHFFFAOYSA-J tetrasodium;3-[2-[bis(2-carboxylatoethyl)amino]ethyl-(2-carboxylatoethyl)amino]propanoate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CCN(CCC([O-])=O)CCN(CCC([O-])=O)CCC([O-])=O CJVPOGPEEJPBFT-UHFFFAOYSA-J 0.000 abstract 1
- 238000000151 deposition Methods 0.000 description 20
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 11
- 238000001514 detection method Methods 0.000 description 7
- 239000002253 acid Substances 0.000 description 5
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 4
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 4
- UBXAKNTVXQMEAG-UHFFFAOYSA-L strontium sulfate Chemical compound [Sr+2].[O-]S([O-])(=O)=O UBXAKNTVXQMEAG-UHFFFAOYSA-L 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- 241000894006 Bacteria Species 0.000 description 2
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 description 2
- 239000013543 active substance Substances 0.000 description 2
- 229920005601 base polymer Polymers 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 230000000536 complexating effect Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 235000012204 lemonade/lime carbonate Nutrition 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 235000016709 nutrition Nutrition 0.000 description 2
- 230000035764 nutrition Effects 0.000 description 2
- 229920000620 organic polymer Polymers 0.000 description 2
- 150000003009 phosphonic acids Chemical class 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000003352 sequestering agent Substances 0.000 description 2
- RWSOTUBLDIXVET-UHFFFAOYSA-O sulfonium Chemical compound [SH3+] RWSOTUBLDIXVET-UHFFFAOYSA-O 0.000 description 2
- 229910021653 sulphate ion Inorganic materials 0.000 description 2
- MCRJLMXYVFDXLS-ZRAJAZRZSA-N (5e,8e,10e,14e,17e)-12-hydroxyicosa-5,8,10,14,17-pentaenoic acid Chemical compound CC\C=C\C\C=C\CC(O)\C=C\C=C\C\C=C\CCCC(O)=O MCRJLMXYVFDXLS-ZRAJAZRZSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- FCKYPQBAHLOOJQ-UHFFFAOYSA-N Cyclohexane-1,2-diaminetetraacetic acid Chemical class OC(=O)CN(CC(O)=O)C1CCCCC1N(CC(O)=O)CC(O)=O FCKYPQBAHLOOJQ-UHFFFAOYSA-N 0.000 description 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical class OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 1
- YMEDZTGTVHUJLI-UHFFFAOYSA-N P.P.[C] Chemical compound P.P.[C] YMEDZTGTVHUJLI-UHFFFAOYSA-N 0.000 description 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 150000002148 esters Chemical group 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 150000002401 hexose derivatives Chemical class 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- ZJAOAACCNHFJAH-UHFFFAOYSA-N phosphonoformic acid Chemical compound OC(=O)P(O)(O)=O ZJAOAACCNHFJAH-UHFFFAOYSA-N 0.000 description 1
- 229920000141 poly(maleic anhydride) Polymers 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 239000012747 synergistic agent Substances 0.000 description 1
Landscapes
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
The scale inhibitor for preventing barium strontium scale deposition is used in oil extraction in oil field to prevent barium strontium scale deposition in oil well. The weight percentages of the components are as follows: dodecyl aminoethyl phosphate ester: 8.5-12%; tetradecylaminoethyl phosphate: 7.5-9.0%; ethylenediaminetetraacetic acid disodium salt: 5-6.5%; ethylenediaminetetrapropionic acid tetrasodium salt: 2.5-3.0%; ethylenediamine tetramethylene phosphonic acid: 3.5 to 4.5; vitamin A: 0.05-0.08%, vitamin C: 0.05-0.12%, potassium iodide: 0.005-0.01%, alpha amino 3-methylbutyric acid: 0.0005 to 0.001%; aspartic acid: 0.0005 to 0.0010%; the balance of water; the sum of the weight percentages of the components is 100 percent. The effect is as follows: when the daily maintenance of an oil well is carried out, under the condition that the addition of the scale inhibitor for preventing the deposition of barium-strontium scales is 25-30 mg/l, the scale inhibition rate is more than 90%, and the pump inspection period of the oil well can be prolonged by more than 1 time.
Description
Technical field
The present invention relates to petroleum industry chemical technical field, relate in particular to the Scale inhibitors that prevents oil well barium strontium dirt deposition in the oil recovery process.
Background technology
During entering, the part oil field behind the high water-cut stage,,, forms hard barium strontium dirt in tube inner wall, sucker rod surface, gathering pipeline inside along with the variation of extraction liquid temp owing to contain barium, strontium, sulfate radical, carbanion in the recovered water.And conventional barium strontium dirt prevents that method is ineffective, and this dirt is insoluble to acid simultaneously, has brought a lot of inconvenience for the oil field production management.
At present, the chemical scale inhibition agent roughly is divided three classes: i.e. aminopolycanboxylic acid's salt, phosphorus compound class and organic polymer class.Aminopolycanboxylic acid's salt is the low molecule sequestrant of a class, as disodium EDTA (EDTA), CDTA salt (DCTA), ethylenediamine tetrapropionic acid(EDTP) salt (EDTP) etc.This class sequestrant is a low molecular compound, and the chelating stability constant is big, can be used for comparatively high temps, but because consumption is big, the cost height, its application is restricted.
Phosphorus compound class scale inhibitor mostly is the organic multicomponent phosphonic acids.As the ethylene diamine tetra methylene phosphonic acid (EDTMP) of methylenephosphonic acid type, with the 1-Hydroxy Ethylidene-1,1-Diphosphonic Acid (HEDP) of carbon diphosphine acid type, 4 of carboxy phosphonic acid type, 4-'-diphosphono-1,7-pimelic acid etc.Organic multicomponent phosphonic acid based scale inhibitor have consumption little, can bear comparatively high temps, lime carbonate is had higher advantages such as antiscale efficient, more in field use, relatively poor to the antiscaling effect of barium sulfate, Strontium Sulphate, scale inhibition performance has only about 40%.
The organic polymer scale inhibitor mainly is polymaleic anhydride and polyacrylic acid and their multipolymer.The antiscale mechanism of this base polymer be on the polymer molecular chain carboxyl can with the polyvalent metal ion complexing, the complexing of a plurality of carboxyls then forms inner complex and has anti-scaling property.This base polymer is to the too late organic multicomponent phosphonic acids of the antiscale efficient of lime carbonate, calcium sulfate, though barium sulfate, Strontium Sulphate are had antiscaling effect, efficient is lower.
Summary of the invention
The objective of the invention is: a kind of Scale inhibitors that prevents barium strontium dirt deposition and preparation method thereof is provided.Add Scale inhibitors when the oil well routine maintenance, when the Scale inhibitors dosage that prevents barium strontium dirt deposition is under the situation of 25～30mg/l, scale inhibition performance is greater than 90%, and the pump detection period of oil well prolongs more than 1 times.
The technical solution used in the present invention is:
Prevent the raw material and the prescription of the Scale inhibitors of barium strontium dirt deposition:
Raw material comprises:
1, dodecyl amido ethyl phosphonic acid ester (industrial goods), another name: C
12HEP;
Huang Hongzhou edits Chinese tensio-active agent overview one book, the 583rd page of Chemical Industry Press.
Factory: department of chemistry of Nanjing Normal University, fine chemistry industry system of East China University of Science.
2, tetradecyl amido ethyl phosphonic acid ester (industrial goods), another name: C
14HEP;
Huang Hongzhou edits Chinese tensio-active agent overview one book, the 584th page of Chemical Industry Press.
Factory: department of chemistry of Nanjing Normal University, fine chemistry industry system of East China University of Science.
3, disodium EDTA (industrial goods);
4, ethylenediamine tetrapropionic acid(EDTP) tetra-na salt (industrial goods);
5, ethylene diamine tetra methylene phosphonic acid (industrial goods);
6, vitamin A (A1 or A2) (industrial goods);
Be a unsaturated monohydroxy-alcohol, comprise two kinds of retinol1, A2 with ester ring.Retinol1 and A2 structural similitude).In this effect: serve as the nutrition source of sulphate reducing bacteria (SRB), stop it that sulfate ion is reduced into the underdeposit corrosion that the sulfonium ion of negative divalence causes.
7, vitamins C (industrial goods);
Acidity has stronger reductibility, heating or easy oxygenolysis in solution, easier to be oxidized under alkaline condition, be the hexose derivative, serve as the nutrition source of sulphate reducing bacteria (SRB), stop it that sulfate ion is reduced into the underdeposit corrosion that the sulfonium ion of negative divalence causes in this effect.
8, potassiumiodide (industrial goods),
Potassiumiodide is stablizer and solubility promoter, and the potassiumiodide of feed grade also can be cooked the supplement as iodine in the feed processing, makes synergistic agent at this.
9, alpha-amino group-3 Methylbutanoic acid (industrial goods) has another name called Xie Ansuan; Structural formula is:
Manufacturer: Chengdu Kai Taixin new technology limited liability company
10, aspartic acid (industrial goods), structural formula is:
Manufacturer: Chengdu Kai Taixin new technology limited liability company
11, water.
Each weight percentages of components that prevents the Scale inhibitors of barium strontium dirt deposition is:
1, dodecyl amido ethyl phosphonic acid ester (industrial goods): 8.5～12%;
2, tetradecyl amido ethyl phosphonic acid ester (industrial goods): 7.5～9.0%;
3, disodium EDTA (industrial goods): 5～6.5%;
4, ethylenediamine tetrapropionic acid(EDTP) tetra-na salt (industrial goods): 2.5～3.0%;
5, ethylene diamine tetra methylene phosphonic acid (industrial goods): 3.5～4.5%;
6, vitamin A (industrial goods): 0.05～0.08%;
7, vitamins C (industrial goods): 0.05～0.12%;
8, potassiumiodide (industrial goods): 0.005～0.01%;
9, alpha-amino group-3 Methylbutanoic acid (industrial goods): 0.0005～0.001%;
10, aspartic acid (industrial goods): 0.0005～0.001%;
11, all the other are water; Each weight percentages of components sum is 100%.
Prevent the preparation method of the Scale inhibitors of barium strontium dirt deposition
Major equipment:
Enamel reaction still with 2000L of stirring, heating, cooling and vacuum system.
Production method:
At first, add dodecyl amido ethyl phosphonic acid ester and tetradecyl amido ethyl phosphonic acid ester in the enamel reaction still in proportion; Add again and need add 8% of entry, after stirring slowly is warmed up to 45～50 ℃ simultaneously, restir 30 minutes; Add disodium EDTA, ethylenediamine tetrapropionic acid(EDTP) tetra-na salt and ethylene diamine tetra methylene phosphonic acid, vitamin A, vitamins C, potassiumiodide successively in proportion, stir while adding; Add alpha-amino group-3 Methylbutanoic acid and aspartic acid then in proportion, stirred 30 minutes; Add the water of remainder at last and stirred 30 minutes, stop heating; Stir while cooling off, be cooled to normal temperature, be prevented the Scale inhibitors of barium strontium dirt deposition.
Beneficial effect of the present invention: when the oil well routine maintenance, add the Scale inhibitors that prevents barium strontium dirt deposition from the oil jacket annular space of oil well, dosage is that every liter of oilwell produced fluid amount adds 25～30mg, and scale inhibition performance makes the pump detection period of oil well prolong more than 1 times greater than 90%.
Embodiment
Embodiment 1: each weight percentages of components that prevents the Scale inhibitors of barium strontium dirt deposition is:
1, dodecyl amido ethyl phosphonic acid ester (industrial goods): 8.5%;
2, tetradecyl amido ethyl phosphonic acid ester (industrial goods): 8.9%;
3, disodium EDTA (industrial goods): 6.5%;
4, ethylenediamine tetrapropionic acid(EDTP) tetra-na salt (industrial goods): 2.5%;
5, ethylene diamine tetra methylene phosphonic acid (industrial goods): 3.6%;
6, vitamin A (industrial goods): 0.06%;
7, vitamins C (industrial goods): 0.07%;
8, potassiumiodide (industrial goods): 0.006%;
9, alpha-amino group-3 Methylbutanoic acid (industrial goods): 0.0005%;
10, aspartic acid (industrial goods): 0.0005%;
11, water: 69.863%.
Its preparation method is:
At first, add dodecyl amido ethyl phosphonic acid ester and tetradecyl amido ethyl phosphonic acid ester in the enamel reaction still in proportion; Add again and need add 8% of entry, after stirring slowly is warmed up to 45～50 ℃ simultaneously, restir 30 minutes; Add disodium EDTA, ethylenediamine tetrapropionic acid(EDTP) tetra-na salt and ethylene diamine tetra methylene phosphonic acid, vitamin A, vitamins C, potassiumiodide successively in proportion, stir while adding; Add alpha-amino group-3 Methylbutanoic acid and aspartic acid then in proportion, stirred 30 minutes; Add the water of remainder at last and stirred 30 minutes, stop heating; Stir while cooling off, be cooled to normal temperature, be prevented the Scale inhibitors of barium strontium dirt deposition.
Effect: when the Scale inhibitors dosage that prevents barium strontium dirt deposition is under the situation of 25mg/l, scale inhibition performance is 91.39%, and the oil well pump detection period prolongs 1.2 times.
Embodiment 2: each weight percentages of components that prevents the Scale inhibitors of barium strontium dirt deposition is:
1, dodecyl amido ethyl phosphonic acid ester (industrial goods): 9%;
2, tetradecyl amido ethyl phosphonic acid ester (industrial goods): 8.5%;
3, disodium EDTA (industrial goods): 6.2%;
4, ethylenediamine tetrapropionic acid(EDTP) tetra-na salt (industrial goods): 2.7%;
5, ethylene diamine tetra methylene phosphonic acid (industrial goods): 3.9%;
6, vitamin A (industrial goods): 0.05%;
7, vitamins C (industrial goods): 0.05%;
8, potassiumiodide (industrial goods): 0.005%;
9, alpha-amino group-3 Methylbutanoic acid (industrial goods): 0.0006%;
10, aspartic acid (industrial goods): 0.0007%;
11, all the other are water; Each weight percentages of components sum is 100% (water is 69.5937%).
The preparation method of embodiment 2 is identical with embodiment 1.
Effect: when the Scale inhibitors dosage that prevents barium strontium dirt deposition is under the situation of 28mg/l, scale inhibition performance is 92.03%, and the pump detection period of oil well prolongs 1.5 times.
Embodiment 3: each weight percentages of components that prevents the Scale inhibitors of barium strontium dirt deposition is:
1, dodecyl amido ethyl phosphonic acid ester (industrial goods): 9.6%;
2, tetradecyl amido ethyl phosphonic acid ester (industrial goods): 8%;
3, disodium EDTA (industrial goods): 6%;
4, ethylenediamine tetrapropionic acid(EDTP) tetra-na salt (industrial goods): 2.8%;
5, ethylene diamine tetra methylene phosphonic acid (industrial goods): 4.1%;
6, vitamin A (industrial goods): 0.07%;
7, vitamins C (industrial goods): 0.08%;
8, potassiumiodide (industrial goods): 0.008%;
9, alpha-amino group-3 Methylbutanoic acid (industrial goods): 0.0007%;
10, aspartic acid (industrial goods): 0.0008%;
11, water is 69.3485%.
The preparation method of embodiment 3 is identical with embodiment 1.
Effect: when the Scale inhibitors dosage that prevents barium strontium dirt deposition is under the situation of 29mg/l, scale inhibition performance is 91.72%, and the pump detection period of oil well prolongs 1.7 times.
Embodiment 4: each weight percentages of components that prevents the Scale inhibitors of barium strontium dirt deposition is:
1, dodecyl amido ethyl phosphonic acid ester (industrial goods): 11%;
2, tetradecyl amido ethyl phosphonic acid ester (industrial goods): 7.8%;
3, disodium EDTA (industrial goods): 5.5%;
4, ethylenediamine tetrapropionic acid(EDTP) tetra-na salt (industrial goods): 2.9%;
5, ethylene diamine tetra methylene phosphonic acid (industrial goods): 4.2%;
6, vitamin A (industrial goods): 0.07%;
7, vitamins C (industrial goods): 0.10%;
8, potassiumiodide (industrial goods): 0.009%;
9, alpha-amino group-3 Methylbutanoic acid (industrial goods): 0.0008%;
10, aspartic acid (industrial goods): 0.0009%;
11, water is 68.4193%.
The preparation method of embodiment 4 is identical with embodiment 1.
Effect: when the Scale inhibitors dosage that prevents barium strontium dirt deposition is under the situation of 28mg/l, scale inhibition performance is 92.32%, and the pump detection period of oil well prolongs 1.9 times.
Embodiment 5: each weight percentages of components that prevents the Scale inhibitors of barium strontium dirt deposition is:
1, dodecyl amido ethyl phosphonic acid ester (industrial goods): 11.8%;
2, tetradecyl amido ethyl phosphonic acid ester (industrial goods): 7.5%;
3, disodium EDTA (industrial goods): 5.2%;
4, ethylenediamine tetrapropionic acid(EDTP) tetra-na salt (industrial goods): 3%;
5, ethylene diamine tetra methylene phosphonic acid (industrial goods): 4.4%;
6, vitamin A (industrial goods): 0.08%;
7, vitamins C (industrial goods): 0.12%;
8, potassiumiodide (industrial goods): 0.01%;
9, alpha-amino group-3 Methylbutanoic acid (industrial goods): 0.001%;
10, aspartic acid (industrial goods): 0.001%;
11, all the other are water; Each weight percentages of components sum is 100% (67.888%).
The preparation method of embodiment 5 is identical with embodiment 1.
Effect: when the Scale inhibitors dosage that prevents barium strontium dirt deposition is under the situation of 25mg/l, scale inhibition performance is 90.69%, and the pump detection period of oil well prolongs 1.3 times.
Claims (2)
1. each weight percentages of components that prevents the Scale inhibitors of barium strontium dirt deposition is:
Dodecyl amido ethyl phosphonic acid ester: 8.5～12%;
Tetradecyl amido ethyl phosphonic acid ester: 7.5～9.0%;
Disodium EDTA: 5～6.5%;
Ethylenediamine tetrapropionic acid(EDTP) tetra-na salt: 2.5～3.0%;
Ethylene diamine tetra methylene phosphonic acid: 3.5～4.5%;
Vitamin A: 0.05～0.08%;
Vitamins C: 0.05～0.12%;
Potassiumiodide: 0.005～0.01%;
Alpha-amino group-3 Methylbutanoic acid: 0.0005～0.001%;
Aspartic acid: 0.0005～0.001%;
All the other are water; Each weight percentages of components sum is 100%.
2. the Scale inhibitors that prevents barium strontium dirt deposition according to claim 1, it is characterized in that: its preparation method is:
At first, add dodecyl amido ethyl phosphonic acid ester and tetradecyl amido ethyl phosphonic acid ester in the enamel reaction still in proportion; Add again and need add 8% of entry, after stirring slowly is warmed up to 45～50 ℃ simultaneously, restir 30 minutes; Add disodium EDTA, ethylenediamine tetrapropionic acid(EDTP) tetra-na salt and ethylene diamine tetra methylene phosphonic acid, vitamin A, vitamins C, potassiumiodide successively in proportion, stir while adding; Add alpha-amino group-3 Methylbutanoic acid and aspartic acid then in proportion, stirred 30 minutes; Add the water of remainder at last and stirred 30 minutes, stop heating; Stir while cooling off, be cooled to normal temperature, be prevented the Scale inhibitors of barium strontium dirt deposition.
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102174315A (en) * | 2011-03-10 | 2011-09-07 | 中国石油天然气股份有限公司 | Scale removing and preventing agent for oil well in later period of tertiary oil recovery |
| CN104962266A (en) * | 2015-06-17 | 2015-10-07 | 成都高普石油工程技术有限公司 | Oil well cleaning scale inhibitor |
| CN105060515A (en) * | 2015-06-30 | 2015-11-18 | 苏州佑君环境科技有限公司 | Scale inhibitor for preventing deposition of barium and strontium scales, and preparation method thereof |
| CN106398659A (en) * | 2016-08-30 | 2017-02-15 | 陕西省石油化工研究设计院 | Calcium fluoride stabilizing agent |
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| US10800963B2 (en) | 2016-12-29 | 2020-10-13 | Petrochina Company Limited | Pressure-reducing and injection-enhancing anti scaling agent for low-permeability water-injection well and preparation method thereof |
| CN112745820A (en) * | 2021-02-01 | 2021-05-04 | 西南石油大学 | Barium sulfate scale dissolving agent |
| CN114106804A (en) * | 2022-01-28 | 2022-03-01 | 胜利油田胜利化工有限责任公司 | High-temperature-resistant esterification type composite scale inhibitor and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1491908A (en) * | 2003-08-20 | 2004-04-28 | 东营联通化工有限责任公司 | Barium-strontium scale resistant agent |
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2010
- 2010-04-09 CN CN 201010144967 patent/CN101798502B/en active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1491908A (en) * | 2003-08-20 | 2004-04-28 | 东营联通化工有限责任公司 | Barium-strontium scale resistant agent |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102174315A (en) * | 2011-03-10 | 2011-09-07 | 中国石油天然气股份有限公司 | Scale removing and preventing agent for oil well in later period of tertiary oil recovery |
| CN104962266A (en) * | 2015-06-17 | 2015-10-07 | 成都高普石油工程技术有限公司 | Oil well cleaning scale inhibitor |
| CN105060515A (en) * | 2015-06-30 | 2015-11-18 | 苏州佑君环境科技有限公司 | Scale inhibitor for preventing deposition of barium and strontium scales, and preparation method thereof |
| CN106398659A (en) * | 2016-08-30 | 2017-02-15 | 陕西省石油化工研究设计院 | Calcium fluoride stabilizing agent |
| US10800963B2 (en) | 2016-12-29 | 2020-10-13 | Petrochina Company Limited | Pressure-reducing and injection-enhancing anti scaling agent for low-permeability water-injection well and preparation method thereof |
| CN107570016A (en) * | 2017-09-27 | 2018-01-12 | 中海油天津化工研究设计院有限公司 | A kind of concentrated water reverse osmosis antisludging agent and preparation method thereof |
| CN112745820A (en) * | 2021-02-01 | 2021-05-04 | 西南石油大学 | Barium sulfate scale dissolving agent |
| CN114106804A (en) * | 2022-01-28 | 2022-03-01 | 胜利油田胜利化工有限责任公司 | High-temperature-resistant esterification type composite scale inhibitor and preparation method thereof |
| CN114106804B (en) * | 2022-01-28 | 2022-05-17 | 胜利油田胜利化工有限责任公司 | High-temperature-resistant esterification type composite scale inhibitor and preparation method thereof |
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